阅读说明：本技术 将两个板粘合在一起以用于燃料电池的方法，尤其是将燃料电池中的双极板胶合的方法 (Method for gluing two plates together for use in a fuel cell, in particular for gluing bipolar plates in a fuel cell ) 是由 D·格罗麦德斯基 S·J·安德烈亚森 M·苏伦森 J·博克 于 2019-11-12 设计创作，主要内容包括：将两个板粘合在一起以用于燃料电池的方法,其中该方法包括将粘合剂施加到至少一个板的表面上,并将两个板与它们之间的粘合剂一起压制。粘合剂包含0.01％-30％PVDF和溶剂以及任选表面活性剂的混合物。(A method of bonding two plates together for use in a fuel cell, wherein the method comprises applying an adhesive to a surface of at least one of the plates and pressing the two plates together with the adhesive between them. The binder comprises a mixture of 0.01% to 30% PVDF and a solvent and optionally a surfactant.)

1. A method of bonding two plates together for use in a fuel cell, wherein the method comprises applying a bonding agent to a surface of at least one of the plates, pressing the two plates together with the bonding agent between them until the bonding agent bonds the plates together, wherein the bonding agent comprises a mixture of PVDF and a solvent, wherein the method comprises providing the bonding agent by mixing PVDF and the solvent and heating and stirring the mixture to dissolve the PVDF in the solvent at a concentration of PVDF in the bonding agent; characterized in that it comprises mixing PVDF in a solvent to a concentration of 0.01% to 30% PVDF with respect to the weight of the solvent to provide a binder.

2. The method according to claim 1, wherein the method comprises mixing the non-ionic surfactant into the PVDF and the solvent at a volume concentration of 0.1% -10% relative to the volume of the solvent.

3. The method according to any one of the preceding claims, wherein the method comprises adding water to the binder while the binder is on the surface, the precipitation of the PVDF being caused by the water.

4. The method of any preceding claim, wherein the method comprises applying an adhesive to the surface at room temperature to evaporate solvent from the glue at room temperature.

5. The method according to any one of the preceding claims, wherein the method comprises pressing the two boards together at a pressure of 1kPa-10 kPa.

6. The method according to any one of the preceding claims, wherein the method comprises hot pressing the two plates together at a temperature above the melting temperature of the PVDF, then reducing the temperature while still pressing until the temperature is below the crystallization temperature of the PVDF.

7. The method of any one of the preceding claims, wherein the method comprises mixing a binder by adding a solvent comprising greater than 50% dimethylacetamide.

8. The method of any preceding claim, wherein the method comprises mixing a binder by adding a surfactant comprising greater than 50% octylphenol ethoxylate.

9. The process according to any one of the preceding claims, wherein the process comprises mixing a solvent with the PVDF and a surfactant at a volume concentration of 0.1% to 10% with respect to the volume of the solvent to obtain a binder, wherein the solvent comprises more than 50% of dimethylacetamide and the surfactant comprises more than 50% of octylphenol ethoxylate; applying an adhesive to the surface after mixing; after applying the binder to the surface, adding water to the binder and causing precipitation of the PVDF by the addition of water; waiting for the solvent to evaporate at room temperature, then bonding the sheets to each other by hot pressing the sheets together under a pressure of 1-10 kPa and at a temperature above the melting temperature of the PVDF, and then reducing the temperature while still pressing until the temperature is below the crystallization temperature of the PVDF.

10. A method according to any one of the preceding claims, the plates being a cathode plate and an anode plate, the method comprising bonding the plates to one another to form a bipolar plate for a fuel cell, or to either side of a cooling plate to form a bipolar plate assembly with a central cooling plate sandwiched between the anode and cathode plates.

Technical Field

The present invention relates to bonding together components, particularly plates, for use in fuel cells, such as fuel cell stacks, particularly bipolar plates in fuel cells.

Background

International patent applications WO2009/010066 and WO2009/010067 to Serenergy disclose Proton Exchange Membrane (PEM) fuel cells in which the membrane is sandwiched between rigid separator plates, particularly bipolar plates, which contain primarily graphite and a binder.

With respect to fuel cell stacks, in particular PEM (proton exchange membrane) fuel cells, the term separator plate is a rigid plate for separating the membranes, which has a flow structure, usually channels, for the flow of hydrogen fuel and oxygen-containing gas, and possibly also for the flow of heat transfer liquids such as water, triethylene glycol (TEG), mineral oil or silicone oil for cooling. The separator includes a bipolar plate, a cooling plate, an anode plate and a cathode plate. The bipolar plate has a first side having a first flow channel field for providing hydrogen fuel to the fuel cell membrane and an opposite second side having a second flow channel field for providing oxygen to an adjacent cell membrane. Oxygen is typically provided by air. In an alternative configuration for a fuel cell, an anode plate having a flow channel field for providing hydrogen to the fuel cell membrane on one side and a cathode plate having a flow channel field for providing oxygen to the fuel cell membrane on one side are provided. The membrane is then disposed between the anode and cathode plates. Optionally, the anode plate or the cathode plate or both have an opposite second side with a flow channel field for coolant flow, e.g. water as coolant. The term separator also includes a cooling plate having a field of water flow channels on both sides for cooling respective anode and cathode plates adjacent to the cooling plate. Examples of various configurations are given in WO2009/010066 and WO2009/010067, wherein the use of a cooling plate between an anode plate and a cathode plate is also disclosed.

An overview of composite materials for producing Bipolar plates is disclosed in "A Review of Thermoplastic Composites for Bipolar plate materials in PEM Fuel Cells", edited by John Cupoletti, Inc., and published in the website WWW. intechopen. com in 2011. In this article, the authors discuss that thermoplastic resins such as polypropylene (PP), Polyethylene (PE), polyvinylidene fluoride (PVDF), Liquid Crystal Polymers (LCP), Polyphenylene Sulfide (PPs), and fluorinated polymers are less useful in bipolar plate fabrication than thermoset resins. Thus, the publication indicates that the thermosetting resin has a low viscosity and thus contains a relatively high proportion of the conductive filler. In particular, epoxy resins are considered a popular choice for the production of polymer composite bipolar plates.

Another production method is disclosed in WO2018/072803 assigned to Serenergy. Bipolar plates and cathode/anode plate assemblies are exemplified. For example, the cathode plate is combined back-to-back with the anode plate to form a bipolar assembly with a cooling channel field therebetween that is part of the back-to-back assembly or provided by a cooling plate between the back surfaces of the cathode and anode plates.

Generally, a gasket is used to ensure tightness between the respective plates. In many cases, fluoropolymers are used, such as discussed in danish utility model DK201800024U 1. Gasket materials comprising polyvinylidene fluoride (PVDF) are disclosed in US5688293 and US 2005/008911. Another example is disclosed in US2007/207364, wherein a mixture comprising PVDF is dissolved in a solvent such as propylene carbonate or ethylene carbonate and applied to a bipolar plate, for example by painting or wire brushing, and then heated under pressure, for example at a temperature of 150-.

The fluoropolymer resin may be prepared fromObtained by companies, in particularSold by specialty Polymers. PVDF polymers are registered trade marks Andsales, such as disclosed in the attribute table disclosed on the following internet web sites:

https://www.solvay.com/sites/g/files/srpend221/files/2018-08/Solef- PVDF-Typical-Properties_EN-v2.7_0.pdf

the gasket material needs to be chemically resistant to the materials in the fuel cell and the heat therein, and must provide long-term tightness despite expansion and contraction of the components in the fuel cell stack. Various proposals regarding the materials and types of gaskets reflect the continuing effect of improving the life of the fuel cell stack.

Summary of the invention/summary of the invention

It is therefore an object of the present invention to provide improvements in the art. In particular, it is an object to provide an improved method for creating a durable tight seal between plates in a fuel cell, such as a fuel cell stack. A tight seal is provided by a polymeric adhesive (used as an adhesive) and gaskets between the plates.

The term "fuel cell" is used herein for individual fuel cells as well as fuel cell stacks, unless explicitly stated, for example, when referred to as a "single fuel cell".

For example, a fuel cell stack includes anode and cathode plates that are assembled into a bipolar plate assembly by joining the plates back-to-back to each other with a sealed flow field of cooling liquid therebetween. In this embodiment, a polymer material is used as the glue.

The invention is applicable to single fuel cells and fuel cell stacks, with particular emphasis on Proton Exchange Membrane (PEM) fuel cells, and in particular High Temperature Proton Exchange Membrane (HTPEM) fuel cells.

In order to achieve the correct functioning of a set of plates in such a fuel cell, including the delivery of reactants, the distribution of coolant fluid and the removal of by-products, the key requirements on the gasket material, in particular the adhesive layer (glue), should imply the following:

the material must be chemically and electrochemically inert to the gases and/or liquids used in the fuel cell;

the material must be thermally stable at the operating temperature of the fuel cell;

the material must be impermeable to the gases/liquids circulating in the fuel cell;

the melting point of the material must be lower than the melting point and decomposition temperature of the other components contained in the plates used in the fuel cell, in particular the polymer binder;

the material must show good adhesion to the materials used in the plates of the fuel cell.

Thermoplastic fluoropolymers, in particular polyvinylidene fluoride (PVDF) and its copolymers, can meet these requirements because they are insoluble in water, do not react with mineral acids, the melting point of some products reaches 175 ℃, and their thermal decomposition occurs only above 375 ℃.

In the following, a mixing method of the adhesive and a specific bonding method are explained, which results in a good lifetime and a proper bonding. Methods have been developed for fuel cells, particularly for gluing cathode and anode plates back to form bipolar plates, with or without cooling flow plates or cooling flow fields in between. However, the adhesive and the specific gluing method can also be used for gluing other components of a fuel cell, such as a fuel cell stack, particularly components in the form of plates, such as membrane frames with separator plates.

The binders were mixed as follows. The PVDF is mixed and dissolved in the solvent, typically by simultaneous heating and stirring. Optionally, the PVDF is added in multiple portions, with one portion added when the previous portion has dissolved or substantially dissolved.

The PVDF is mixed with the solvent at a concentration of 0.01 wt% to 30 wt%, such as 1 wt% to 25 wt%, optionally 10 wt% to 20 wt% PDVF, relative to the weight of the solvent to provide the binder. The PVDF comprises a homopolymer of PVDF or a copolymer of PVDF or both. Particularly useful are high molecular weight PVDF homopolymers, e.g.Is/are as follows6020 and (c) the product.

Examples of the solvent used alone or in combination include acetone, dimethylacetamide, dimethylformamide, dimethylsulfoxide, hexamethylphosphoramide, methylethylketone, N-methyl-2-pyrrolidone, tetrahydrofuran, tetramethylurea, tributyl phosphate, tricresyl phosphate, triethyl phosphate, trimethyl phosphate. Good results have been obtained experimentally with dimethylacetamide. In some embodiments, the solvent comprises greater than 50% dimethylacetamide, such as greater than 75%.

Good experimental results of the binder are obtained when the surfactant, in particular the non-ionic surfactant, is added in a concentration of, for example, 0.1% to 10%, optionally 1% to 4%, by volume with respect to the volume of the solvent. Croda may be used as such an additiveIs/are as followsHypermer^TMAnd DowTriton (R) of^TM. Discovery of Triton^TMUseful concentrations of X-100 (also known as octylphenol ethoxylate) in the solvent are about 2% by volume. The surfactant aids in forming a uniform liquid blend with the PVDFReducing the surface tension and improving the adhesion of the adhesive layer to the surface of the board, since the polymer penetrates more easily into the top layer of the board (using its natural microroughness and porosity), in particular for boards moulded according to WO 2018/071803. In some embodiments, the nonionic surfactant comprises greater than 50% octylphenol ethoxylate, for example greater than 75%.

The adhesive is applied to the surface of a plate-form member, such as a cathode plate or an anode plate or both, or to other plate-form members, such as the rigid frame of a membrane in a fuel cell.

Once the binder is on the surface, water (typically deionized water) is added to the binder, which causes precipitation of the PVDF. When a solvent mixed with water is used (e.g., dimethylacetamide), precipitation of PVDF results because it is not mixed with water. This crystallization and precipitation accelerates the time until the adhesive is ready for bonding. Compared to the prior art, where evaporation is carried out using high temperatures, the described process allows the evaporation stage to be carried out using room temperature, while still being faster than the prior art process.

After the solvent has evaporated, the adhesive is ready for bonding. For this purpose, the components to be bonded (for example two plates) are hot-pressed together at elevated temperature. The temperature during hot pressing is above the melting temperature of the PVDF, for example above 171 ℃, after which the temperature is reduced while still under pressure, until the temperature is below the crystallization temperature of the PVDF, for example 133 ℃, these temperatures being illustrated in pairs with6020 is effective.

For example, the pressure may be from 1kPa to 10kPa, optionally from 3kPa to 7 kPa. Experimentally, a value of 5kPa will produce good adhesion.

Although there are some clear similarities to the disclosure of US2013/0034801 (where bipolar plates are bonded with PDVF polymer), there are some key differences between the two approaches: in the above method, a homogeneous multi-component liquid mixture is used to form an adhesive layer having desired properties, in which PVDF is used as the adhesive material, dimethylethylAmide as a liquid medium for dissolving PVDF, water as a reagent for promoting precipitation of PVDF and removal of dimethylacetamide, octylphenol ethoxylate (e.g. Triton)^TMX-100) is used as a surfactant to accelerate dissolution of the PVDF and enhance penetration of the adhesive to the board surface. In contrast to such liquid adhesives, the polymers used in US2013/0034801 are used to prepare solid glues. The above-mentioned adhesives are provided as a homogeneous liquid mixture and the formation of the adhesive layer can be carried out at room temperature while the polymers used in US2013/0034801 are heat activated. While PVDF-based adhesives are applied in the form of liquid solutions, the viscosity and surface tension thereof can be adjusted within a wide range of parameters according to practical requirements, the viscosity of the molten solid polymers used in US2013/0034801 can only be changed very little and only by changing the temperature. In comparison to US2013/0034801, no grooves for fixing the adhesive layer are needed, since the adhesive composition adheres very well to the board surface. As a result, the compression required to glue the panels together is much lower than US 2013/0034801.

Brief description of the drawings

The invention is explained in more detail with reference to the drawings, in which

FIG. 1a is a schematic diagram of a fuel cell assembly in which cathode and anode plates are placed back-to-back and assembled into a bipolar plate with a cooling channel field therebetween;

fig. 1b is a schematic diagram of a fuel cell assembly in which cathode and anode plates are placed back-to-back with a cooling plate sandwiched in between.

FIG. 1c is a schematic diagram of a fuel cell assembly in which cathode and anode plates are placed back-to-back and assembled into a bipolar plate without a cooling channel field therebetween;

figure 2 is an example of a fuel cell assembly.

Figure 3 is a simplified diagram of a panel for gluing,

figure 4 is a schematic view of the principle of pressing the boards together while gluing.

FIG. 5 is a schematic diagram of the process;

figure 6 shows the performance results.

Detailed description/preferred embodiments

Reference is therefore made to fuel cell stacks and plates and their manufacture, for example using the polymer and carbon powder manufacture described by SerEnergy in WO 2018/071803. Deviating from fig. 6 and 7 of publication WO2018/071803, a fuel cell assembly is shown in fig. 1a and 1b, where a bipolar assembly with a cathode plate 34 of the cathode side 26 and an anode plate 36 of the anode side 28 is shown, with a field of cooling flow channels in the space 32 between the back of the cathode plate 34 and the anode plate 36, optionally with the interposition of a cooling plate 38, as shown in fig. 1 b.

For the assembly in fig. 1, either cathode plate 34 or anode plate 36 or both have a flow channel pattern integrated into the plate, such as provided by milling a flow channel field into the plate or by molding the plate to have such a flow channel field.

Cathode plate 34 and anode plate 36 are glued together with an adhesive, optionally with a cooling plate 38 therebetween, as part of the glued assembly.

In some embodiments, cathode plate 34 and anode plate 36 are glued together back-to-back with no cooling flow between the two plates, which is shown in fig. 1c, and adhesive 2 for gluing is also shown. The term back-to-back is used to secure the back surfaces of the cathode and anode plates, where the back surfaces are opposite the cathode and anode sides 26, 28 of the respective plates, and the anode and cathode sides of the opposite anode and cathode plates are facing each other and disposed on each side of the membrane 30. On the anode side 28, a hydrogen gas stream is provided to provide protons to the electrolyte membrane 30, and on the cathode side 26, an oxygen or air or other fluid stream is provided to receive protons from the membrane 30. A cathode fluid, typically oxygen or air, is used as a cooling medium to cool the bipolar plates. For example, the cathode side 26 of the final bipolar plate assembly has a serpentine channel pattern. Exemplary details of the channel pattern and other details of the bipolar plate are explained in WO2009/010066 and WO 2009/010067.

The adhesive 2 may also be used to glue other components in the fuel cell stack together.

Fig. 2 shows an embodiment of a PEM fuel cell stack 1, the PEM fuel cell stack 1 comprising a plurality of bipolar plates 12 assembled between end plates 4 and 6, including manifolds through which various fluids are directed. A Proton Exchange Membrane (PEM)30 between adjacent bipolar plates 12 is sealed to the bipolar plates 12 and resists the environment by a sealant 10. In fig. 2, bipolar plate 12 is shown as a bipolar assembly with cathode plate 34 and anode plate 36 glued together back-to-back with adhesive 2, similar to the illustration of fig. 1 c.

Fig. 3 is a simplified view of a plate 18, such as a cathode plate 34, an anode plate 36 or a bipolar plate 12, to which an adhesive 2 is applied for gluing into other components of a fuel cell stack. The plate 18 includes inlet and outlet manifolds 14 for conveying cooling fluid, oxygen, fuel or vapor to and from the flow channel field 16.

In order to assemble cathode plate 34 and anode plate 36 into bipolar plate 12, adhesive 2 layer must cover at least one plate, but covering both plates generally results in improved adhesion. In fig. 3, a plate is shown in a simplified design having inlet and outlet manifolds 14 for use in a fuel cell, in particular a PEM fuel cell, more particularly a HTPEM fuel cell.

However, as mentioned above, the gluing principle is equally applicable to plate members of other types of fuel cells.

The fuel cell as specified and explained in detail is an illustrative example and the adhesive and gluing method described herein has been found to be particularly useful.

The adhesive is applied, for example, by spraying, printing or painting. It should be mentioned that the formation of the adhesive layer on the surface of the plate is generally not limited by the specific design of the plate, including the size of the plate or the presence or absence of gas flow channels.

The successive steps I, II and III in fig. 5a, 5b and 5c illustrate a scheme of a useful method.

In the first step, as shown in fig. 5a, PVDF is mixed and dissolved in a solvent, typically by simultaneous heating and stirring.

The binder comprises a homopolymer of PVDF or a copolymer of PVDF. Particularly useful are high molecular weight PVDF homopolymers, e.g.Is/are as follows6020 and (c) the product. The polymer with the PVDF polymer is completely dissolved in a polar non-aqueous solvent or a mixture of such solvents.

Examples of the solvent used alone or in combination include acetone, dimethylacetamide, dimethylformamide, dimethylsulfoxide, hexamethylphosphoramide, methylethylketone, N-methyl-2-pyrrolidone, tetrahydrofuran, tetramethylurea, tributyl phosphate, tricresyl phosphate, triethyl phosphate, trimethyl phosphate. Good results were obtained with dimethylacetamide.

Advantageously, a nonionic surfactant is also added to the solvent or solvent mixture. For example, of Croda InternationalHypermer^TMAnd Triton from Dow Chemical fabrics^TMPossible are such additives, the concentration of which is generally up to 10% by volume, based on the amount of solvent. Discovery of Triton^TMA useful concentration of X-100 (also known as octylphenol ethoxylate) in the solvent is 2% by volume. The surfactant helps to form a homogeneous liquid mixture with the PVDF, reduces the surface tension, and improves the adhesion of the adhesive layer to the board surface as the polymer penetrates more easily into the top layer of the board (using its natural microroughness and porosity), especially boards molded according to WO 2018/071803. Optionally, the surface roughness of the panel may be increased by surface treatment with sandpaper or other abrasives in order to obtain better adhesion.

Advantageously, the concentration of PVDF is between 0.01 and 30% by weight, based on the amount of solvent. This is well below the concentration of 60% PVDF in the propylene carbonate disclosed in US2007/0207364, and coating and forming a PVDF gasket on the outer region of a bipolar plate or membrane-electrode assembly is disclosed in US 2007/0207364. A concentration of 15 wt% has been found useful to render the adhesive not highly tacky, which can cause difficulties in applying the adhesive.

It should be mentioned that the dissolution of the polymer in the solvent or solvent mixture generally proceeds slowly, why it is useful to add small portions of the polymer to the solvent already containing the surfactant while stirring and heating (for example up to 100 ℃). When the desired concentration is reached, the mixture containing PVDF is cooled to room temperature.

A possible way to apply the adhesive to the surface of the plate is to pump it through the tip at the end of the needle by means of a syringe, as shown in fig. 5 b. Advantageously, to achieve high accuracy, the syringe was mounted on an XYZ printing table that extrudes the mixture from the syringe through the tip directly onto the surface of the plate. The use of a dilute solution for the operation allows better dispensing of the PVDF-based glue thereon, thus forming a thin and dense layer. Furthermore, the diluted adhesive prevents overloading of the syringe.

The printing process is carried out at a temperature not exceeding the boiling point of the solvent used in the binder, for example below 165 ℃ in the case of dimethylacetamide. In general, it has been found useful to work at room temperature because of the slow evaporation of the solvent from the gum.

In some experiments, PVDF/dimethylacetamide/surfactant (Triton) was used^TMX-100) mixture was used to cover the plate, two methods were used to crystallize the PVDF in the adhesive layer.

In one method, by heating to not more than T₀Removing liquid from the binder mixture at a temperature of (1), wherein T₀Is the boiling point of the solvent used, for example 165 ℃ for dimethylacetamide.

In another approach, also shown in fig. 5b, which results in faster crystallization, deionized water is added to the mixture once it is coated on the surface of the plate, for example by spraying water onto the adhesive. The temperature of the binder in this step is below 100 c in order not to evaporate the water. Water was chosen because it readily reacts with dimethylacetamide and Triton^TMX-100 mixes but is not absorbed by the PVDF, resulting in its precipitation. It was found that the risk of undesired binder flow during hardening is minimized by adding water to crystallize more quickly. The polymer is uniformly distributed on the surface of the plate and is firmly bonded with the composite material of the plate,a film-like structure having a prescribed thickness and width is formed within a few seconds when water is added, whereas the first method is that the heating process requires a significantly longer curing time. For example, as disclosed in US2007/0207364, the heating duration of a PVDF mat coated by a concentrated solution reaches 5h, while crystallization with water is many times faster and therefore highly advantageous.

One possible gluing method is described below. When crystallization is complete, one or more pairs of plates are placed in a pressing tool, such as a hot pressing tool, at a location that provides contact over the entire area coated with the adhesive layer. Connected inside the press in this way, the plates are compressed, as shown for example in figure 4.

Fig. 4 is a schematic diagram in which a bipolar assembly having cathode and anode plates 34 and 36 is placed back-to-back with adhesive 2 between two press nips 20, and pressure 22, optionally with heat, is applied. The method can also be applied to other plate-form components.

A useful compression value sufficient for gluing has been found to be 1kPa-10kPa, for example about 5 kPa.

If the panel is made of a composite material with a thermoplastic polymer, the temperature T of the adhesive layer is kept at the melting point T of PVFD₁Melting point T of the polymeric binder of the plate material₂As also shown in fig. 5 c. It is important to note that the bipolar plate is maintained in a pressurized state until the temperature of the adhesive layer reaches T₃To date, T₃Is the crystallization point of PVDF.

Value T₁And T₃Depending on its molecular weight and whether it is a homopolymer or a copolymer, it is determined by the melting and crystallization points, respectively, of the particular type of PVDF used. For example, for6020 type of PVDF, T₁＝171℃，T₃＝133℃。

Value T₂Is the melting point of the major polymer binder of the panel. For example, polyphenylene sulfide is one commonly used in HTPEM fuel cells, and has a melting point of 272 ℃ to 290 ℃ depending on its morphology and crystallinity, as also described in Rahate AS, Nemade KR, Waghuley SA. polyphenylene sulfite (PPS), state of the art and applications, Rev Chem Eng 29(2013) 471-. Thus, for this particular example, T is₂The temperature was set to 272 ℃.

T₁、T₂And T₃The value of (c) varies depending on the type of PVDF and the plate material.

Finally, the bipolar plate was removed from the press tool and tested for tightness (leak tightness) under the required conditions.

In experiments, HTPEM fuel cell stacks were assembled based on these glued bipolar plates and their electrochemical performance was recorded in terms of voltage drop over time. The measurement results are shown in fig. 6.

As shown in FIG. 6, at 165 ℃ and 0.2A/cm²With an applied current density of 5000h, there was only a slight degradation rate of 0.12 mV/h. This experiment demonstrates the excellent durability of PVDF layers made from the multi-component mixture described above, which makes them well suited for use as binders in HTPEM fuel cells.