阅读说明：本技术 一种洗毛污泥提脂工艺 (Wool scouring sludge fat extraction process ) 是由 孙进 徐学骁 陆曦 张帆 夏银 于 2020-12-31 设计创作，主要内容包括：本发明属于羊毛脂回收利用领域,具体涉及一种洗毛污泥提脂工艺,包括以下步骤：(1)向羊毛脂污泥加入表面活性剂,加热并搅拌得到混合物；(2)将(1)得到的混合物进行离心分离,得到乳浊液；(3)向乳浊液加入破乳剂,蒸馏得到精制羊毛脂；其中,步骤(1)中羊毛脂污泥和表面活性剂质量比例为1：2～1：10；步骤(1)中所述表面活性剂为皂素、硬脂酸、十二烷基硫酸钠、十二烷基苯磺酸钠中的一种或多种；所述表面活性剂的质量浓度为2～10％。本发明改变传统单一的处理工艺,大大提高了羊毛脂的提取率,羊毛脂提取率可达到88％。(The invention belongs to the field of lanolin recycling, and particularly relates to a wool washing sludge fat extraction process, which comprises the following steps: (1) adding a surfactant into the lanolin sludge, heating and stirring to obtain a mixture; (2) carrying out centrifugal separation on the mixture obtained in the step (1) to obtain emulsion; (3) adding a demulsifier into the emulsion, and distilling to obtain refined lanolin; wherein, the mass ratio of the lanolin sludge to the surfactant in the step (1) is 1: 2-1: 10; the surfactant in the step (1) is one or more of saponin, stearic acid, sodium dodecyl sulfate and sodium dodecyl benzene sulfonate; the mass concentration of the surfactant is 2-10%. The invention changes the traditional single treatment process, greatly improves the extraction rate of the lanolin, and the extraction rate of the lanolin can reach 88 percent.)

1. A wool scouring sludge fat extraction process is characterized by comprising the following steps:

(1) adding a surfactant into the lanolin sludge, heating and stirring to obtain a mixture;

(2) carrying out centrifugal separation on the mixture obtained in the step (1) to obtain emulsion;

(3) adding a demulsifier into the emulsion, and distilling to obtain refined lanolin;

wherein, the mass ratio of the lanolin sludge to the surfactant in the step (1) is 1: 2-1: 10;

the surfactant in the step (1) is one or more of saponin, stearic acid, sodium dodecyl sulfate and sodium dodecyl benzene sulfonate; the mass concentration of the surfactant is 2-10%.

2. The wool scouring sludge fat extracting process according to claim 1, wherein the heating temperature in the step (1) is 50-90 ℃.

3. The wool washing sludge fat extraction process as claimed in claim 1, wherein the stirring time in the step (1) is 5-15 minutes, and the stirring speed is 200-500 rpm.

4. The wool washing sludge fat extraction process according to claim 1, wherein the centrifugal rotation speed of the centrifugal separation in the step (2) is 2000-5000 rpm, and the centrifugal time is 5-10 min.

5. The wool scouring sludge fat extraction process according to claim 1, wherein the distillation temperature in the step (3) is 110-140 ℃, and the distillation times are 1-5.

6. The wool washing sludge fat-extraction process according to claim 1, wherein the demulsifier is one of an SP-type demulsifier, an AP-type demulsifier, an AE-type demulsifier and an AR-type demulsifier.

7. The wool washing sludge fat-extraction process according to claim 1 or 7, wherein the concentration of the demulsifier is 200-1000 ppm.

Technical Field

The invention belongs to the field of lanolin recycling, and particularly relates to a wool washing sludge fat extraction process.

Background

Lanolin, also called wool wax, is an oily secretion secreted by sebaceous glands of sheep and deposited on wool, can maintain and protect the physical properties of wool, is an important natural chemical raw material, and is widely applied to the fields of medicine, daily chemical industry, leather, paper making and the like.

Lanolin enters wool washing wastewater through a wool washing process, and excess sludge in the wool washing wastewater is a main source for recovering the lanolin. The wool yield of China is the second world, the raw wool is produced in the second year, the fat content of the wool is 9% -12%, and if the recovery rate is 50% according to the average 10% of the fat content, 1.25 ten thousand tons of lanolin can be recovered every year. However, the recovery amount is less than 1000 tons in practice, and more than 90 percent of lanolin is discharged along with waste water, so that the environment is polluted and resources are wasted.

The recovery and utilization of lanolin were studied from the last 40 th century abroad, mechanical centrifugation and other technologies were developed, and foam separation, flocculation, ultrafiltration and subcritical fluid extraction were successively developed in the future. At present, two methods of centrifugal separation and precipitation extraction are widely adopted in China, but the recovery rate is not high, and the post-treatment of waste liquid is difficult.

The invention patent with the prior patent application number of 201110119744.1 discloses a method for extracting lanolin from wool scouring wastewater sludge, and proposes that petroleum ether, alkane or halogenated alkane is used as an extracting agent to extract lanolin from dry sludge.

Disclosure of Invention

In order to solve the problems in the prior art, the invention provides a wool washing sludge fat extraction process, which can greatly improve the recovery rate of lanolin in wool wastewater, reduce the discharge of high pollutants in the wastewater and has high safety in the treatment process.

The specific technical scheme of the invention is as follows:

a wool scouring sludge fat extraction process comprises the following steps:

(1) adding a surfactant into the lanolin sludge, heating and stirring to obtain a mixture;

(2) carrying out centrifugal separation on the mixture obtained in the step (1) to obtain emulsion;

(3) adding a demulsifier into the emulsion, and distilling to obtain refined lanolin;

wherein, the mass ratio of the lanolin sludge to the surfactant in the step (1) is 1: 2-1: 10;

the surfactant in the step (1) is one or more of saponin, stearic acid, sodium dodecyl sulfate and sodium dodecyl benzene sulfonate; the mass concentration of the surfactant is 2-10%.

Wherein the heating temperature in the step (1) is 50-90 ℃.

Wherein, the stirring time in the step (1) is 5-15 minutes, and the stirring speed is 200-500 rpm.

Wherein the centrifugal rotation speed of the centrifugal separation in the step (2) is 2000-5000 rpm, and the centrifugal time is 5-10 min.

Wherein, the distillation temperature in the step (3) is 110-140 ℃, and the distillation times are 1-5 times.

Wherein the demulsifier is one of SP type demulsifier, AP type demulsifier, AE type demulsifier and AR type demulsifier.

Wherein the concentration of the demulsifier is 200-1000 ppm.

Advantageous effects

The invention adopts surfactant as washing agent to change the interface state of lanolin sludge liquid oil, water and solid, so that the oil phase and the washing liquid are emulsified (form a stable double electric layer structure) and separated from the solid phase. And secondly, breaking a stable double electric layer structure of the emulsion by using a demulsifier, thereby realizing separation of oil phase and water phase. The invention changes the traditional single treatment process, greatly improves the extraction rate of the lanolin, and the extraction rate of the lanolin can reach 88 percent.

Detailed Description

In the following examples of the present invention,

the dry sludge containing lanolin is obtained from sewage treatment plants in certain park in Cao county, Shandong,

the saponin, stearic acid, sodium dodecyl sulfate and sodium dodecyl benzene sulfonate are commercially available raw materials.

The AP type demulsifier, the SP type demulsifier, the AE type demulsifier and the AR type demulsifier are commercially available medicaments.

The lanolin extraction rate is the quality of refined lanolin/the quality of dried sludge containing lanolin.

Example 1

(1) Taking 100g of lanolin dried sludge, putting into a stirring device, adding 200g of saponin with the concentration of 2 wt% as a surfactant, controlling the heating temperature to be 50-55 ℃, stirring by adopting a mechanical paddle type, stirring at the speed of 200rpm, and stirring for 15 min.

(2) And (3) centrifuging the mixture stirred and activated in the step (1) at the rotating speed of 3000rpm for 8min to obtain emulsion.

(3) Adding 200ppm AP demulsifier into the separated emulsion, distilling at 140 deg.C for 1 time to obtain the remainder as refined lanolin, wherein the refined lanolin content in this example is 58g, i.e. the lanolin extraction rate is 58%.

Example 2

(1) Taking 100g of lanolin dried sludge, putting into a stirring device, adding 500g of stearic acid with the concentration of 10 wt% as a surfactant, controlling the heating temperature to be 85-90 ℃, stirring by adopting a mechanical paddle type, and stirring at the stirring speed of 400rpm for 10 min.

(2) And (3) centrifuging the mixture stirred and activated in the step (1) at the rotating speed of 5000rpm for 5min to obtain emulsion.

(3) Adding 800ppm SP type demulsifier into the separated emulsion, distilling at 130 deg.C for 3 times to obtain the remainder, i.e. refined lanolin, wherein the refined lanolin obtained in this example is 88g, i.e. the extraction rate of lanolin is 88%.

Example 3

(1) Taking 100g of lanolin dried sludge, putting into a stirring device, adding 1000g of sodium dodecyl sulfate with the concentration of 5 wt% as a surfactant, controlling the heating temperature to be 65-70 ℃, stirring by adopting a mechanical paddle type, and stirring at the speed of 500rpm for 5 min.

(2) And (3) centrifuging the mixture stirred and activated in the step (1) at 2000rpm for 8min to obtain emulsion.

(3) Adding 500ppm AE demulsifier into the separated emulsion, distilling at 110 deg.C for 5 times to obtain the remainder as refined lanolin, wherein the refined lanolin obtained in this example is 75g, i.e. the extraction rate of lanolin is 75%.

Example 4

(1) Taking 100g of lanolin dried sludge, putting into a stirring device, adding 800g of sodium dodecyl benzene sulfonate with the concentration of 8 wt% as a surfactant, controlling the heating temperature to be 75-80 ℃, and stirring by adopting a mechanical paddle type at the stirring speed of 400rpm for 10 min.

(2) And (3) centrifuging the mixture stirred and activated in the step (1) at the rotating speed of 4000rpm for 5min to obtain emulsion.

(3) Adding 1000ppm AR demulsifier into the separated emulsion, distilling at 120 deg.C for 3 times to obtain the remainder as refined lanolin, wherein the refined lanolin content in this example is 63g, i.e. the extraction rate of lanolin is 63%.