阅读说明：本技术 一种易剥离、绝缘、阻燃、防水高分子材料及其制备方法 (Easily-stripped, insulating, flame-retardant and waterproof high polymer material and preparation method thereof ) 是由 赵大力 于 2020-10-30 设计创作，主要内容包括：本发明提出了一种易剥离、绝缘、阻燃、防水高分子材料及其制备方法,涉及硅橡胶技术领域。该易剥离、绝缘、阻燃、防水高分子材料主要由如下重量份的原料制备而成：硅橡胶90～110份、丁苯热塑性弹性体140～160份、Sb2O3二氧化硅改性填料6～8份、轻质碳酸钙13～17份、硅藻土13～17份、白炭黑13～17份、偶联剂2～4份和硫化剂1～3份。本发明还提出一种易剥离、绝缘、阻燃、防水高分子材料的制备方法。本发明的优点在于,通过添加特定比例的不同方法制备的Sb2O3,同时调整Sb2O3的添加比例,有效提高了硅橡胶的阻燃性能,通过加入气象白炭黑、轻质碳酸钙和硅藻土作为补强填料,使其远远优于基础硅橡胶的各项性能。(The invention provides an easily-stripped, insulating, flame-retardant and waterproof high polymer material and a preparation method thereof, and relates to the technical field of silicone rubber. The easily-stripped, insulating, flame-retardant and waterproof high polymer material is mainly prepared from the following raw materials in parts by weight: 90-110 parts of silicon rubber, 140-160 parts of butylbenzene thermoplastic elastomer, 6-8 parts of Sb2O3 silicon dioxide modified filler, 13-17 parts of light calcium carbonate, 13-17 parts of diatomite, 13-17 parts of white carbon black, 2-4 parts of coupling agent and 1-3 parts of vulcanizing agent. The invention also provides a preparation method of the easily-stripped, insulating, flame-retardant and waterproof high polymer material. The invention has the advantages that the Sb2O3 prepared by different methods with specific proportions is added, the addition proportion of the Sb2O3 is adjusted, the flame retardant property of the silicone rubber is effectively improved, and the performance of the silicone rubber is far better than that of the basic silicone rubber by adding the fumed silica, the light calcium carbonate and the diatomite as reinforcing fillers.)

1. An easily-stripped, insulating, flame-retardant and waterproof high polymer material is characterized by being mainly prepared from the following raw materials in parts by weight: 90-110 parts of silicone rubber, 140-160 parts of butylbenzene thermoplastic elastomer, 36-8 parts of modified Sb2O, 13-17 parts of light calcium carbonate, 13-17 parts of diatomite, 13-17 parts of white carbon black, 2-4 parts of coupling agent and 1-3 parts of vulcanizing agent.

2. The easily-stripped, insulating, flame-retardant and waterproof high polymer material as claimed in claim 1, which is characterized by being mainly prepared from the following raw materials in parts by weight: 100 parts of silicon rubber, 150 parts of butylbenzene thermoplastic elastomer, 36 parts of modified Sb2O, 15 parts of silicon modified filler, 15 parts of light calcium carbonate, 15 parts of diatomite, 15 parts of white carbon black, 3 parts of coupling agent and 2 parts of vulcanizing agent.

3. A method for preparing the easily peelable, insulating, flame retardant, waterproof polymeric material according to claim 1 or 2, comprising the steps of:

dissolving SbCl3 in absolute ethyl alcohol, adding a surfactant, mixing uniformly, dropwise adding ammonia water, filtering after the reaction is finished, taking a precipitate, washing, drying at 200-300 ℃ for more than 2 hours, and grinding to obtain Sb2O3 powder;

adding Sb2O3 powder into a dispersion medium for uniform dispersion, dripping ethyl orthosilicate under the stirring state, adjusting the pH to 3.0-3.5, continuing to react for 0.5-1 h, adjusting the pH to 8-9, continuing to stir for 1-2 h to obtain gel, washing the gel with absolute ethyl alcohol, then performing vacuum drying, sintering at the temperature of 300-400 ℃ for more than 2h, and grinding to obtain modified Sb2O 3;

uniformly mixing silicon rubber, the butylbenzene thermoplastic elastomer, the light calcium carbonate, the diatomite and the white carbon black, adding the modified Sb2O3, uniformly mixing to obtain a master batch, adding a coupling agent and a vulcanizing agent into the master batch, and uniformly mixing to obtain the silicon rubber.

4. The preparation method of claim 3, wherein the ratio of SbCl3 to absolute ethyl alcohol is 1 (5-6) g/mL.

5. The method according to claim 3, wherein the rotation speed of the grinding is 400r/min, and the grinding time is 24 h.

6. The preparation method according to claim 3, wherein the mass ratio of the Sb2O3 powder to the tetraethoxysilane is 1: 1-3.

7. The preparation method according to claim 3, wherein the dropping speed of the tetraethoxysilane is 60-100 mL/min.

8. The method according to claim 3, wherein the ammonia water is added dropwise at a rate of 100 to 120 mL/min.

9. The production method according to claim 3, wherein the dispersion medium comprises 73.5 vol% of ethanol, 17 vol% of N, N-dimethylformamide, and 9.5 vol% of deionized water.

10. The method according to claim 5, wherein the dispersion time is 25 to 35 min.

Technical Field

The invention relates to the technical field of silicone rubber, in particular to an easily-stripped, insulating, flame-retardant and waterproof high polymer material and a preparation method thereof.

Background

"silicon" in silicone rubber means an inorganic Si-O main chain contained in a polymer, which is classified into a heat vulcanization type, a room temperature vulcanization type, wherein the room temperature vulcanization type is also classified into a polycondensation reaction type and an addition reaction type. The high-temperature silicon rubber is mainly used for manufacturing various silicon rubber products, and the room-temperature silicon rubber is mainly used as an adhesive, a potting material or a mold. The heat vulcanization type is the most used, and the heat vulcanization type is divided into methyl silicone rubber, methyl vinyl phenyl silicone rubber, other silicone rubber, fluorine silicone rubber and the like. Generally, an electric and electronic device body needs to work in a charged state, a material coated on the surface of the electric and electronic device body needs to have good insulation performance to ensure normal operation of work, and also needs to have good flame retardance and water resistance, in addition, the electric and electronic device body can be rapidly detached during replacement to deal with sudden situations in the charged working process and performance reduction caused by possible accelerated aging in severe weather, and in addition, how to rapidly replace the coated material with the reduced performance with a new coated material with good performance is also a challenge faced by the current silicone rubber.

Disclosure of Invention

The invention aims to provide an easily-stripped, insulating, flame-retardant and waterproof polymer material which has good flame retardance, waterproofness and weather resistance.

The invention also aims to provide a preparation method of the easily-stripped, insulating, flame-retardant and waterproof high polymer material, which is simple and convenient to operate and convenient to popularize.

The technical problem to be solved by the invention is realized by adopting the following technical scheme.

On one hand, the embodiment of the application provides an easily-stripped, insulating, flame-retardant and waterproof high polymer material which is mainly prepared from the following raw materials in parts by weight: 90-110 parts of silicon rubber, 140-160 parts of butylbenzene thermoplastic elastomer, 6-8 parts of Sb2O3 silicon dioxide modified filler, 13-17 parts of light calcium carbonate, 13-17 parts of diatomite, 13-17 parts of white carbon black, 2-4 parts of coupling agent and 1-3 parts of vulcanizing agent.

On the other hand, the embodiment of the application provides a preparation method of an easily-stripped, insulating, flame-retardant and waterproof high polymer material, which comprises the following steps: dissolving SbCl3 in absolute ethyl alcohol, adding a surfactant, mixing uniformly, dropwise adding ammonia water, filtering after the reaction is finished, taking a precipitate, washing, drying at 200-300 ℃ for more than 2 hours, and grinding to obtain Sb2O3 powder; adding Sb2O3 powder into a dispersion medium for uniform dispersion, dripping ethyl orthosilicate under the stirring state, adjusting the pH to 3.0-3.5, continuing to react for 0.5-1 h, adjusting the pH to 8-9, continuing to stir for 1-2 h to obtain gel, washing the gel with absolute ethyl alcohol, then performing vacuum drying, sintering at the temperature of 300-400 ℃ for more than 2h, and grinding to obtain modified Sb2O 3; uniformly mixing silicon rubber, the butylbenzene thermoplastic elastomer, the light calcium carbonate, the diatomite and the white carbon black, adding the modified Sb2O3, uniformly mixing to obtain a master batch, adding a coupling agent and a vulcanizing agent into the master batch, and uniformly mixing to obtain the silicon rubber.

In summary, compared with the prior art, the embodiments of the present invention have at least the following advantages or beneficial effects:

according to the easily-stripped, insulating, flame-retardant and waterproof high polymer material provided by the invention, Sb2O3 prepared by different methods with specific proportions is added, the addition proportion of Sb2O3 is adjusted, the flame retardant property of the silicone rubber is effectively improved, and the weather white carbon black, light calcium carbonate and diatomite are added as reinforcing fillers, so that the silicone rubber forms a three-dimensional net structure with the center thereof, the original molecular structure is changed, the mechanical property of the silicone rubber is improved on the original basis, and the water content of the fillers can be reduced, so that the silicone rubber is far superior to various properties of basic silicone rubber. Overall, the organic group on the silicon atom in the easily-peelable, insulating, flame-retardant and waterproof polymer material provided by the invention has good electrical insulation, weak surface tension and small surface energy, and prevents the phenomena of surface creepage and the like caused by condensation of water molecules, so that the easily-peelable, insulating, flame-retardant and waterproof polymer material has better hydrophobicity and water resistance, effectively prevents water from entering the interior of equipment, and prevents various equipment faults caused by water inflow.

Detailed Description

In order to make the objects, technical solutions and advantages of the embodiments of the present invention clearer, the technical solutions in the embodiments of the present invention will be clearly and completely described below. The examples, in which specific conditions are not specified, were conducted under conventional conditions or conditions recommended by the manufacturer. The reagents or instruments used are not indicated by the manufacturer, and are all conventional products available commercially.

The embodiment of the application provides an easily-stripped, insulating, flame-retardant and waterproof high polymer material which is mainly prepared from the following raw materials in parts by weight: 90-110 parts of silicone rubber, 140-160 parts of butylbenzene thermoplastic elastomer, 36-8 parts of modified Sb2O, 13-17 parts of light calcium carbonate, 13-17 parts of diatomite, 13-17 parts of white carbon black, 2-4 parts of coupling agent and 1-3 parts of vulcanizing agent.

In some embodiments of the present invention, the easily peelable, insulating, flame retardant, and waterproof polymer material is mainly prepared from the following raw materials in parts by weight: 100 parts of silicon rubber, 150 parts of butylbenzene thermoplastic elastomer, 36 parts of modified Sb2O, 15 parts of silicon modified filler, 15 parts of light calcium carbonate, 15 parts of diatomite, 15 parts of white carbon black, 3 parts of coupling agent and 2 parts of vulcanizing agent.

On the other hand, the embodiment of the present application provides a preparation method of the easily peelable, insulating, flame retardant, waterproof polymer material, including the following steps: dissolving SbCl3 in absolute ethyl alcohol, adding a surfactant, mixing uniformly, dropwise adding ammonia water, filtering after the reaction is finished, taking a precipitate, washing, drying at 200-300 ℃ for more than 2 hours, and grinding to obtain Sb2O3 powder; adding Sb2O3 powder into a dispersion medium for uniform dispersion, dripping ethyl orthosilicate under the stirring state, adjusting the pH to 3.0-3.5, continuing to react for 0.5-1 h, adjusting the pH to 8-9, continuing to stir for 1-2 h to obtain gel, washing the gel with absolute ethyl alcohol, then performing vacuum drying, sintering at the temperature of 300-400 ℃ for more than 2h, and grinding to obtain modified Sb2O 3; uniformly mixing silicon rubber, the butylbenzene thermoplastic elastomer, the light calcium carbonate, the diatomite and the white carbon black, adding the modified Sb2O3, uniformly mixing to obtain a master batch, adding a coupling agent and a vulcanizing agent into the master batch, and uniformly mixing to obtain the silicon rubber.

In some embodiments of the invention, the ratio of the SbCl3 to the absolute ethyl alcohol in the preparation method is 1 (5-6) g/mL.

In some embodiments of the present invention, the rotation speed of the grinding in the above preparation method is 400r/min, and the grinding time is 24 h. The grinding speed and the grinding time are controlled, so that the particle size of the Sb2O3 can be effectively controlled, and the SiO2 can be uniformly included in the Sb2O3 during the subsequent preparation of the modified Sb2O 3.

In some embodiments of the invention, the mass ratio of the Sb2O3 powder to the tetraethoxysilane in the preparation method is 1: 1-3.

In some embodiments of the invention, the dropping speed of the tetraethoxysilane in the preparation method is 60-100 mL/min. The dropping speed is proper, so that the generated SiO2 can be uniformly included in the Sb2O3, and the SiO2 is prevented from self-aggregating or the cladding degree is insufficient.

In some embodiments of the invention, the dropping speed of the ammonia water in the preparation method is 100-120 mL/min. The dropping speed of the ammonia water is controlled, so that the reaction speed can be effectively controlled.

In some embodiments of the present invention, the dispersion medium in the above preparation method comprises 73.5 vol% of ethanol, 17 vol% of N, N-dimethylformamide, and 9.5 vol% of deionized water.

In some embodiments of the present invention, the dispersion time in the above preparation method is 25 to 35 min.

The features and properties of the present invention are described in further detail below with reference to examples.

Example 1

The purpose of this embodiment is to provide an easily-peelable, insulating, flame-retardant, waterproof polymeric material.

Weighing SbCl3, putting the SbCl3 into a dry reaction container, pre-weighing absolute ethyl alcohol in the reaction container, wherein the ratio of SbCl3 to the absolute ethyl alcohol is 1:5g/mL, stirring the absolute ethyl alcohol by using a stirring device to ensure that SbCl3 is fully dissolved in the absolute ethyl alcohol, controlling the temperature of the absolute ethyl alcohol to be 45 ℃ during stirring, adding a surfactant SDS after stirring for reaction for 1.5h, stirring by using ultrasonic assistance, slowly dropping ammonia water at the speed of 60mL/min during the process, then carrying out centrifugal filtration, washing for 3 times, drying for more than 2h at the temperature of 200-300 ℃, grinding for 24h in a planetary ball mill to obtain Sb2O3 colloid, and the rotation speed during grinding is 400 r/min;

adding Sb2O3 powder into a dispersion medium to be uniformly dispersed, wherein the dispersion medium comprises 73.5 vol% of ethanol, 17 vol% of N, N-dimethylformamide and 9.5 vol% of deionized water, dropwise adding tetraethoxysilane under the stirring state, the mass ratio of Sb2O3 powder to tetraethoxysilane is 1:1, the dropwise adding speed of tetraethoxysilane is 90mL/min, adding a hydrochloric acid solution to adjust the pH value of the system to 3.5-4, continuously reacting for 0.5-1 h, gradually dropwise adding ammonia water at the ammonia water rate of 110mL/min, adjusting the pH value of the whole reaction system to 8-9, continuously stirring and reacting for 1-2 h to obtain gel, washing the gel by using absolute ethanol to fully remove inorganic salt ions in the gel, fully drying the washed gel in a vacuum environment, transferring the gel into a sintering device at 300-400 ℃ to be sintered for more than 2h, and finally grinding the gel in a planetary ball mill for 24h to obtain modified Sb2O3, the rotating speed during grinding is 400 r/min;

100g of silicon rubber, 150g of butylbenzene thermoplastic elastomer, 15g of light calcium carbonate, 15g of diatomite and 15g of white carbon black are mixed uniformly, then modified Sb2O 36 g is added, the mixture is mixed uniformly to obtain master batch, 3g of coupling agent and 2g of vulcanizing agent are added into the master batch, and the silicon rubber is obtained after mixing uniformly.

Example 2

The purpose of this embodiment is to provide an easily-peelable, insulating, flame-retardant, waterproof polymeric material.

Weighing SbCl3, putting the SbCl3 into a dry reaction container, pre-weighing absolute ethyl alcohol in the reaction container, wherein the ratio of SbCl3 to the absolute ethyl alcohol is 1:6g/mL, stirring the absolute ethyl alcohol by using a stirring device to ensure that SbCl3 is fully dissolved in the absolute ethyl alcohol, controlling the temperature of the absolute ethyl alcohol to be 45 ℃ during stirring, adding a surfactant SDS after stirring for reaction for 1.5h, stirring by using ultrasonic assistance, slowly dropping ammonia water at the speed of 60mL/min during the process, then carrying out centrifugal filtration, washing for 3 times, drying for more than 2h at the temperature of 200-300 ℃, grinding for 24h in a planetary ball mill to obtain Sb2O3 colloid, and the rotation speed during grinding is 400 r/min;

adding Sb2O3 powder into a dispersion medium to be uniformly dispersed, wherein the dispersion medium comprises 73.5 vol% of ethanol, 17 vol% of N, N-dimethylformamide and 9.5 vol% of deionized water, dropwise adding tetraethoxysilane under the stirring state, the mass ratio of Sb2O3 powder to tetraethoxysilane is 1:2, the dropwise adding speed of tetraethoxysilane is 90mL/min, adding a hydrochloric acid solution to adjust the pH value of the system to 3.5-4, continuously reacting for 0.5-1 h, gradually dropwise adding ammonia water at the ammonia water rate of 120mL/min, adjusting the pH value of the whole reaction system to 8-9, continuously stirring and reacting for 1-2 h to obtain gel, washing the gel by using absolute ethanol to fully remove inorganic salt ions in the gel, fully drying the washed gel in a vacuum environment, transferring the gel into a sintering device at the temperature of 300-400 ℃ to be sintered for more than 2h, and finally grinding the gel in a planetary ball mill for 24h to obtain modified Sb2O3, the rotating speed during grinding is 400 r/min;

uniformly mixing 90g of silicon rubber, 160g of butylbenzene thermoplastic elastomer, 13g of light calcium carbonate, 15g of diatomite and 17g of white carbon black, adding modified Sb2O 36 g, uniformly mixing to obtain a master batch, adding 2g of coupling agent and 4g of vulcanizing agent into the master batch, and uniformly mixing to obtain the silicon rubber.

Example 3

The purpose of this embodiment is to provide an easily-peelable, insulating, flame-retardant, waterproof polymeric material.

Weighing SbCl3, putting the SbCl3 into a dry reaction container, pre-weighing absolute ethyl alcohol in the reaction container, wherein the ratio of SbCl3 to the absolute ethyl alcohol is 1:5g/mL, stirring the absolute ethyl alcohol by using a stirring device to ensure that SbCl3 is fully dissolved in the absolute ethyl alcohol, controlling the temperature of the absolute ethyl alcohol to be 45 ℃ during stirring, adding a surfactant SDS after stirring for reaction for 1h, stirring by using ultrasonic assistance, slowly dropping ammonia water at the speed of 60mL/min during the process, then performing centrifugal filtration, washing for 3 times, drying for more than 2h at the temperature of 200-300 ℃, grinding for 24h in a planetary ball mill to obtain Sb2O3 colloid, wherein the rotation speed during grinding is 400 r/min;

adding Sb2O3 powder into a dispersion medium to be uniformly dispersed, wherein the dispersion medium comprises 73.5 vol% of ethanol, 17 vol% of N, N-dimethylformamide and 9.5 vol% of deionized water, dropwise adding ethyl orthosilicate under the stirring state, the mass ratio of Sb2O3 powder to the ethyl orthosilicate is 1:3, the dropwise adding speed of the ethyl orthosilicate is 80mL/min, adding a hydrochloric acid solution to adjust the pH value of the system to 3.5-4, continuously reacting for 0.5-1 h, gradually dropwise adding ammonia water at the ammonia water rate of 100mL/min, adjusting the pH value of the whole reaction system to 8-9, further continuously stirring and reacting for 1-2 h to obtain gel, washing the gel by using absolute ethanol to fully remove inorganic salt ions in the gel, fully drying the washed gel in a vacuum environment, transferring the gel into a sintering device at 300-400 ℃ to be sintered for more than 2h, and finally grinding the gel in a planetary ball mill for 24h to obtain modified Sb2O3, the rotating speed during grinding is 400 r/min;

uniformly mixing 90g of silicon rubber, 150g of butylbenzene thermoplastic elastomer, 17g of light calcium carbonate, 17g of diatomite and 17g of white carbon black, adding modified Sb2O 38 g, uniformly mixing to obtain a master batch, adding 4g of coupling agent and 3g of vulcanizing agent into the master batch, and uniformly mixing to obtain the silicon rubber.

Example 4

The purpose of this embodiment is to provide an easily-peelable, insulating, flame-retardant, waterproof polymeric material.

Weighing SbCl3, putting the SbCl3 into a dry reaction container, pre-weighing absolute ethyl alcohol in the reaction container, wherein the ratio of SbCl3 to the absolute ethyl alcohol is 1:5g/mL, stirring the absolute ethyl alcohol by using a stirring device to ensure that SbCl3 is fully dissolved in the absolute ethyl alcohol, controlling the temperature of the absolute ethyl alcohol to be 45 ℃ during stirring, adding a surfactant SDS after stirring for reaction for 1.5h, stirring by using ultrasonic assistance, slowly dropping ammonia water at the speed of 60mL/min during the process, then carrying out centrifugal filtration, washing for 3 times, drying for more than 2h at the temperature of 200-300 ℃, grinding for 24h in a planetary ball mill to obtain Sb2O3 colloid, and the rotation speed during grinding is 400 r/min;

adding Sb2O3 powder into a dispersion medium to be uniformly dispersed, wherein the dispersion medium comprises 73.5 vol% of ethanol, 17 vol% of N, N-dimethylformamide and 9.5 vol% of deionized water, dropwise adding ethyl orthosilicate under the stirring state, the mass ratio of Sb2O3 powder to the ethyl orthosilicate is 1:2, the dropwise adding speed of the ethyl orthosilicate is 100mL/min, adding a hydrochloric acid solution to adjust the pH value of the system to 3.5-4, continuously reacting for 0.5-1 h, gradually dropwise adding ammonia water at the ammonia water rate of 100mL/min, adjusting the pH value of the whole reaction system to 8-9, further continuously stirring and reacting for 1-2 h to obtain gel, washing the gel by using absolute ethanol to fully remove inorganic salt ions in the gel, fully drying the washed gel in a vacuum environment, transferring the gel into a sintering device at 300-400 ℃ to be sintered for more than 2h, and finally grinding the gel in a planetary ball mill for 24h to obtain modified Sb2O3, the rotating speed during grinding is 400 r/min;

uniformly mixing 90g of silicon rubber, 150g of butylbenzene thermoplastic elastomer, 17g of light calcium carbonate, 17g of diatomite and 17g of white carbon black, adding modified Sb2O 36 g, uniformly mixing to obtain a master batch, adding 4g of coupling agent and 3g of vulcanizing agent into the master batch, and uniformly mixing to obtain the silicon rubber.

Example 5

The purpose of this embodiment is to provide an easily-peelable, insulating, flame-retardant, waterproof polymeric material.

Weighing SbCl3, putting the SbCl3 into a dry reaction container, pre-weighing absolute ethyl alcohol in the reaction container, wherein the ratio of SbCl3 to the absolute ethyl alcohol is 1:6g/mL, stirring the absolute ethyl alcohol by using a stirring device to ensure that SbCl3 is fully dissolved in the absolute ethyl alcohol, controlling the temperature of the absolute ethyl alcohol to be 45 ℃ during stirring, adding a surfactant SDS after stirring for reaction for 1.5h, stirring by using ultrasonic assistance, slowly dropping ammonia water at the speed of 60mL/min during the process, then carrying out centrifugal filtration, washing for 3 times, drying for more than 2h at the temperature of 200-300 ℃, grinding for 24h in a planetary ball mill to obtain Sb2O3 colloid, and the rotation speed during grinding is 400 r/min;

adding Sb2O3 powder into a dispersion medium to be uniformly dispersed, wherein the dispersion medium comprises 73.5 vol% of ethanol, 17 vol% of N, N-dimethylformamide and 9.5 vol% of deionized water, dropwise adding ethyl orthosilicate under the stirring state, the mass ratio of Sb2O3 powder to the ethyl orthosilicate is 1:2, the dropwise adding speed of the ethyl orthosilicate is 60mL/min, adding a hydrochloric acid solution to adjust the pH value of the system to 3.5-4, continuously reacting for 0.5-1 h, gradually dropwise adding ammonia water at the ammonia water rate of 120mL/min, adjusting the pH value of the whole reaction system to 8-9, further continuously stirring and reacting for 1-2 h to obtain gel, washing the gel by using absolute ethanol to fully remove inorganic salt ions in the gel, fully drying the washed gel in a vacuum environment, transferring the gel into a sintering device at 300-400 ℃ to be sintered for more than 2h, and finally grinding the gel in a planetary ball mill for 24h to obtain modified Sb2O3, the rotating speed during grinding is 400 r/min;

uniformly mixing 90g of silicon rubber, 150g of butylbenzene thermoplastic elastomer, 17g of light calcium carbonate, 17g of diatomite and 17g of white carbon black, adding modified Sb2O 37 g, uniformly mixing to obtain a master batch, adding 4g of coupling agent and 3g of vulcanizing agent into the master batch, and uniformly mixing to obtain the silicon rubber.

Example 6

The purpose of this embodiment is to provide an easily-peelable, insulating, flame-retardant, waterproof polymeric material.

Weighing SbCl3, putting the SbCl3 into a dry reaction container, pre-weighing absolute ethyl alcohol in the reaction container, wherein the ratio of SbCl3 to the absolute ethyl alcohol is 1:6g/mL, stirring the absolute ethyl alcohol by using a stirring device to ensure that SbCl3 is fully dissolved in the absolute ethyl alcohol, controlling the temperature of the absolute ethyl alcohol to be 45 ℃ during stirring, adding a surfactant SDS after stirring for reaction for 2 hours, stirring by using ultrasonic assistance, slowly dropping ammonia water at the speed of 60mL/min during the process, then performing centrifugal filtration, washing for 3 times, drying for more than 2 hours at the temperature of 200-300 ℃, grinding for 24 hours in a planetary ball mill to obtain Sb2O3 colloid, wherein the rotation speed during grinding is 400 r/min;

adding Sb2O3 powder into a dispersion medium to be uniformly dispersed, wherein the dispersion medium comprises 73.5 vol% of ethanol, 17 vol% of N, N-dimethylformamide and 9.5 vol% of deionized water, dropwise adding ethyl orthosilicate under the stirring state, the mass ratio of Sb2O3 powder to the ethyl orthosilicate is 1:2, the dropwise adding speed of the ethyl orthosilicate is 70mL/min, adding a hydrochloric acid solution to adjust the pH value of the system to 3.5-4, continuously reacting for 0.5-1 h, gradually dropwise adding ammonia water at the ammonia water rate of 110mL/min, adjusting the pH value of the whole reaction system to 8-9, further continuously stirring and reacting for 1-2 h to obtain gel, washing the gel by using absolute ethanol to fully remove inorganic salt ions in the gel, fully drying the washed gel in a vacuum environment, transferring the gel into a sintering device at 300-400 ℃ to be sintered for more than 2h, and finally grinding the gel in a planetary ball mill for 24h to obtain modified Sb2O3, the rotating speed during grinding is 400 r/min;

100g of silicon rubber, 150g of butylbenzene thermoplastic elastomer, 15g of light calcium carbonate, 15g of diatomite and 15g of white carbon black are mixed uniformly, then modified Sb2O 37 g is added, the mixture is mixed uniformly to obtain master batch, 3g of coupling agent and 2g of vulcanizing agent are added into the master batch, and the silicon rubber is obtained after mixing uniformly.

Example 7

The purpose of this embodiment is to provide an easily-peelable, insulating, flame-retardant, waterproof polymeric material.

Weighing SbCl3, putting the SbCl3 into a dry reaction container, pre-weighing absolute ethyl alcohol in the reaction container, wherein the ratio of SbCl3 to the absolute ethyl alcohol is 1:6g/mL, stirring the absolute ethyl alcohol by using a stirring device to ensure that SbCl3 is fully dissolved in the absolute ethyl alcohol, controlling the temperature of the absolute ethyl alcohol to be 45 ℃ during stirring, adding a surfactant SDS after stirring for reaction for 2 hours, stirring by using ultrasonic assistance, slowly dropping ammonia water at the speed of 60mL/min during the process, then performing centrifugal filtration, washing for 3 times, drying for more than 2 hours at the temperature of 200-300 ℃, grinding for 24 hours in a planetary ball mill to obtain Sb2O3 colloid, wherein the rotation speed during grinding is 400 r/min;

adding Sb2O3 powder into a dispersion medium to be uniformly dispersed, wherein the dispersion medium comprises 73.5 vol% of ethanol, 17 vol% of N, N-dimethylformamide and 9.5 vol% of deionized water, dropwise adding ethyl orthosilicate under the stirring state, the mass ratio of Sb2O3 powder to the ethyl orthosilicate is 1:3, the dropwise adding speed of the ethyl orthosilicate is 80mL/min, adding a hydrochloric acid solution to adjust the pH value of the system to 3.5-4, continuously reacting for 0.5-1 h, gradually dropwise adding ammonia water at the ammonia water rate of 110mL/min, adjusting the pH value of the whole reaction system to 8-9, further continuously stirring and reacting for 1-2 h to obtain gel, washing the gel by using absolute ethanol to fully remove inorganic salt ions in the gel, fully drying the washed gel in a vacuum environment, transferring the gel into a sintering device at 300-400 ℃ to be sintered for more than 2h, and finally grinding the gel in a planetary ball mill for 24h to obtain modified Sb2O3, the rotating speed during grinding is 400 r/min;

100g of silicon rubber, 150g of butylbenzene thermoplastic elastomer, 15g of light calcium carbonate, 15g of diatomite and 15g of white carbon black are mixed uniformly, then modified Sb2O 38 g is added, the mixture is mixed uniformly to obtain master batch, 3g of coupling agent and 2g of vulcanizing agent are added into the master batch, and the silicon rubber is obtained after mixing uniformly.

Example 8

The purpose of this embodiment is to provide an easily-peelable, insulating, flame-retardant, waterproof polymeric material.

Weighing SbCl3, putting the SbCl3 into a dry reaction container, pre-weighing absolute ethyl alcohol in the reaction container, wherein the ratio of SbCl3 to the absolute ethyl alcohol is 1:6g/mL, stirring the absolute ethyl alcohol by using a stirring device to ensure that SbCl3 is fully dissolved in the absolute ethyl alcohol, controlling the temperature of the absolute ethyl alcohol to be 45 ℃ during stirring, adding a surfactant SDS after stirring for reaction for 2 hours, stirring by using ultrasonic assistance, slowly dropping ammonia water at the speed of 60mL/min during the process, then performing centrifugal filtration, washing for 3 times, drying for more than 2 hours at the temperature of 200-300 ℃, grinding for 24 hours in a planetary ball mill to obtain Sb2O3 colloid, wherein the rotation speed during grinding is 400 r/min;

adding Sb2O3 powder into a dispersion medium to be uniformly dispersed, wherein the dispersion medium comprises 73.5 vol% of ethanol, 17 vol% of N, N-dimethylformamide and 9.5 vol% of deionized water, dropwise adding tetraethoxysilane under the stirring state, the mass ratio of Sb2O3 powder to tetraethoxysilane is 1:1, the dropwise adding speed of tetraethoxysilane is 90mL/min, adding a hydrochloric acid solution to adjust the pH value of the system to 3.5-4, continuously reacting for 0.5-1 h, gradually dropwise adding ammonia water at the ammonia water rate of 110mL/min, adjusting the pH value of the whole reaction system to 8-9, continuously stirring and reacting for 1-2 h to obtain gel, washing the gel by using absolute ethanol to fully remove inorganic salt ions in the gel, fully drying the washed gel in a vacuum environment, transferring the gel into a sintering device at 300-400 ℃ to be sintered for more than 2h, and finally grinding the gel in a planetary ball mill for 24h to obtain modified Sb2O3, the rotating speed during grinding is 400 r/min;

the preparation method comprises the steps of uniformly mixing 110g of silicon rubber, 140g of butylbenzene thermoplastic elastomer, 15g of light calcium carbonate, 15g of diatomite and 15g of white carbon black, adding modified Sb2O 36 g, uniformly mixing to obtain master batch, adding 3g of coupling agent and 2g of vulcanizing agent into the master batch, and uniformly mixing to obtain the silicon rubber.

Example 9

The purpose of this embodiment is to provide an easily-peelable, insulating, flame-retardant, waterproof polymeric material.

Weighing SbCl3, putting the SbCl3 into a dry reaction container, pre-weighing absolute ethyl alcohol in the reaction container, wherein the ratio of SbCl3 to the absolute ethyl alcohol is 1:6g/mL, stirring the absolute ethyl alcohol by using a stirring device to ensure that SbCl3 is fully dissolved in the absolute ethyl alcohol, controlling the temperature of the absolute ethyl alcohol to be 45 ℃ during stirring, adding a surfactant SDS after stirring for reaction for 1h, stirring by using ultrasonic assistance, slowly dropping ammonia water at the speed of 60mL/min during the process, then performing centrifugal filtration, washing for 3 times, drying for more than 2h at the temperature of 200-300 ℃, grinding for 24h in a planetary ball mill to obtain Sb2O3 colloid, wherein the rotation speed during grinding is 400 r/min;

adding Sb2O3 powder into a dispersion medium to be uniformly dispersed, wherein the dispersion medium comprises 73.5 vol% of ethanol, 17 vol% of N, N-dimethylformamide and 9.5 vol% of deionized water, dropwise adding ethyl orthosilicate under the stirring state, the mass ratio of Sb2O3 powder to the ethyl orthosilicate is 1:1, the dropwise adding speed of the ethyl orthosilicate is 100mL/min, adding a hydrochloric acid solution to adjust the pH value of the system to 3.5-4, continuously reacting for 0.5-1 h, gradually dropwise adding ammonia water at the ammonia water rate of 120mL/min, adjusting the pH value of the whole reaction system to 8-9, further continuously stirring and reacting for 1-2 h to obtain gel, washing the gel by using absolute ethanol to fully remove inorganic salt ions in the gel, fully drying the washed gel in a vacuum environment, transferring the gel into a sintering device at 300-400 ℃ to be sintered for more than 2h, and finally grinding the gel in a planetary ball mill for 24h to obtain modified Sb2O3, the rotating speed during grinding is 400 r/min;

the preparation method comprises the steps of uniformly mixing 110g of silicon rubber, 140g of butylbenzene thermoplastic elastomer, 15g of light calcium carbonate, 15g of diatomite and 15g of white carbon black, adding modified Sb2O 36 g, uniformly mixing to obtain master batch, adding 3g of coupling agent and 2g of vulcanizing agent into the master batch, and uniformly mixing to obtain the silicon rubber.

Example 10

The purpose of this embodiment is to provide an easily-peelable, insulating, flame-retardant, waterproof polymeric material.

Weighing SbCl3, putting the SbCl3 into a dry reaction container, pre-weighing absolute ethyl alcohol in the reaction container, wherein the ratio of SbCl3 to the absolute ethyl alcohol is 1:5g/mL, stirring the absolute ethyl alcohol by using a stirring device to ensure that SbCl3 is fully dissolved in the absolute ethyl alcohol, controlling the temperature of the absolute ethyl alcohol to be 45 ℃ during stirring, adding a surfactant SDS after stirring for reaction for 1h, stirring by using ultrasonic assistance, slowly dropping ammonia water at the speed of 60mL/min during the process, then performing centrifugal filtration, washing for 3 times, drying for more than 2h at the temperature of 200-300 ℃, grinding for 24h in a planetary ball mill to obtain Sb2O3 colloid, wherein the rotation speed during grinding is 400 r/min;

adding Sb2O3 powder into a dispersion medium to be uniformly dispersed, wherein the dispersion medium comprises 73.5 vol% of ethanol, 17 vol% of N, N-dimethylformamide and 9.5 vol% of deionized water, dropwise adding ethyl orthosilicate under the stirring state, the mass ratio of Sb2O3 powder to the ethyl orthosilicate is 1:1, the dropwise adding speed of the ethyl orthosilicate is 60mL/min, adding a hydrochloric acid solution to adjust the pH value of the system to 3.5-4, continuously reacting for 0.5-1 h, gradually dropwise adding ammonia water at the ammonia water rate of 100mL/min, adjusting the pH value of the whole reaction system to 8-9, further continuously stirring and reacting for 1-2 h to obtain gel, washing the gel by using absolute ethanol to fully remove inorganic salt ions in the gel, fully drying the washed gel in a vacuum environment, transferring the gel into a sintering device at 300-400 ℃ to be sintered for more than 2h, and finally grinding the gel in a planetary ball mill for 24h to obtain modified Sb2O3, the rotating speed during grinding is 400 r/min;

the preparation method comprises the steps of uniformly mixing 110g of silicon rubber, 140g of butylbenzene thermoplastic elastomer, 15g of light calcium carbonate, 15g of diatomite and 15g of white carbon black, adding modified Sb2O 36 g, uniformly mixing to obtain master batch, adding 3g of coupling agent and 2g of vulcanizing agent into the master batch, and uniformly mixing to obtain the silicon rubber.

Test examples

The purpose of this test example is to verify the performance of the easily peelable, insulating, flame retardant, and waterproof polymeric materials provided in examples 1 to 10.

The easily peelable, insulating, flame retardant and waterproof polymer materials provided in examples 1 to 10 were respectively prepared into samples with a thickness of 3mm, which were numbered in sequence as 1 to 10, and the Limit Oxygen Index (LOI) of the easily peelable, insulating, flame retardant and waterproof polymer material provided in the present invention was tested with reference to the requirements of GB/T10707-2008, and the Heat Release Rate (HRR) of the easily peelable, insulating, flame retardant and waterproof polymer material provided in the present invention was tested with reference to ISO 5660-1. The results of the flame retardancy test are shown in Table 1, with modified Sb2O3 added in a specific ratioThe flame retardant effectively increases the LOI value of the easily-peelable, insulating, flame-retardant and waterproof polymer material provided by the invention, which is significantly larger than the limit (27%) of the industry on the LOI value of the flame-retardant material, wherein the LOI value of the easily-peelable, insulating, flame-retardant and waterproof polymer material provided by the embodiment 1 is the highest. Meanwhile, the specific flame retardant is added to modify the silicone rubber, so that the HRR value of the easily-stripped, insulating, flame-retardant and waterproof high polymer material provided by the invention can be 301.13kW/m at least²。

TABLE 1

Numbering	LOI(％)	HRR(kW/m2)
			1	31.0	301.13
2	29.9	311.6
			3	30.8	319.4
4	29.2	321.2
			5	28.9	325.1
6	28.6	317.1
			7	31.2	314.7
8	30.1	315.5
			9	28.1	314.2
10	28.4	309.6

In addition to the above detection, the easily-peelable, insulating, flame-retardant and waterproof polymer material provided by the invention is sent to a third party to detect the dielectric strength (the test temperature is 22.6, and the test humidity is 38.5), and the detection results show that the dielectric strength of the silicone rubber provided in the embodiments 1-10 is more than or equal to 15kv/mm, so that the requirement of the industry on the insulation of the silicone rubber is met. In addition, the third party detects the toughness, strength, water resistance, weather resistance and expansibility of the easily-stripped, insulating, flame-retardant and waterproof high polymer material, and the detection result shows that the water resistance and weather resistance of the material are obviously higher than the average industrial level, and the material is green and environment-friendly as a whole, low in smoke, free of halogen and free of toxic substances.

In summary, the easily peelable, insulating, flame retardant and waterproof polymer material provided by the embodiment of the invention is prepared by adding Sb2O3 prepared by different methods with specific proportions and adjusting the addition proportion of Sb2O3, so that the flame retardant property of the silicone rubber is effectively improved, and the silicone rubber forms a three-dimensional network structure with the center thereof by adding the fumed silica, the light calcium carbonate and the diatomite as reinforcing fillers, so that the original molecular structure is changed, the mechanical property of the silicone rubber is improved on the basis of the original structure, the water content of the fillers can be reduced, and the performances of the fillers are far better than those of the basic silicone rubber. Overall, the organic group on the silicon atom in the easily-peelable, insulating, flame-retardant and waterproof polymer material provided by the invention has good electrical insulation, weak surface tension and small surface energy, and prevents the phenomena of surface creepage and the like caused by condensation of water molecules, so that the easily-peelable, insulating, flame-retardant and waterproof polymer material has better hydrophobicity and water resistance, effectively prevents water from entering the interior of equipment, and prevents various equipment faults caused by water inflow. It can be widely used for the protection of high and low voltage cables, cable interlayers and pipelines.

The embodiments described above are some, but not all embodiments of the invention. The detailed description of the embodiments of the present invention is not intended to limit the scope of the invention as claimed, but is merely representative of selected embodiments of the invention. All other embodiments, which can be derived by a person skilled in the art from the embodiments given herein without making any creative effort, shall fall within the protection scope of the present invention.