阅读说明：本技术 用于制备共价适应性网络的化学方法 (Chemical process for the preparation of covalent adaptive networks ) 是由 S.帕拉勒 K.萨加尔 于 2018-03-09 设计创作，主要内容包括：本公开提供了形成共价交联的大分子网络的方法,其包括使被定义为R<Sub>1</Sub>-L-X-R<Sub>3</Sub>的式(I)的化合物与被定义为HZ-R<Sub>2</Sub>的式(II)的化合物反应,以形成被定义为R<Sub>1</Sub>-L-Y的式(III)的大分子化合物,其中R<Sub>1</Sub>代表大分子聚合物主链,L代表芳基或芳基烷基,R<Sub>2</Sub>独立地代表任选取代的支化或直链C<Sub>1</Sub>-C<Sub>10</Sub>烷烃、C<Sub>2</Sub>-C<Sub>10</Sub>烯烃、C<Sub>2</Sub>-C<Sub>10</Sub>炔烃,其中任选取代基是第二HZ部分或羧酸酯部分,R<Sub>3</Sub>代表CF<Sub>3</Sub>、H或C<Sub>1</Sub>-C<Sub>10</Sub>烷烃,X代表-C(O)-、-C(O)-C(CH<Sub>2</Sub>)-或-C(CH<Sub>2</Sub>)-C(O)-,Y代表-C(OH)(R<Sub>3</Sub>)-Z-R<Sub>2</Sub>、-C(O)-CH(R<Sub>3</Sub>)-CH<Sub>2</Sub>-Z-R<Sub>2</Sub>或–CH(C(O)R<Sub>3</Sub>)-CH<Sub>2</Sub>-Z-R<Sub>2</Sub>；且Z代表S或NH。本公开另外提供通过如上文定义的方法形成的共价连接的适应性网络。(The present disclosure provides a method of forming a covalently crosslinked macromolecular network comprising reacting a compound defined as R 1 ‑L‑X‑R 3 A compound of formula (I) with a compound defined as HZ-R 2 To form a compound of formula (II) defined as R 1 -L-Y macromolecular compounds of formula (III) in which R 1 Represents a macromolecular polymer backbone, L represents an aryl or arylalkyl group, R 2 Independently represents optionally substituted branched or straight-chain C 1 ‑C 10 Alkane, C 2 ‑C 10 Olefin, C 2 ‑C 10 Alkyne of whichThe optional substituent being a second HZ moiety or a carboxylate moiety, R 3 Represents CF 3 H or C 1 ‑C 10 Alkane, X represents-C (O) -, -C (O) -C (CH) 2 ) -or-C (CH) 2 ) -C (O) -, Y represents-C (OH) (R) 3 )‑Z‑R 2 、‑C(O)‑CH(R 3 )‑CH 2 ‑Z‑R 2 or-CH (C (O) R 3 )‑CH 2 ‑Z‑R 2 (ii) a And Z represents S or NH. The present disclosure additionally provides covalently linked adaptive networks formed by the methods as defined above.)