Copper electrolysis cathode washing stripping process and cathode washing stripping unit thereof

文档序号:1334072 发布日期:2020-07-17 浏览:39次 中文

阅读说明:本技术 铜电解阴极洗涤剥片工艺及其阴极洗涤剥片机组 (Copper electrolysis cathode washing stripping process and cathode washing stripping unit thereof ) 是由 刘望保 邓瑛 刘秉 王皓炜 王勇刚 于 2019-09-05 设计创作,主要内容包括:本发明属于电解冶炼技术领域,公开一种铜电解阴极洗涤剥片工艺及其阴极洗涤剥片机组,包括以下步骤:S1.附着阴极铜的阴极板经推板扩距进行第一次洗涤;S2.经第一次洗涤后的附着阴极铜的阴极板被送入剥片系统进行阴极铜剥离;S3.将从阴极板两侧表面上剥离的两块相互连接的阴极铜进行躺平;S4.使两块相互连接的阴极铜撕离;S5.阴极铜从撕离处被移出,对阴极铜光滑面进行第二次洗涤;S6.将二次洗涤后的阴极铜转移至输送链,输送链将合格的阴极铜移送至打包链进行打包。本发明创造性地将阴极板两侧的阴极铜在剥离时即进行翻转撕离,避免两块阴极铜继续粘连导致无法将其光滑面展露于外界,随后又对光滑面朝上的阴极铜二次洗涤,使其光滑面上的杂质得以最大限度去除。(The invention belongs to the technical field of electrolytic smelting, and discloses a copper electrolysis cathode washing stripping process and a cathode washing stripping unit thereof, which comprise the following steps: s1, carrying out primary washing on a cathode plate attached with cathode copper through distance expansion of a push plate; s2, sending the cathode plate which is washed for the first time and is attached with cathode copper into a stripping system to strip the cathode copper; s3, laying two pieces of mutually connected cathode copper stripped from the surfaces of the two sides of the cathode plate; s4, tearing off the two pieces of cathode copper which are connected with each other; s5, moving the cathode copper out of the tearing position, and washing the smooth surface of the cathode copper for the second time; and S6, transferring the secondarily washed cathode copper to a conveying chain, and transferring the qualified cathode copper to a packing chain by the conveying chain for packing. The cathode copper on the two sides of the cathode plate is turned and torn away when being stripped creatively, the problem that the smooth surface of the cathode copper cannot be exposed outside due to continuous adhesion of the two pieces of cathode copper is avoided, and then the cathode copper with the smooth surface facing upwards is washed for the second time, so that impurities on the smooth surface of the cathode copper are removed to the maximum extent.)

1. The copper electrolysis cathode washing stripping process is characterized by comprising the following steps of:

s1, carrying out primary washing on a copper-loaded negative plate through distance expansion of a push plate;

s2, feeding the copper-loaded cathode plate subjected to the first washing into a stripping system for cathode copper stripping;

s3, laying two pieces of mutually connected cathode copper stripped from the surfaces of the two sides of the cathode plate;

s4, tearing off the two pieces of cathode copper which are connected with each other;

s5, moving the cathode copper out of the tearing position, and washing the smooth surface of the cathode copper for the second time;

and S6, transferring the secondarily washed cathode copper to a conveying chain, and transferring the qualified cathode copper to a packing chain by the conveying chain for packing.

2. The copper electrolysis cathode washing flaking process of claim 1, characterized in that the cathode copper in S3 needs to be turned until lying flat and can be repeatedly turned over rapidly during the turning process.

3. The copper electrolysis cathodic washing exfoliation process of claim 1, wherein the cathodic copper is tilted during the secondary washing in S5.

4. A cathode washing and stripping unit for realizing the copper electrolysis cathode washing and stripping process according to any one of claims 1 to 3, which is characterized by comprising a stripping conveying chain, a stripping system arranged on the stripping conveying chain, a finished product conveying chain, a transfer device for transferring cathode copper from the stripping system to the finished product conveying chain, a stacking conveying chain and a packing device arranged at the tail end of the finished product conveying chain, wherein the stripping system comprises a stripping device for stripping the cathode copper from a cathode plate, a turnover device for enabling the stripped cathode copper in S3 to lie flat, and a tearing device for clamping and separating the two connected cathode copper in the lying flat state one by one;

the turnover device comprises a turnover frame, one end of the turnover frame is hinged to the frame of the stripping system, a connecting rod mechanism capable of enabling the turnover frame to swing up and down by taking the hinged part of the end part as a fulcrum is further arranged between the turnover frame and the frame, and a first driving mechanism is arranged on the frame and provides power for the swing of the turnover frame;

the transfer device comprises a conveying mechanism for conveying the cathode copper and a flushing mechanism for carrying out secondary washing on the cathode copper during conveying.

5. The cathode washing and stripping unit as claimed in claim 4, wherein the roll-over stand comprises two roll-over positioning plates respectively disposed at two sides of the stripping device, the link mechanism is hinged to the outer side surfaces of the roll-over positioning plates, the link mechanism comprises a first link connected to the roll-over positioning plates and a second link connected to the stripping system frame, the first link and the second link are hinged at ends, the hinged parts of the first link and the second link at two sides of the roll-over stand are connected through a link shaft, and the link shaft is hinged to both the first link and the second link.

6. The cathode washing and stripping unit as claimed in claim 4, wherein the stripping device comprises two vertically disposed fixing plates disposed on two sides of the cathode copper, two bottom plates uniformly distributed on two ends of the inner surface of the fixing plates and capable of horizontally sliding along the fixing plates, a clamping mechanism capable of biting the cathode copper by rotation or translation is mounted on the bottom plates, and two second driving mechanisms capable of controlling the two bottom plates to simultaneously slide in opposite directions are further disposed on the fixing plates.

7. The cathode washing and stripping unit according to claim 6, wherein the clamping mechanism comprises a swing cylinder hinged to the base plate, a mounting seat fixed to the base plate, and a pressing part hinged to the mounting seat through a rotating shaft, the pressing part is fixedly connected to the rotating shaft, the other end of the swing cylinder is hinged to a crank, the crank is fixedly connected to the rotating shaft, the pressing part comprises an upper dental plate and a lower dental plate which are respectively attached to the upper surface and the lower surface of the cathode copper, and the upper dental plate or the lower dental plate is provided with the pressing cylinder.

8. The cathode washing and stripping unit set forth in claim 4, wherein the conveying mechanism comprises a first translating mechanism and a second translating mechanism for horizontally conveying the cathode copper, a jacking mechanism for jacking from the bottom of the cathode copper to transfer the cathode copper from the first translating mechanism to the second translating mechanism, and a lowering mechanism for grabbing the cathode copper from the second translating mechanism and placing the cathode copper on the finished product conveying chain, the first translating mechanism and the second translating mechanism can slide along the stripping conveying chain, and the overturning device lays the cathode copper on the first translating mechanism.

9. The cathode washing stripping unit according to claim 8, wherein the flushing mechanism comprises a shower pipe disposed above the jacking mechanism, the jacking mechanism comprises a jacking frame contacting with the bottom of the cathode copper, the jacking frame is located in the middle of the stripping conveying chain, the jacking frame has a horizontal part and an arc part, the middle section of the arc part is connected to the unit frame through a telescopic mechanism, the end of the arc part is connected to a bearing seat, the bearing seat is mounted on the unit frame, and the jacking frame can rotate with the bearing seat as a pivot under the action of the telescopic mechanism.

10. The cathode washing and stripping unit set forth in claim 4, wherein the packing device comprises a lifting mechanism for lifting cathode copper in the stacking conveyor chain, at least one closed belt penetrating frame arranged parallel to the stacking conveyor chain, and packing heads for joint locking of the packing belts, wherein the number of the packing heads is matched with the number of the belt penetrating frames.

Technical Field

The invention relates to the technical field of electrolytic smelting, in particular to a copper electrolysis cathode washing stripping process and a cathode washing stripping unit thereof.

Background

In a traditional cathode washing and stripping unit, a cathode plate attached with cathode copper is firstly washed, then the cathode copper with the mutually adhered bottoms is taken down through a receiving mechanism below the cathode plate when the cathode copper on two sides of the cathode plate is stripped from the cathode plate, two adhered cathode copper are taken down to be put into a finished product conveying chain, two smooth surfaces are mutually attached, and then the cathode copper is conveyed to the finished product conveying chain in the state to be packaged.

The traditional unit can only wash away electrolyte and anode mud attached to the outer side of cathode copper because the washing operation is completed before the cathode copper is stripped, however, the electrolyte and the anode mud are also attached to the inner side of the cathode copper under the following conditions: on the one hand, the negative plate is in the transfer process or in the electrolytic deposition process, the edge clamping strips (preventing that the cathode copper sides on the two sides are connected together and are difficult to strip) arranged on the two sides of the negative plate are loosened, the edge clamping strips and the negative plate sides generate gaps, electrolyte or anode mud can be retained in the gaps, when the cathode copper is stripped in a stripping system, the retained electrolyte or anode mud enters the gaps between the negative plate and the cathode copper and is attached to the inner side surface of the cathode copper and is always retained. On the other hand, in the transportation process of the cathode plate with the cathode copper attached, the cathode copper and the cathode plate have certain probability of opening (the cathode copper is separated from the cathode plate at the upper part) in the process of taking out the tank and before washing, and the electrolyte and the anode mud which are supposed to flow away along with the washing flow enter the inner side of the cathode copper from the opening position and are left in the washing process. Because the cathode copper is a commodity which can be marketed, the market has strict index requirements on the chemical composition of the cathode copper, if the electrolyte and the anode mud are excessive, the chemical composition of the cathode copper cannot meet the requirements, and the cathode copper produced in a factory is rejected or sold at a reduced price. Meanwhile, the anode slime is a valuable raw material containing a large amount of precious metals, and the low recovery rate affects the income of a factory.

Therefore, how to display the smooth surface of the cathode copper and treat the electrolyte, anode mud and the like of the smooth surface becomes a technical problem which needs to be solved urgently.

Disclosure of Invention

The technical problem to be solved by the invention is to overcome the defects of the prior art and provide a copper electrolysis cathode washing stripping process which can display a smooth surface and perform impurity treatment when cathode copper is stripped.

The invention also provides a cathode washing stripping unit which realizes the process treatment and finally enables the cathode copper to be placed with the smooth surface facing upwards when being packed.

The purpose of the invention is realized by the following technical scheme:

a copper electrolysis cathode washing stripping process comprises the following steps:

s1, carrying out primary washing on a copper-loaded negative plate through distance expansion of a push plate;

s2, feeding the copper-loaded cathode plate subjected to the first washing into a stripping system for cathode copper stripping;

s3, laying two pieces of mutually connected cathode copper stripped from the surfaces of the two sides of the cathode plate;

s4, tearing off the two pieces of cathode copper which are connected with each other;

s5, moving the cathode copper out of the tearing position, and washing the smooth surface of the cathode copper for the second time;

and S6, transferring the secondarily washed cathode copper to a conveying chain, and transferring the qualified cathode copper to a packing chain by the conveying chain for packing.

Further, the cathode copper in S3 needs to be flipped until it lies flat, and can be flipped rapidly and repeatedly during the flipping process.

Further, the cathode copper is tilted in the secondary washing in S5.

A cathode washing and stripping unit for realizing the copper electrolysis cathode washing and stripping process comprises a stripping conveying chain, a stripping system arranged on the stripping conveying chain, a finished product conveying chain, a transfer device for transferring cathode copper from the stripping system to the finished product conveying chain, a stacking conveying chain arranged at the tail end of the finished product conveying chain and a packing device, wherein the stripping system comprises a stripping device for stripping the cathode copper from a cathode plate, a turnover device for enabling the stripped cathode copper in S3 to lie flat, and a tearing device for clamping and separating the two connected cathode copper in the lying flat state one by one.

The turnover device comprises a turnover frame, one end of the turnover frame is hinged to the frame of the stripping system, a link mechanism capable of enabling the turnover frame to swing up and down by taking the hinged position of the end part as a fulcrum is further arranged between the turnover frame and the frame, and a first driving mechanism is mounted on the frame and provides power for the turnover frame to swing.

The transfer device comprises a conveying mechanism for conveying the cathode copper and a flushing mechanism for carrying out secondary washing on the cathode copper during conveying.

Further, the roll-over stand comprises two roll-over positioning plates which are respectively positioned on two sides of the stripping device, the connecting rod mechanism is hinged to the outer side surface of the roll-over positioning plate and comprises a first connecting rod connected with the roll-over positioning plate and a second connecting rod connected to the stripping system rack, the end parts of the first connecting rod and the second connecting rod are hinged, the hinged parts of the first connecting rod and the second connecting rod on two sides of the roll-over stand are connected through a connecting rod shaft, and the connecting rod shaft is hinged with the first connecting rod and the second connecting rod.

Further, tear from the device including the fixed plate that is located the vertical placing of negative pole copper both sides, two evenly distributed can make the bottom plate that the level slided at the fixed plate along the fixed plate at fixed plate internal surface both ends, install the clamping mechanism that accessible rotation or translation gripped the negative pole copper on the bottom plate, still be equipped with two steerable two bottom plates simultaneously towards the second actuating mechanism that opposite direction slided on the fixed plate.

Furthermore, the clamping mechanism comprises a swing oil cylinder hinged on the bottom plate, a mounting seat fixed on the bottom plate and a pressing part hinged on the mounting seat through a rotating shaft, the pressing part is fixedly connected with the rotating shaft, the other end of the swing oil cylinder is hinged with a crank, the crank is fixedly connected with the rotating shaft, the pressing part comprises an upper dental plate and a lower dental plate which are respectively attached to the upper surface and the lower surface of the cathode copper, and the upper dental plate or the lower dental plate is provided with a pressing oil cylinder.

Furthermore, the conveying mechanism comprises a first translation mechanism and a second translation mechanism for horizontally supporting and conveying cathode copper, a jacking mechanism for supporting from the bottom of the cathode copper to transfer the cathode copper from the first translation mechanism to the second translation mechanism, and a lowering mechanism for grabbing the cathode copper from the second translation mechanism and placing the cathode copper on a finished product conveying chain, wherein the first translation mechanism and the second translation mechanism can slide along the stripping conveying chain, and the turning device lays the cathode copper on the first translation mechanism.

Furthermore, the washing mechanism comprises a spray pipe arranged above the jacking mechanism, the jacking mechanism comprises a jacking frame in contact with the bottom of the cathode copper, the jacking frame is positioned in the middle of the stripping conveying chain and is provided with a horizontal part and an arc-shaped part, the middle section of the arc-shaped part is connected onto the unit frame through a telescopic mechanism, the tail end of the arc-shaped part is connected onto a bearing seat, the bearing seat is arranged on the unit frame, and the jacking frame can rotate under the action of the telescopic mechanism by taking the bearing seat as a fulcrum.

Furthermore, the packing device comprises a lifting mechanism which is positioned in the stacking conveying chain and used for lifting cathode copper, at least one closed belt penetrating frame which is arranged in parallel to the stacking conveying chain, and a packing machine head for performing joint locking on a packing belt, wherein the number of the packing machine heads is matched with that of the belt penetrating frames.

Compared with the prior art, the invention has the following beneficial effects:

1) the traditional copper electrolysis cathode washing stripping process is overturned, cathode copper on two sides of a cathode plate is turned and torn away when stripped creatively, the problem that smooth surfaces of two cathode copper cannot be exposed outside due to continuous adhesion of the bottoms of the two cathode copper is avoided, and then secondary washing is carried out on the cathode copper with the smooth surfaces facing upwards, so that impurities on the smooth surfaces of the cathode copper are removed to the maximum extent;

2) the smooth surface of the cathode copper on the surface layer of the stack is upward in a packaging state, so that a purchaser can conveniently check the quality of the cathode copper in real time, and the value of the cathode copper is effectively improved;

3) in the cathode washing stripping unit, the two pieces of cathode copper with the bottom adhered to the cathode plate can be smoothly laid, separated and surface impurities are removed after the cathode copper is stripped from the cathode plate by arranging the turnover device, the tearing device, the transfer device and the flushing mechanism, the transfer device skillfully transfers the cathode copper for multiple times, ensures that long-distance travel from the stripping position to a finished product conveying chain can be easily realized under the grabbing of an inorganic robot arm, can keep the smooth surface of the cathode copper upward from beginning to end, and is convenient for the evaporation of residual washing water on the surface and the stacking of the cathode copper in a state that the outermost surface faces upward smoothly during the subsequent stacking of the cathode copper;

4) the jacking frame in the jacking mechanism rotates by taking the bearing seat as a fulcrum to support the cathode copper, and the creative design can enable the cathode copper to slightly incline during secondary washing, so that washing water can rapidly flow along the smooth surface of the cathode copper automatically and cannot be accumulated on the surface of the cathode copper;

5) in the packing device, the belt penetrating frames are arranged in parallel to the stacking conveying chain, so that the conveying of cathode copper is not influenced, the two belt penetrating frames are in a double-side packing mode, the packing efficiency can be effectively improved, and in addition, even if one belt penetrating frame fails, the packing task can be easily finished by one belt penetrating frame.

Drawings

FIG. 1 is a flow diagram of a copper electrolytic cathodic scrubbing and stripping process as described in example 1;

FIG. 2 is an overall layout of the cathode washing and stripping unit according to example 2;

FIG. 3 is a schematic view showing the structure of a flaking system in embodiment 2;

FIG. 4 is a schematic structural view of a turning device in embodiment 2;

FIG. 5 is a schematic view showing the structure of the tearing-off means in example 2;

FIG. 6 is a schematic view showing the structure of the transfer device according to embodiment 2 (without a flushing mechanism);

FIG. 7 is a schematic view of the structure of the transfer device (including a flushing mechanism) in example 2;

FIG. 8 is a schematic structural view of a jack mechanism in embodiment 2;

FIG. 9 is a schematic view showing the construction of a packing apparatus in embodiment 2;

FIG. 10 is a schematic view showing the construction of a lifting device and a swing mechanism in embodiment 2;

fig. 11 is a schematic structural diagram of a baling device in the prior art.

Detailed Description

The present invention will be further described with reference to the following detailed description, wherein the drawings are provided for illustrative purposes only and are not intended to be limiting; to better illustrate the embodiments of the present invention, some parts of the drawings may be omitted, enlarged or reduced, and do not represent the size of an actual product; it will be apparent to those skilled in the art that certain well-known structures in the drawings and descriptions thereof may be omitted.

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