阅读说明：本技术 一种动物用的补钙营养液及其制备方法 (A kind of calcium-supplementing nutritive liquid of animal and preparation method thereof ) 是由 解学祥 赵加军 赵娜 于 2019-09-20 设计创作，主要内容包括：本发明涉及动物营养品,具体涉及一种动物用的补钙营养液及其制备方法。一种动物用的补钙营养液,按重量份计,包括以下组分：钙源4.5～7份、乳糖2.3～2.7份、氨基酸1.14～2.22份、L-抗坏血酸0.02～0.04份、蔗糖2～2.5份、抑菌剂3.16～4.12份、酸奶香精0.4～0.6份、柠檬酸0.2～0.4份、氯化钾0.08～0.12份、乙醇0.63～0.95份、羧甲基纤维素钠0.2～0.5份、消泡剂0.1～0.2份、甘油2.52～6.31份、1,2-丙二醇10.36～20.72份、水70～80份。本发明制备得到的动物用的补钙营养液具有优异的离心稳定性和低温稳定性,乳化完全,不分层,均匀度好,保质期长(2～3年)。此外,能够给动物高效补钙,钙的吸收好,动物吃5～7天后,即可明显缓解骨关节病,保证了动物的正常发育和生长。(The present invention relates to animal nutritions, and in particular to a kind of calcium-supplementing nutritive liquid of animal and preparation method thereof.A kind of calcium-supplementing nutritive liquid of animal, by weight, including following components: 4.5~7 parts of calcium source, 2.3~2.7 parts of lactose, amino acid 1 .14~2.22 part, 0.02~0.04 part of L-AA, 2~2.5 parts of sucrose, 3.16~4.12 parts of bacteriostatic agent, 0.4~0.6 part of yoghurt flavours, 0.2~0.4 part of citric acid, 0.08~0.12 part of potassium chloride, 0.63~0.95 part of ethyl alcohol, 0.2~0.5 part of sodium carboxymethylcellulose, 0.1~0.2 part of defoaming agent, 2.52~6.31 parts of glycerol, 10.36~20.72 parts of 1,2-PD, 70~80 parts of water.The calcium-supplementing nutritive liquid for the animal that the present invention is prepared has excellent centrifugal stability and low-temperature stability, and emulsification is complete, not stratified, good evenness, long shelf-life (2~3 years).Furthermore it is possible to replenish the calcium to high efficiency animal, the good absorbing of calcium can obviously relieve osteoarthropathy after animal eats 5~7 days, ensure that the normal development and growth of animal.)

1. a kind of calcium-supplementing nutritive liquid of animal, which is characterized in that by weight, including following components: 4.5~7 parts of calcium source, 2.3~2.7 parts of lactose, amino acid 1 .14~2.22 part, 0.02~0.04 part of L-AA, 2~2.5 parts of sucrose, bacteriostatic agent 3.16~4.12 parts, 0.4~0.6 part of yoghurt flavours, 0.2~0.4 part of citric acid, 0.08~0.12 part of potassium chloride, ethyl alcohol 0.63 ~0.95 part, 0.2~0.5 part of sodium carboxymethylcellulose, 0.1~0.2 part of defoaming agent, 2.52~6.31 parts of glycerol, 1,2- the third two 10.36~20.72 parts of alcohol, 70~80 parts of water.

2. the calcium-supplementing nutritive liquid of animal according to claim 1, which is characterized in that the calcium source includes following weight The raw material of part: 3.0~4.0 parts of tricalcium phosphate, 1~2 part of calcium lactate, 0.5~1 part of precipitated calcium carbonate.

3. the calcium-supplementing nutritive liquid of animal according to claim 1, which is characterized in that the amino acid is selected from L- Soviet Union ammonia One or more of acid, L-lysine, L-arginine, Serine, Pidolidone, taurine.

4. the calcium-supplementing nutritive liquid of animal according to claim 1, which is characterized in that the bacteriostatic agent is selected from benzoic acid One of sodium, lauric monoglyceride, ethylparaben, methylparaben are several.

5. the calcium-supplementing nutritive liquid of animal according to claim 1, which is characterized in that the bacteriostatic agent includes following heavy Measure part component: 1.0~1.3 parts of sodium benzoate, 2.0~2.5 parts of lauric monoglyceride, 0.08~0.2 part of ethylparaben, 0.02~0.1 part of methylparaben.

6. the calcium-supplementing nutritive liquid of animal according to claim 4, which is characterized in that the lauric monoglyceride and The weight ratio of sodium carboxymethylcellulose is (2~15): 1.

7. the calcium-supplementing nutritive liquid of described in any item animals according to claim 1~6, which is characterized in that 1, the 2- third The weight ratio of two pure and mild glycerol is (1~10): 1.

8. the calcium-supplementing nutritive liquid of animal according to claim 7, which is characterized in that the glycerol and carboxymethyl cellulose The weight ratio of plain sodium is (7~13): 1.

9. a kind of preparation method of the calcium-supplementing nutritive liquid of any one according to claim 1~8 animal, which is characterized in that It at least includes the following steps:

(1) the first parts by weight water, calcium source, lactose, amino acid, L-AA and sucrose are added to the water of vacuum homogeneous emulsifying machine In pot, it is stirred 5~15min；

(2) sodium carboxymethylcellulose is added in the second parts by weight water and impregnates 12~36h；

(3) step (2) obtained material and third parts by weight water, glycerol, 1,2- propylene glycol are added to the oil of vacuum homogeneous emulsifying machine In pot, after mixing 5~10min, bacteriostatic agent, yoghurt flavours, citric acid, potassium chloride, ethyl alcohol and defoaming agent is added, is stirred 5 ~15min；

(4) by the material of oil cauldron and kettle be added emulsion tank in, emulsifying to get.

10. the preparation method of the calcium-supplementing nutritive liquid of animal according to claim 9, which is characterized in that described first, Two and third parts by weight water weight ratio be (4~6): 1:(1~3).

Technical field

The present invention relates to animal nutrition technical fields, and in particular to a kind of calcium-supplementing nutritive liquid of animal and its preparation side Method.

Background technique

Calcium is that one of the most abundant mineral matter element of animal in-vivo content and important metallic element or animal body are normal The important substance of metabolism, all life processes of basic upper machine body are required to the participation of calcium.Calcium deficiency can cause a variety of diseases, If cub calcium deficiency will affect normal development, cause the figure speed of growth slow, if also will cause in the dental transitional period calcium deficiency of cub Permanent tooth growth is insecure, irregular；Adults calcium deficiency can cause textured bone, bone pain, osteoproliferation and easily occur The bone and joint diseases such as fracture.

Animal absorbs a large amount of calcium daily from food, these calcium mainly pass through small intestinal absorption, wherein 35% calcium uptake Enter blood circulation afterwards, most of calcium will be deposited in bone, also have small part to be present in soft tissue and extracellular fluid.Calcium Mechanism there are mainly three types of absorbing: 1. cell gulps down drink and secretion；2. intracellular Ca2+ is transported；3. paracellular pathway.Through digesting and assimilating It can also be metabolized afterwards and a certain amount of calcium is discharged through sweat or urine.Rational diet, it is more to take in the high food of calcium content, it is to mend One of important channel of calcium.In addition, selecting suitable calcium-supplementing nutritive liquid, and prevent and treat the effective ways of calcium deficiency.

The calcium-supplementing nutritive liquid huge number of presently commercially available animal, quality are irregular.However, due to such battalion that replenishes the calcium Nutrient solution is in the form of an emulsion, often there are the wild effects such as creaming of emulsion, need to shake up before use mostly, especially low Temperature stability is poor, and lotion is easily layered after freezing, to affect the quality of nutrient solution.

Summary of the invention

To solve the above-mentioned problems, first aspect of the present invention provides a kind of calcium-supplementing nutritive liquid of animal, by weight Part meter, including following components: 4.5~7 parts of calcium source, 2.3~2.7 parts of lactose, amino acid 1 .14~2.22 part, L-AA 0.02~0.04 part, 2~2.5 parts of sucrose, 3.16~4.12 parts of bacteriostatic agent, 0.4~0.6 part of yoghurt flavours, citric acid 0.2~ 0.4 part, 0.08~0.12 part of potassium chloride, 0.63~0.95 part of ethyl alcohol, 0.2~0.5 part of sodium carboxymethylcellulose, defoaming agent 0.1 ~0.2 part, 2.52~6.31 parts of glycerol, 10.36~20.72 parts of 1,2- propylene glycol, 70~80 parts of water.

As a preferred technical solution of the present invention, the calcium source includes the raw material of following parts by weight: tricalcium phosphate 3.0~4.0 parts, 1~2 part of calcium lactate, 0.5~1 part of precipitated calcium carbonate.

As a preferred technical solution of the present invention, the amino acid is selected from L-threonine, L-lysine, L- essence ammonia One or more of acid, Serine, Pidolidone, taurine.

As a preferred technical solution of the present invention, the bacteriostatic agent be selected from sodium benzoate, lauric monoglyceride, One of ethylparaben, methylparaben are several.

As a preferred technical solution of the present invention, the bacteriostatic agent is comprised the following components in parts by weight: benzoic acid 1.0~1.3 parts of sodium, 2.0~2.5 parts of lauric monoglyceride, 0.08~0.2 part of ethylparaben, methylparaben 0.02~ 0.1 part.

As a preferred technical solution of the present invention, the weight of the lauric monoglyceride and sodium carboxymethylcellulose Amount is than being (2~15): 1.

As a preferred technical solution of the present invention, the weight ratio of the 1,2-PD and glycerol is (1~10): 1。

As a preferred technical solution of the present invention, the weight ratio of the glycerol and sodium carboxymethylcellulose be (7~ 13): 1.

The second aspect of the present invention provides a kind of preparation method of the calcium-supplementing nutritive liquid of animal, includes at least following step It is rapid:

(1) vacuum homogeneous emulsifying machine is added in the first parts by weight water, calcium source, lactose, amino acid, L-AA and sucrose Kettle in, be stirred 5~15min；

(2) sodium carboxymethylcellulose is added in the second parts by weight water and impregnates 12~36h；

(3) vacuum homogeneous emulsifying machine is added in step (2) obtained material and third parts by weight water, glycerol, 1,2- propylene glycol Oil cauldron in, after mixing 5~10min, bacteriostatic agent, yoghurt flavours, citric acid, potassium chloride, ethyl alcohol and defoaming agent is added, stirring is mixed Close 5~15min；

(4) by the material of oil cauldron and kettle be added emulsion tank in, emulsifying to get.

As a preferred technical solution of the present invention, the weight ratio of the first, second, and third parts by weight water is (4~6): 1:(1~3).

The utility model has the advantages that the calcium-supplementing nutritive liquid for the animal that the present invention is prepared, by using special technique and component, It is reasonably combined, on the one hand, can to replenish the calcium to high efficiency animal, the good absorbing of calcium after animal eats 5~7 days, that is, can obviously relieve bone pass Section disease, ensure that the normal development and growth of animal；On the other hand, under specific ratio, due to interfacial film and liquid crystalline phase Collective effect, so that lotion has excellent centrifugal stability and low-temperature stability, emulsification is completely, not stratified, even across -18 DEG C frost after, then heat up reply after it is also not stratified, freeze-thaw stability is good, the calcium-supplementing nutritive liquid have the longer shelf-life (2~ 3 years), and good evenness.

Specific embodiment

It is further clear, complete that the technical characteristic work in technical solution is provided to the present invention With reference to embodiment Description, not to the limitation of its protection scope.Unless otherwise defined, all technologies used herein and scientific term have With the normally understood identical meaning of one skilled in the art of the present invention.When there is a conflict, in this specification Subject to definition.

Word " preferred ", " preferred ", " most preferred " in the present invention etc. refer to, can provide in some cases The embodiment of the present invention of certain beneficial effects.However, other embodiments can also under identical circumstances or in the case of other It can be preferred.In addition, not implying that other embodiments are unavailable to the statement of one or more preferred embodiments, simultaneously yet It is not intended to exclude other embodiments except the scope of the present invention.

To solve the above-mentioned problems, first aspect of the present invention provides a kind of calcium-supplementing nutritive liquid of animal, by weight Part meter, including following components: 4.5~7 parts of calcium source, 2.3~2.7 parts of lactose, amino acid 1 .14~2.22 part, L-AA 0.02~0.04 part, 2~2.5 parts of sucrose, 3.16~4.12 parts of bacteriostatic agent, 0.4~0.6 part of yoghurt flavours, citric acid 0.2~ 0.4 part, 0.08~0.12 part of potassium chloride, 0.63~0.95 part of ethyl alcohol, 0.2~0.5 part of sodium carboxymethylcellulose, defoaming agent 0.1 ~0.2 part, 2.52~6.31 parts of glycerol, 10.36~20.72 parts of 1,2- propylene glycol, 70~80 parts of water.

In a preferred embodiment, the calcium-supplementing nutritive liquid of animal of the present invention, by weight, including with Lower component: 5.75 parts of calcium source, 2.5 parts of lactose .68 parts of amino acid 1,0.03 part of L-AA, 2.25 parts of sucrose, bacteriostatic agent 3.75 parts, 0.5 part of yoghurt flavours, 0.3 part of citric acid, 0.1 part of potassium chloride, 0.79 part of ethyl alcohol, 0.3 part of sodium carboxymethylcellulose, 0.15 part of defoaming agent, 3 parts of glycerol, 15 parts of 1,2- propylene glycol, 75 parts of water.

Calcium source

Calcium source of the present invention refers to the substance for being capable of providing calcium constituent, including inorganic calcium, calcium of organic acid, amino acid calcium With four major class of nanometer calcium.

In a preferred embodiment, calcium source of the present invention includes the raw material of following parts by weight: tricalcium phosphate 3.0~4.0 parts, 1~2 part of calcium lactate, 0.5~1 part of precipitated calcium carbonate.

Tricalcium phosphate of the present invention, also known as calcium phosphate, synthos (2:3), three alkali calcium phosphates, raw calcium phosphate, Defluorinated calcium phosphate, precipitated calcium phosphate, chemical structure this product are the mixture of different form calcium phosphate composition.Insoluble in ethyl alcohol and third Ketone is slightly soluble in water, is soluble in dilute hydrochloric acid and nitric acid.In the food industry be used as anticaking agent, acidity regulator, nutritional supplement, Fumet, stabilizer, water retention agent.

Calcium lactate of the present invention is a kind of calcium supplement, and there is the calcification for promoting bone and tooth to be formed, maintain nerve With the normal excitability of muscle and the effects of reduce capillary permeability.It is generally only for oral administration because its solubility is smaller. Oral absorption is slow, and process is similar to calcium chloride in vivo.For preventing and treating acalcicosis, not such as osteoporosis, bone development Congruence.

Precipitated calcium carbonate also known as winnofil of the present invention are made by chemical processes.Due to sinking for it Drop volume (2.4-2.8mL/g) compares the powdered whiting settling volume (1.1-1.9mL/g) mechanically produced greatly, therefore quilt Referred to as precipitated calcium carbonate.The pH value of precipitated calcium carbonate aqueous solution is 9.5~10.2；The pH of saturation of the air precipitated calcium carbonate aqueous solution Value is 8.0~8.6；Precipitated calcium carbonate is nontoxic, odorless, nonirritant, usually white.Precipitated calcium carbonate is a kind of inorganic calcium.

In a kind of preferred embodiment, calcium source of the present invention includes the raw material of following parts by weight: tricresyl phosphate 3.5 parts of calcium, 1.5 parts of calcium lactate, 0.75 part of precipitated calcium carbonate.

Lactose

Lactose of the present invention is distinctive carbohydrate in mammal milk.It is by glucose and galactolipin group At disaccharide.In the growth and development process of animal, lactose can not only provide energy, also participate in the developmental process of brain.Cream Sugared is all the source of animal body thermal energy as other carbohydrates, also helps the absorption of calcium and other materials.

Amino acid

Amino acid of the present invention is the compound after the hydrogen atom on carboxylic acid carbon atom is replaced by amino, Amino acid score Contain amino and carboxyl Liang Zhong functional group in son.Amino acid is the base substance of protein needed for constituting Animal nutrition.Amino connects It is a-amino acid on α-carbon, the amino acid of constitutive protein matter is largely a-amino acid.

In a preferred embodiment, amino acid of the present invention is selected from L-threonine, L-lysine, L- essence ammonia One or more of acid, Serine, Pidolidone, taurine.

In a kind of preferred embodiment, amino acid of the present invention is L-lysine, L-arginine, L- paddy ammonia Acid, taurine.

L-lysine of the present invention, also known as left-handed -2,6- diaminocaproic acid mono-hydrochloric salts, L-2,6- diamino oneself Acid, L-lysine (food grade), lysine, be one of important component of protein, be animal body cannot itself synthesis but ten Divide one of the eight kinds of amino acid needed, is a kind of excellent food additive.Because lacking lysine in food, so also known as " the One essential amino acid ".Lysine is added to the utilization rate that protein can be improved in food, thus the battalion of condensed food significantly It supports, plays the role of enhancing development, increase appetite, reduce disease, is constitutional, for there is the work of deodorizing and fresh-keeping in can With.

L-arginine of the present invention, also known as 2- amino -5- guanidinopentanoic acid, L- Argine Monohydrochloride, arginine, essence Propylhomoserin, L-2- amino-guanidinopentanoic acid, L- arginine, L-arginine alkali lose crystallization in 105 DEG C after water recrystallizes Water, water solubility be in strong basicity, can from air absorbing carbon dioxide.It is dissolved in water (15%, 21 DEG C), does not dissolve in ether, slightly soluble In ethyl alcohol.It is largely present in nucleoprotamine etc., is also the basic composition of various protein, therefore there are very extensive.

Pidolidone of the present invention, also known as glutamic acid, alpha-amido glutaric acid, bran propylhomoserin, be white crystalline powder, It is almost odorless, there are special flavour and tart flavour.224 DEG C~225 DEG C decomposition.The pH value of saturated aqueous solution is about 3.2.Water is insoluble in, It is practical not dissolve in ethyl alcohol and ether, be highly soluble in formic acid.As for salt agent, nutritional supplement, tasty agents (be mainly used for meat, Soup class and poultry etc.).

Taurine of the present invention, also known as 2-aminoethanesulfonic acid, cholaic acid, Taurine are a kind of structures in animal body Simple sulfur-containing amino acid, chemical name are 2-aminoethanesulfonic acid, and odorless slightly sour, weak solution is in neutrality, to thermostabilization, in people With in conjunction with cholic acid, exist in animal bile with combining form；And in brain, ovary, heart, liver, milk, pine nut, hypophysis, view In the tissue such as film, adrenal gland, exist in a free form, 12~18g of total amount, but be not involved in the synthesis of protein.Taurine is people The conditionally essential amino acid of body plays an important role to the development of fetus, baby's nervous system.Taurine can be widely applied to cure The fields such as medicine, food additives, fluorescent whitening agent, organic synthesis, it is also possible to make biochemical reagents, wetting agent, pH buffer etc..

In a kind of preferred embodiment, amino acid of the present invention is comprised the following components in parts by weight: L- relies 0.04~0.06 part of propylhomoserin, 0.04~0.06 part of L-arginine, 0.06~0.1 part of Pidolidone, 1~2 part of taurine.

In a most preferred embodiment, amino acid of the present invention is comprised the following components in parts by weight: L- relies ammonia Sour 0.05 part, 0.05 part of L-arginine, 0.08 part of Pidolidone, 1.5 parts of taurine.

L-AA

L-AA of the present invention, also known as vitamin C, ascorbic acid, structure are a kind of polyhydroxys similar to glucose Based compound, the 2nd and the 3rd upper two adjacent enolic hydroxyls easily dissociate and release H in molecule⁺, therefore there is acid Property, also known as ascorbic acid.L-AA has very strong reproducibility, it is easy to be oxidized to hydroascorbic acid, but its Reaction is reversible, and ascorbic acid and hydroascorbic acid have same physiological function, if but hydroascorbic acid after Continuous oxidation generates the ancient happy saccharic acid of diketone, then reacts irreversible and lose physiological potency completely.

Sucrose

Sucrose, that is, sugar of the present invention, one kind of disaccharide, by the hemiacetal hydroxyl and a molecule of a molecule glucose The hemiacetal hydroxyl of fructose is condensed each other to be dehydrated.Sucrose is pleasantly sweet, odorlessness, and soluble easily in water and glycerol is slightly soluble in alcohol.Phase To density 1.587 (25 DEG C).There is optical activity, but without mutarotation.Sucrose be almost prevalent in the leaf of plant kingdom, flower, stem, In seed and fruit.Content is especially abundant in sugarcane, beet and maple syrup.Sucrose is sweet, is important food and sweet taste tune Taste product.

Bacteriostatic agent

Bacteriostatic agent of the present invention, also known as preservative, antistaling agent, refer to and are able to suppress microbial activities, prevent food Putrid and deteriorated a kind of food additives.

In a preferred embodiment, bacteriostatic agent of the present invention be selected from sodium benzoate, lauric monoglyceride, One of ethylparaben, methylparaben are several.

Sodium benzoate of the present invention, also known as sodium benzoate, are a kind of white particle or crystal powder, odorless or micro- Band benzoin odor, it is slightly sweet, there is astringent taste.Relative molecular mass 144.12.It is stable in the air, it is soluble easily in water, it is water-soluble The pH value of liquid is 8, is dissolved in ethyl alcohol.Benzoic acid and its esters are broad spectrum antimicrobial reagents, but its anti-microbial effectiveness depends on The pH value of food.With increasing for acidity of medium, sterilization, inhibitory effect enhancing then lose sterilization, antibacterial in alkaline medium Effect.

Lauric monoglyceride also known as lauric acid/dodecanoic acid monoglyceride of the present invention is a kind of lipophilic non-ionic table Face activating agent, the compound being naturally present in some plants.It is added to after extracting frequently as fungicide and antiphlogistic In food, daily necessities or cosmetics.It is both the antibacterial agent of excellent emulsifier and safe and efficient wide spectrum, and is not limited by pH System still has preferable antibacterial effect under the conditions of neutral or alkalescence, the disadvantage is that it is not soluble in water, it limits its application.

Ethylparaben of the present invention, also known as ethyl-para-hydroxybenzoate are white crystals thing, mildly bitter flavor, fiber crops of burning. It is stronger to the fungistatic effect of fungi but weaker to the fungistatic effect of bacterium.As bacteriostatic preservative, be widely used in liquid preparation and Semisolid preparation, it can also be used to the anti-corrosion of food and cosmetics.

Methylparaben of the present invention, also known as methyl p-hydroxybenzoate, methyl hydroxybenzoate, be white crystalline powder or Colourless crystallization, is soluble in alcohol, ether and acetone, atomic to be dissolved in water, and 270-280 DEG C of boiling point.It is mainly used as organic synthesis, food, change The sterilization antiseptic of cosmetic, medicine, also serves as in feed anticorrosion agent.Since it has phenolic hydroxyl structure, so bacteria resistance energy It is all stronger than benzoic acid, sorbic acid.Its mechanism of action is: destroying the cell membrane of microorganism, makes intracellular protein denaturation, and can Inhibit the respiratory enzyme of microbial cell and the activity of electron transmission enzyme system.

In a kind of preferred embodiment, bacteriostatic agent of the present invention is comprised the following components in parts by weight: benzene first 1.0~1.3 parts of sour sodium, 2.0~2.5 parts of lauric monoglyceride, 0.08~0.2 part of ethylparaben, methylparaben 0.02 ~0.1 part.

In a kind of most preferred embodiment, bacteriostatic agent of the present invention is comprised the following components in parts by weight: benzene first 1.15 parts of sour sodium, 2.4 parts of lauric monoglyceride, 0.14 part of ethylparaben, 0.06 part of methylparaben.

Yoghurt flavours

Yoghurt flavours of the present invention are mainly by propylene glycol, lactic acid, diacetyl, stabilizer, maltol, vanillic aldehyde, second Sulfonylmethyl carbinol, ethyl lactate, ethyl laurate etc. utilize the natural component for having stronger compatibility to dairy produce at being grouped as Yoghourt fermentation liquid, milk ketone musk use natural yogurt essence as food additives as stabilizer, to enhance fermentation The fermentation sense of cream, leben final products, and natural mouthfeel is brought, it is higher than the heat resistance of product, aroma quality The level of domestic similar essence.

Citric acid

Citric acid also known as citric acid of the present invention are a kind of important organic acid, clear crystal, Chang Hanyi molecule knot Brilliant water, it is odorless, there is very strong tart flavour, it is soluble easily in water.Its calcium salt is more soluble than in hot water in cold water, this property is commonly used to identify And separation of citric acid.Suitable temperature is controlled when crystallization can get anhydrous citric acid.In industry, grocery trade, makeup industry etc. has Extremely more purposes.

Potassium chloride

Potassium chloride of the present invention, chemical formula KCl are a kind of colourless elongated diamond shapes or at a cubic crystal or white Color crystallising small particles powder, appearance are odorless, taste is salty such as salt.It is usually used in the additive of Cardia Salt, mineral water.Potassium chloride It is that clinically used electrolyte balance adjusts medicine, clinical efficacy is definite, is widely used in clinical departments.

Ethyl alcohol

Ethyl alcohol of the present invention, also known as alcohol, spirit are a kind of inflammable, volatile colourless at normal temperatures and pressures Prescribed liquid, hypotoxicity, neat liquid are not directly drunk；It is stimulated with peat-reek, and slightly；Micro-sweet, and with irritant pungent Peppery flavour.Inflammable, steam can form explosive mixture with air, and energy and water are dissolved each other with any ratio.Can with chloroform, ether, Methanol, acetone and other most immiscible organic solvents, relative density 0.789g/cm³(20℃).Having many uses for ethyl alcohol, can Acetic acid, beverage, essence, dyestuff, fuel etc. are manufactured with ethyl alcohol.The ethyl alcohol that volume fraction is 70%~75% is medically also commonly used to make Disinfectant etc. all has been widely used in national defence chemical industry, health care, food industry, industrial and agricultural production.

Sodium carboxymethylcellulose

Sodium carboxymethylcellulose of the present invention, (also known as: sanlose, carboxymethyl cellulose, CMC- Na, CMC, Carboxymethyl, Cellulose Sodium, Sodium salt of Caboxy Methyl Cellulose) It is that use scope is most wide in the world today, the maximum cellulose type of dosage, is the fiber that glucose polymerization degree is 100~2000 Plain derivative, relative molecular mass 242.16.White fibrous or particulate powder.It is odorless, have hygroscopicity, be dissolved in water, it is insoluble In ethyl alcohol, ether and trimerization methane.Have the effects that bonding, thickening, enhancing, emulsification, water conservation, suspension.

CMC is not only good emulsion stabilizer, thickener in food applications, and freezes, melts with excellent Stability, and the flavor of product can be improved, extend storage time.In soymilk, ice cream, ice cream, jelly, beverage, can Dosage is about 1%~1.5%.CMC can also be with the stable cream of forming properties such as vinegar, soy sauce, vegetable oil, fruit juice, gravy, vegetable juice Change dispersion liquid, dosage is 0.2%~0.5%.Especially to the emulsifiability of animal oil, vegetable oil, protein and aqueous solution It is extremely excellent, the stable homogeneous emulsion of performance can be formed it into.

In a preferred embodiment, sodium carboxymethylcellulose of the present invention is food-grade carboxymethyl cellulose Sodium.

In a kind of preferred embodiment, food level sodium carboxymethylcellulose of the present invention can be by commercially available It obtains, such as the food level sodium carboxymethylcellulose being available commercially includes but is not limited to buy from the happy chemical products of Henan China to have Limit company, model FH9 product.

In a preferred embodiment, the weight of lauric monoglyceride and sodium carboxymethylcellulose of the present invention Amount is than being (2~15): 1.

In a kind of preferred embodiment, lauric monoglyceride and sodium carboxymethylcellulose of the present invention Weight ratio is 8:1.

Defoaming agent

Defoaming agent of the present invention, also referred to as defomaing agent are that surface tension is reduced in food processing process, inhibit foam Generate or eliminate the food additives for having generated foam.China, which is permitted workable defoaming agent, silicone emulsion, high-carbon polyol fatty acid Ester complexes, polyoxyethylene polyoxypropylene pentaerythrite ether, polyoxyethylene polyoxy propyl alcohol amidogen ether, polypropylene glycerol aether and polyoxy 7 kinds of propylene polyoxyethylene glycerol ether, dimethyl silicone polymer etc..

In a preferred embodiment, defoaming agent of the present invention can be commercially available, such as commercially available Obtained defoaming agent includes but is not limited to buy from the safe and sound Fine Chemical Co., Ltd of Dongguan City, the product of model MT-30.

Glycerol

Glycerol of the present invention, also known as Glycerin, glycerine, colourless, odorless, sweet, appearance is in clear and bright glutinous Magma state is a kind of organic matter.And triol can absorb hydrogen sulfide, hydrogen cyanide, sulfur dioxide, and it can be miscible with water, ethyl alcohol, 1 part The product can be dissolved in 11 parts of ethyl acetate, about 500 parts of ether, not dissolve in benzene, carbon disulfide, chloroform, carbon tetrachloride, petroleum Ether, chloroform, oils.It is easily dehydrated, dehydration generates diglycerol and polyglycereol etc..Oxidation generates glyceraldehyde and glyceric acid etc..At 0 DEG C Lower solidification, is formed with the oblique square crystal of flash of light.At 150 DEG C of temperature or so, it may occur that polymerization.With acetic anhydride acid anhydride, permanganic acid Potassium, strong acid, corrosive agent, fatty amine, isocyanates, oxidant are unable to compatibility.

1,2- propylene glycol

1,2-PD of the present invention, also known as Propylene Glycol, 2- propylene glycol, propylene glycol, 1,2- dihydroxypropane, α-propylene glycol is a kind of chemical reagent, with water, ethyl alcohol and a variety of immiscible organic solvents.It is colourless viscous liquid under normality, almost It is tasteless, thin Wen Weitian.Propylene glycol can be used as the raw material of unsaturated polyester resin, can be with glycerol in cosmetics, toothpaste and perfumed soap Or sorbierite cooperation is used as wetting agent.It is used as damping, even hair agent in hair dye, also serves as antifreezing agent, is also used to glassine paper, increases Mould agent and pharmaceuticals industry.

In a preferred embodiment, the weight ratio of 1,2-PD and glycerol of the present invention is (1~10): 1。

In a kind of preferred embodiment, the weight ratio of 1,2-PD and glycerol of the present invention is 5:1.

In a preferred embodiment, the weight ratio of glycerol and sodium carboxymethylcellulose of the present invention be (7~ 13): 1.

In a kind of preferred embodiment, the weight ratio of glycerol and sodium carboxymethylcellulose of the present invention is 10:1.

The second aspect of the present invention provides a kind of preparation method of the calcium-supplementing nutritive liquid of animal, includes at least following step It is rapid:

(1) vacuum homogeneous emulsifying machine is added in the first parts by weight water, calcium source, lactose, amino acid, L-AA and sucrose Kettle in, be stirred 5~15min；

(2) sodium carboxymethylcellulose is added in the second parts by weight water and impregnates 12~36h；

(3) vacuum homogeneous emulsifying machine is added in step (2) obtained material and third parts by weight water, glycerol, 1,2- propylene glycol Oil cauldron in, after mixing 5~10min, bacteriostatic agent, yoghurt flavours, citric acid, potassium chloride, ethyl alcohol and defoaming agent is added, stirring is mixed Close 5~15min；

(4) by the material of oil cauldron and kettle be added emulsion tank in, emulsifying to get.

The process of step (4) described emulsifying are as follows: open stirring system stirring, stop stirring after 2~15min；It opens Homogenizer homogeneous stops homogenizer work after 3~12min；Stirring is opened, after stirring 2~15min, opens homogenizer homogeneous 0.2 ~0.8min stops homogeneous stirring；Only 5~15min is stirred with raker stirrer with the revolving speed of 30~80r/min to stop.

In a preferred embodiment, the weight ratio of the first, second, and third parts by weight water of the present invention is (4~6): 1:(1~3).

In a kind of preferred embodiment, the weight ratio of the first, second, and third parts by weight water of the present invention For 5:1:2.

Since sodium carboxymethylcellulose (CMC) is a kind of important ionic cellulose element derivative, have in the food industry It is widely applied.The aqueous solution of CMC has pseudoplastic behavior, and effect of the CMC of Different structural parameters for stable emulsion is different, works as addition CMC concentration it is too low when, latex particle easily occurs bridge flocculation and makes system unstability, and the CMC of higher concentration can just make system become In stabilization.

However, inventor is it was unexpectedly observed that when control lauric monoglyceride and sodium carboxymethylcellulose in the application Weight ratio is (2~15): 1, the weight ratio of 1,2-PD and glycerol is (1~10): and 1, glycerol and sodium carboxymethylcellulose Weight ratio is (7~13): 1, and sodium carboxymethylcellulose be can be improved into lotion when using 12~36h of preceding abundant immersion Centrifugal stability and low-temperature stability.It may be since inventor uses special technique in the application, in specific scale bar Under part, made between lauric monoglyceride, sodium carboxymethylcellulose, 1,2-PD and glycerol by mutually cooperateing with and combining With saltouing, permeate in system, diluting, assembling and a variety of effects such as solubilising, interfacial film and liquid crystalline phase is promoted to change Become, to be conducive to the formation of emulsion system；After CMC dosage is appropriate and by sufficiently swelling, be conducive to it in system Flowing, and then improve interface film strength so that emulsion intercalation method improve, and when CMC dosage increase when, CMC can be reduced Fluid ability in system, so that emulsion intercalation method declines.

The present invention is specifically described below by embodiment, in addition, if without other explanations, it is raw materials used to be all It is commercially available.