阅读说明：本技术 一种珐琅彩瓷装饰用宝石粘结剂及其应用方法 (A kind of enamel ceramics decoration jewel adhesive and application method thereof ) 是由 曹红燕 于 2019-09-20 设计创作，主要内容包括：本发明涉及一种珐琅彩瓷装饰用宝石粘结剂及其应用方法,所述粘结剂的重量百分比组成为：钾长石35～40%、方解石15～20%、苏州土5～10%、石英25～30%、滑石5～10%、霞石粉5～10%、透明熔块0～6%,外加石英纤维5%,经配料、球磨、过筛、添加石英纤维并搅拌均匀获得宝石粘结剂。本发明通过在瓷胎表面利用粘结剂对宝石进行固定,不仅创新出传统珐琅彩与宝石相互结合的装饰方式,极大的提升了传统珐琅彩的装饰效果,因此具有广阔的市场空间。(The present invention relates to a kind of enamel ceramics decoration jewel adhesive and application method thereof, the weight percent of the binder forms are as follows: potassium feldspar 35~40%, calcite 15~20%, Suzhou soil 5~10%, quartzy 25~30%, talcum 5~10%, nepheline powder 5~10%, clear frit 0~6%, additional quartz fibre 5% through ingredient, ball milling, sieving, addition quartz fibre and stirs evenly acquisition jewel binder.The present invention is not only created the decorating method that traditional colour enamels and jewel be combined with each other, is greatly improved the decorative effect of traditional colour enamels, therefore have a vast market space by the way that jewel is fixed using binder on porcelain body surface.)

1. a kind of enamel ceramics decoration jewel binder, it is characterised in that: the weight percent of the binder forms are as follows: potassium Feldspar 35~40%, calcite 15~20%, Suzhou soil 5~10%, quartz 25~30%, talcum 5~10%, nepheline powder 5~10%, thoroughly Bright frit 0~6%, additional quartz fibre 5% through ingredient, ball milling, sieving, add quartz fibre and stir evenly acquisition jewel and glue Tie agent.

2. jewel binder according to claim 1, it is characterised in that: the weight percent composition of the clear frit is excellent It is selected as 3~6%；Sieving process are as follows: cross 380 meshes, tailing over is 0.

3. jewel binder according to claim 1, it is characterised in that: the clear frit is by clear frit A and transparent Frit B is that 0~100:0~100 mix by weight percentage.

4. jewel binder according to claim 3, it is characterised in that: the chemical composition percentage of the clear frit A Are as follows: SiO₂ 34%、B₂O₃ 12%、Al₂O₃ 13%、Li₂O 12%, MgO 15%, ZnO 14% through ingredient, grinding, high temperature melting, quench Cold, ball milling, sieving process obtain clear frit A.

5. jewel binder according to claim 4, it is characterised in that: the parameter of the high temperature melting process are as follows: heating Rate is 5 DEG C/min, and highest glass melting temperature is 1200 DEG C, soaking time 30min；The sieving process are as follows: 380 meshes are crossed, Tail over is 0.

6. jewel binder according to claim 3, it is characterised in that: the chemical composition percentage of the clear frit B Are as follows: SiO₂ 26%、B₂O₃ 28%、Al₂O₃ 28%、Na₂O 7%、CaO 8%、ZrO₂3%, through ingredient, grinding, high temperature melting, quench Cold, ball milling, sieving process obtain clear frit B.

7. jewel binder according to claim 6, it is characterised in that: the parameter of the high temperature melting process are as follows: heating Rate is 5 DEG C/min, and highest glass melting temperature is 1300 DEG C, soaking time 30min；The sieving process are as follows: 380 meshes are crossed, Tail over is 0.

8. the application method of jewel binder according to claim 1, it is characterised in that according to following steps:

(1) the excellent porcelain body fired through 1260~1320 DEG C is chosen, the porcelain body includes carcass and glaze layer；

(2) decoration position of the jewel on enamel ceramics is pressed, machinery is carried out on porcelain body surface and gets into the cave, the depth of hole is that porcelain body is thick 2/3rds of degree；

(3) colour enamels pattern decorative is carried out on porcelain body surface；

(4) jewel binder and water and guar gum are uniformly packed into hole step (2) bored by weight 85:10:5 mix afterwards It is interior, and jewel bottom is mounted in hole；

(5) it will decorate through colour enamels and be mounted with that the porcelain body of jewel enters kiln, fired in 1000~1100 DEG C, after kiln discharge

It obtains the colour enamels with jewel and decorates porcelain body.

9. the application method of jewel binder according to claim 8, it is characterised in that: jewel bonds in the step (4) The amount that agent and water and guar gum are packed into hole is the one third of hole volume.

10. the application method of jewel binder according to claim 8, it is characterised in that: the step (3) is on porcelain body surface The mode for carrying out colour enamels pattern decorative is Freehandhand-drawing or decal paper.

Technical field

The present invention relates to ceramic technology fields, especially a kind of enamel ceramics decoration jewel binder and its application side Method.

Background technique

Have a long history, referred to as " faience queen ", " government porcelain kiln in government porcelain kiln " enamel ceramics, be to be developed by cloisonne enamel , cloisonne enamel is to form in copper tire enamelling glaze, and enamel ceramics are then fired in porcelain body enamelling glaze, so enamel Thinkling sound's faience is also known as " enamel painting on porcelain ", although colour enamels has, porcelain is fine and smooth, color material is dignified, lovely luster is beautiful, painter is exquisite The features such as, however traditional colour enamels decoration technique has been unable to meet the pursuit that people live to high-quality.

Summary of the invention

The technical problem to be solved in the present invention is to provide a kind of firm, low in cost, health environment-friendly enamel ceramics of bonding Decoration jewel adhesive and application method thereof.

The technical scheme is that a kind of enamel ceramics decoration jewel binder, it is characterised in that: the binder Weight percent composition are as follows: potassium feldspar 35~40%, calcite 15~20%, Suzhou soil 5~10%, quartzy 25~30%, talcum 5~10%, nepheline powder 5~10%, clear frit 0~6%, additional quartz fibre 5% are fine through ingredient, ball milling, sieving, addition quartz It ties up and stirs evenly and obtain jewel binder.

The weight percent composition preferably 3~6% of the clear frit；Sieving process are as follows: cross 380 meshes, tailing over is 0.

The clear frit by clear frit A and clear frit B be by weight percentage 0~100:0~100 mixing and At.

The chemical composition percentage of the clear frit A are as follows: SiO₂ 34%、B₂O₃ 12%、Al₂O₃ 13%、Li₂O 12%、 MgO 15%, ZnO 14% obtain clear frit A through ingredient, grinding, high temperature melting, quenching, ball milling, sieving process.

The parameter of the high temperature melting process are as follows: heating rate is 5 DEG C/min, and highest glass melting temperature is 1200 DEG C, heat preservation Time is 30min；The sieving process are as follows: cross 380 meshes, tailing over is 0.

The chemical composition percentage of the clear frit B are as follows: SiO₂ 26%、B₂O₃ 28%、Al₂O₃ 28%、Na₂O 7%、CaO 8%、ZrO₂3%, clear frit B is obtained through ingredient, grinding, high temperature melting, quenching, ball milling, sieving process.

The parameter of the high temperature melting process are as follows: heating rate is 5 DEG C/min, and highest glass melting temperature is 1300 DEG C, heat preservation Time is 30min；The sieving process are as follows: cross 380 meshes, tailing over is 0.

The application method of the jewel binder, it is characterised in that according to following steps:

(1) the excellent porcelain body fired through 1260~1320 DEG C is chosen, the porcelain body includes carcass and glaze layer；

(2) decoration position of the jewel on enamel ceramics is pressed, machinery is carried out on porcelain body surface and gets into the cave, the depth in hole is porcelain body thickness 2/3rds；

(3) colour enamels pattern decorative is carried out on porcelain body surface；

(4) jewel binder and water and guar gum are uniformly packed into hole step (2) bored by weight 85:10:5 mix afterwards It is interior, and jewel bottom is mounted in hole；

(5) it will decorate through colour enamels and be mounted with that the porcelain body of jewel enters kiln, fired in 1000~1100 DEG C, it is precious that band is obtained after kiln discharge The colour enamels of stone decorates porcelain body.

Jewel binder and water and guar gum are packed into that the amount of hole is hole volume in the step (4) three/ One.

The step (3) is Freehandhand-drawing or decal paper in the mode that porcelain body surface carries out colour enamels pattern decorative.

The formulation thinking of enamel ceramics decoration jewel binder formula of the present invention and technique: binder is mainly solved The problem of bonding stability and binder of jewel and the coefficient of expansion of jewel, porcelain body carcass and porcelain body glaze layer are mutually matched.

First, for the adhesive property for improving binder, the present invention uses trivalent and divalent in material formula Oxide and boride cooperate and use quartz fibre in material formula, and to the particle of material in preparation process Fineness, firing temperature have carried out the mode of strict control, its material particles is made to can be good at cooperating with quartz fibre, right Jewel bottom surface carries out bonding wrapped, ensure that the firm bonding of binder and jewel；

Second, to be applicable in thermal expansion coefficient different between binder and various jewels, porcelain body carcass and porcelain body glaze layer, the present invention Composite transparent frit is used in material formula, by adjusting the different ratio of clear frit A and clear frit B, is realized Adjusting to binder thermal expansion coefficient, while the present invention also especially has adjusted Al in binder₂O₃、SiO₂、MgO、CaO、 Ka₂The content of O improves the elasticity of binder, ensure that binder and the perfect of jewel bond；

Third, to improve the stability that position at porcelain body surface initial stage of jewel, the present invention in binder application outside added Guar Bean gum fixes the position progress initial stage of jewel, ensure that jewel in porcelain by guar gum and the mixed adhesive property of water Positioning on tire.

The decoration technique of horn of plenty enamel ceramics of the present invention creates the decoration side that traditional colour enamels and jewel be combined with each other Formula, and the good adhesive property of this jewel binder is utilized, realize fixation of the jewel on various different shaping porcelain bodies surface, pole It is big to improve the decorative effect of traditional colour enamels, and the raw materials used major part of jewel binder be natural mineral raw not only Abundance is cheap, and without any side effects to human body, therefore has a vast market space.

Specific embodiment

For further illustrate the present invention, to reach the technical means and efficacy that predetermined goal of the invention is taken, tie below Preferred embodiment is closed, the present invention is described in detail: