阅读说明：本技术 一种铅网板栅在涂板线的在线预处理方法 (Online pretreatment method for lead mesh grid on-coating line ) 是由 韩祖孟 陈含 于 2021-07-26 设计创作，主要内容包括：本发明涉及一种铅网板栅在涂板线的在线预处理方法,所述铅网板栅的预处理方法包括喷助焊剂、在线吹干、喷焊料和铅线表面焊料保护共四个步骤,第一道预处理方法为喷淋助焊剂,即采用耐酸泵把助焊剂对准在涂板线上运行的铅网中心间隙进行喷淋,控制适当的流量和喷淋宽度,保证都喷在铅网的中心间隙内,以去除去铅网中心间隙铅线的表面氧化物。该铅网板栅在涂板线的在线预处理方法,由于采用涂板线在线中心间隙预处理方法,铅线玻璃纤维内芯无法吸到助焊剂,同时能及时风干,不会出现现水平电池铸焊前预处理方法中常出现的虚焊、铸焊模具腐蚀和无法脱模等现象,因此能大大提高产品质量,减少设备模具损耗,并且降低工人的劳动强度。(The invention relates to an on-line pretreatment method of a lead mesh grid on a plate coating line, which comprises four steps of spraying soldering flux, on-line drying, spraying solder and lead line surface solder protection, wherein the first pretreatment method is spraying the soldering flux, namely, an acid-proof pump is adopted to aim the soldering flux at the central gap of the lead mesh running on the plate coating line for spraying, and the proper flow and spraying width are controlled to ensure that the soldering flux is sprayed in the central gap of the lead mesh so as to remove surface oxides of the lead line in the central gap of the lead mesh. According to the online pretreatment method of the lead mesh grid on the plate coating line, due to the adoption of the online central gap pretreatment method of the plate coating line, the inner core of the lead wire glass fiber cannot absorb soldering flux, and meanwhile, the lead wire glass fiber can be dried in time, so that the phenomena of insufficient soldering, cast-weld mold corrosion, incapability of demolding and the like which are commonly generated in the pretreatment method before cast-weld of the existing horizontal battery can be avoided, the product quality can be greatly improved, the equipment mold loss can be reduced, and the labor intensity of workers can be reduced.)

1. The on-line pretreatment method of the lead mesh grid on the plate coating line comprises the lead mesh grid (7), external connection end lines (1) of a positive terminal plate and a negative terminal plate, a bipolar polar plate (2), the lead mesh polar plate (21), a positive single polar plate (3), a lead mesh positive plate terminal line (31), a negative single polar plate (4), a lead mesh negative plate terminal line (41), an external terminal (5) and a busbar (6), and is characterized in that: the pretreatment method of the lead mesh grid (7) comprises four steps of spraying soldering flux, drying in an online mode, spraying solder and protecting the solder on the surface of a lead wire;

1) the first pretreatment method is spraying the soldering flux, namely, the soldering flux is aligned to the central gap of the lead screen running on the board coating line by adopting an acid-resistant pump to spray, and the proper flow and the spraying width are controlled to ensure that the soldering flux is sprayed in the central gap of the lead screen so as to remove the surface oxide of the lead line in the central gap of the lead screen;

2) the second pretreatment method is online blow-drying, wherein multiple heads of continuously compressed air are adopted, multi-step blow-drying is carried out on the lead wire in the central gap of the lead screen in an aligning manner, so that residual soldering flux and oxides on the surface of the lead wire in the central gap of the lead screen are blown off, and the blown residual soldering flux is naturally guided back to the soldering flux storage barrel;

3) the third pretreatment method is spraying solder, heating the solder to a certain temperature to melt the solder and ensure certain fluidity, adopting a motor to spray the solder aiming at the central gap of the lead screen running on the board coating line, controlling proper flow and width of the sprayed solder to ensure that the solder is sprayed in the central gap and firmly combined with the lead line of the central gap of the lead screen;

4) the fourth pretreatment method is surface solder protection of the lead wire in the center gap, paraffin is heated to a certain temperature to be melted and ensure certain fluidity, the paraffin is sprayed by a motor aiming at the center gap of the lead net running on the plate coating line, proper flow and spraying width are controlled to ensure that the paraffin is sprayed in the center gap and the paraffin covers the surface of the solder, so that the sprayed solder can not be oxidized in the processes of pole plate solidification and the like in the post-process production.

2. The on-line pretreatment method of the lead mesh grid on the coating line according to claim 1, characterized by comprising the following steps: the lead mesh grid (7) is formed by adopting a solid-state extrusion process to coat lead with glass fiber to form lead wires, and then weaving a mesh to form the continuous lead mesh grid (7).

3. The on-line pretreatment method of the lead mesh grid on the coating line according to claim 1, characterized by comprising the following steps: when the bipolar polar plate (2) made of the lead mesh grid (7) is used as a terminal polar plate, a lead wire with a gap in the center of the lead mesh grid (7) is required to be used as an external connection end wire (1) of a positive and negative terminal polar plate, and the external terminal (5) is cast-welded together through the bus bar (6).

4. The on-line pretreatment method of the lead mesh grid on the coating line according to claim 1, characterized by comprising the following steps: the bipolar plate (2) is characterized in that a positive active substance is coated on one half of a lead mesh grid (7) to serve as a positive single-pole plate (3), and a negative active substance is coated on the other half of the lead mesh grid (7) to serve as a negative single-pole plate (4).

5. The on-line pretreatment method of the lead mesh grid on the coating line according to claim 1, characterized by comprising the following steps: certain gaps are left between the positive and negative active materials of the bipolar plate (2) and are not coated with active materials, so that the active materials are used for wire connection between unit cells or used as external connecting end wires (1) of positive and negative terminal plates.

6. The on-line pretreatment method of the lead mesh grid on the coating line according to claim 1, characterized by comprising the following steps: when the bipolar plate (2) needs to be used as an external connection terminal, the bipolar plate needs to be cut from the central gap of the bipolar plate (2) to be used as a positive single-pole plate (3) and a negative single-pole plate (4), and after a battery core is assembled, the external connection terminal (1) of the positive terminal plate and the external terminal (5) need to be cast-welded together through a bus bar (6) to be used as external connection.

7. The on-line pretreatment method of the lead mesh grid on the coating line according to claim 1, characterized by comprising the following steps: when the external connecting end line (1) of the positive and negative terminal polar plates and the external terminal (5) are cast-welded through the busbar (6), the terminal line in the gap between the positive and negative lead mesh grids (7) needs to be pretreated so as to ensure the firm cast-welding.

8. The on-line pretreatment method of the lead mesh grid on the coating line according to claim 1, characterized by comprising the following steps: the online pretreatment method of the plate coating line is characterized in that in the plate coating process of the continuous lead mesh grid (7), before the positive and negative lead mesh grids (7) are coated with paste, the online pretreatment is firstly carried out on the lead wire in the central gap of the positive and negative lead mesh grids (7), but not before the cast-weld process.

9. The on-line pretreatment method of the lead mesh grid on the coating line according to claim 1, characterized by comprising the following steps: the soldering flux is a mixture of phosphoric acid and alcohol in a certain proportion.

10. The on-line pretreatment method of the lead mesh grid on the coating line according to claim 1, characterized by comprising the following steps: the solder is lead-tin alloy with a certain proportion.

Technical Field

The invention relates to the technical field of lead mesh grids, in particular to an online pretreatment method for a lead mesh grid on a plate coating line.

Background

The lead net grid is the main component of lead-acid accumulator, and is the current collecting skeleton of electrode, which plays the role of conducting, collecting current and making the current distribute uniformly, and at the same time, it plays the role of supporting active material, and is the carrier of active material.

When the horizontal bipolar battery lead mesh grid is used as a terminal plate, lead wires in a central gap area of the lead mesh grid, which is not coated with active substances, are seriously oxidized after the lead mesh grid is subjected to normal processes of coating, pickling, curing, drying and the like, and if the lead wires in the central gap area are not subjected to oxidation layer removal treatment, the terminal wires, external terminals and busbars are frequently subjected to false welding to seriously affect the quality of the battery, the conventional pretreatment method before welding of the horizontal battery basically adopts a method that the whole battery terminal wire group is dipped with soldering flux together after the battery is assembled, and then is dried by wind and then is welded with the external terminals and the busbars, but the method needs the whole battery terminal wire group to be dipped with the soldering flux together for treatment, glass fiber cores of the lead wires can directly absorb the soldering flux, and the soldering flux has certain corrosivity, so that a certain amount of the soldering flux is still absorbed in the lead mesh wire core after the surface is dried by the wind, when the cast-weld is carried out with the external terminal and the busbar, small explosions are formed around the lead wire due to the fact that high temperature meets liquid, virtual welding holes are formed around the lead wire, the cast-weld quality of the battery is seriously affected, in addition, the residual soldering flux liquid can damage a cast-weld mold due to the fact that the soldering flux is corrosive liquid, the cast-weld demolding difficulty can be caused due to the residual soldering flux liquid, the cast-weld lead wire of the battery is easily separated from the busbar or the mold is damaged, the battery quality is affected, and the cast-weld production cost is improved.

Disclosure of Invention

Aiming at the defects of the prior art, the invention provides an online pretreatment method of a lead wire grid on a coating line, which has the advantages of reducing the loss of equipment molds and the like, and solves the problems that the whole battery terminal line cluster is dipped with soldering flux together, the glass fiber core of the lead wire can directly absorb the soldering flux, and the soldering flux has certain corrosivity, so that after the surface is dried, a certain amount of the soldering flux is still absorbed in the lead wire core of the lead wire grid, when the lead wire is cast-welded with an external terminal and a busbar, small explosion is formed around the lead wire due to high temperature liquid, virtual welding holes are formed around the lead wire, the cast-welding quality of the battery is seriously influenced, the residual soldering flux is corrosive liquid, the cast-welding mold is damaged by the residual soldering flux, the cast-welding demolding is difficult due to the residual soldering flux, and the cast-welding lead wire of the battery is easy to separate from the busbar or damage the mold, the quality of the battery is affected and the cast-weld production cost is increased.

In order to achieve the purpose, the invention provides the following technical scheme: an online pretreatment method of a lead mesh grid on a plate coating line comprises the steps of spraying soldering flux, drying by blowing on line, spraying welding flux and protecting the surface welding flux of lead wires, wherein the lead mesh grid comprises external connection end lines of a lead mesh grid, positive and negative terminal plates, a bipolar plate, a lead mesh plate, a positive single-pole plate, a lead mesh positive plate terminal line, a negative single-pole plate, a lead mesh negative plate terminal line, an external terminal and a busbar;

1) the first pretreatment method is spraying the soldering flux, namely, the soldering flux is aligned to the central gap of the lead screen running on the board coating line by adopting an acid-resistant pump to spray, and the proper flow and the spraying width are controlled to ensure that the soldering flux is sprayed in the central gap of the lead screen so as to remove the surface oxide of the lead line in the central gap of the lead screen;

2) the second pretreatment method is online blow-drying, wherein multiple heads of continuously compressed air are adopted, multi-step blow-drying is carried out on the lead wire in the central gap of the lead screen in an aligning manner, so that residual soldering flux and oxides on the surface of the lead wire in the central gap of the lead screen are blown off, and the blown residual soldering flux is naturally guided back to the soldering flux storage barrel;

3) the third pretreatment method is spraying solder, heating the solder to a certain temperature to melt the solder and ensure certain fluidity, adopting a motor to spray the solder aiming at the central gap of the lead screen running on the board coating line, controlling proper flow and width of the sprayed solder to ensure that the solder is sprayed in the central gap and firmly combined with the lead line of the central gap of the lead screen;

4) the fourth pretreatment method is surface solder protection of the lead wire in the center gap, paraffin is heated to a certain temperature to be melted and ensure certain fluidity, the paraffin is sprayed by a motor aiming at the center gap of the lead net running on the plate coating line, proper flow and spraying width are controlled to ensure that the paraffin is sprayed in the center gap and the paraffin covers the surface of the solder, so that the sprayed solder can not be oxidized in the processes of pole plate solidification and the like in the post-process production.

Further, the lead mesh grid is manufactured by adopting a solid-state extrusion process to coat lead with glass fiber to prepare lead wires and then weaving the lead wires into a continuous lead mesh grid.

Further, when the bipolar plate made of the lead mesh grid is used as a terminal plate, a lead wire in a gap between centers of the lead mesh grid is required to be used as an external connection end wire of the positive and negative terminal plates, and the lead wire and an external terminal are cast-welded together through a bus bar.

Furthermore, the bipolar plate is formed by coating a positive active substance on one half of a lead mesh grid to serve as a positive unipolar plate, and coating a negative active substance on the other half of the lead mesh grid to serve as a negative unipolar plate.

Furthermore, a certain gap is left between the positive and negative active materials of the bipolar plate and is not coated with the active materials, so that the active materials are used for wire connection between unit cells or used as external connection end wires of the positive and negative terminal plates.

Furthermore, when the bipolar plate is used as an external connection terminal, the bipolar plate needs to be cut from the central gap of the bipolar plate to be used as a positive single-pole plate and a negative single-pole plate, and after the battery core is assembled, the external connection terminal of the positive terminal plate and the external terminal need to be cast-welded together through a bus bar to be used as external connection.

Furthermore, when the external connection end wire of the positive and negative terminal plates and the external terminal are subjected to cast welding through the busbar, the terminal wire in the gap between the positive and negative lead grid center needs to be pretreated so as to ensure firm cast welding.

Further, the online pretreatment method of the plate coating line is that the online pretreatment is firstly carried out on the lead wire in the center gap of the positive and negative lead mesh plate grids before the paste is coated on the positive and negative lead mesh plate grids in the plate coating process of the continuous lead mesh plate grids, but not before the cast welding process.

Furthermore, the soldering flux is a mixture of phosphoric acid and alcohol in a certain proportion.

Further, the solder is lead-tin alloy with a certain proportion.

Compared with the prior art, the technical scheme of the application has the following beneficial effects:

1. according to the online pretreatment method of the lead mesh grid on the plate coating line, the lead mesh grid plate coating line can greatly improve the product quality, reduce the equipment mould loss, simultaneously improve the terminal cast-weld efficiency by more than five times compared with the original horizontal battery pretreatment method, and greatly reduce the labor intensity of workers through four steps of spraying the soldering flux, drying on line, spraying the solder and the solder on the surface of the lead wire.

2. According to the online pretreatment method of the lead mesh grid on the plate coating line, due to the adoption of the online central gap pretreatment method of the plate coating line, the inner core of the lead wire glass fiber cannot absorb soldering flux, and meanwhile, the lead wire glass fiber can be dried in time, so that the phenomena of insufficient soldering, cast-weld mold corrosion, incapability of demolding and the like which are commonly generated in the pretreatment method before cast-weld of the existing horizontal battery can be avoided, the product quality can be greatly improved, the equipment mold loss can be reduced, the labor intensity of workers can be reduced, and the cost can be reduced.

Drawings

Fig. 1 is a diagram of a lead mesh grid pre-treatment location according to an embodiment of the present application;

fig. 2 is a diagram illustrating an active material coating position of a lead mesh grid according to an embodiment of the present application;

FIG. 3 is a diagram of a bipolar plate according to an embodiment of the present application;

FIG. 4 is a diagram of a positive terminal plate according to an embodiment of the present application;

FIG. 5 is a diagram of a negative terminal plate according to an embodiment of the present application;

FIG. 6 is a diagram of a battery assembly according to an embodiment of the present application;

fig. 7 is a diagram illustrating the effect of cast-on-welding of a battery according to an embodiment of the present application.

In the figure: the lead-free battery comprises 1 external connecting end line of positive and negative terminal polar plates, 2 bipolar polar plates, 21 lead net polar plates, 3 positive single polar plates, 31 lead net positive polar plate terminal lines, 4 negative single polar plates, 41 lead net negative polar plate terminal lines, 5 external terminals, 6 busbars and 7 lead net grids.

Detailed Description

The technical solutions in the embodiments of the present invention will be clearly and completely described below with reference to the drawings in the embodiments of the present invention, and it is obvious that the described embodiments are only a part of the embodiments of the present invention, and not all of the embodiments. All other embodiments, which can be derived by a person skilled in the art from the embodiments given herein without making any creative effort, shall fall within the protection scope of the present invention.

Referring to fig. 1-7, in the embodiment, an on-line pretreatment method of a lead mesh grid in a plate coating line is shown, in which the on-line pretreatment of the plate coating line is performed at a pretreatment position of the lead mesh grid 7 by using the technology, and the grid is a bipolar continuous grid, which will be described in detail below.

An online pretreatment method of a lead mesh grid 7 on a coating line comprises the lead mesh grid 7, external connection end lines 1 of positive and negative terminal polar plates, a bipolar polar plate 2, a positive single polar plate 3, a lead mesh positive polar plate terminal line 31, a negative single polar plate 4, a lead mesh negative polar plate terminal line 41, an external terminal 5 and a busbar 6, wherein the pretreatment method of the lead mesh grid 7 comprises four steps of spraying soldering flux, drying by blowing on line, spraying solder and protecting the surface solder of the lead wire;

1) the method comprises the steps that the lead wires at the position of the lead mesh grid 7 central gap pretreatment position are pretreated on a coating line on line, the first pretreatment method is to spray soldering flux, namely, an acid-proof pump is adopted to align the soldering flux to the lead mesh central gap running on the coating line for spraying, the proper flow and spraying width are controlled, the soldering flux is guaranteed to be sprayed in the lead mesh central gap, so that surface oxides of the lead wires in the lead mesh central gap are removed, and the soldering flux is a mixture of phosphoric acid and alcohol in a certain proportion;

2) the method for pretreating the pretreatment position by running the lead screen to the second procedure is online blow-drying, multiple heads are adopted to continuously compress air side by side and aim at the lead line in the central gap of the lead screen to carry out multi-step blow-drying so as to blow off residual soldering flux and oxides on the surface of the lead line in the central gap of the lead screen, and the blown residual soldering flux is naturally guided back to the soldering flux storage barrel;

3) the method for pretreating the pretreatment position by the lead screen running to the third process is to spray solder, heat the solder to a certain temperature to melt the solder and ensure certain fluidity, adopt a motor to spray the solder aiming at the lead screen center gap running on the coating line, control proper flow and solder spraying width, ensure that the solder is sprayed in the center gap, so that the solder is firmly combined with the lead screen center gap lead line, and the solder is lead-tin alloy with a certain proportion;

4) the method for pretreating the pretreatment position by the lead net running to the fourth process is characterized in that solder on the surface of a lead wire in a center gap is protected, paraffin is heated to a certain temperature to be melted and ensure certain fluidity, the paraffin is sprayed by a motor aiming at the center gap of the lead net running on a plate coating line, appropriate flow and spraying width are controlled, the paraffin is guaranteed to be sprayed in the center gap, the surface of the solder is wrapped by the paraffin, and the sprayed solder is prevented from being oxidized in the processes of pole plate solidification and the like in the post-process production.

In the invention, the lead mesh grid 7 is made by adopting a solid extrusion process to coat glass fiber with lead to form lead wires, and then weaving the lead wires into a continuous lead mesh grid 7.

In the invention, when the bipolar plate 2 made of the lead mesh grid 7 is used as a terminal plate, a lead wire in the central gap of the lead mesh grid 7 is required to be used as an external connecting end wire 1 of a positive and negative terminal plate, and the external connecting end wire 1 and an external terminal 5 are cast and welded together through a bus 6.

In the invention, the bipolar plate 2 is formed by coating a positive active substance on one half of a lead mesh grid 7 to be used as a positive unipolar plate 3, and a negative active substance on the other half of the lead mesh grid 7 to be used as a negative unipolar plate 4.

In the present invention, a certain gap is left between the positive and negative active materials of the bipolar plate 2 without coating active materials for wire connection between cells or as the external connection terminal wire 1 of the positive and negative terminal plates.

In the invention, when the bipolar plate 2 is used as an external connection terminal, the bipolar plate 2 is cut from the central gap of the bipolar plate 2 to be used as a positive single-pole plate 3 and a negative single-pole plate 4, and after a battery core is assembled, the external connection terminal 1 of the positive terminal plate and the external terminal 5 are cast-welded together through the bus bar 6 to be used as external connection.

In the invention, when the external connecting end lines 1 of the positive and negative terminal polar plates and the external terminal 5 are cast-welded by the bus bar 6, the terminal lines in the gap between the positive and negative lead mesh grids 7 need to be pretreated so as to ensure the firm cast-welding.

In the invention, the online pretreatment method of the plate coating line is that the central gap lead wire of the positive and negative lead mesh grids 7 is pretreated online before the paste is coated on the positive and negative lead mesh grids 7 in the plate coating process of the continuous lead mesh grids 7, but not before the cast-weld process.

In the invention, the soldering flux is a mixture of phosphoric acid and alcohol in a certain proportion.

In the invention, the solder is lead-tin alloy with a certain proportion.

Referring to fig. 1, the external connection terminal line 1 of the positive and negative terminal plates at the preprocessing position is a lead line of the central gap of a lead mesh grid 7, and when the battery is assembled, the external connection terminal line is cut from the middle position of the central gap and cast-welded together with an external terminal 5 through a bus bar 6, and the position needs to be preprocessed online.

The bipolar plate 2 is the width of the lead net, the positive monopolar plate 3 of the lead net is a positive active material coated area and is used as a positive plate, and the negative monopolar plate 4 of the lead net is a negative active material coated area and is used as a negative plate.

Referring to fig. 1 and 2, after the lead mesh pretreatment is completed, a modern automatic plate coating machine is used to coat the lead mesh to obtain a bipolar plate 2, a positive active material is coated on the positive electrode position of the lead mesh of a lead mesh grid 7 to serve as a positive monopolar plate 3, a negative active material is coated on the negative electrode of the lead mesh grid 7 to serve as a negative monopolar plate 4, and the pretreatment position between the positive and negative active materials of the bipolar plate 2 serves as an external connection terminal 1 of the positive and negative terminal plates.

Referring to fig. 3, the bipolar plate 2 is obtained after cutting the continuous bipolar plate, wherein the lead mesh plate 21 is a pre-processing position.

Referring to fig. 4 and 5, when the bipolar plate 2 is to be used as an external connection terminal, the positive monopolar plate 3 is obtained by cutting the bipolar plate 2 from the central gap thereof, wherein the lead mesh positive plate terminal wire 31 is a lead mesh positive plate pretreatment position, and the lead mesh negative plate terminal wire 41 is a lead mesh negative plate pretreatment position.

Referring to fig. 6, the battery is assembled by the bipolar plate 2, the positive monopolar plate 3 and the negative monopolar plate 4, wherein the lead mesh positive plate terminal wire 31 is a lead mesh positive plate pretreatment position, and the lead mesh negative plate terminal wire 41 is a lead mesh negative plate pretreatment position.

Referring to fig. 7, a positive electrode of a battery is cast-welded to the external terminal 5 and the bus bar 6 by the positive lead plate terminal wire 31, and a negative electrode of a battery is cast-welded to the external terminal 5 and the bus bar 6 by the negative lead plate terminal wire 41.

According to the method for the on-line pretreatment of the coated wire of the lead mesh grid 7, the post cast-weld process equipment and process are reduced, the efficiency can be improved by more than five times compared with the prior pretreatment method of the horizontal battery, and due to the adoption of the method for the on-line pretreatment of the coated wire, the inner core of the glass fiber of the lead wire can not absorb soldering flux and can be dried in time, and the phenomena of insufficient solder, cast-weld mold corrosion, demoulding and the like which are usually generated in the pretreatment method before the cast-weld of the horizontal battery can not occur, so that the product quality can be greatly improved, the equipment mold loss can be reduced, and the labor intensity of workers can be reduced.

It is noted that, herein, relational terms such as first and second, and the like may be used solely to distinguish one entity or action from another entity or action without necessarily requiring or implying any actual such relationship or order between such entities or actions. Also, the terms "comprises," "comprising," or any other variation thereof, are intended to cover a non-exclusive inclusion, such that a process, method, article, or apparatus that comprises a list of elements does not include only those elements but may include other elements not expressly listed or inherent to such process, method, article, or apparatus. Without further limitation, an element defined by the phrase "comprising an … …" does not exclude the presence of other identical elements in a process, method, article, or apparatus that comprises the element.

Although embodiments of the present invention have been shown and described, it will be appreciated by those skilled in the art that changes, modifications, substitutions and alterations can be made in these embodiments without departing from the principles and spirit of the invention, the scope of which is defined in the appended claims and their equivalents.