阅读说明：本技术 金属空气电池及其电堆系统 (Metal-air battery and electric pile system thereof ) 是由 黄宗洪 曾玉府 陈寄喜 于 2019-10-22 设计创作，主要内容包括：本发明公开了一种金属空气电池及其电堆系统,电堆由多个电池单体级联叠装组成,电池单体包括单体框架、正极和负极：单体框架设有反应腔体以及反应腔体侧面的反应窗口,正极通过通气板压紧在反应窗口外侧的单体框架上,将反应窗口覆盖遮蔽,正极的内侧面与反应腔体的电解液接触；负极插装固定在反应腔体内部,与正极的内侧面平行设置,在单体框架上设置电解液以及空气的流通结构,叠合拼装的电堆结构简单、紧凑,提高了空气电池的体积能量密度,并且使得多个电池单体叠装的电堆电解液循环管路布置更加简化高效,进气通道通过管路主动提供流动的循环空气,并且可以在特定应用场景下连接氧气瓶运行,电堆组装方式简单可靠、组装效率高、一致性好,更适合工业化流水线批量生产。(The invention discloses a metal-air battery and a galvanic pile system thereof, wherein the galvanic pile is formed by cascading and overlapping a plurality of battery monomers, and each battery monomer comprises a monomer frame, a positive electrode and a negative electrode: the single frame is provided with a reaction cavity and a reaction window on the side surface of the reaction cavity, the positive electrode is tightly pressed on the single frame outside the reaction window through a vent plate to cover and shield the reaction window, and the inner side surface of the positive electrode is in contact with the electrolyte of the reaction cavity; the negative pole cartridge is fixed inside reaction cavity, with anodal medial surface parallel arrangement, set up the circulation structure of electrolyte and air on monomer frame, the pile simple structure that the coincide was assembled, it is compact, the volume energy density of air battery has been improved, and make the pile electrolyte circulation pipeline of a plurality of battery monomer stackings arrange and simplify the high efficiency more, inlet channel provides mobile circulating air through the pipeline initiative, and can connect the oxygen cylinder operation under the specific application scene, the pile package assembly mode is simple reliable, high assembly efficiency, the uniformity is good, more be fit for industrialization assembly line batch production.)

1. A metal-air battery, characterized by comprising:

the single frame is provided with a reaction cavity and a reaction window on the side surface of the reaction cavity;

the positive electrodes are symmetrically arranged on two side surfaces of the single frame, the positive electrodes are tightly pressed on the single frame outside the reaction window through the vent plate to cover and shield the reaction window, and the inner side surface of each positive electrode is in contact with the electrolyte inside the reaction cavity;

the cathode is inserted and fixed in the reaction cavity and is arranged in parallel with the inner side surface of the anode;

the single frame is provided with a water inlet and a water outlet which are communicated with the interior of the reaction cavity, and two sides of the top of the reaction cavity are provided with overflow ports which are communicated with the reflux cavity through the overflow ports; the water inlet is positioned in the middle of the bottom of the reaction cavity; the water outlet is positioned at the bottom of the backflow cavity; electrolyte in the reaction cavity enters the reaction cavity from the water inlet, then circulates between the cathode and the anode, and flows out from the water outlet through the overflow port and the backflow cavity;

and the ventilation plate is provided with a ventilation window for exposing the outer side surface of the anode.

2. The metal-air battery of claim 1, wherein a single frame at the periphery of the reaction window is provided with a circle of positive sealing groove, a circle of positive sealing ring is embedded in the positive sealing groove, a circle of hot melting columns are arranged along the positive sealing groove, positioning holes corresponding to the hot melting columns in a one-to-one manner are respectively arranged on the positive sealing ring, the positive electrode and the vent plate, and the ends of the hot melting columns penetrating through the positioning holes on the positive electrode and the vent plate are expanded into hot melting heads by hot melting so as to seal and fix the vent plate and the positive electrode on the single frame.

3. The metal-air cell of claim 2, the cell frame reaction window being provided with an insulating strip separating the positive electrode from the negative electrode inside the cell.

4. The metal-air battery of claim 3, wherein the side edge of the positive electrode is provided with a leading-out folding edge extending to the front end surface and the rear end surface of the single frame, the positive electrode leading-out copper sheet and the leading-out folding edge are tightly pressed and fixed on the end surface of the single frame, the leading-out folding edge adopts a metal mesh electrically contacted with the positive electrode, and a terminal of the positive electrode leading-out copper sheet is led out to the top of the single frame for battery wiring.

5. The metal-air battery of claim 1, wherein the reaction chamber or the return chamber is provided with a breathing port on the single frame at a position higher than the overflow port.

6. The metal-air battery of any of claims 1-5, the negative electrode comprising a substrate and a negative plate attached to a surface of the substrate, the negative plate being in contact with a negative lead-out copper sheet exposed and secured to an end of an insulating handle disposed on top of the substrate.

7. The metal-air battery of claim 6, wherein the outer edge of the substrate exceeds the outer edge of the negative plate to form a positioning rib, a negative slot with the same width as the negative electrode is arranged on the top monomer frame of the reaction cavity, a negative positioning baffle for inserting and positioning the negative electrode is arranged inside the reaction cavity, and a negative positioning groove for guiding and limiting the positioning rib on the negative electrode is arranged on the inner side of the negative positioning baffle.

8. The metal-air battery of claim 7, wherein the cathode positioning baffles on both sides of the cathode separate the reaction chamber from the return chambers on both sides, two overflow ports are disposed on the top of the cathode positioning baffle and communicate the reaction chamber with the return chambers on both sides, and an overflow platform of a tongue structure is disposed on each of the two overflow ports and extends toward the return chamber.

9. The galvanic pile system is characterized in that: cascading, stacking and assembling the metal-air battery of any one of claims 1-8;

the outer side surface of the vent plate is provided with a plurality of vent grooves, and at least one end of each vent groove is communicated with the vent window; the single frames are provided with air inlets and air outlets communicated with the vent grooves, the air inlets, the air outlets, the water inlets and the water outlets of the single frames of adjacent batteries are overlapped and spliced and then are in one-to-one butt joint with one another, a continuous water inlet channel, a continuous water drainage channel, a continuous air inlet channel and a continuous air outlet channel are formed inside the whole galvanic pile, and a plurality of air flow channels communicated with the air inlet channel and the air outlet channel are formed between the anodes of the adjacent batteries through the vent windows and the vent grooves on the vent plates;

the bottom of the reaction cavity is a funnel-shaped slope, the water inlet is arranged at the lowest position of the slope in a butt joint mode, and a spoiler for disturbing the flow balance of flowing liquid is arranged in the water inlet;

wherein, the water inlet of the outside is connected to electrolyte delivery apparatus, and the delivery port of the outside is connected to electrolyte recovery plant, and the air inlet of the outside is connected to the delivery apparatus who takes gas purification function, and the gas vent of the outside is connected to gas recovery plant.

10. The stack system according to claim 9, the gas inlet port being located below the cell internal cell frame aeration panel and the gas outlet port being located on both sides and above the cell internal cell frame aeration panel.

Technical Field

The invention belongs to a metal-air battery, and particularly relates to a metal-air battery and a galvanic pile system thereof.

Background

The metal-air battery monomer is a chemical power supply which takes oxygen in the air as a positive active material, takes metal as a negative active material and takes a conductive solution as an electrolyte, and generates electric energy through chemical reaction under the catalysis of a positive catalyst.

The single body of the metal-air battery has a plurality of unique advantages, and the fuel is metal materials, such as aluminum, magnesium and zinc, and metals such as lithium and sodium; because the reserves of aluminum, magnesium and zinc are abundant, the metal-air battery resource can be supplied in a sufficient amount. The positive active material is oxygen in the air, the battery does not need to be carried, the energy carried by the battery is determined by the amount of the negative metal, so that the actual specific energy of the battery can reach more than 865Wh/kg (the current lithium ion battery is below 300 Wh/kg), and the battery has great performance advantage. The product after reaction can be processed into oxides widely used, such as raw materials of alumina, magnesia and the like, and can be applied to various industries of sapphire, mobile phone screens, ceramics, cosmetics and the like. Or the aluminum oxide (or magnesium oxide) can be electrolyzed again by using clean energy sources such as wind energy, solar energy, water energy and the like or electric energy in areas with abundant electric energy to be changed into metal, and then the metal-air battery is installed again to discharge. Therefore, centralized large-scale production can be realized, pollution can be reduced, emission is reduced, centralized power supply and decentralized use can be realized, green electric energy with lower cost is transferred to a place with high electric energy cost for use, and electric energy is transferred from a place where the energy is easy to obtain to a place where the energy is difficult to obtain for use. The pollution-free and carbon-emission-free new energy automobile power battery can be really realized, pollution-free and carbon-emission-free green energy recycling is realized in the process, and the metal air battery increasingly draws attention in the world.

The existing metal-air battery needs to continuously provide electrolyte and air, the electrolyte and air channels inside the assembled electric pile are complex, the whole structure of the electric pile is complicated, nano-scale reaction products easily block a circulating channel of the electrolyte, the maintenance difficulty is extremely high, the system operation cost is greatly occupied, and the working efficiency of the battery is reduced.

Meanwhile, the negative electrode in the metal-air battery is a consumable electrode, the metal negative electrode of the metal-air battery is mostly of a single-chip structure at present, the metal negative electrode is thinner and thinner in the using process, so that a certain thickness or a longitudinal and transverse framework structure is reserved to prevent the metal negative electrode from falling into a reaction cavity of a battery monomer, and the negative electrode metal plate of the battery is not completely used, so that the waste of negative electrode materials is caused. The electrode leading-out connecting piece has small area, complicated connecting mode, complex assembly, large connecting resistance and serious line loss, and the discharging efficiency is influenced.

Disclosure of Invention

The technical problem solved by the invention is as follows: aiming at the problem of low battery working efficiency caused by complex structure of the existing metal-air battery, a novel metal-air battery and a pile system thereof are provided.

The invention is realized by adopting the following technical scheme:

the metal-air battery comprises a single frame, anodes symmetrically arranged on two side surfaces of the single frame and a cathode arranged in the middle of the single frame;

the monomer frame is provided with a reaction cavity and a reaction window on the side surface of the reaction cavity; the anode is tightly pressed on the monomer frame outside the reaction window through the vent plate to cover and shield the reaction window, and the inner side surface of the anode is in contact with the electrolyte inside the reaction cavity; the cathode is inserted and fixed in the reaction cavity and is arranged in parallel with the inner side surface of the anode;

the single frame is provided with a water inlet and a water outlet which are communicated with the interior of the reaction cavity, and two sides of the top of the reaction cavity are provided with overflow ports which are communicated with the reflux cavity through the overflow ports; the water inlet is positioned in the middle of the bottom of the reaction cavity; the water outlet is positioned at the bottom of the backflow cavity; electrolyte in the reaction cavity enters the reaction cavity from the water inlet, then circulates between the cathode and the anode, and flows out from the water outlet through the overflow port and the backflow cavity;

and the ventilation plate is provided with a ventilation window for exposing the outer side surface of the anode.

Further, set up the anodal seal groove of round on the monomer frame of reaction window periphery, anodal seal ring of embedded dress round in the seal groove of positive pole follows the anodal seal groove is equipped with a plurality of hot melt posts of round, be equipped with the locating hole with hot melt post one-to-one on anodal seal ring, positive pole, the breather plate respectively, the hot melt post passes the tip of the locating hole on anodal seal ring, positive pole and the breather plate and expands into the hot melt head through the hot melt, fixes anodal seal ring, positive pole and breather plate seal on the monomer frame.

Furthermore, the reaction window of the monomer frame is provided with an insulating strip which separates the anode from the cathode in the battery.

Furthermore, the side edge of the positive electrode is provided with a leading-out folding edge which extends to the front end face and the rear end face of the single frame, the positive electrode leading-out copper sheet and the leading-out folding edge are pressed and fixed on the end faces of the single frame, and the wiring terminal of the positive electrode leading-out copper sheet is led out to the top of the single frame for battery wiring.

Further, the leading-out folded edge is a metal mesh or a metal plate of the positive current collector.

Furthermore, the reaction cavity or the backflow cavity is provided with a breathing port on the monomer frame higher than the overflow port

In the metal-air battery, the negative electrode comprises a substrate and a negative plate attached to the surface of the substrate, the negative plate is in contact with a negative lead copper sheet, and the negative lead copper sheet is exposed and fixed at the end part of an insulating handle arranged at the top of the substrate.

Furthermore, the outer edge of the substrate exceeds the outer edge of the negative plate to form a positioning convex rib, a negative electrode slot with the same width as the negative electrode is arranged on the top monomer frame of the reaction cavity, a negative electrode positioning baffle plate used for negative electrode insertion positioning is arranged inside the reaction cavity, and a negative electrode positioning groove which is limited by the positioning convex rib on the negative electrode is arranged on the inner side of the negative electrode positioning baffle plate.

Furthermore, the negative positioning baffle plates on the two sides of the negative electrode separate the reaction cavity from the backflow cavities on the two sides, two overflow ports communicated with the reaction cavity and the backflow cavities on the two sides are arranged at the top of the negative positioning baffle plate, and overflow platforms of a platform tongue structure extending towards the backflow cavities are arranged on the two overflow ports.

Furthermore, a negative electrode sealing ring is arranged on the surface of the substrate between the insulating handle and the negative electrode plate.

The invention also discloses a galvanic pile system which is formed by cascading, superposing and assembling the metal-air battery monomers;

the outer side surface of the vent plate is provided with a plurality of vent grooves, and at least one end of each vent groove is communicated with the vent window; the single frames are provided with air inlets and air outlets communicated with the vent grooves, the air inlets, the air outlets, the water inlets and the water outlets of the single frames of adjacent batteries are overlapped and spliced and then are in one-to-one butt joint with one another, a continuous water inlet channel, a continuous water drainage channel, a continuous air inlet channel and a continuous air outlet channel are formed inside the whole galvanic pile, and a plurality of air flow channels communicated with the air inlet channel and the air outlet channel are formed between the anodes of the adjacent batteries through the vent windows and the vent grooves on the vent plates;

the bottom of the reaction cavity is a funnel-shaped slope, the water inlet is arranged at the lowest position of the slope in a butt joint mode, and a spoiler for disturbing the flow balance of flowing liquid is arranged in the water inlet;

wherein, the water inlet in the outside is connected to electrolyte delivery apparatus, and the delivery port in the outside is connected to electrolyte recovery plant, and the air inlet in the outside is connected to the gas delivery apparatus who takes gas purification performance, and gas recovery plant is connected to the gas vent in the outside.

Further, the air inlet is located below the single frame ventilation plate inside the battery, and the air outlet is located on two side faces and above the single frame ventilation plate inside the battery.

According to the metal-air battery, the water inlet is arranged at the bottom of the reaction cavity, the electrolyte enters from the bottom of the reaction cavity, then gradually fills the reaction cavity, overflows to the backflow cavity through the top of the reaction cavity and finally flows out of the water outlet, and circulation of the electrolyte is achieved. The electrolyte fully soaks the cathode and the anode of the battery, so that the discharge reaction of the electrode material is more balanced, and the electrode material can be more efficiently utilized to participate in the discharge reaction.

Still be provided with on monomer frame and breathe mouth and reaction cavity intercommunication, guarantee that the inside pressure of reaction cavity is unanimous with outside atmospheric pressure, can not cause tensile damage to the positive pole because of the malleation or the negative pressure that electrolyte business turn over produced, can discharge or collect the gas that the battery during operation produced simultaneously.

The single batteries are directly connected with each other in a butt joint mode through the water inlet and the water outlet, and only the two ends of the outermost side of each electric pile are connected with electrolyte conveying equipment and electrolyte recovery (purification treatment) equipment through pipelines, so that the electrolyte pipeline of the whole electric pile is simpler.

Electrolyte can be regarded as long pipe-line transportation at the circulation channel of pile, and electrolyte can produce "fish belly formula when long inside the pipe-line flows and distribute" effect in the perpendicular to direction of transfer to the range inconsistent that leads to the inside liquid level of each battery monomer reaction cavity in the pile to rise, the concrete expression does: (1) when the liquid is supplied in a single direction, the height of the liquid increases from one end of the water inlet to the other end, and (2) when the liquid is supplied in a double direction, the water inlet ends at the two ends are lower, the middle part of the liquid is higher, and even the liquid level of electrolyte in the reaction cavity of some single batteries cannot reach the overflow height, so that the electrolyte circulation cannot be formed. In order to avoid the phenomenon, the spoilers are arranged inside the water inlets of the single frames, and the spoilers disturb the electrolyte flowing in the water inlet butt joint channels, so that the rising amplitude and the flow rate of the electrolyte level in the reaction cavities inside the cascade-stacked single batteries are consistent.

Electrolyte reaches an upper outlet through the reaction cavity and flows out from the return cavities at two sides to the water outlet, so that the rising flow rate of the electrolyte in the cascaded and overlapped single batteries tends to be consistent, the discharging reaction among the single batteries is consistent, and the discharging efficiency is consistent.

Monomer frame generally adopts the plastic material preparation of high temperature resistant alkali, in monomer frame on the plastic surface with electrolyte contact, all spray have the super hydrophobic material of resistant alkali, utilize the rejection that super hydrophobic material has to water, the water droplet is unable to slide on its surface and spreads and keep the ball-type roll form to reach the effect of roll automatically cleaning, can make the chamber wall of monomer frame inside can keep clean, can also prevent that electrolyte from causing the corruption to monomer frame inner wall.

The super-hydrophobic materials with high temperature resistance and strong alkali resistance are coated on the plastic surface in the reaction cavity, the overflow platform at the top and the backflow cavity, which are in contact with the electrolyte, and have the effects that firstly, nanoscale reaction organisms cannot be adhered to the surface of the reaction cavity to form patch blockage, and secondly, when the electrolyte falls down to the backflow cavity through the overflow platform, liquid forms intermittent cutoff and unidirectional conduction, so that the resistance of the water outlet of the single battery is increased, and the electric energy loss caused by liquid flow short circuit at the output end when a plurality of single batteries are cascaded is greatly reduced.

The super-hydrophobic material in the invention is other materials with the same function, such as high temperature resistant and strong alkali resistant PTFE paint. The invention also solves the problem of active positive pressure air circulation supply among all battery monomers in the pile, the airflow channel is combined with the positive electrode fixing structure, the positive electrodes on the battery monomers are fixed by adopting the vent plate, the vent plate is used as a part contacted with the positive electrode, and simultaneously the vent plate is superposed with the adjacent battery monomers to form a vent part for supplying air to the positive electrode. The vent plate is provided with a vent window and a vent groove, an air inlet channel and an air outlet channel which are formed after the air inlet and the air outlet on the battery monomer are overlapped are combined to form an air flow channel communicated between the galvanic piles, air enters the two side surfaces of the battery monomer from the inner pipeline of the monomer frame by the air of air conveying equipment with air purification function such as a fan, and passes through the air flow channel formed after the vent plates of the adjacent battery monomers are overlapped, the air is discharged from the air outlets at two sides of the vent groove or two sides of the upper part of the vent plate to realize air circulation among a plurality of battery units, the air actively circulating at positive pressure not only provides enough oxygen required by the discharge reaction for the anode, but also takes away the heat on the surface of the anode, improves the cooling and heat dissipation problem of the anode, prolongs the service life of the anode and enables the galvanic pile to be used under a closed environment.

The metal-air battery also solves the problems of complicated operation and poor sealing of the positive electrode sealing installation, the periphery of the reaction window of the single frame is provided with a plurality of protruded hot melting columns, the hot melting columns and the single frame are integrally formed, the edge of the reaction window is provided with a positive electrode sealing groove, a positive electrode sealing ring is arranged in the positive electrode sealing groove, the outer side of the positive electrode sealing ring is provided with the positive electrode, and the outer side of the positive electrode is provided with the vent plate. All be equipped with the location hole site that corresponds with hot melt post on the monomer frame on anodal and the breather plate, after location hole site and hot melt post on with all anodals and the breather plate align one by one, compress tightly breather plate and anodal, then once with the hot melt head of all hot melt post tip hot melts formation back-off through hot melt equipment, the diameter of location hole site on the size exceedes the breather plate after the hot melt head inflation, it is spacing to the breather plate formation, compress tightly the fastening with anodal through this kind of mode, reaction window on the monomer frame forms sealedly.

The metal-air battery adopts a composite negative electrode structure of the substrate and the negative plates, the negative plates participating in discharge reaction are inserted and fixed in the monomer frame through the substrate, only the negative plates react with the positive electrode in the discharge reaction process, all the negative plates can be directly and completely reacted, and the use efficiency of the negative metal material is improved; the substrate is a stainless steel plate or a non-metal plate which does not participate in the discharge reaction, so that loss can not occur in the use process, and the single negative electrode is installed through the substrate slots on the two sides in the reaction cavity, so that the situation that the negative electrode falls into the battery due to fracture can not occur; the composite cathode is placed in the groove and the positioning groove, so that metal fuel is replaced more simply and quickly; and a negative sealing ring is arranged between the negative electrode and the monomer frame, so that the electrolyte in the monomer frame can be effectively sealed.

In conclusion, the invention starts with the structural design of the battery by using materials, an extraction electrode connection mode, an air circulation mode and an electrolyte circulation mode, solves the problems of sealing the positive electrode of single batteries, balanced oxygen supply of the positive electrode, ventilation and cooling of the positive electrode and the like, the problems of sealing and use efficiency of the negative electrode, extraction and connection of the positive electrode and the negative electrode, and high-efficiency circulation of the electrolyte, has simple and compact structure of a superposed and assembled galvanic pile, reduces the volume of the galvanic pile after superposed and installed, improves the utilization rate of electrode materials, simplifies the arrangement of electrolyte circulation pipelines of the galvanic pile when a plurality of groups of single batteries are cascaded and superposed, provides flowing circulating air through the pipelines by positive pressure actively, improves the cooling and heat dissipation problems of the positive electrode, prolongs the service life of the positive electrode, can be connected with an oxygen bottle to operate in an anoxic state, and greatly improves the output capacity and the use efficiency of the metal-air battery, the application range of the metal-air battery is improved; the galvanic pile has simple and reliable assembly mode, high assembly efficiency and good consistency, is more suitable for batch production, and can be recycled in an environment-friendly classification way during retirement. The invention is further described with reference to the following figures and detailed description.

Drawings

Fig. 1 is a schematic structural diagram of a metal-air battery cell in an embodiment.

Fig. 2 is an exploded view of a metal-air battery cell in an embodiment.

Fig. 3 is a first schematic view of a single frame structure in an embodiment.

Fig. 4 is a schematic diagram of a single frame structure in the embodiment.

FIG. 5 is a schematic diagram showing the positions of the reaction chamber and the reflow chamber inside the single frame in the example.

Fig. 6 is a partial schematic view of a reaction chamber between a positive electrode and a negative electrode inside a cell frame in an example.

Fig. 7 is a schematic view of the negative electrode structure in the example.

Fig. 8 is a schematic diagram of the structure of the positive electrode in the example.

Fig. 9 is a schematic diagram of a structure of the vent plate in the embodiment.

Fig. 10 is a side view of an aeration panel in an embodiment.

Fig. 11 is a schematic diagram of a flow path of an electrolyte inside a battery in an embodiment.

Fig. 12 is a schematic view of the air flow path on the surface of the battery in the embodiment.

FIG. 13 is a schematic diagram of a cell stack according to an embodiment.

Reference numbers in the figures:

1-monomer frame, 100-reaction window, 101-insulating strip, 102-reaction cavity, 103-negative slot, 104-negative positioning groove, 105-negative leading-out fixing hole, 106-hot melting column, 107-positive sealing groove, 111-water inlet, 112-water outlet, 113-spoiler, 114-breathing port, 115-overflow port, 116-backflow cavity, 121-air inlet, 122-exhaust hole, 123-diversion trench and 131-fixing through hole;

2-positive pole, 200-positive pole leading copper sheet, 201-leading folding edge, 202-sealing positioning hole, 203-leading fixing hole, 21-positive pole sealing ring, 22-vent plate, 221-vent window, 222-vent groove, 223-vent plate positioning hole, 23-side cover and 24-nut blocking piece;

3-negative pole, 300-negative pole leading-out copper sheet, 301-substrate, 302-negative plate, 303-positioning convex rib, 304-insulating handle and 305-negative pole sealing ring.

Detailed Description

Examples

Referring to fig. 1 and fig. 2, the metal-air battery shown in the figure is a specific embodiment of the present invention, and specifically includes a cell frame 1, a positive electrode 2 and a negative electrode 3, where the negative electrode 3 is a metal electrode capable of participating in a discharge reaction of the metal-air battery, and the metal participating in the discharge reaction is an aluminum plate, a magnesium plate or a zinc plate, and is fixedly inserted into an internal reaction cavity of the cell frame 1, the positive electrode 2 is fixedly installed on a reaction window 100 of the cell frame 1, and covers and shields the reaction window 100 communicated with the reaction cavity, and the positive electrode 2 can seal an electrolyte and provide oxygen for the discharge reaction inside the reaction cavity.

Specifically, as shown in fig. 2, the positive electrode 2 of the present embodiment is mounted on the single frame outside the reaction window 100 by pressing the vent plate 22, and covers and shields the reaction window 100 on the side of the reaction chamber inside the single frame. The two side surfaces of the single frame 1 of the embodiment are both provided with the reaction windows 100 directly communicated to the reaction cavity, so that the two side surfaces of the single frame 1 are respectively and symmetrically provided with two groups of anodes 2, and the two groups of anodes and two negative plates fixedly inserted in the single frame 1 are respectively opposite to form two groups of discharge reactions. The side edge of the anode 2 extends to the front end face and the rear end face of the monomer frame 1, the front end face and the rear end face of the monomer frame 1 are sealed by the side covers 23, the side edge of the anode 2 is pressed and fixed on the side covers 23 of the monomer frame 1 together with the anode lead-out copper sheet 200 through the nut retaining sheet 24, and the anode lead-out copper sheet 200 is used for anode lead-out wiring.

Referring to fig. 4 in combination, a circle of positive seal groove 107 is formed in the monomer frame 1 located at the periphery of the reaction window 100, a circle of positive seal ring 21 is embedded in the seal groove 107, the positive electrode 2 is pressed against the monomer frame through the vent plate 22, and the positive seal ring 21 is pressed against the positive seal groove 107, so that sealing between the positive electrode 2 and the reaction window 100 of the monomer frame 1 is formed, and the electrolyte in the reaction cavity is prevented from leaking. Meanwhile, a circle of a plurality of hot melting columns 106 are arranged along the periphery of the anode sealing groove 107 or the reaction window 100, and the hot melting columns 106 are of uniform-section columnar structures which are integrally injection-molded with the single frame 1. Referring to fig. 8 and 9 in combination, a circle of sealing positioning holes 202 corresponding to the heat-fusible pillars 106 one by one is provided on the positive electrode 2, the air-passing plate 22 is provided with a circle of air-passing plate positioning holes 223 corresponding to the hot melting columns 106 one by one, the sealing positioning holes 202 and the air-passing plate positioning holes 223 have the same cross section with the hot melting columns 106 and keep clearance fit, when the anode 2 and the vent plate 22 are installed, after all the heat-fusible columns 106 are respectively passed through the sealing positioning holes 202 on the anode 2 and the vent plate positioning holes 223 on the vent plate 22, keeping the vent plate 22 pressed against the positive electrode 2, the end of the heat stake 106 extending out of the vent plate positioning hole 223, and then, forming a hot melting head by hot melting the end part of the hot melting column 106 through hot melting equipment, wherein the diameter of the hot melting head after hot melting exceeds the aperture of the vent plate positioning hole 223 on the vent plate 22, limiting and locking the vent plate 22 from the outer side, and tightly pressing and sealing the anode 2 on the single frame 1 through the vent plate 22.

This embodiment is directly arranged hot melt post 106 inside positive seal groove 107, simultaneously, be equipped with the locating hole of round and hot melt post 106 one-to-one on anodal sealing washer 21, anodal sealing washer 21 adopts the whole shaping of mould for corrosion-resistant soft plastic, has certain elastic deformation ability, can be less than the external diameter of hot melt post with the setting of locating hole aperture on anodal sealing washer 21, can make like this and keep certain extrusion deformation between sealing washer and the hot melt post, improve the location and the sealed effect of sealing washer.

Referring to fig. 4 again, the reaction window 100 of the cell frame 1 is further provided with a plurality of parallel insulating strips 101, the insulating strips 101 separate the anode from the cathode inside the battery, the reaction window 100 is divided by the insulating strips 101, and the anode 2 is supported, so that the anode 2 is prevented from contacting and short-circuiting with the cathode after being deformed due to the overlarge area of the reaction window 100.

Referring to fig. 8 again, one side of the positive electrode 2 is provided with a leading-out folded edge 201 extending to the front and rear end faces of the single frame 1, a row of leading-out folded edge fixing holes 203 are formed in the leading-out folded edge 201, the leading-out folded edge 201 is extended to and fixed on the end face of the single frame 1, the leading-out folded edge 201 and the positive electrode leading-out copper sheet 200 are pressed and contacted through the leading-out folded edge fixing holes 203 by screws and nuts, and the terminal of the positive electrode leading-out copper sheet 200 is led out to the top of the single frame for battery wiring, so that. The leading-out folding edge 201 is made of a metal net or a metal plate of a positive pole current collector, the metal net or the metal plate is used as the leading-out folding edge 201 to connect the positive pole 2 with the positive pole leading-out copper sheet 200, the contact area between the metal net and the positive pole leading-out copper sheet 200 on two sides of the positive pole is large, the metal net and the positive pole leading-out copper sheet 200 are tightly pressed and connected to the end face of the single frame 1 through a plurality of screws, the resistance is small, the current-carrying capacity is large, the micro-ohm-level connection resistance is achieved, and the problem of heat distribution and loss of. The positive lead-out copper sheet 200 can extend to the planes on two sides of the top of the next battery monomer arranged in an overlapped mode after being bent to be connected with the negative lead-out copper sheet 300, so that the electric pile wire arrangement formed by combining a plurality of battery monomers is realized, and the structure is simple. The sealing assembly of the anode 2 and the vent plate 22 is completed by hot melting of hot melting equipment to the hot melting column at one time, the anode 2 is sealed by the complete anode sealing ring 21, the operation is easy, and the mass production can be realized by a die.

The vent plate 22 in the present embodiment not only serves as a pressing member for pressing and fixing the positive electrode 2 to the cell frame 1, but also serves as a vent member for ventilating the positive electrode 2. Referring to fig. 9 again, the vent plate 22 is the same as the plane of the positive electrode except for the opening of the leading-out edge, so that the positive electrode 2 can be tightly pressed on the single frame 1, the inner side surface of the vent plate 22, which is tightly attached to the positive electrode 2, is a smooth plane, so as to ensure that the surface of the positive electrode 2 is flattened, the vent window 221 is arranged on the vent plate 22 in the area corresponding to the reaction window 100, in order to avoid the outward bulging and deformation of the positive electrode due to the excessively large vacant area of the vent window 221, the vent window 221 is divided into a plurality of rib structures, external oxygen or air contacts the positive electrode through the vent window 221 on the vent plate 22, and enters the reaction window 100 through the positive electrode to provide oxygen required by the discharge reaction. Because the discharge capacity of the battery cells is improved by cascade lamination, a plurality of vent grooves 222 communicated with the vent windows 221 are arranged on the outer side surface of the vent plate 22 far away from the positive electrode, one end of each vent groove 222 is finally communicated with the vent window 221, and the other end of each vent groove penetrates through the outer edge of the vent plate 22 to be in butt joint with an air inlet channel or an air outlet channel of a battery system. The vent grooves 222 may be semicircular grooves arranged on the outer side surface of the vent plate 22 in a criss-cross manner as shown in fig. 5, or may be arranged in other forms according to the arrangement of the vent channels of the battery. The stack formed by cascading a plurality of battery cells together can realize the flow supply of air or oxygen through the vent grooves 222, so that the cooling and heat dissipation problems of the positive electrode are improved.

In this embodiment, the negative electrode 3 is a composite plate type structure, as shown in fig. 2 and 7, the negative electrode 3 is a composite plate type structure, and includes a negative lead-out copper sheet 300, a substrate 301 and a negative plate 302, wherein the negative plate 302 is made of a negative metal material participating in a discharge reaction inside the metal-air battery, and is generally an aluminum plate, a magnesium plate or a zinc plate, the substrate 301 is a fixed mounting structure of the whole negative electrode, and is made of a high temperature resistant and high strength thin plate material that does not react with an electrolyte, and is vertically positioned at a middle portion of the single frame; the negative electrode plate 302 is attached and fixed to the surface of the substrate 301, fixed to the inside of the cell frame 1 via the substrate 301, and held in parallel and at an equal distance between the positive and negative electrodes on both sides. The negative lead-out copper sheet 300 is a lead-out negative connecting component of the whole battery, one end of the negative lead-out copper sheet is in electrified contact with the negative plate 302, the other end of the negative lead-out copper sheet is led out and fixed to the top of the substrate 301, after the whole composite negative is inserted into the battery monomer, the top of the substrate 301 and the negative lead-out copper sheet 300 are exposed outside the monomer frame, and therefore the battery wiring is facilitated.

Specifically, in this embodiment, the negative plates 302 are attached to both side surfaces of the substrate 301, one end of the negative lead-out copper sheet 300 corresponding to the two negative plates 302 is sandwiched between the negative plates 302 and the substrate 301, and the other end is led out to both ends of the top of the substrate, respectively, after the composite negative electrode is inserted into the reaction cavity of the cell frame, the negative plates 302 on both side surfaces can respectively perform two sets of parallel discharge reactions with the positive electrodes on both side surfaces of the cell frame, thereby increasing the power generation of the battery cell. In practical applications, the negative electrode plate 302 may be disposed on one or both sides of the substrate 301 according to the internal structure of the battery cell and the rated power design of the battery. The negative plate 302 can be fixedly attached to the surface of the substrate in a high temperature and strong alkali resistant gluing, welding, cold rolling, hot rolling and explosion compounding manner.

Referring to fig. 3, a reaction cavity 102 is arranged inside the cell frame 1, reaction windows 100 are formed in the cell frame on two sides of the reaction cavity 102, a negative electrode slot 103 having the same width as the negative electrode 3 is arranged at the top of the reaction cavity 102, and the negative electrode 3 is inserted into the reaction cavity 102 inside the cell frame 1 from the negative electrode slot 103. Set up two negative pole constant head tanks 104 and butt joint with negative pole slot 103 in the reaction chamber, the base plate 301 outward flange of negative pole 3 surpasss negative plate 302 outward flange and forms location protruding muscle 303, insert the inside in-process of reaction chamber 102 through negative pole slot 103 with negative pole 3, the protruding muscle 303 of location just in time is embedded into negative pole constant head tank 104 inside, whole negative pole 3 is installed under the guide effect of negative pole constant head tank 104 and is target in place, and negative pole 3 is inside by negative pole constant head tank 104 location at the reaction chamber, as shown in fig. 5, avoid the negative pole board to take place to shift the back and take place the short circuit with anod.

The positive electrode 2 of the metal-air battery is fixed on the outer side surface of the monomer frame 1, the reaction window 100 of the reaction cavity 102 is covered and sealed, a channel for free circulation of electrolyte is formed between the positive electrode 2 and the negative plate 302 of the negative electrode 3, the reaction window 100 is sealed through the positive electrode 2, the electrolyte in the reaction cavity 102 cannot flow out of the reaction window, meanwhile, external air is allowed to enter the positive electrode, oxygen in the air is subjected to discharge reaction with the negative electrode metal and the electrolyte through the reaction window 100 to generate electricity, the reaction window 100 is further divided by a plurality of insulating strips 101 and is supported by the positive electrode 2, and the short circuit caused by deformation of the positive electrode 2 due to the overlarge area of the reaction window 100 is prevented. The positive electrode 2 extends to the top of the monomer frame through the positive electrode lead-out copper sheets on the two end faces of the monomer frame 1, and is arranged with the negative electrode lead-out copper sheets together. The positive electrode material of the metal-air battery is the existing material, and this embodiment only describes the composite negative electrode of the present invention in detail, and the electrolysis principle and the positive electrode material of the metal-air battery are conventional technologies in the art, and are not described herein again.

After the negative electrode is inserted into the single frame 1, the top of the substrate 301 is exposed at the top of the single frame, so that the negative electrode leading copper sheet 300 is convenient to arrange, and the negative electrode is convenient to grasp and replace. This embodiment sets up insulating handle 304 with the fixed insulating handle 304 that sets up in top of base plate 301, insulating handle 304 adopts rigid plastic material parcel base plate top integrated into one piece, whole insulating handle 304 is along monomer frame's transverse arrangement, after inserting negative pole 3 to the inside reaction cavity 102 of monomer frame, seal negative pole slot 103, the fixed top that sets up at insulating handle 304 and stretch out from the tip of insulating handle of copper sheet 300 is drawn forth to two sets of negative poles that correspond two sets of negative plates, draw out fixed orifices 105 locking with the negative pole at monomer frame 1 top and fix.

After the negative electrode 3 is inserted into the cell frame 1, in order to prevent the electrolyte from leaking from the assembly gap between the negative electrode 3 and the cell frame, a circle of negative electrode sealing ring 305 is provided between the insulating handle 304 and the negative electrode plate 302 on the top of the substrate of the negative electrode 3, the substrate directly contacting the cell frame, the negative electrode sealing ring 305 seals the assembly gap between the substrate of the negative electrode 3 and the cell frame, and the negative electrode sealing ring 305 may be directly and integrally injection-molded on the substrate 301 by using a sealing material. The width of the substrate where the negative sealing ring 305 is arranged is set to be smaller than that of the substrate where the negative plate is arranged, a neck is formed, and an overflow channel for circulating electrolyte is formed between the region with two vacant sides and the reaction cavity after the negative electrode is inserted into the monomer frame.

In order to ensure the continuous discharge reaction of the metal-air battery, electrolyte needs to be continuously introduced into the reaction cavity, and with reference to fig. 3 and fig. 4, reaction windows 100 are respectively arranged at positions, corresponding to two side faces of the monomer frame 1, of the reaction cavity 102 inside the monomer frame 1, the anode 2 is tightly assembled on the side faces of the monomer frame 1 through the vent plate 22, the reaction window 100 is covered and sealed, a circle of anode sealing ring 21 is assembled between the anode 2 and the monomer frame 1 at the periphery of the reaction window 100, the sealing of the electrolyte inside the reaction cavity 102 at the reaction window 100 is realized, the sealing of the electrolyte can be realized by the anode 2, and meanwhile, air can enter the anode and provide oxygen for the discharge reaction inside the reaction cavity through the reaction window. Two vertical backflow cavities 116 are arranged on two sides of the reaction cavity 102, the top of the reaction cavity 102 is communicated with the top of the backflow cavities 116 in an overflowing manner, a water inlet 111 is arranged on a single frame 1 corresponding to the middle of the bottom of the reaction cavity 102, two groups of water outlets 112 are respectively arranged on the single frames 1 corresponding to the bottoms of the two backflow cavities 116, electrolyte in the reaction cavity 102 flows between a negative electrode and a positive electrode after entering the reaction cavity 102 from the water inlet 111, and after the reaction cavity 102 is filled with the electrolyte and the discharge reaction area of the negative electrode and the positive electrode is completely immersed, the electrolyte overflows from the top of the reaction cavity 102 to the backflow cavities 116 and flows out from the water outlets 112.

Referring to fig. 5 again, the top of the reaction cavity 102 is provided with an open negative electrode slot 103, the negative electrode 3 of the battery is inserted into the reaction cavity 102 through the negative electrode slot 103, two sets of negative electrode positioning baffles corresponding to the side edges of the negative electrode 3 are arranged inside the reaction cavity 102, after the negative electrode 3 is inserted into the reaction cavity 102, the two side edges are embedded into the negative electrode positioning groove of the negative electrode positioning baffle, the negative electrode is fixed inside the reaction cavity 102, and the negative electrode lead-out copper sheets 300 are fixed at the two ends of the top of the negative electrode 3, so that the electric energy output of the negative. The reaction cavity 102 and the backflow cavity 116 are separated by a negative electrode positioning baffle, an overflow port 115 is arranged between the top of the negative electrode positioning baffle and the inside of the monomer frame, the electrolyte filled in the reaction cavity 102 enters the backflow cavity through the overflow port 115, the electrolyte in the reaction cavity 102 completely immerses the negative electrode metal plate on the negative electrode 3, meanwhile, the reaction window 100 is completely positioned in the side surface of the reaction cavity 102, the positive electrode 2 covering and sealing the reaction window 100 is parallel and opposite to the negative electrode 3 inserted into the reaction cavity 102 through the reaction window 100, and a parallel and equidistant space is separated from each other for the circulation of the electrolyte, as shown in fig. 6, the discharge reaction of the battery just occurs in the reaction area where the positive electrode and the negative electrode are opposite.

In addition, as shown in fig. 4, a breathing port 114 is further disposed on the single frame corresponding to the reaction chamber 102 or the backflow chamber 116, so that during the process of rising or falling of the liquid level of the electrolyte inside the reaction chamber 102, the pressure inside the reaction chamber 102 is kept balanced with the external atmospheric pressure, the anode 2 is prevented from being deformed and damaged due to the pressure change inside the reaction chamber 102, and meanwhile, the breathing port 114 can be used for collecting the gas generated during the operation of the battery. The position of the breathing opening 114 is higher than the position of the overflow opening, so that the electrolyte is prevented from leaking from the breathing opening 114. The bottom of the reaction cavity 102 is arranged into a funnel-shaped slope, and the lowest position of the slope is butted with the water inlet, so that large-particle residues generated by the reaction in the reaction cavity can be concentrated and precipitated at the bottom of the reaction cavity, and the large-particle residues can be conveniently and uniformly collected after the reaction.

Referring to fig. 11, in the metal-air battery cell of this embodiment, the electrolyte enters the reaction cavity 102 from the water inlet 111 at the bottom of the middle of the cell frame 1, along with the continuous input of the electrolyte, the liquid level of the electrolyte inside the reaction cavity 102 gradually rises until the liquid level reaches the topmost end of the negative positioning baffle at the two sides of the reaction cavity 102, at this time, the electrolyte fills the space between the positive electrode and the negative electrode, so as to ensure the overall reaction of the electrode material, along with the continuous transportation of the electrolyte, the electrolyte in the reaction cavity 102 overflows through the overflow port 115 at the top to enter the backflow cavities 116 at the two sides, and is recovered from the water outlet 112 through the backflow cavity 116, the overflow port 115 is provided with a tongue structure extending toward the backflow cavity as an overflow platform, when the electrolyte falls down through the overflow platform to the backflow cavity, the liquid forms intermittent cutoff and is conducted in a unidirectional manner, the electric energy loss caused by the liquid flow short circuit of the output end when a plurality of battery single cells are cascaded is greatly reduced. In the whole process, the gas in the reaction cavity can enter and exit the reaction cavity through the breathing port 114, so that the stability of the internal pressure of the reaction cavity is ensured.

In the stack shown in fig. 13, two or more groups of metal-air battery cells in this embodiment are stacked and assembled in cascade to form a large-capacity metal-air battery stack system, and electrolyte circulation channels on all the battery cells are butted to form a stack electrolyte circulation system. First, the water inlet 111, the water outlet 112, and the breathing port 114 in this embodiment all penetrate through the single frame along the overlapping assembly direction of the single frame, in addition, a fixing through hole 131 for overlapping and connecting the battery cells in series is further disposed in the non-reaction cavity region on the single frame 1, the fixing through hole 131 also penetrates through the single frame along the overlapping assembly direction of the single frame, the water inlet 111, the water outlet 112, the breathing port 114, and the fixing through hole 131 all adopt cylindrical holes, wherein the top of the water inlet 111 and the top of the water outlet 112 are respectively communicated with the reaction cavity 102 and the backflow cavity 116 in the respective single frame.

When all battery monomers are cascaded and overlapped, the connecting rods penetrate through the fixing through holes 131 which are coaxially aligned on the monomer frame 1, all the battery monomers are overlapped and pressed by utilizing the pressing plates from two ends, the water inlets 111, the water outlets 112 and the breathing ports 114 on the adjacent monomer frames are respectively in one-to-one coaxial butt joint communication, the adjacent butt joint channels are hermetically assembled through the sealing rings, the water inlets on the battery monomers on the outermost side are connected to electrolyte conveying equipment, generally a conveying pump, the water outlets on the outermost side are connected to electrolyte recovery equipment, generally a recovery box, and the breathing ports on the outermost side are connected to atmosphere or gas recovery equipment through pipelines.

Electrolyte can be regarded as long pipe-line transportation at the circulation channel of pile, and electrolyte can produce "fish belly formula when long inside the pipe-line flows and distribute" effect in the perpendicular to direction of transfer to the range inconsistent that leads to the inside liquid level of each battery monomer reaction cavity in the pile to rise, the concrete expression does: (1) when the liquid is supplied in a single direction, the height of the liquid increases from one end of the water inlet to the other end, and (2) when the liquid is supplied in a double direction, the water inlet ends at the two ends are low, the middle part is high, and even the liquid level of electrolyte in the reaction cavity of a part of single batteries can not reach the overflow height, so that the electrolyte circulation can not be formed. In order to avoid this phenomenon, referring to fig. 4 again, in this embodiment, a spoiler 113 is disposed inside the water inlet 111 of the cell frame, and the spoiler 113 disturbs the electrolyte flowing in the water inlet butt-joint channel, so that the rising amplitude and the flow rate of the electrolyte level in the reaction chamber inside the cascade-stacked battery cells are finally made to be consistent.

In addition, in the stack in fig. 13, during the cascade lamination assembly process of the plurality of battery cells, an air inlet channel and an air outlet channel of the stack air supply system and an air flow channel between each battery cell are formed between the cell frames 1 of the battery cells, and the gas inlet 121 on the outermost side is connected to a gas conveying device to actively supply air to each metal air battery cell of the stack at positive pressure, so as to supply oxygen to the positive electrode 2, and the air outlet 122 realizes discharge and collection of air flow, so as to realize free circulation of air inside and outside the stack. Referring to fig. 4 again, reaction windows 100 are respectively arranged at positions of the reaction cavity inside the monomer frame 1 corresponding to two side faces of the monomer frame 1, a vent plate 22 is attached to the outer side of the anode 2, the anode 2 is tightly pressed and assembled on the side face of the monomer frame 1 through the vent plate 22, the reaction window 100 is covered and sealed, a circle of anode sealing ring 21 is assembled between the anode 2 and the monomer frame 1 at the periphery of the reaction window 100, the monomer frame 1 is provided with an anode sealing groove 107 for embedding the anode sealing ring at the periphery of the reaction window 100, sealing of electrolyte inside the reaction cavity 102 at the reaction window 100 is realized, the anode 2 can realize sealing of the electrolyte, and air can enter the anode and the reaction window 100 to provide oxygen for discharge reaction inside the reaction cavity.

Referring to fig. 9 and 10, after the positive electrode 2 and the vent plate 22 are assembled and fixed, the inner side surface of the positive electrode 2 contacts with the reaction region inside the cell frame, the vent plate 22 is provided with a vent window 221 exposing the positive electrode 2, the outer side surface of the vent plate 22 is provided with a plurality of vent grooves 222, and at least one end of each vent groove 222 is communicated with the vent window. The outer side of the vent plate 22 is provided with a circle of vent plate positioning holes 223, and the vent plate 22 is fixed with the single frame 1 through the vent plate positioning holes 223, so that the positive electrode 2 is tightly pressed and assembled.

As shown in fig. 10, the inside surface of the vent plate 22, which is close to the positive electrode 2, is a smooth plane to ensure that the surface of the positive electrode 2 is flattened, the vent window 221 on the vent plate 22 is located in the projection range of the cell internal reaction region on the positive electrode 2, in order to avoid the outward bulging and deformation of the positive electrode caused by the excessively large vacant area of the vent window 221, the vent window 221 is divided into a plurality of parts by a plurality of partition ribs, and the partition ribs are also provided with vent grooves for communicating the vent windows 221.

The vent grooves 222 arranged on the vent plate 22 are semicircular in cross section, the vent grooves 222 are arranged in the length direction and the width direction of the vent plate 22, namely the vent grooves 222 arranged in the width direction are arranged between the vent window 221 and the length side edge of the vent plate 22, the vent grooves 222 arranged in the length direction are arranged between the vent window 221 and the width side edge of the vent plate 22, and the vent grooves penetrate through the side edge of the vent plate and the side edge of the vent window, so that one end of each vent groove 222 is communicated with the vent window, the other end of each vent groove extends to the end face of the vent plate 22, in the stack formed by stacking a plurality of groups of single batteries, the single frames of adjacent single batteries are pressed and contacted through the vent plate 22, and the corresponding vent grooves 222 and the vent windows 221 on the vent plate 22 form airflow flow channels communicating the internal reaction area of the batteries with the external parts of the.

Referring to fig. 1 and 4 again, the cell frame 1 is further provided with an air inlet 121 and an air outlet 122, the air inlet 121 is located below the cell frame vent plate inside the cell, the air outlet 122 is located on both sides and above the cell frame vent plate inside the cell, the air inlet 121 and the air outlet 122 are respectively communicated with the vent grooves 222 on the vent plate 22 assembled on the cell frame 1, the air inlets 121 and the air outlets 122 of the cell main bodies 1 of adjacent cells in the cell stack are in one-to-one butt joint after the cells are cascaded, overlapped and spliced, so as to form continuous air inlet channels and air outlet channels inside the cell stack, the air inlet channels and the air outlet channels are independently separated and respectively communicated with air flow channels formed by the vent windows and the vent grooves between the vent plates 22 between the adjacent cells, so as to form an air supply channel network inside the whole cell stack, and the air inlet of the outermost cell is communicated with a gas conveying device with a gas, for example, the air pump conveys air flow to the air flow channels among the battery monomers through the air inlet channel, and then the air flow is discharged and collected through the air outlet channel, so that the free flow of air in the electric pile is realized, and the utilization efficiency of oxygen required by the reaction area in the battery is improved.

As shown in fig. 4 and 12, in the present embodiment, the air inlet 121 and the air outlet 122 are respectively located on the two cell frames of the cell internal reaction region, wherein the air inlet 121 is located on the cell frame below the vent plate 22, and the air outlet 122 is located on the two sides of the cell frame above the vent plate 22, because the vent plate 22 only covers the region where the positive electrode is located, the flow guide grooves 123 are provided on the outer side surfaces of the cell frames between the air inlet 121 and the bottom edge of the vent plate 22 and between the air outlet 122 and the top edge of the vent plate 22, so as to respectively communicate the air guide grooves on the vent plate 22 with the air inlet 121 and the. The air flow entering from the air inlet 121 enters the ventilation grooves 222 on the ventilation plate 22 through the flow guide grooves 123 at the bottom and enters the anode 2 through the ventilation windows 221 along the ventilation grooves 222, so as to ensure the continuous supply of oxygen required for the discharge reaction of the anode 2, and the flowing air flow partially directly exits the cell stack from the ventilation grooves 222 on both sides of the ventilation plate 22, and the other part enters the air outlet 122 from the ventilation grooves 222 on the upper part of the ventilation plate 22 through the upper flow guide grooves 123 and is collected through the air outlet channel.

The galvanic pile is cascaded the coincide through a plurality of battery monomer and is assembled, be equipped with the fixed through hole 131 who concatenates the battery monomer coincide on the battery monomer along the coincide orientation, and simultaneously, all link up the battery monomer setting along the free coincide orientation of battery with air inlet 121 and the gas vent 122 on the battery monomer, after the coincide assembly galvanic pile, between the fixed through hole 131, coaxial butt joint becomes complete passageway between air inlet 121 and the gas vent 122, wherein fixed through hole 131 passes through guide arm and connecting piece location locking galvanic pile, air inlet 121 and gas vent 122 form the inlet channel and the exhaust passage of air supply.

The above description is only for the purpose of illustrating the technical solutions of the present invention and not for the purpose of limiting the same, and other modifications or equivalent substitutions made by those skilled in the art to the technical solutions of the present invention should be covered within the scope of the claims of the present invention without departing from the spirit and scope of the technical solutions of the present invention.