阅读说明：本技术 一种有机-无机杂化高效协同阻燃成炭剂及其制备方法 (Organic-inorganic hybrid efficient synergistic flame-retardant char-forming agent and preparation method thereof ) 是由 吴唯 武文政 于 2020-11-25 设计创作，主要内容包括：本发明涉及应用于聚合物材料的大分子阻燃成炭剂技术领域,公开了一种有机-无机杂化高效协同成炭剂及其制备方法,其结构式如下所示。该成炭剂通过亲核取代,在不同温度下由对苯二甲胺将三聚氯氰上两个氯原子依次取代,形成一种由对苯二甲胺作为扩链剂的线性大分子三嗪中间体,随后升高温度,将已经通过羟基相连纳米水滑石和γ-氨丙基三乙氧基硅烷通过与对苯二甲胺和三聚氯氰取代方式相同的原理将中间体上侧基上的氯取代制得。该成炭剂具有成炭性好、分子量高、耐迁移、耐高温、不影响基体材料的力学性能特点,解决三嗪类衍生物作为成炭剂的抗迁移性能,进而导致无法形成致密性良好,形貌完整的成炭性能不佳的问题,应用于热塑性聚酯弹性体中。(The invention relates to the technical field of macromolecular flame-retardant char-forming agents applied to polymer materials, and discloses an organic-inorganic hybrid efficient synergistic char-forming agent and a preparation method thereof, wherein the structural formula of the organic-inorganic hybrid efficient synergistic char-forming agent is shown as follows. The carbon forming agent is prepared by sequentially substituting two chlorine atoms on cyanuric chloride by p-xylylenediamine at different temperatures through nucleophilic substitution to form a linear macromolecular triazine intermediate taking the p-xylylenediamine as a chain extender, then raising the temperature, and substituting chlorine on a side group on the intermediate by nano hydrotalcite and gamma-aminopropyltriethoxysilane which are connected through hydroxyl through the principle the same as the substitution mode of the p-xylylenediamine and the cyanuric chloride. The carbon forming agent has the characteristics of good carbon forming property, high molecular weight, migration resistance, high temperature resistance and no influence on the mechanical property of a matrix material, and solves the problem of the triazine derivativesThe preparation method is applied to the thermoplastic polyester elastomer for solving the problem that the carbonization performance with good compactness and complete appearance is not good due to the migration resistance of the carbonization agent.)

1. An organic-inorganic hybrid efficient synergistic charring agent, the molecular structural formula of which is:

2. the preparation method of the organic-inorganic hybrid efficient synergistic char-forming agent according to claim 1, characterized in that: the organic-inorganic hybrid efficient synergistic charring agent comprises the following raw materials and components: nano hydrotalcite, cyanuric chloride, p-xylylenediamine, triethylamine and gamma-aminopropyltriethoxysilane; the carbon forming agent is prepared by nucleophilic substitution, sequentially substituting two chlorine atoms on cyanuric chloride by p-xylylenediamine at different temperatures to form a linear macromolecular triazine intermediate with the p-xylylenediamine as a chain extender, then raising the temperature, and substituting chlorine on the side group of the intermediate by nano hydrotalcite and gamma-aminopropyltriethoxysilane which are connected through hydroxyl in the same way as the substitution mode of the p-xylylenediamine and the cyanuric chloride.

3. A method for preparing the organic-inorganic hybrid high-efficiency synergistic charring agent as claimed in claim 2, which is characterized in that: the preparation method comprises the following steps:

(1) adding cyanuric chloride into an acetone solvent, keeping the temperature of the system at 0-25 ℃ to completely dissolve the cyanuric chloride, simultaneously dissolving p-xylylenediamine and sodium hydroxide into deionized water, dropwise adding the p-xylylenediamine and the sodium hydroxide into the reaction system within 0.5-2 h, and keeping the reaction at 0-25 ℃ for 2.5-7 h after dropwise adding; after the reaction is finished, heating the reaction system to 40-60 ℃, and then dropwise adding the aqueous solution of p-xylylenediamine and sodium hydroxide into the reaction system again, wherein the dropwise adding time and the reaction time are controlled to be 0.5-3.5 h and 2.5-7 h respectively at the temperature; after the synthesized product is kept stand and filtered, washing the solid product by using deionized water and ethanol, and fully drying to prepare an intermediate;

(2) dispersing nano hydrotalcite and gamma-aminopropyltriethoxysilane in dioxane, keeping the reaction temperature of 80-95 ℃, continuously stirring for 10-30 h, heating to 85-120 ℃, adding an intermediate into the reaction system, uniformly stirring, dissolving triethylamine in the dioxane, dropwise adding the solution within 0.5-2 h, and keeping the reaction for 3-15 h after dropwise adding; and after the synthesized product is kept stand and filtered, washing the solid product by using deionized water and ethanol, and fully drying to prepare the nano hydrotalcite modified p-xylyl amino macromolecular triazine charring agent.

4. The method for preparing the organic-inorganic hybrid high-efficiency synergistic charring agent as claimed in claim 3, wherein: the mass ratio of the cyanuric chloride to the p-xylylenediamine to the sodium hydroxide is 2-3: 1: 1-2.

5. The method for preparing the organic-inorganic hybrid high-efficiency synergistic charring agent as claimed in claim 3, wherein: the mass ratio of the nano hydrotalcite to the gamma-aminopropyltriethoxysilane to the triethylamine to the intermediate is 0.5-1: 2-3: 0.5-1: 2-3.

Technical Field

The invention relates to the technical field of macromolecular flame-retardant char-forming agents applied to polymer materials, in particular to a novel organic-inorganic hybrid efficient synergistic flame-retardant char-forming agent and a preparation method thereof.

Background

Over the past few decades, halogen-containing Flame Retardants (FRs) have been widely used to limit the flammability of polymeric materials. However, the flame retardant process often has many negative effects, such as the generation of corrosive and toxic fumes or volatiles, which can be extremely harmful to the environment and human health. Therefore, halogen-free flame retardants, especially Intumescent Flame Retardants (IFR), can meet the requirements of various industries on personal safety and environmental protection due to their characteristics of being halogen-free, low-toxicity, droplet-inhibiting, high in flame-retardant efficiency, and low in preparation cost, and therefore, the synthesis of novel intumescent flame retardants and the design of intumescent flame retardant formulations are receiving more and more attention from research and development personnel.

The intumescent flame retardants are classified according to their action principle and can be classified into physical type and chemical type.

Physical intumescent flame retardants are generally referred to as Expandable Graphite (EG), which absorbs heat from the polymer combustion system and expands rapidly (up to 280 times its initial volume) and the expanded carbon residue forms a coating on the surface of the polymer. This layer of char can both hinder the transfer of heat, combustible gases and oxygen between the combustion zone and the polymer matrix; meanwhile, the carbon residue is attached to a melting area of the burning polymer, and also has the functions of preventing molten drops and slowing down the spread of fire, thereby having the function of flame retardance. However, EG as an intumescent flame retardant also has the following problems: firstly, EG hardly generates chemical reaction with polymer, the acting force between carbon layers is small, excessive expansion occurs during combustion, the formed carbon layers are often too loose and not compact enough, so-called 'popcorn effect' occurs, and the flame retardant effect may not reach the expectation; secondly, the expanded residual carbon is observed under a scanning electron microscope to be in a worm shape, gaps among carbon layers are large and not compact enough, and the flame retardant efficiency is not high; thirdly, the larger the particle size of EG is, the poorer the compatibility between EG and the polymer matrix is, and the mechanical properties of materials and the like are reduced. These problems directly affect the flame retardant effect of EG on polymers.

Chemical intumescent flame retardants often consist of three sources: an acid source, a carbon source, and a gas source. Commonly used acid sources consist of mineral acids and ammonium salts, such as diethyl aluminum hypophosphite, phosphates and borates, and the like; carbon sources are mainly hydroxyl-containing compounds such as polyhydric alcohols (sorbitol, pentaerythritol and dipentaerythritol), triazine derivatives, polyamides and the like; the air supply mainly comprises: melamine, urea, and urea-formaldehyde resins, and the like. Flame retardant principle of IFR: during combustion, the acid source releases inorganic acid substances containing phosphorus under the action of heat, the inorganic acid containing phosphorus can promote the carbon source to perform esterification and char formation, and simultaneously, the gas source decomposes to release a large amount of volatile gas, so that a molten substance formed between the acid source and the carbon source forms an expanded carbon foam protective layer on the surface of the polymer matrix under the action of the volatile gas, and the protective carbon layer can not only dilute the combustible gas, but also isolate the heat, oxygen and combustible substance from being transferred between a combustion area and the interior of the polymer.

The chemical intumescent flame retardant is widely applied due to the advantages of no halogen and strong char-forming performance. However, the small-molecule char-forming agent in the traditional IFR system has the defects of low flame retardant efficiency and poor thermal stability. This has forced more and more researchers to focus on how to enhance the char-forming capability of IFR systems. The triazine diffractometer mainly comprises H, C, N and three elements, and a stable triazine ring structure is also present in the molecular structure of the triazine diffractometer, so that the triazine diffractometer can simultaneously play the roles of a gas source and a carbon source in the combustion process. Therefore, the development of new triazine-based char-forming agents is still one of the important research directions for realizing high-efficiency intumescent flame retardant. Cyanuric chloride, because of its high selectivity, is often used as a raw material for the synthesis of a series of triazine-based char-forming agents. Although the charring agent mainly comprising the triazine derivative has many advantages compared with other charring agents, the charring agent is easy to migrate to the surface of a polymer due to the reasons of small molecular weight and the like, and the problems of low flame retardant efficiency, poor thermal stability and poor charring performance exist all the time, so that a charcoal layer with good appearance cannot be generated in required time, and efficient coordination of three sources cannot be realized. The nanometer hydrotalcite serving as a common inorganic flame-retardant synergist has a synergistic flame-retardant effect with IFR, but has poor compatibility with polymers, is difficult to uniformly disperse in a polymer matrix, and seriously influences the synergistic flame-retardant effect of the nanometer hydrotalcite and the IFR in polymer materials. The above problems ultimately lead to unsatisfactory flame retardant effects.

Because the quality of the expanded carbon layer greatly influences the flame retardant efficiency of the IFR in the polymer material, and the quality of the expanded carbon layer is closely related to the property of the carbon forming agent, two important research directions for improving the carbon forming performance of the carbon forming agent and simultaneously improving the flame retardant efficiency of the IFR by using the synergist are provided.

Disclosure of Invention

In order to overcome the defects of the prior art, the invention provides the following technical scheme: an organic-inorganic hybrid efficient synergistic charring agent, the molecular structural formula of which is:

further, the organic-inorganic hybrid efficient synergistic charring agent comprises the following raw materials and components: nano hydrotalcite, cyanuric chloride, p-xylylenediamine, triethylamine and gamma-aminopropyltriethoxysilane.

The preparation method of the organic-inorganic hybrid efficient synergistic charring agent comprises the following steps:

(1) adding cyanuric chloride into an acetone solvent, keeping the temperature of the system at 0-25 ℃ to completely dissolve the cyanuric chloride, simultaneously dissolving p-xylylenediamine and sodium hydroxide into deionized water, dropwise adding the p-xylylenediamine and the sodium hydroxide into the reaction system within 0.5-2 h, and keeping the reaction at 0-25 ℃ for 2.5-7 h after the dropwise adding is finished. After the reaction is finished, heating the reaction system to 40-60 ℃, and then dropwise adding the aqueous solution of p-xylylenediamine and sodium hydroxide into the reaction system again, wherein the dropwise adding time and the reaction time are controlled to be 0.5-3.5 hours and 2.5-7 hours respectively at the temperature. Finally, after the synthesized product is kept stand and filtered, washing the solid product by using deionized water and ethanol, and fully drying to prepare an intermediate;

(2) dispersing nano hydrotalcite and gamma-aminopropyltriethoxysilane in dioxane, keeping the reaction temperature of 80-95 ℃, continuously stirring for 10-30 h, heating to 85-120 ℃, adding an intermediate into the reaction system, uniformly stirring, dissolving triethylamine in the dioxane, dropwise adding the solution within 0.5-2 h, and keeping the reaction for 3-15 h after dropwise adding; and after the synthesized product is kept stand and filtered, washing the solid product by using deionized water and ethanol, and fully drying to prepare the nano hydrotalcite modified p-xylyl amino macromolecular triazine charring agent.

Preferably, the mass ratio of the cyanuric chloride to the p-xylylenediamine to the sodium hydroxide is 2-3: 1: 1-2.

Preferably, the mass ratio of the nano hydrotalcite to the gamma-aminopropyltriethoxysilane to the triethylamine to the intermediate is 0.5-1: 2-3: 0.5-1: 2-3.

The invention organically modifies the nano hydrotalcite with the organic modifier (triazine-based macromolecule) with high flame retardance by a chemical synthesis method to synthesize a novel organic-inorganic hybrid efficient synergistic charring agent.

Compared with the prior art, the invention has the following beneficial technical effects:

the novel organic-inorganic hybrid efficient synergistic charring agent is prepared by sequentially substituting two chlorine atoms on cyanuric chloride by p-xylylenediamine at different temperatures through nucleophilic substitution to form a linear macromolecular triazine intermediate taking the p-xylylenediamine as a chain extender, then raising the temperature, and substituting chlorine on the side group on the intermediate by nano hydrotalcite and gamma-aminopropyltriethoxysilane which are connected through hydroxyl groups according to the principle the same as the substitution mode of the p-xylylenediamine and the cyanuric chloride.

The nano hydrotalcite of the novel triazine-based macromolecular charring agent with the efficient catalytic charring function can promote in-situ catalytic charring reaction of triazine-based macromolecules, and can form an expanded charcoal layer capable of isolating heat and combustible gas transmission on the surface of a polymer through esterification and charring reaction with an acid source. Meanwhile, the viscous glass melt generated by the interaction between the decomposition product of the acid source and the nano hydrotalcite can bond the carbon layer on the surface of the polymer, so that the compactness and the thermal stability of the carbon layer can be improved. Not only reduces the generation of combustible gas, but also improves the barrier property of the barrier layer. The compact carbon layer with good thermal stability greatly promotes the flame-retardant efficiency of a three-source expansion flame-retardant system, so that a barrier layer formed on the surface of a polymer melt has a certain inhibiting effect on the mass and heat transfer process between a condensed phase and a gas phase, and the char forming performance of the char forming agent is greatly improved. Through the synergistic effect between the nano hydrotalcite and the intumescent flame retardant system, the flame retardant property of the polymer material is obviously improved, the char forming agent has the characteristics of good char forming property, high molecular weight, migration resistance, high temperature resistance, no influence on the mechanical property of a base material and the like, and the problems that the triazine derivatives as the char forming agent have good migration resistance, so that the char forming agent cannot form good compactness and has complete appearance and poor char forming property are solved, and the specific mechanism is shown in fig. 1.

Drawings

FIG. 1 is a schematic diagram of the flame retardant mechanism of the organic-inorganic hybrid efficient synergistic char-forming agent of the present invention.

Detailed Description

Preferred embodiments of the present invention are explained below. It should be understood that the preferred embodiments described herein are for purposes of illustration and explanation only and are not intended to limit the present invention.

Examples 1 to 15

(1) Examples 1 to 15 were carried out by changing the contents of three chemically synthesized components of cyanuric chloride, p-xylylenediamine and nano-hydrotalcite as shown in table 1, sequentially synthesizing the novel organic-inorganic hybrid high-efficiency synergistic charring agent, and using thermoplastic polyester elastomer (TPEE) as an application object, and preparing 15 novel organic-inorganic hybrid high-efficiency synergistic charring agents and TPEE sequentially synthesized into a flame retardant TPEE material.

TABLE 1 summary of contents of different components in synthesis of novel organic-inorganic hybrid efficient synergistic char-forming agent

(2) The following procedures and conditions were carried out in sequence according to the contents of the components in Table 1: adding cyanuric chloride and 200mL of acetone into a 500mL flask, keeping the system temperature at 0-25 ℃ to completely dissolve the cyanuric chloride, simultaneously dissolving p-xylylenediamine and 4.00g of sodium hydroxide into 20mL of deionized water, dropwise adding the dissolved p-xylylenediamine into the reaction system within 0.5-2 h, and keeping the reaction at 0-25 ℃ for 2.5-7 h after dropwise adding. After the reaction is finished, heating the reaction system to 40-60 ℃, and then dropwise adding an aqueous solution of p-xylylenediamine (the addition amount of the p-xylylenediamine is the same in two times) and sodium hydroxide (4.00g) into the reaction system again, wherein the dropwise adding time and the reaction time are controlled to be 0.5-3.5 hours and 2.5-7 hours respectively at the temperature. And finally, after standing and filtering the synthesized product, alternately washing the product for 3 times by using ethanol and deionized water, and drying the product in a vacuum oven at 70 ℃ for 12 hours to obtain 15 intermediates.

(3) The 15 intermediates obtained in the previous step are sequentially operated according to the following same method and conditions: dispersing nano hydrotalcite and 11.07g of KH550 in 300mL of dioxane, keeping the reaction temperature of 80-95 ℃ and continuously stirring for 10-30 h, heating to 85-120 ℃, adding 10g of intermediate into the reaction system, uniformly stirring, dissolving 5.06g of triethylamine in 25mL of 1, 4-dioxane, dropwise adding into the solution within 0.5-2 h, and keeping the reaction for 3-15 h after dropwise adding. After the reaction is finished, filtering the obtained solid, alternately washing the solid for 3 times by using distilled water and ethanol, and drying the solid for 24 hours at the temperature of 80 ℃ to obtain 15 novel organic-inorganic hybrid efficient synergistic charring agents MCA-SiO₂。

(4) Before a thermoplastic polyester elastomer (TPEE), diethyl aluminum hypophosphite and a novel triazine-based macromolecular charring agent with an efficient catalytic charring function are used, the thermoplastic polyester elastomer (TPEE), the diethyl aluminum hypophosphite and the novel triazine-based macromolecular charring agent are placed in an oven at 70 ℃ to be dried for 8 hours. Based on 100 parts by mass of TPEE, 16 parts by mass of diethyl aluminum hypophosphite and MCA-SiO₂4 parts by mass are respectively weighed. TPEE is added into a torque rheometer (the set temperature and the set rotating speed are respectively 175 ℃ and 50r/min) to be heated and melted for 2min, and then premixed diethyl aluminum hypophosphite and MCA-SiO are added₂And banburying for 6 min. Placing the internal mixed sample into a mold for testing the size specification, placing the internal mixed sample into a flat vulcanizing machine with the set temperature of 180 ℃ for preheating for 3min, maintaining the pressure for 4min, and naturally cooling to room temperature to obtain 15 kinds of internal mixed samplesTPEE/diethyl aluminum hypophosphite/MCA-SiO₂Flame retardant material analysis test required standard sample bars.

Examples 16 to 20

(1) In examples 16 to 20, the novel organic-inorganic hybrid efficient synergistic charring agent was synthesized with the addition amount of cyanuric chloride being 18g, the addition amounts of p-xylylenediamine being 3.05g for both times and the addition amount of nano-hydrotalcite being 1 g.

(2) Adding cyanuric chloride and 200mL of acetone into a 500mL flask, keeping the system temperature at 0-25 ℃ to completely dissolve the cyanuric chloride, simultaneously dissolving p-xylylenediamine and 4.00g of sodium hydroxide into 20mL of deionized water, dropwise adding the dissolved p-xylylenediamine into the reaction system within 0.5-2 h, and keeping the reaction at 0-25 ℃ for 2.5-7 h after dropwise adding. After the reaction is finished, heating the reaction system to 40-60 ℃, and then dropwise adding an aqueous solution of p-xylylenediamine (the addition amount of the p-xylylenediamine is the same in two times) and sodium hydroxide (4.00g) into the reaction system again, wherein the dropwise adding time and the reaction time are controlled to be 0.5-3.5 hours and 2.5-7 hours respectively at the temperature. And finally, after the synthesized product is kept stand and filtered, alternately washing the synthesized product for 3 times by using ethanol and deionized water, and drying the product in a vacuum oven at 70 ℃ for 12 hours to obtain an intermediate.

(3) Dispersing nano hydrotalcite and 11.07g of KH550 in 300mL of dioxane, keeping the reaction temperature of 80-95 ℃ and continuously stirring for 10-30 h, heating to 85-120 ℃, adding 10g of intermediate into the reaction system, uniformly stirring, dissolving 5.06g of triethylamine in 25mL of 1, 4-dioxane, dropwise adding into the solution within 0.5-2 h, and keeping the reaction for 3-15 h after dropwise adding. After the reaction is finished, filtering the obtained solid, alternately washing the solid for 3 times by using distilled water and ethanol, and drying the solid for 24 hours at the temperature of 80 ℃ to obtain 15 novel organic-inorganic hybrid efficient synergistic charring agents MCA-SiO₂。

(4) Before a thermoplastic polyester elastomer (TPEE), diethyl aluminum hypophosphite and a novel triazine-based macromolecular charring agent with an efficient catalytic charring function are used, the thermoplastic polyester elastomer (TPEE), the diethyl aluminum hypophosphite and the novel triazine-based macromolecular charring agent are placed in an oven at 70 ℃ to be dried for 8 hours. TPEE, aluminum diethylphosphinate and MCA-SiO as shown in Table 2₂The proportions of the three components are respectively weighed, TPEE is added into the mixture firstlyHeating and melting in a rectangular rheometer (setting temperature and rotation speed at 175 deg.C and 50r/min respectively) for 2min, and adding pre-mixed diethyl aluminum hypophosphite and MCA-SiO₂And banburying for 6 min. Placing the internally mixed sample into a mold for testing the dimension specification, placing the mold in a plate vulcanizing machine with the set temperature of 180 ℃ for preheating for 3min, maintaining the pressure for 4min, and naturally cooling to room temperature to obtain 5 TPEE/diethyl aluminum hypophosphite/MCA-SiO₂Flame retardant material analysis test required standard sample bars.

TABLE 2 summary of components and content of flame retardant TPEE composite

Comparative example 1

Before the thermoplastic polyester elastomer (TPEE) is used, the thermoplastic polyester elastomer is dried in an oven at 70 ℃ for 8 hours and then weighed according to 100 parts by mass of the thermoplastic polyester elastomer. First, a thermoplastic polyester elastomer was heated and melted for 2min in a torque rheometer (set temperature and rotation speed were 175 ℃ and 50r/min, respectively), and then a premixed flame retardant was added and banburying was carried out for 6 min. And (3) placing the internally mixed sample into a mold with a test size specification, placing the mold into a flat vulcanizing machine with a set temperature of 180 ℃ for preheating for 3min, maintaining the pressure for 4min, and naturally cooling to room temperature to obtain the standard sample strip required by the analysis test.

Comparative example 2

Before using the thermoplastic polyester elastomer (TPEE) and the aluminum diethylhypophosphite, the thermoplastic polyester elastomer (TPEE) and the aluminum diethylhypophosphite are placed in an oven at 70 ℃ for drying for 8 hours, and then 100 parts by mass of the thermoplastic polyester elastomer and 20 parts by mass of the aluminum diethylhypophosphite are weighed. First, a thermoplastic polyester elastomer was heated and melted for 2min in a torque rheometer (set temperature and rotation speed were 175 ℃ and 50r/min, respectively), and then a premixed flame retardant was added and banburying was carried out for 6 min. And (3) placing the internally mixed sample into a mold with a test size specification, placing the mold into a flat vulcanizing machine with a set temperature of 180 ℃ for preheating for 3min, maintaining the pressure for 4min, and naturally cooling to room temperature to obtain the standard sample strip required by the analysis test.

Effect verification:

the standard samples obtained in examples 1, 2, 3, 4, 5, 6, 7, 8, 9, 10, 11, 12, 13, 14, 15, 16, 17, 18, 19, 20, 1, and 2 were subjected to a vertical burning test in accordance with GB/T2408-₂The thermogravimetric analysis was carried out at a flow rate of 40ml/min, starting from 15 ℃ and increasing to 700 ℃ at a heating rate of 5 ℃/min. The test results are shown in table 3.

TABLE 3 test results of flame retardancy and mechanical properties of standard samples of various examples

The invention has many applications, and the above description is only a preferred embodiment of the invention. It should be noted that the above examples are only for illustrating the present invention, and are not intended to limit the scope of the present invention. It will be apparent to those skilled in the art that various modifications can be made without departing from the principles of the invention and these modifications are to be considered within the scope of the invention.