阅读说明：本技术 噻吩并-茚并-单体和聚合物 (Thieno-indeno-monomers and polymers ) 是由 陈虎 W·张 M·胡尔汉吉 I·麦卡洛克 P·哈约兹 D·克尔布莱因 于 2017-12-06 设计创作，主要内容包括：本发明涉及聚合物,其包含至少一个式1或1’的单元,和式2或2’的化合物,其中在式1、1’、2和2’中,n是0、1、2、3或4,m是0、1、2、3或4,M1和M2互相独立地是芳族或杂芳族的单环或双环体系；X在每次出现时是选自O、S、Se或Te；Q在每次出现时是选自C、Si或Ge；R在每次出现时是选自氢,C<Sub>1-100</Sub>烷基,C<Sub>2-100</Sub>链烯基,C<Sub>2-100</Sub>炔基,C<Sub>5-12</Sub>环烷基,C<Sub>6-18</Sub>芳基,5至20员杂芳基,C(O)-C<Sub>1-100</Sub>烷基,C(O)-C<Sub>5-12</Sub>环烷基和C(O)-OC<Sub>1-100</Sub>烷基。R<Sup>2</Sup>、R<Sup>2’</Sup>、R<Sup>2”</Sup>、R<Sup>*</Sup>在每次出现时是独立地选自氢,C<Sub>1-30</Sub>烷基,C<Sub>2-30</Sub>链烯基,C<Sub>2-30</Sub>炔基,C<Sub>5-12</Sub>环烷基,C<Sub>6-18</Sub>芳基,5至20员杂芳基,OR<Sup>21</Sup>,OC(O)-R<Sup>21</Sup>,C(O)-OR<Sup>21</Sup>,C(O)-R<Sup>21</Sup>,NR<Sup>21</Sup>R<Sup>22</Sup>,NR<Sup>21</Sup>-C(O)R<Sup>22</Sup>,C(O)-NR<Sup>21</Sup>R<Sup>22</Sup>,N[C(O)R<Sup>21</Sup>][C(O)R<Sup>22</Sup>],SR<Sup>21</Sup>,卤素,CN,SiR<Sup>Sis</Sup>R<Sup>Sit</Sup>R<Sup>Siu</Sup>和OH；L<Sup>1</Sup>和L<Sup>2</Sup>互相独立地和在每次出现时是选自C<Sub>6-30</Sub>亚芳基、5至30员亚杂芳基、(A)、(B)和(C)。<Image he="801" wi="700" file="DDA0002085331730000011.GIF" imgContent="drawing" imgFormat="GIF" orientation="portrait" inline="no"></Image><Image he="319" wi="700" file="DDA0002085331730000021.GIF" imgContent="drawing" imgFormat="GIF" orientation="portrait" inline="no"></Image>(The present invention relates to polymers comprising at least oneA unit of formula 1 or 1 ', and a compound of formula 2 or 2', wherein in formulae 1,1 ', 2 and 2', n is 0, 1,2, 3 or 4, M1 and M2 are, independently of one another, an aromatic or heteroaromatic, monocyclic or bicyclic ring system; x, at each occurrence, is selected from O, S, Se or Te; q at each occurrence is selected from C, Si or Ge; r is selected at each occurrence from hydrogen, C 1‑100 alkyl radical, C 2‑100 Alkenyl radical, C 2‑100 Alkynyl, C 5‑12 cycloalkyl radical, C 6‑18 Aryl, 5-to 20-membered heteroaryl, C (O) -C 1‑100 Alkyl radical, C (O) -C 5‑12 Cycloalkyl and C (O) -OC 1‑100 An alkyl group. R 2 、R 2' 、R 2” 、R * Independently at each occurrence, is selected from hydrogen, C 1‑30 Alkyl radical, C 2‑30 Alkenyl radical, C 2‑30 Alkynyl, C 5‑12 Cycloalkyl radical, C 6‑18 Aryl, 5-to 20-membered heteroaryl, OR 21 ，OC(O)‑R 21 ，C(O)‑OR 21 ，C(O)‑R 21 ，NR 21 R 22 ，NR 21 ‑C(O)R 22 ，C(O)‑NR 21 R 22 ，N[C(O)R 21 ][C(O)R 22 ]，SR 21 Halogen, CN, SiR Sis R Sit R Siu And OH; l is 1 And L 2 Independently of each other and at each occurrence is selected from C 6‑30 Arylene, 5-to 30-membered heteroarylene, (A), (B) and (C).)