阅读说明：本技术 一种连续折叠式减振拉胀纺织复合材料的加工装置与方法 (Device and method for processing continuous folding type vibration-damping and auxetic textile composite material ) 是由 杜赵群 顾龙鑫 刘倬然 刘一铭 陈韦韦 顾婧 朱秋雨 苏玛艳·阿力甫 邵一怡 梅忠 于 2021-08-13 设计创作，主要内容包括：本发明公开了一种连续折叠式减振拉胀纺织复合材料的加工装置与方法。所述装置包括铰链板及其两侧带有刻度的泡沫板；所述铰链板由多块铰链板片活动连接而成,铰链板片的边缘设有多个间隔布置且同轴排列的套,一侧两端的套通过钉二与泡沫板连接,相邻两片铰链板片的套相互交错为同轴布置并通过钉一连接。加工方法为：将双面胶粘在铰链板的外表面,然后铺上布,以手糊成型方法将树脂刷在布上,固定后取下；按照同样方式对布的另一面进行复合处理。该复合材料具备优异的抗缓冲性能、能量吸收性能、抗压缩性能等,可以用在运动员护板、防弹防刺服、头盔、装甲车、减震器等体育商品中。(The invention discloses a device and a method for processing a continuous folding type vibration-damping and auxetic textile composite material. The device comprises a hinge plate and foam plates with scales on two sides of the hinge plate; the hinge plate is formed by movably connecting a plurality of hinge plate pieces, a plurality of sleeves which are arranged at intervals and are coaxially arranged are arranged at the edge of each hinge plate piece, the sleeves at two ends of one side are connected with the foam board through nails II, and the sleeves of two adjacent hinge plate pieces are mutually staggered and coaxially arranged and are connected through nails I. The processing method comprises the following steps: adhering double-sided adhesive on the outer surface of the hinge plate, then laying cloth, brushing resin on the cloth by a hand lay-up forming method, and taking down the cloth after fixing; the other side of the cloth is subjected to composite treatment in the same manner. The composite material has excellent anti-buffering performance, energy absorption performance, compression resistance and the like, and can be used in sports goods such as sportsman guard plates, bulletproof and stab-resistant clothes, helmets, armored vehicles, shock absorbers and the like.)

1. A continuous folding type processing device for damping, pulling and expanding textile composite materials is characterized by comprising a hinge plate (1) and foam plates (2) with scales on two sides of the hinge plate; the hinge plate (1) is formed by movably connecting a plurality of hinge plate pieces, a plurality of sleeves (12) which are arranged at intervals and are coaxially arranged are arranged at the edge of each hinge plate piece, the sleeves (12) at two ends of one side are connected with the foam plate (2) through a nail II (13), and the sleeves (12) of two adjacent hinge plate pieces are mutually staggered and coaxially arranged and are connected through a nail I (11).

2. An asymmetric continuous folding, shock absorbing auxetic textile composite material processing device according to claim 1, characterized in that said foam board (2) is a starch-based foam, a lignin-based foam, a protein-based foam or a cellulose-based foam.

3. A processing method of a continuous folding type vibration-damping and auxetic textile composite material is characterized in that corresponding hinge plate pieces are selected according to the size of a required product and combined into a corresponding hinge plate (1), the hinge plate (1) is opened at the same angle according to the folding angle of the product, double-sided glue is adhered to the outer surface of the hinge plate (1), then cloth is laid, resin is brushed on the cloth by a hand pasting forming method, and the cloth is taken down after being fixed; the other side of the cloth is also brushed with resin in the same way for composite treatment.

4. The method as claimed in claim 3, wherein the continuous folding type vibration-damping and auxetic textile composite material is formed by connecting a plurality of folding units in sequence, the folding units are symmetrical or asymmetrical, and the cross-sectional structure is a concave hexagonal folding structure, a double-arrow folding structure, a star folding structure or a combination of the folding structures.

5. A method of manufacturing a continuous folded, shock absorbing auxetic textile composite material according to claim 3, characterized in that the circular arc or bend of the continuous folded, shock absorbing auxetic textile composite material is soft textile material (32) and the flat portion is hard textile material (31).

6. The method of claim 5, wherein the hard textile material (31) comprises a matrix and a reinforcement, and the matrix is made of at least one of epoxy resin composite, unsaturated polyester resin composite, phenolic resin composite, vinyl ester composite, polyvinyl ester composite, polyimide composite, bismaleimide composite, polybenzimidazole composite, polyetheretherketone composite, polycarbonate composite, polysulfone composite, polyphenylene sulfide composite, and polyetheretherketone composite; the reinforcement is made of a non-woven fabric composite material, a knitted fabric composite material, a woven fabric composite material or a braided fabric composite material; the fiber type of the hard textile material (31) is aramid fiber composite material, ultra-high molecular weight polyethylene fiber composite material, carbon fiber composite material, glass fiber composite material, basalt fiber composite material, ceramic fiber composite material, polyphenylene sulfide fiber composite material, PBO fiber composite material, M5 fiber composite material, cotton, wool, silk, hemp, regenerated fiber composite material, differential fiber composite material or functional fiber composite material; the number of composite layers of the hard textile material (31) is single layer or multiple layers.

7. A process for the manufacture of a continuous, folded, shock absorbing auxetic textile composite material according to claim 5, characterised in that the soft textile material (32) is a polyurethane, silicone rubber, acrylate, neoprene, polyamide, polyolefin or styrenic thermoplastic elastomer.

8. A method of manufacturing a continuously folded, shock absorbing auxetic textile composite material according to any of the claims 4-7, characterized in that a manufacturing device for a continuously folded, shock absorbing auxetic textile composite material is used, which comprises a flap (1) and its foam panels (2) with scales on both sides; the hinge plate (1) is formed by movably connecting a plurality of hinge plate pieces, a plurality of sleeves (12) which are arranged at intervals and are coaxially arranged are arranged at the edge of each hinge plate piece, the sleeves (12) at two ends of one side are connected with the foam plate (2) through a second nail (13), the sleeves (12) of two adjacent hinge plate pieces are mutually staggered to be coaxially arranged and are connected through a first nail (11), and the processing method comprises the following steps:

step 1): selecting hinge plate pieces according to the size of a product to be produced, opening the hinge plate (1) by a corresponding angle according to the folding angle of the product by taking a protractor and ruler scales on the foam plate (2) as reference bases, and connecting two ends of the outermost side of the hinge plate (1) with the foam plate (2) through a second nail (13);

step 2): brushing the whole combined hinge plate (1) flat by using double-sided adhesive and paper scraps;

step 3): placing the cloth on the processed hinge plate (1), and pulling the cloth to be flat under the fixing action of the double-sided adhesive tape; then, brushing hard resin on the cloth with a rod structure in a hand pasting forming mode, and sticking the arc part/the bent part by using a transparent adhesive tape in order to prevent the resin from diffusing to the arc part/the bent part; after the rod part structure is fixed, compounding the arc part/the bending part; after the whole process is finished, the other side of the cloth is subjected to the same composite treatment in the same way.

Technical Field

The invention relates to a device and a method for processing a continuous folding type vibration-damping and auxetic textile composite material, belonging to the field of textile materials and technologies.

Background

"auxetic materials", also known as "negative poisson's ratio materials", differ from traditional positive poisson's ratio materials in that they expand laterally when stretched longitudinally; when compressed longitudinally, a pinching effect occurs in the transverse direction. Below the pressure point, the conventional material collapses and thins, while the "auxetic material" compresses and hardens more quickly. The material actually becomes thicker, rather than thinner, when stretched. One of the structural properties of the auxetic material is improved by the indentation resistance. When the material is impacted, the "flow" and density of the material in the impacted area increases for non-auxetic materials, resulting in a decrease in the stiffness of the material. But for a dilatant material, the impact causes expansion of the material in the surrounding area, which action results in an increase in the density of the material below the impact. As a result, the hardness (indentation resistance, H) of the material increases to resist impact ". In recent years, researchers have noticed that even if a pomelo falls from a high place, the pomelo cannot crack, and the pulp is hardly damaged, because the honeycomb-shaped pomelo peel has good impact resistance, and the self-weight is light, which is equivalent to a self-damping effect, and the structure of the pomelo peel is called as an "auxetic material" in materials science.

Researchers in BMW groups improve the layered structure and the fiber trend in the existing fiber composite material according to the principle structure of the 'auxetic material' of the grapefruit, produce a new material with excellent protection effect, and creatively combine the functions of anti-collision, anti-impact, shock absorption and the like. The results of current research have been beyond expectations, with new materials being lighter, stronger, more stable than those currently used, with performance improvements of up to 20%. The innovative material can be produced and processed in an economic way, and has good industrial production application prospect.

With the continuous development of science and technology, new materials come out one after another, and composite materials required in the fields of bulletproof, aviation, navigation and the like are changed from initial metal materials, polyamide composite materials, glass fiber composite materials and the like to ultrahigh molecular weight polyethylene fiber composite materials, high-strength high-modulus carbon fiber composite materials, aramid fiber composite materials and the like. The high-performance fiber is mainly applied to materials in special fields in four types of one-dimensional fiber, two-dimensional fabric, three-dimensional fabric and weftless fabric.

The application of the negative Poisson's ratio effect to the fields of bulletproof, stab-resistant, earthquake-resistant, noise-reducing, marine navigation and the like is a great development trend in the future. The folding type auxetic textile composite material prepared by the invention not only has excellent mechanical property and noise reduction function, but also has the advantages of light weight and ventilation, can save energy consumption when being used in the field of aerospace, and can enable athletes to freely move when being used in sports goods. Helmets made with the composite material of the invention weigh much less than conventional products on the market, but provide the same level of protection.

At present, most of foams in China market are petroleum-based foams such as Polyethylene (PE), polypropylene (PP), Polystyrene (PS), polyvinyl chloride (PVC), polyethylene terephthalate (PET) and the like, and the foams are widely applied to packaging of industrial products such as electronics, precision equipment and the like and living goods. However, these petroleum-based foam packaging materials are difficult to degrade and have been used in some foreign restrictions. In addition, the raw materials for the preparation of these foamed packaging materials are derived from petroleum, which is a non-renewable energy source. With the development and utilization of people being increasingly reduced, the search for new materials to replace petroleum-based foam packaging materials is urgent.

The biomass foam packaging material has the advantages of rich sources, reproducibility, degradability and the like. Therefore, the adoption of biomass materials instead of petroleum-based materials in the field of packaging has become a hot spot of research in various countries. The foam used in the invention does not need to have excellent mechanical properties, and is discarded after being used for a certain number of times, so that degradable biological foam is selected.

Disclosure of Invention

The technical problem to be solved by the invention is as follows: provides an asymmetric continuous folding type vibration-damping auxetic textile composite material.

In order to solve the technical problem, the invention provides a processing device of a continuous folding type vibration-damping and auxetic textile composite material, which comprises a hinge plate and foam plates with scales on two sides of the hinge plate; the hinge plate is formed by movably connecting a plurality of hinge plate pieces, a plurality of sleeves which are arranged at intervals and are coaxially arranged are arranged at the edge of each hinge plate piece, the sleeves at two ends of one side are connected with the foam board through nails II, and the sleeves of two adjacent hinge plate pieces are mutually staggered and coaxially arranged and are connected through nails I.

Preferably, the foam board is a starch-based foam, a lignin-based foam, a protein-based foam, or a cellulose-based foam.

The invention also provides a processing method of the continuous folding type vibration-damping and auxetic textile composite material, which comprises the steps of selecting corresponding hinge plate pieces according to the size of a required product and combining the hinge plate pieces into a corresponding hinge plate, opening the hinge plate at the same angle according to the folding angle of the product, gluing double-sided glue on the outer surface of the hinge plate, then laying cloth, brushing resin on the cloth by a hand lay-up forming method, fixing and taking down the cloth; the other side of the cloth is also brushed with resin in the same way for composite treatment. The folding type auxetic textile composite material has excellent anti-buffering performance, energy absorption performance, compression resistance and the like, and can be used in bulletproof, explosion-proof and stab-resistant helmets, gloves and clothes, armored vehicles, energy absorption buffers, shock absorbers, submarine power equipment cabin sections, deep sea compression resistance, vibration reduction of a real ship main engine, automobile sound absorption boxes, sports shoe soles, football player guard plates, racing driver helmets, skiing and bicycle helmets and other sports goods.

Preferably, the continuous folding type vibration-damping and auxetic textile composite material is formed by sequentially connecting a plurality of folding units, the folding units are of symmetrical structures or asymmetrical structures, and the cross-sectional structures of the folding units are concave hexagonal folding structures, double-arrow folding structures, star folding structures or the combination of the folding structures.

Preferably, the circular arc part or the bending part of the continuous folding type vibration-damping and auxetic textile composite material is made of a soft textile material, and the plane part is made of a hard textile material.

More preferably, the hard textile material comprises a matrix and a reinforcement, wherein the matrix is made of at least one of an epoxy resin composite material, an unsaturated polyester resin composite material, a phenolic resin composite material, a vinyl ester composite material, a polyvinyl ester composite material, a polyimide composite material, a bismaleimide composite material, a polybenzimidazole composite material, a polyether-ether-ketone composite material, a polycarbonate composite material, a polysulfone composite material, a polyphenylene sulfide composite material and a polyether-ether-ketone composite material; the reinforcement is made of a non-woven fabric composite material, a knitted fabric composite material, a woven fabric composite material or a braided fabric composite material; the fiber type of the hard textile material is aramid fiber composite material, ultra-high molecular weight polyethylene fiber composite material, carbon fiber composite material, glass fiber composite material, basalt fiber composite material, ceramic fiber composite material, polyphenylene sulfide fiber composite material, PBO fiber composite material, M5 fiber composite material, cotton, wool, silk, hemp, regenerated fiber composite material, differential fiber composite material or functional fiber composite material; the composite layer number of the hard textile material is single layer or multi-layer.

More preferably, the soft textile material is polyurethane, silicon rubber, acrylate, chloroprene rubber, polyamide, polyolefin or styrene thermoplastic elastomer.

Preferably, a continuous folding type processing device for damping vibration and expanding the textile composite material is adopted, and comprises a hinge plate and foam plates with scales on two sides of the hinge plate; the hinge plate is formed by movably connecting a plurality of hinge plate pieces, a plurality of sleeves which are arranged at intervals and are coaxially arranged are arranged at the edge of each hinge plate piece, the sleeves at two ends of one side are connected with the foam board through nails II, the sleeves of two adjacent hinge plate pieces are mutually staggered to be coaxially arranged and connected through nails I, and the processing method comprises the following steps:

step 1): selecting a hinge plate sheet according to the size of a product to be produced, opening the hinge plate by a corresponding angle according to the folding angle of the product by taking the protractor and ruler scales on the foam plate as reference, and connecting two ends of the outermost side of the hinge plate with the foam plate through a second nail;

step 2): brushing the whole combined hinge plate flat by using double-sided adhesive and paper scraps;

step 3): placing the cloth on the processed hinge plate, and pulling the cloth to be flat under the fixing action of the double-sided adhesive tape; then, brushing hard resin on the cloth with a rod structure in a hand pasting forming mode, and sticking the arc part/the bent part by using a transparent adhesive tape in order to prevent the resin from diffusing to the arc part/the bent part; after the rod part structure is fixed, compounding the arc part/the bending part; after the whole process is finished, the other side of the cloth is subjected to the same composite treatment in the same way.

The preparation method is simple, and the production technology is easy to master: the corresponding hinge plate pieces are combined according to the required product size, the hinge plates are opened at a certain angle according to the folding angle of the product, the hinge plates are fixed on the plate, double sides of the hinge plates are glued on the outer surfaces of the hinge plates, the hinge plates are glued flat, cloth is laid, resin is brushed on the cloth in a hand lay-up forming method, and the cloth is fixed and then taken down (the other side of the hinge plate is subjected to composite treatment in the same way).

The folding type auxetic textile composite material can be used in bulletproof, explosion-proof and stab-resistant helmets, gloves and clothes, armored vehicles, energy absorption buffers, shock absorbers, submarine power equipment cabin sections, deep sea compression resistance, vibration reduction of a real ship main machine, automobile sound absorption boxes, sports shoe soles, football player guard plates, racing driver helmets, skiing and bicycle helmets and other sports goods.

The folding textile composite material has excellent buffer resistance, energy absorption performance, compression resistance and the like. The material can be used in bulletproof, explosion-proof and stab-resistant helmets, gloves and clothes, armored vehicles, energy absorption buffers, shock absorbers, submarine power equipment cabin sections, deep sea compression resistance, vibration reduction of a real ship main machine, sound absorption boxes of automobiles, sports shoes, soles of football players, racing drivers and helmets, skiing and bicycle helmets and other sports goods.

Drawings

FIG. 1 is a schematic view of a continuous folding type vibration-damping and auxetic textile composite material processing device provided by the invention;

FIG. 2 is a schematic view of a hinge plate;

fig. 3 is an asymmetric continuous folded, shock absorbing auxetic textile composite prepared in example 1.

Detailed Description

In order to make the invention more comprehensible, preferred embodiments are described in detail below with reference to the accompanying drawings.

The processing device of the continuous folding type vibration-damping and auxetic textile composite material adopted by each embodiment comprises a hinge plate 1 and foam plates 2 with scales on two sides thereof; the hinge plate 1 is formed by movably connecting a plurality of hinge plate pieces, a plurality of sleeves 12 which are arranged at intervals and are coaxially arranged are arranged at the edge of each hinge plate piece, the sleeves 12 at two ends of one side are connected with the foam plate 2 through second nails 13, and the sleeves 12 of two adjacent hinge plate pieces are mutually staggered and coaxially arranged and are connected through first nails 11.

The processing method of the continuous folding type vibration-damping and auxetic textile composite material adopted by each embodiment comprises the following steps:

step 1: selecting hinge plate pieces according to the size of a product to be produced, opening the hinge plate 1 by a corresponding angle according to the folding angle of the product by taking the protractor and ruler scales on the foam plate 2 as reference bases, and connecting the two ends of the outermost side of the hinge plate 1 with the foam plate 2 through a second nail 13;

step 2: brushing the whole combined hinge plate 1 flat by using double-sided adhesive and paper scraps;

and step 3: placing the cloth on the processed hinge plate 1, and pulling the cloth to be flat under the fixing action of the double-sided adhesive tape; then, brushing hard resin on the cloth with a rod structure in a hand pasting forming mode, and sticking the arc part/the bent part by using a transparent adhesive tape in order to prevent the resin from diffusing to the arc part/the bent part; after the rod part structure is fixed, compounding the arc part/the bending part; after the whole process is finished, the other side of the cloth is subjected to the same composite treatment in the same way.

Examples 1 to 5

Examples 1 to 5 respectively prepared a recessed hexagonal polyamide/rigid polyurethane composite, a double-arrow UHMWPE/silicone rubber composite, a star-shaped aramid/epoxy resin composite, a double-arrow star-shaped aramid/epoxy resin composite, and a recessed hexagonal-star-shaped glass fiber composite.

Corresponding parameter settings were made for the components according to 5 examples, including (1) various parameter settings (length, width, height) for the hinge model; (2) the type, the number of layers and the thickness of the reinforcement; (3) the types of the two matrix materials and the types and the proportion of matched curing agents; (4) compounding and curing process parameters such as temperature and time. The setup parameters for examples 1-5 are shown in Table 1.

TABLE 1