阅读说明：本技术 一种非边彩釉玻璃 (Non-edge colored glazed glass ) 是由 张小利 杨振 于 2021-08-03 设计创作，主要内容包括：本发明公开了一种非边彩釉玻璃,包括包括以下份额的原材料：玻璃基材、石英、长石、颜料、稀释剂、碳酸钡和碳酸锶,所述石英的份额为50％-55％,所述长石的份额为32％-37％,所述颜料的份额为1％-3％,所述稀释剂的份额为2％-5％,所述碳酸钡的份额为2.5％-5％,所述碳酸锶的份额为2.5％-5％。本发明所述的一种非边彩釉玻璃,通过加入的碳酸钡可使得釉料更加洁白和增大其乳白感,使得颜料更容易上色,碳酸锶在进行对石英和长石的搅拌时能减少釉料中的气泡,还能消除釉料表面的针孔缺陷,增加釉料表面的光泽,同时还能改善釉浆的悬浮性,增加釉料的烧成范围,克服烟熏发黄的缺陷,经过细磨后的石英和长石可以使得各种添加的材料能更加均匀的混合。(The invention discloses non-edge colored glaze glass, which comprises the following raw materials in parts by weight: the glass comprises a glass base material, quartz, feldspar, a pigment, a diluent, barium carbonate and strontium carbonate, wherein the quartz accounts for 50% -55%, the feldspar accounts for 32% -37%, the pigment accounts for 1% -3%, the diluent accounts for 2% -5%, the barium carbonate accounts for 2.5% -5%, and the strontium carbonate accounts for 2.5% -5%. According to the non-edge colored glaze glass, the added barium carbonate can make the glaze material more white and increase the milky white feeling of the glaze material, so that the pigment is easier to color, the strontium carbonate can reduce bubbles in the glaze material when stirring quartz and feldspar, can eliminate pinhole defects on the surface of the glaze material, increase the luster of the surface of the glaze material, improve the suspension property of glaze slurry, increase the sintering range of the glaze material, overcome the defect of smoke yellowing, and the quartz and feldspar after being finely ground can enable various added materials to be more uniformly mixed.)

1. A non-edge colored glazed glass is characterized in that: comprises the following raw materials in parts by weight: the glass comprises a glass base material, quartz, feldspar, a pigment, a diluent, barium carbonate and strontium carbonate, wherein the quartz accounts for 50% -55%, the feldspar accounts for 32% -37%, the pigment accounts for 1% -3%, the diluent accounts for 2% -5%, the barium carbonate accounts for 2.5% -5%, and the strontium carbonate accounts for 2.5% -5%.

2. The non-edge colored glazed glass according to claim 1, wherein: the quartz content is 52%, the feldspar content is 34%, the pigment content is 2%, the diluent content is 4%, the barium carbonate content is 4%, and the strontium carbonate content is 4%.

3. The non-edge colored glazed glass according to claim 1, wherein: the quartz content is 54%, the feldspar content is 36%, the pigment content is 3%, the diluent content is 2%, the barium carbonate content is 2.5%, and the strontium carbonate content is 2.5%.

4. The non-edge colored glazed glass according to claim 1, wherein: the method comprises the following steps:

s1: taking out quartz and feldspar according to the parts, washing the quartz and the feldspar, removing mud and dust on the surfaces of the quartz and the feldspar, placing the quartz into a calcining furnace for calcining, wherein the temperature of the calcining furnace is higher than 800 ℃, iron impurities in the quartz and the feldspar can be exposed after the calcining is finished, taking out the iron impurities, crushing and granulating the washed feldspar by using a granulator, and when glaze is manufactured, ensuring that a manufacturing workshop is sealed and dust-free, controlling suspended matters such as dust and the like in the workshop, and placing the quartz and the feldspar for later use;

s2: pouring quartz and feldspar into a ball mill according to the parts, adding water to grind the quartz and feldspar, and grinding the quartz and feldspar into a slurry;

s3: adding barium carbonate and strontium carbonate into the ball mill according to the parts, continuously grinding the barium carbonate and the strontium carbonate to enable the barium carbonate and the strontium carbonate to be completely fused with the pasty quartz and feldspar, then adding a specified part of pigment, continuously stirring the pigment to enable the color of the pigment to be displayed, ensuring the uniformity of the color, and standing for later use;

s4: taking out 15% of n-butyl acetate, 15% of ethyl acetate, 10% -15% of n-butanol, 10% of ethanol, 5% -10% of acetone, 20% of benzene and 20% of xylene, pouring all the n-butyl acetate, the ethyl acetate, the n-butanol, the benzene and the xylene into a reagent bottle, stirring the reagent bottle by using a test tube to fully and uniformly mix the reagent bottle to obtain a diluent, and standing for later use;

s5: taking out a specified portion of the diluent according to the proportion, adding the diluent into a ball mill, fully stirring the diluent, generating heat with slurry quartz and feldspar during stirring to increase the temperature, standing for 5-10 minutes after stirring is finished, and using the diluent after the temperature is recovered to room temperature;

s6: the method comprises the steps that the gauze with the ratio of the mesh number of the silk screen to the granularity of glaze being 1:4 is selected to print the glass substrate, a scraper is in line contact with the glass substrate from the position before the glass substrate is 100-200mm and before the glass substrate is in the initial position of printing, the contact value between the scraper and the surface of the glass substrate is ensured to be 1mm, and the prepared glaze is added to the gauze on the way of hanging the scraper and is placed for later use;

s7: placing the glass substrate coated with the glaze material into a drying box, ensuring the temperature to be 150-180 ℃, adjusting the overall drying speed according to the thickness of the glass substrate and the drying section, and placing for later use after drying is finished;

s8: the glass substrate after will drying is placed and is sintered in the tempering furnace, strict control sintering temperature and time, the high temperature or the low temperature all can cause the color or make the glaze acid and alkali resistance not good, the temperature of glass substrate when the tempering furnace sintering should be higher than the melting point of glaze, so should be higher than 800 degrees, then according to the change of glaze color suitably adjust the heating time, the time reduces when the color is dark, the time extension when the color is light, after the sintering is accomplished, take out the non-limit colored glaze glass of finished product in the tempering furnace.

Technical Field

The invention relates to the field of colored glaze glass, in particular to non-edge colored glaze glass.

Background

The glazed glass is made up through printing inorganic glaze on the surface of glass, baking, toughening or thermalization, and permanent sintering of glaze on the surface of glass.

Disclosure of Invention

The invention mainly aims to provide non-edge colored glaze glass which can effectively solve the problems in the background technology.

In order to achieve the purpose, the invention adopts the technical scheme that:

a non-edge glazed glass comprising the following proportions of raw materials: the glass comprises a glass base material, quartz, feldspar, a pigment, a diluent, barium carbonate and strontium carbonate, wherein the quartz accounts for 50% -55%, the feldspar accounts for 32% -37%, the pigment accounts for 1% -3%, the diluent accounts for 2% -5%, the barium carbonate accounts for 2.5% -5%, and the strontium carbonate accounts for 2.5% -5%.

Preferably, the quartz content is 52%, the feldspar content is 34%, the pigment content is 2%, the diluent content is 4%, the barium carbonate content is 4%, and the strontium carbonate content is 4%.

Preferably, the quartz content is 54%, the feldspar content is 36%, the pigment content is 3%, the diluent content is 2%, the barium carbonate content is 2.5%, and the strontium carbonate content is 2.5%.

Preferably, the quartz and the feldspar are taken out according to the parts, washed, dirt and dust on the surfaces of the quartz and the feldspar are removed, the quartz is placed in a calcining furnace to be calcined, the temperature of the calcining furnace is higher than 800 ℃, iron impurities in the quartz and the feldspar are exposed after the calcining is finished, the iron impurities are taken out, the washed feldspar is crushed and granulated by using a granulator, when glaze is manufactured, the manufacturing workshop is guaranteed to be sealed and dust-free, suspended matters such as dust in the workshop are controlled, and the quartz and the feldspar are placed for standby.

Preferably, the quartz and the feldspar are poured into a ball mill in portions, are ground by adding water, and are ground into a slurry shape.

Preferably, the barium carbonate and the strontium carbonate are added into the ball mill according to the proportion, the ball mill is continuously ground, so that the barium carbonate and the strontium carbonate are completely fused with the pasty quartz and feldspar, the pigment with the specified proportion is added, the ball mill is continuously stirred, the color is displayed, the uniformity of the color is ensured, and the ball mill is placed for standby.

Preferably, the removed portion of n-butyl acetate is 15%, the portion of ethyl acetate is 15%, the portion of n-butanol is 10% -15%, the portion of ethanol is 10%, the portion of acetone is 5% -10%, the portion of benzene is 20%, and the portion of xylene is 20%, all of which are poured into a reagent bottle, and the reagent bottle is stirred by using a test tube to be fully mixed to obtain the diluent, and the diluent is placed for standby.

Preferably, the diluent is taken out according to the proportion, added into a ball mill, fully stirred, heated with the pasty quartz and feldspar during stirring to increase the temperature, and kept stand for 5-10 minutes after the stirring is finished, and used after the temperature is returned to the room temperature.

Preferably, the glass substrate is printed by using the gauze with the ratio of the mesh number of the silk screen to the granularity of the glaze material being 1:4, the scraper is in line contact with the glass substrate from the beginning position of printing before the glass substrate is 100-200mm, the contact value of the scraper and the surface of the glass substrate is ensured to be 1mm, and the prepared glaze material is added to the gauze in the process of hanging the scraper and is placed for standby.

Preferably, the glass substrate coated with the glaze is placed in a drying box, the temperature is ensured to be 180 ℃, the overall drying speed is adjusted according to the thickness and the drying section of the glass substrate, and the glass substrate is placed for standby after drying.

Preferably, the dried glass substrate is placed in a tempering furnace for sintering, the sintering temperature and time are strictly controlled, too high or too low temperature can cause color or lead the glaze to have poor acid and alkali resistance, the temperature of the glass substrate during sintering in the tempering furnace is higher than the melting point of the glaze, so the temperature is higher than 800 ℃, then the heating time is properly adjusted according to the change of the color of the glaze, the time is reduced when the color is deep, the time is prolonged when the color is light, and after the sintering is completed, the finished product of the non-edge colored glaze glass is taken out from the tempering furnace.

Compared with the prior art, the invention has the following beneficial effects:

in the invention, the added barium carbonate can make the glaze more white and increase the milky feel of the glaze, so that the pigment is easier to color, the strontium carbonate can reduce bubbles in the glaze when stirring quartz and feldspar, can also eliminate the pinhole defect on the surface of the glaze, increase the gloss on the surface of the glaze, improve the suspension property of glaze slurry, increase the firing range of the glaze, overcome the defect of smoke yellowing, the quartz and feldspar after being finely ground can make various added materials more uniformly mixed, simultaneously enlarge the granularity reaction surface, easily cause melting, reduce the firing temperature, generate good gloss, and ensure that no dust is adsorbed on the surface of the glaze to control the environment of a production workshop, thereby influencing the quality of the surface of finished glass, and the quantitative diluent can prevent the glaze from poor wettability to the glass due to overlarge viscosity, the defect of pinhole occurrence caused by the fact that the printing ink is not easy to transfer to the surface of the glass through the silk screen is prevented, and the phenomenon that the mark is enlarged due to the fact that the viscosity of the printing ink is small is avoided, so that the edge of the printed pattern is fuzzy and even is connected with an adjacent pattern.

Detailed Description

The technical solutions in the embodiments of the present invention will be clearly and completely described below with reference to the embodiments of the present invention, and it is obvious that the described embodiments are only a part of the embodiments of the present invention, and not all of the embodiments. All other embodiments, which can be derived by a person skilled in the art from the embodiments given herein without making any creative effort, shall fall within the protection scope of the present invention.

The first embodiment is as follows:

a non-edge glazed glass comprising the following proportions of raw materials: the glass substrate, quartz, feldspar, pigment, diluent, barium carbonate and strontium carbonate, wherein the quartz accounts for 50% -55%, the feldspar accounts for 32% -37%, the pigment accounts for 1% -3%, the diluent accounts for 2% -5%, the barium carbonate accounts for 2.5% -5%, and the strontium carbonate accounts for 2.5% -5%.

The proportion of quartz is 52%, that of feldspar is 34%, that of pigment is 2%, that of diluent is 4%, that of barium carbonate is 4%, and that of strontium carbonate is 4%.

The method comprises the following manufacturing steps:

s1: taking out quartz and feldspar according to the parts, washing the quartz and the feldspar, removing mud and dust on the surfaces of the quartz and the feldspar, placing the quartz into a calcining furnace for calcining, wherein the temperature of the calcining furnace is higher than 800 ℃, iron impurities in the quartz and the feldspar can be exposed after calcining is finished, taking out the iron impurities, crushing and granulating the washed feldspar by using a granulator, and when glaze is manufactured, ensuring that a manufacturing workshop is sealed and dust-free, controlling suspended matters such as dust and the like in the workshop, and placing the quartz and the feldspar for later use;

s2: pouring quartz and feldspar into a ball mill according to the parts, adding water to grind the quartz and feldspar into a slurry;

s3: adding barium carbonate and strontium carbonate into the ball mill according to the proportion, continuously grinding the barium carbonate and the strontium carbonate to ensure that the barium carbonate and the strontium carbonate are completely fused with the pasty quartz and feldspar, then adding a specified proportion of pigment, continuously stirring the pigment to ensure that the color is displayed, ensuring the uniformity of the color, and standing for later use;

s4: taking out n-butyl acetate with the share of 15%, ethyl acetate with the share of 15%, n-butanol with the share of 10% -15%, ethanol with the share of 10%, acetone with the share of 5% -10%, benzene with the share of 20% and xylene with the share of 20%, pouring all the n-butyl acetate, ethyl acetate with the share of 15%, ethanol with the share of 10%, acetone with the share of 5% -10%, benzene with the share of 20% and xylene with the share of 20% into a reagent bottle, stirring the reagent bottle by using a test tube, fully and uniformly mixing the reagent bottle to obtain a diluent, and standing for later use;

s5: taking out a specified portion of the diluent according to the proportion, adding the diluent into a ball mill, fully stirring the diluent, generating heat with slurry quartz and feldspar during stirring to increase the temperature, standing for 5-10 minutes after stirring is finished, and using the diluent after the temperature is recovered to room temperature;

s6: selecting a gauze with the mesh number of the silk screen and the granularity of glaze being 1:4 to print the glass substrate, wherein a scraper is in line contact with the glass substrate from the initial position of printing before the glass substrate is 100-200mm away from the surface of the glass substrate, the contact value of the scraper and the surface of the glass substrate is ensured to be 1mm, and the prepared glaze is added to the gauze on the way of hanging the scraper and is placed for standby;

s7: placing the glass substrate coated with the glaze material into a drying box, ensuring the temperature to be at 150-;

s8: placing the glass substrate after will drying in the tempering furnace and sintering, strictly will controlling the temperature and the time of sintering, the high temperature or too low all can cause the color or make the glaze acid and alkali resistance not good, the temperature of glass substrate when the tempering furnace sintering should be higher than the melting point of glaze, so should be higher than 800 degrees, then according to the change of glaze colour appropriately adjust the heating time, the time reduces when the colour is dark, the time extension when the colour is light, after the sintering is accomplished, take out the non-limit colored glaze glass of finished product in the tempering furnace.

The second embodiment is as follows:

a non-edge glazed glass comprising the following proportions of raw materials: the glass substrate, quartz, feldspar, pigment, diluent, barium carbonate and strontium carbonate, wherein the quartz accounts for 50% -55%, the feldspar accounts for 32% -37%, the pigment accounts for 1% -3%, the diluent accounts for 2% -5%, the barium carbonate accounts for 2.5% -5%, and the strontium carbonate accounts for 2.5% -5%.

The proportion of quartz is 54%, the proportion of feldspar is 36%, the proportion of pigment is 3%, the proportion of diluent is 2%, the proportion of barium carbonate is 2.5% and the proportion of strontium carbonate is 2.5%.

The method comprises the following manufacturing steps:

s1: taking out quartz and feldspar according to the parts, washing the quartz and the feldspar, removing mud and dust on the surfaces of the quartz and the feldspar, placing the quartz into a calcining furnace for calcining, wherein the temperature of the calcining furnace is higher than 800 ℃, iron impurities in the quartz and the feldspar can be exposed after calcining is finished, taking out the iron impurities, crushing and granulating the washed feldspar by using a granulator, and when glaze is manufactured, ensuring that a manufacturing workshop is sealed and dust-free, controlling suspended matters such as dust and the like in the workshop, and placing the quartz and the feldspar for later use;

s2: pouring quartz and feldspar into a ball mill according to the parts, adding water to grind the quartz and feldspar into a slurry;

s3: adding barium carbonate and strontium carbonate into the ball mill according to the proportion, continuously grinding the barium carbonate and the strontium carbonate to ensure that the barium carbonate and the strontium carbonate are completely fused with the pasty quartz and feldspar, then adding a specified proportion of pigment, continuously stirring the pigment to ensure that the color is displayed, ensuring the uniformity of the color, and standing for later use;

s4: taking out n-butyl acetate with the share of 15%, ethyl acetate with the share of 15%, n-butanol with the share of 10% -15%, ethanol with the share of 10%, acetone with the share of 5% -10%, benzene with the share of 20% and xylene with the share of 20%, pouring all the n-butyl acetate, ethyl acetate with the share of 15%, ethanol with the share of 10%, acetone with the share of 5% -10%, benzene with the share of 20% and xylene with the share of 20% into a reagent bottle, stirring the reagent bottle by using a test tube, fully and uniformly mixing the reagent bottle to obtain a diluent, and standing for later use;

s5: taking out a specified portion of the diluent according to the proportion, adding the diluent into a ball mill, fully stirring the diluent, generating heat with slurry quartz and feldspar during stirring to increase the temperature, standing for 5-10 minutes after stirring is finished, and using the diluent after the temperature is recovered to room temperature;

s6: selecting a gauze with the mesh number of the silk screen and the granularity of glaze being 1:4 to print the glass substrate, wherein a scraper is in line contact with the glass substrate from the initial position of printing before the glass substrate is 100-200mm away from the surface of the glass substrate, the contact value of the scraper and the surface of the glass substrate is ensured to be 1mm, and the prepared glaze is added to the gauze on the way of hanging the scraper and is placed for standby;

s7: placing the glass substrate coated with the glaze material into a drying box, ensuring the temperature to be at 150-;

s8: placing the glass substrate after will drying in the tempering furnace and sintering, strictly will controlling the temperature and the time of sintering, the high temperature or too low all can cause the color or make the glaze acid and alkali resistance not good, the temperature of glass substrate when the tempering furnace sintering should be higher than the melting point of glaze, so should be higher than 800 degrees, then according to the change of glaze colour appropriately adjust the heating time, the time reduces when the colour is dark, the time extension when the colour is light, after the sintering is accomplished, take out the non-limit colored glaze glass of finished product in the tempering furnace.

The glaze is more white and the milky feeling of the glaze is increased through the added barium carbonate, so that pigment is easier to color, the strontium carbonate can reduce bubbles in the glaze when stirring quartz and feldspar, can eliminate pinhole defects on the surface of the glaze, increase the gloss of the surface of the glaze, improve the suspension property of glaze slurry, increase the firing range of the glaze, overcome the defect of smoke yellowing, and ensure that various added materials can be more uniformly mixed through the finely ground quartz and feldspar, meanwhile, the granularity reaction surface is enlarged, so that melting is easy to cause, the firing temperature is reduced, good gloss is generated, and for controlling the environment of a production workshop, dust can not be adsorbed on the surface of the glaze, so that the quality of the surface of finished glass is influenced, and the quantitative diluent can ensure that the glaze cannot cause poor wettability to the glass due to overlarge viscosity, the defect of pinhole occurrence caused by the fact that the printing ink is not easy to transfer to the surface of the glass through the silk screen is prevented, and the phenomenon that the mark is enlarged due to the fact that the viscosity of the printing ink is small is avoided, so that the edge of the printed pattern is fuzzy and even is connected with an adjacent pattern.

Although embodiments of the present invention have been shown and described, it will be appreciated by those skilled in the art that changes, modifications, substitutions and alterations can be made in these embodiments without departing from the principles and spirit of the invention, the scope of which is defined in the appended claims and their equivalents.