阅读说明：本技术 一种抛光砖制备过程中的防滑防污方法 (Anti-skid and anti-fouling method in polished brick preparation process ) 是由 祁明 钟保民 徐瑜 于 2019-10-31 设计创作，主要内容包括：一种抛光砖制备过程中的防滑防污方法,包括以下步骤：S1、将瓷砖进行抛光加工,抛光至40-50度；S2、采用清洗液将抛光后的砖面进行清洗,然后用水冲洗砖面；S3、使用抛光机把防滑蜡水加工至砖面及打进砖面的毛细孔内；所述步骤S3后可选择地进行步骤S4和步骤S5中的任意一个或组合的步骤；S4、用抛光机把防污剂A打在砖面上；S5、用打蜡机把防污剂B打在砖面上,防污剂B是氟化硅类防污液。本发明制备的瓷砖,其光泽度大于等于91度,摩擦系数为0.75(干法)和0.65(湿法),防污能力为五级；对比现有的普通防滑砖,其光泽度接近现今普通未经防滑防污处理的砖,具有很好的镜面效果,具有优异的防滑能力和防污能力。(An anti-slip and anti-fouling method in the preparation process of a polished tile comprises the following steps: s1, polishing the ceramic tile to 40-50 ℃; s2, cleaning the polished brick surface by using a cleaning solution, and then washing the brick surface by using water; s3, processing the anti-skid wax water to the brick surface and into the capillary holes on the brick surface by using a polishing machine; the step S3 is optionally followed by any one or a combination of steps S4 and S5; s4, using a polishing machine to polish the antifouling agent A on the brick surface; s5, using a waxing machine to apply the antifouling agent B on the brick surface, wherein the antifouling agent B is a silicon fluoride antifouling liquid. The ceramic tile prepared by the invention has the glossiness more than or equal to 91 degrees, the friction coefficient of 0.75 (dry method) and 0.65 (wet method), and the antifouling capacity of five grades; compared with the existing common anti-skid brick, the glossiness of the anti-skid brick is close to that of the common brick without anti-skid and anti-fouling treatment, and the anti-skid brick has a good mirror effect and excellent anti-skid capacity and anti-fouling capacity.)

1. An anti-slip and anti-fouling method in the preparation process of a polished tile is characterized by comprising the following steps:

s1, polishing the ceramic tile to 40-50 ℃;

s2, cleaning the polished brick surface by using a cleaning solution, and then washing the brick surface by using water;

s3, processing the anti-skid wax water to the brick surface and into the capillary holes on the brick surface by using a polishing machine;

the step S3 is optionally followed by any one or a combination of steps S4 and S5;

s4, using a polishing machine to polish the antifouling agent A on the brick surface;

s5, using a waxing machine to apply the antifouling agent B on the brick surface, wherein the antifouling agent B is a silicon fluoride antifouling liquid.

2. The method according to claim 1, wherein in step S3, the anti-slip wax solution comprises; an anti-skid material A and an anti-skid material B;

the molecular structural formula of the antiskid material A is as follows:

R₁and R₂Are each an alkyl group;

the molecular structural formula of the antiskid material B is as follows:

3. the method of claim 1, wherein in step S4, the anti-fouling agent A comprises: an antifouling material A; the structure of the antifouling material A is as follows:

4. the method of claim 1, wherein in step S5, the anti-fouling agent B comprises: an antifouling material B; the structural formula of the antifouling material B is as follows:

R₁and R₂Are each an alkyl group.

5. The method of claim 4, wherein R is selected from the group consisting of₁And R₂Are respectively-CH₂-CH₂-; the molecular structural formula of the antifouling material B is as follows:

6. the method of claim 2, wherein the weight ratio of the anti-slip agent A to the anti-slip agent B is (1-3): 1.

7. the method of claim 3, wherein the anti-slip and anti-fouling agent A comprises: a low boiling point solvent; the low boiling point solvent includes: one or a combination of ethanol, acetone, ethyl acetate, butyl acetate and water.

8. The method of claim 7, wherein the mass ratio of the low-boiling solvent to the anti-fouling agent A is 1: (3-5).

9. The method according to any one of claims 1 to 8, wherein the cleaning solution in step S2 comprises: any one or combination of aqueous polymer, organic acid, inorganic acid, organic base and inorganic base.

10. The method of any one of claims 1 to 8, further comprising: step S11; the step S11 is performed between the steps S1 and S2;

and step S11, polishing the nano silicon solution on the brick surface of step S1 by a polishing machine.

Technical Field

The invention relates to the technical field of tile preparation processes, in particular to an anti-skid and anti-fouling method in a polished tile preparation process.

Background

The living standard of people is higher and higher, the ceramic tiles are pursued to have more than decoration effect, the safety requirement on the ceramic tiles is higher and higher, and the antiskid effect is required while the decoration effect is not influenced; this is certainly a problem with polishing tiles in the present stage; although the polished tiles on the surface have high glossiness, the surfaces of the polished tiles have no rough feeling due to smooth surfaces, and the anti-skid effect cannot be well achieved; although the prior art has a non-slip layer disposed on the brick surface, the anti-fouling property is reduced due to the presence of the non-slip layer.

Disclosure of Invention

The invention aims to provide an anti-slip and anti-fouling method in the preparation process of a polished tile, which uses anti-slip wax water and is matched with polishing in step S3, uses an anti-fouling agent A and is matched with polishing in step S4, and uses an anti-fouling agent B and is matched with waxing in step S5.

In order to achieve the purpose, the invention adopts the following technical scheme:

an anti-slip and anti-fouling method in the preparation process of a polished tile comprises the following steps:

s1, polishing the ceramic tile to 40-50 ℃;

s2, cleaning the polished brick surface by using a cleaning solution, and then washing the brick surface by using water;

s3, processing the anti-skid wax water to the brick surface and into the capillary holes on the brick surface by using a polishing machine;

the step S3 is optionally followed by any one or a combination of steps S4 and S5;

s4, using a polishing machine to polish the antifouling agent A on the brick surface;

s5, using a waxing machine to apply the antifouling agent B on the brick surface, wherein the antifouling agent B is a silicon fluoride antifouling liquid.

More specifically, in step S3, the anti-skid wax solution includes; an anti-skid material A and an anti-skid material B;

the molecular structural formula of the antiskid material A is as follows:

R₁and R₂Are each an alkyl group;

the molecular structural formula of the antiskid material B is as follows:

in step S4, the antifouling agent a includes: an antifouling material A; the structure of the antifouling material A is as follows:

in step S5, the antifouling agent B includes: an antifouling material B; the structural formula of the antifouling material B is as follows:

R₁and R₂Are each an alkyl group.

Further, R is₁And R₂Are respectively-CH₂-CH₂-; the molecular structural formula of the antifouling material B is as follows:

further, the mass ratio of the antiskid material A to the antiskid material B is (1-3): 1.

more specifically, the antifouling agent A includes: a low boiling point solvent; the low boiling point solvent includes: one or a combination of ethanol, acetone, ethyl acetate, butyl acetate and water.

Further, the mass ratio of the low-boiling point solvent to the antifouling material A is 1: (3-5).

In step S2, the cleaning solution is a weak acid or weak base cleaning solution, and the retention time of the cleaning solution on the brick surface is 6 to 10 seconds.

Further, in step S2, the cleaning solution includes: any one or combination of aqueous polymer, organic acid, inorganic acid, organic base and inorganic base.

Further, the method further comprises the following steps: step S11; the step S11 is performed between the steps S1 and S2;

and step S11, polishing the nano silicon solution on the brick surface of step S1 by a polishing machine. Further comprising: step S11; the step S11 is performed between the steps S1 and S2;

and step S11, polishing the nano silicon solution on the brick surface of step S1 by a polishing machine. Further comprising: step S11; the step S11 is performed between the steps S1 and S2;

and step S11, polishing the nano silicon solution on the brick surface of step S1 by a polishing machine.

The invention has the beneficial effects that:

the ceramic tile prepared by the invention has the glossiness more than or equal to 91 degrees, the friction coefficient of 0.75 (dry method) and 0.65 (wet method), and the antifouling capacity of five grades; compared with the existing common anti-skid brick, the glossiness of the anti-skid brick is close to that of the common brick without anti-skid and anti-fouling treatment, and the anti-skid brick has a good mirror effect and excellent anti-skid capacity and anti-fouling capacity.

Detailed Description

The technical solution of the present invention is further explained by the following embodiments.

An anti-slip and anti-fouling method in the preparation process of a polished tile comprises the following steps:

s1, polishing the ceramic tile to 40-50 ℃;

and (3) finely polishing the surface of the fired ceramic tile to the glossiness of 40-50 ℃ by a polishing machine, and polishing the edge of the ceramic tile by an edge grinding machine. The green tile with a certain gloss is prepared for the following polishing.

Optionally, step S1 may be completed before step S11 and then step S2, or step S2 may be performed directly after S1 is completed.

And S11, polishing the nano silicon solution on the brick surface in the step S1 by a polishing machine.

Through 10-12 grinding discs of a polishing machine (each grinding disc is provided with 10-12 grinding heads, each grinding head is made of soft fiber or soft wool material), the rotation speed is 200-300 revolutions per minute, the pressure is 9-12MPa, nano silicon solution (such as the existing ultra-clean and bright solution) is thrown on the brick surface, original capillary holes of the brick surface are blocked, the brick surface has a certain transparent and glossy effect, and the whole brick surface is good in effect.

S2, cleaning the polished brick surface by using a cleaning solution, and then washing the brick surface by using water;

and (3) cleaning the brick surface by weak acid (weak base) cleaning solution (the acid pH is 6-7, and the alkaline pH is 7-8), wherein the process is maintained for about 8-10 seconds, then washing the brick surface by tap water, and cleaning the polishing waste residue and the cleaning solution which are not reacted in the micropores, so as to prevent the polishing waste residue and the acidic (alkaline) cleaning solution from remaining in the capillary pores of the brick surface.

The weak acid (weak base) comprises aqueous polymer, organic acid, inorganic acid, organic base, inorganic base, etc. The process is prepared for the next step of polishing the anti-skid wax liquid, and the anti-skid wax liquid is extruded into the capillary holes, so that the anti-skid wax liquid is more firmly arranged on the surface of the brick.

S3, processing the anti-skid wax water to the brick surface and into the capillary holes on the brick surface by using a polishing machine;

10-12 grinding discs (each grinding disc is provided with 10-12 grinding heads made of soft fiber or wool soft materials) are used for polishing the anti-skid wax water into the capillary holes and the brick surfaces through a polishing machine (a brushing machine with certain pressure can also be used), the rotating speed is 200-300 r/min, and the pressure is 9-12 MPa. The water of the anti-skid wax belongs to a neutral or cationic metal polymer, and the water of the anti-skid wax can be crystallized under the dry condition, so that the surface is rough at the microscopic level. Meanwhile, the anti-skid wax liquid also has a certain filling effect. The crystal anti-slip layer is firmly fixed on the brick surface under the action of capillary pores. (the rotation speed and pressure are determined by the surface effect of the brick, and can be the same or different)

The step S3 is optionally followed by any one or a combination of steps S4 and S5;

s4, using a polishing machine (polishing and brushing machine) to polish the antifouling agent A on the brick surface;

the temperature of the brick surface of the brick treated by the process 3 reaches 50 to 60 ℃. Polishing the permeable antifouling agent A on the brick surface by using 3-5 grinding discs of a polishing machine (each grinding disc is provided with 10-12 grinding heads, each grinding head is made of soft fiber or wool soft material), the rotating speed is 200-300 r/min, and the pressure is 4-6 MPa. The antifouling agent can effectively permeate into crystal gaps to play a role in preventing fouling. (the rotation speed and pressure here are determined by the surface effect of the brick, and may be the same or different).

S5, using a waxing machine (this is only a noun, a polishing and brushing machine with certain pressure can also be used) to polish the antifouling agent B on the brick surface, wherein the antifouling agent B is a silicon fluoride antifouling liquid.

The brick treated by the 4 processes is characterized in that 2-3 grinding discs of a waxing machine (each rotary disc is provided with 3-5 grinding heads which are made of soft sponge or cotton cloth materials) are used for polishing an antifouling agent B on the surface of the brick at the rotating speed of 10-20 r/min and the pressure of 0-1MPa, wherein the antifouling agent B is a silicon fluoride antifouling liquid and has certain antifouling capacity and certain anti-slip performance. (the rotation speed and the pressure are determined according to the surface effect of the brick, and can be the same or different.)

More specifically, in step S3, the anti-skid wax solution includes; an anti-skid material A and an anti-skid material B;

the molecular structural formula of the antiskid material A is as follows:

R₁and R₂Are each an alkyl group;

R₃and R₄Respectively, is a common terminal group, such as hydrogen atom (-H), hydroxyl group (-COOH), carboxyl group (-OH), and hydrocarbon group (-C)_aH_b) One of (1);

the molecular structural formula of the antiskid material B is as follows:

R₉、R₁₀、R₁₁、R₁₂respectively, is a common terminal group, such as hydrogen atom (-H), hydroxyl group (-COOH), carboxyl group (-OH), and hydrocarbon group (-C)_aH_b) One of (1); in the structural formula, s, t, z and the like represent the degree of polymerization.

The application discloses antiskid wax water passes through antiskid material A and antiskid material B's use, and antiskid material has unique fillibility, and this antiskid wax water can be crystallized under the dry condition for the surface is rough in microcosmic time. Meanwhile, the anti-skid wax liquid also has a certain filling effect, and the crystal anti-skid layer is firmly fixed on the brick surface under the action of capillary pores. Because the transparent performance, the crystallization effect at normal temperature and the anti-skid effect are excellent, the super-clean and bright glass can replace the prior art.

In step S4, the antifouling agent a includes: an antifouling material A; the structure of the antifouling material A is as follows:

R₅、R₆、R₉、R₁₀is an end group, and can be a hydrogen atom (-H), a hydrocarbon group (-C)_aH_b) Isomolecular chains; or other monofunctional end capping group, such as one of hydroxyl (-COOH), carboxyl (-OH), and amino. The antifouling material A has better permeability and antiskid performance, can permeate into the surface of antiskid wax water to improve the antiskid and antifouling capacity of the surface and prolong the duration time of the antiskid and antifouling capacityAnd the anti-skid and anti-fouling effects can be achieved by fully utilizing the permeability of the polishing solution, combining the polishing solution with an anti-skid wax water layer and matching the anti-skid wax water layer particularly after the polishing process.

In step S5, the antifouling agent B includes: an antifouling material B; the structural formula of the antifouling material B is as follows:

R₁and R₂Are each an alkyl group.

R₇、R₈Is an end group, and can be a hydrogen atom (-H), a hydrocarbon group (-C)_aH_b) Isomolecular chains; or other monofunctional end capping group, such as one of hydroxyl (-COOH), carboxyl (-OH), and amino.

Further, R is₁And R₂Are respectively-CH₂-CH₂-; the molecular structural formula of the antifouling material B is as follows:

the antifouling agent B is provided with an antifouling material B which has antifouling and anti-skid effects, can improve the surface roughness and the pollution resistance when being coated on a plane product, and solves the problems that the existing antifouling liquid has single function and does not have an anti-skid function.

Further, the mass ratio of the antiskid material A to the antiskid material B is (1-3): 1.

more specifically, the antifouling agent A includes: a low boiling point solvent; the low boiling point solvent includes: one or a combination of ethanol, acetone, ethyl acetate, butyl acetate and water.

In the polishing of step S4, the temperature of the brick surface is raised by the polishing operation, and when the temperature reaches the boiling point of the low boiling point solvent, which is easy to evaporate or accelerate the volatilization of the low boiling point solvent, only the antifouling material a is present on the brick surface.

Further, the mass ratio of the low-boiling point solvent to the antifouling material A is 1: (3-5).

In step S2, the cleaning solution is a weak acid or weak base cleaning solution, and the retention time of the cleaning solution on the brick surface is 6 to 10 seconds.

Further, in step S2, the cleaning solution includes: any one or combination of aqueous polymer, organic acid, inorganic acid, organic base and inorganic base.

A polished-surface non-slip tile comprising: a brick body and a functional layer;

the functional layer includes: a surface layer and an anti-skid wax crystal layer;

the surface layer is arranged on the surface of the brick body; capillary holes are reserved in the surface layer after the surface layer is cleaned by cleaning liquid, and the anti-skid wax crystal layer is filled in the capillary holes and is positioned on the upper surface of the surface layer.

The functional layer includes: an antifouling agent A layer and an antifouling agent B layer;

the antifouling agent A layer is arranged on the upper surface of the anti-skid wax crystal layer, and the antifouling agent B layer is arranged on the upper surface of the antifouling agent A layer.

And (3) performance testing:

gloss:

a. the tiles were subjected to gloss performance tests in strict accordance with GB/T4100-2015.

Anti-skid property:

b. the tiles were subjected to a friction coefficient measurement in strict accordance with GB/T4100-2015.

Antifouling capacity:

c. the tiles were tested for antifouling properties strictly in accordance with GB/T4100-2015.

Comparative examples a1,

S2, cleaning the brick surface by weak acid cleaning solution (with acid pH of 6), wherein the process is maintained for about 10 seconds, and then washing the brick surface by using a large amount of tap water.

S3, polishing 10 grinding discs (each grinding disc is provided with 10 grinding heads made of soft fiber or wool soft materials) through a polishing machine, wherein the rotation speed is 200 r/min, the pressure is 9MPa, and anti-skid wax water is sprayed into capillary holes and the brick surface.

S4, polishing the permeable antifouling agent A on the brick surface by using 3 grinding discs of a polishing machine (each grinding disc is provided with 10 grinding heads, each grinding head is made of soft fiber or wool soft material), and the rotation speed is 200 r/min and the pressure is 4 MPa.

S5, using 2 grinding discs of the waxing machine (each rotary disc is provided with 3 grinding heads which are made of soft sponge or cotton cloth materials), and polishing the antifouling agent B on the surface of the brick at the rotating speed of 10 r/min and the pressure of 1MPa, wherein the antifouling agent B is silicon fluoride antifouling liquid.

Comparative examples a2,

And S1, cleaning the fired ceramic tile, finely polishing the surface of the ceramic tile to the glossiness of 40 ℃ by using a polishing machine, and polishing the edge of the ceramic tile by using an edge grinding machine.

And S2, washing the brick surface with a large amount of tap water.

S3, passing through 10 grinding discs of the polishing machine (each grinding disc is provided with 10 grinding heads, each grinding head is made of soft fiber or wool soft material), the rotating speed is 200 r/min, and the pressure is 9 MPa.

S4, polishing the permeable antifouling agent A on the brick surface by using 3 grinding discs of a polishing machine (each grinding disc is provided with 10 grinding heads, each grinding head is made of soft fiber or wool soft material), and the rotation speed is 200 r/min and the pressure is 4 MPa.

S5, using 2 grinding discs of the waxing machine (each rotary disc is provided with 3 grinding heads which are made of soft sponge or cotton cloth materials), and polishing the antifouling agent B on the surface of the brick at the rotating speed of 10 r/min and the pressure of 1MPa, wherein the antifouling agent B is silicon fluoride antifouling liquid.

Comparative examples a3,

And S1, cleaning the fired ceramic tile, finely polishing the surface of the ceramic tile to the glossiness of 40 ℃ by using a polishing machine, and polishing the edge of the ceramic tile by using an edge grinding machine.

S2, cleaning the brick surface by weak acid cleaning solution (with acid pH of 6), wherein the process is maintained for about 10 seconds, and then washing the brick surface by using a large amount of tap water.

S3, polishing 10 grinding discs (each grinding disc is provided with 10 grinding heads made of soft fiber or wool soft materials) through a polishing machine, wherein the rotation speed is 200 r/min, the pressure is 9MPa, and anti-skid wax water is sprayed into capillary holes and the brick surface.

S4, coating the permeable antifouling agent A on the brick surface, and completely drying.

S5, using 2 grinding discs of the waxing machine (each rotary disc is provided with 3 grinding heads which are made of soft sponge or cotton cloth materials), and polishing the antifouling agent B on the surface of the brick at the rotating speed of 10 r/min and the pressure of 1MPa, wherein the antifouling agent B is silicon fluoride antifouling liquid.

Comparative examples a4,

And S1, cleaning the fired ceramic tile, finely polishing the surface of the ceramic tile to the glossiness of 40 ℃ by using a polishing machine, and polishing the edge of the ceramic tile by using an edge grinding machine.

And S2, cleaning the brick surface by weak acid cleaning solution (with the acid pH of 6), maintaining the process for about 10 seconds, then washing the brick surface by using a large amount of tap water, and cleaning the polishing waste residue and the cleaning solution which are not reacted in the micropores.

S3, polishing 10 grinding discs (each grinding disc is provided with 10 grinding heads made of soft fiber or wool soft materials) through a polishing machine, wherein the rotation speed is 200 r/min, the pressure is 9MPa, and anti-skid wax water is sprayed into capillary holes and the brick surface.

S4, polishing the permeable antifouling agent A on the brick surface by using 3 grinding discs of a polishing machine (each grinding disc is provided with 10 grinding heads, each grinding head is made of soft fiber or wool soft material), and the rotation speed is 200 r/min and the pressure is 4 MPa. The antifouling agent can effectively permeate into crystal gaps to play a role in preventing fouling.

S5, smearing the antifouling agent B on the brick surface, wherein the antifouling agent B is a silicon fluoride antifouling liquid, and completely drying.

Examples A1,

And S1, cleaning the fired ceramic tile, finely polishing the surface of the ceramic tile to the glossiness of 40 ℃ by using a polishing machine, and polishing the edge of the ceramic tile by using an edge grinding machine.

And S2, cleaning the brick surface by weak acid cleaning solution (with the acid pH of 6), maintaining the process for about 10 seconds, then washing the brick surface by using a large amount of tap water, and cleaning the polishing waste residue and the cleaning solution which are not reacted in the micropores.

S3, polishing 10 grinding discs (each grinding disc is provided with 10 grinding heads made of soft fiber or wool soft materials) through a polishing machine, wherein the rotation speed is 200 r/min, the pressure is 9MPa, and anti-skid wax water is sprayed into capillary holes and the brick surface.

S4, polishing the permeable antifouling agent A on the brick surface by using 3 grinding discs of a polishing machine (each grinding disc is provided with 10 grinding heads, each grinding head is made of soft fiber or wool soft material), and the rotation speed is 200 r/min and the pressure is 4 MPa. The antifouling agent can effectively permeate into crystal gaps to play a role in preventing fouling.

S5, polishing the brick processed by the 4 processes by 2 grinding discs of a wax polishing machine (each rotary disc is provided with 3 grinding heads which are made of soft sponge or cotton cloth materials) at the rotation speed of 10 r/min and the pressure of 1MPa on the brick surface, wherein the antifouling agent B is silicon fluoride antifouling liquid.

The anti-skid wax comprises; an anti-skid material A and an anti-skid material B; the mass ratio of the anti-skid material A to the anti-skid material B is 2: 1; the molecular structural formula of the antiskid material A is as follows:

R₁and R₂Are respectively-CH₂-CH₂-；

The molecular structural formula of the antiskid material B is as follows:

the antifouling agent A comprises: antifouling material A and low boiling point solvent; the mass ratio of the low-boiling point solvent to the antifouling material A is 1: 3; the structure of the antifouling material A is as follows:

the low boiling point solvent is acetone;

the structural formula of the antifouling material B is

The above comparative examples a1-a4 were tested for gloss, slip and stain resistance with example A1 to give Table 1.

TABLE 1-Performance testing of comparative examples a1-a4 and example A1

Description of the drawings:

1. as can be seen from comparison of comparative examples a1-a2 with example A1, comparative example a1, which was not polished, showed a substantial decrease in gloss of only 60 degrees, and a comparable decrease in coefficient of friction of 0.70 (dry process) and 0.62 (wet process), was lower than that of example A1, and was unable to achieve high gloss and high slip resistance.

While comparative example a2 was not washed with the washing solution, the bricks in step S1 did not form a micro-porous structure and were also slightly reduced in gloss; importantly, because the subsequent anti-skid wax cannot be well matched with the microporous structure, the anti-skid performance of the anti-skid wax is greatly reduced to only 0.55 (dry method) and 0.44 (wet method), the final anti-skid performance is influenced, and the performances of the steps S3-S5 cannot be fully exerted.

2. It is understood from comparative example A3 and example a1 that step S4 of comparative example A3 is poor in surface effect by simply applying the antifouling agent a to the brick surface without using a polishing process, so that the subsequent step S5 cannot be performed, the final gloss of the product is slightly lowered, the grip performance is also lowered to 0.64 (dry method) and 0.54 (wet method), and the performance is better than that of other commercial bricks, but is still insufficient for example a 1. Meanwhile, the process of the antifouling agent A is not well applied, the permeation effect is not exerted, and the antifouling capability of the product is reduced and is only four-grade.

3. It can be seen from comparative example a4 and example A1 that step S5 of comparative example a4 affects the final properties of the product by applying it to the tile surface only by ordinary application, without using a waxing machine, and without applying a suitable cloth to the stain resist B. Since the antifouling material B is the outermost layer, which directly affects the gloss of the brick surface, the gloss is still not high and the antifouling property is not good without using a waxing machine.

Example B:

examples B1,

And S1, cleaning the fired ceramic tile, finely polishing the surface of the ceramic tile to the glossiness of 50 degrees by using a polishing machine, and polishing the edge of the ceramic tile by using an edge grinding machine.

And S2, cleaning the brick surface by using weak base cleaning solution (PH is 8), maintaining the process for about 10 seconds, then washing the brick surface by using a large amount of tap water, and cleaning the polishing waste residue and the cleaning solution which are not reacted in the micropores.

S3, polishing the anti-skid wax water into the capillary holes and the brick surface by 12 grinding discs of a polishing machine (each grinding disc is provided with 12 grinding heads made of soft fiber or wool soft material), wherein the rotating speed is 200 r/min, and the pressure is 12 MPa.

Example B2

And S1, cleaning the fired ceramic tile, finely polishing the surface of the ceramic tile to the glossiness of 50 degrees by using a polishing machine, and polishing the edge of the ceramic tile by using an edge grinding machine.

And S2, cleaning the brick surface by using weak base cleaning solution (PH is 8), maintaining the process for about 10 seconds, then washing the brick surface by using a large amount of tap water, and cleaning the polishing waste residue and the cleaning solution which are not reacted in the micropores.

S3, polishing the anti-skid wax water into the capillary holes and the brick surface by 12 grinding discs of a polishing machine (each grinding disc is provided with 12 grinding heads made of soft fiber or wool soft material), wherein the rotating speed is 200 r/min, and the pressure is 12 MPa.

S4, polishing the brick surface with 5 grinding discs of a polishing machine (each grinding disc is provided with 12 grinding heads made of soft fiber or wool soft material), rotating at 200 r/min and 4MPa to apply the permeable antifouling agent A on the brick surface. The antifouling agent can effectively permeate into crystal gaps to play a role in preventing fouling.

Example B3

And S1, cleaning the fired ceramic tile, finely polishing the surface of the ceramic tile to the glossiness of 50 degrees by using a polishing machine, and polishing the edge of the ceramic tile by using an edge grinding machine.

And S2, cleaning the brick surface by using weak base cleaning solution (PH is 8), maintaining the process for about 10 seconds, then washing the brick surface by using a large amount of tap water, and cleaning the polishing waste residue and the cleaning solution which are not reacted in the micropores.

S3, polishing the anti-skid wax water into the capillary holes and the brick surface by 12 grinding discs of a polishing machine (each grinding disc is provided with 12 grinding heads made of soft fiber or wool soft material), wherein the rotating speed is 200 r/min, and the pressure is 12 MPa.

S5, using 3 grinding discs of the waxing machine (each rotary disc is provided with 5 grinding heads which are made of soft sponge or cotton cloth materials), and applying the antifouling agent B on the surface of the brick at the rotating speed of 20 r/min and the pressure of 0.5MPa, wherein the antifouling agent B is silicon fluoride antifouling liquid.

Example B4

And S1, cleaning the fired ceramic tile, finely polishing the surface of the ceramic tile to the glossiness of 50 degrees by using a polishing machine, and polishing the edge of the ceramic tile by using an edge grinding machine.

And S2, cleaning the brick surface by using weak base cleaning solution (PH is 8), maintaining the process for about 10 seconds, then washing the brick surface by using a large amount of tap water, and cleaning the polishing waste residue and the cleaning solution which are not reacted in the micropores.

S3, polishing the anti-skid wax water into the capillary holes and the brick surface by 12 grinding discs of a polishing machine (each grinding disc is provided with 12 grinding heads made of soft fiber or wool soft material), wherein the rotating speed is 200 r/min, and the pressure is 12 MPa.

S4, polishing the brick surface with 5 grinding discs of a polishing machine (each grinding disc is provided with 12 grinding heads made of soft fiber or wool soft material), rotating at 200 r/min and 4MPa to apply the permeable antifouling agent A on the brick surface. The antifouling agent can effectively permeate into crystal gaps to play a role in preventing fouling.

S5, using 3 grinding discs of the waxing machine (each rotary disc is provided with 5 grinding heads which are made of soft sponge or cotton cloth materials), and applying the antifouling agent B on the surface of the brick at the rotating speed of 20 r/min and the pressure of 0.5MPa, wherein the antifouling agent B is silicon fluoride antifouling liquid.

Example B5

And S1, cleaning the fired ceramic tile, finely polishing the surface of the ceramic tile to the glossiness of 50 degrees by using a polishing machine, and polishing the edge of the ceramic tile by using an edge grinding machine.

And S2, cleaning the brick surface by using weak base cleaning solution (PH is 8), maintaining the process for about 10 seconds, then washing the brick surface by using a large amount of tap water, and cleaning the polishing waste residue and the cleaning solution which are not reacted in the micropores.

S3, polishing the anti-skid wax water into the capillary holes and the brick surface by 12 grinding discs of a polishing machine (each grinding disc is provided with 12 grinding heads made of soft fiber or wool soft material), wherein the rotating speed is 200 r/min, and the pressure is 12 MPa.

S5, using 3 grinding discs of the waxing machine (each rotary disc is provided with 5 grinding heads which are made of soft sponge or cotton cloth materials), and applying the antifouling agent B on the surface of the brick at the rotating speed of 20 r/min and the pressure of 0.5MPa, wherein the antifouling agent B is silicon fluoride antifouling liquid.

S4, polishing the brick surface with 5 grinding discs of a polishing machine (each grinding disc is provided with 12 grinding heads made of soft fiber or wool soft material), rotating at 200 r/min and 4MPa to apply the permeable antifouling agent A on the brick surface. The antifouling agent can effectively permeate into crystal gaps to play a role in preventing fouling.

The anti-skid wax comprises; an anti-skid material A and an anti-skid material B; the mass ratio of the antiskid material A to the antiskid material B is 3: 1; the molecular structural formula of the antiskid material A is as follows:

the molecular structural formula of the antiskid material B is as follows:

the antifouling agent A comprises: antifouling material A and low boiling point solvent; the mass ratio of the low-boiling point solvent to the antifouling material A is 1: 4; the structure of the antifouling material A is as follows:

the low boiling point solvent is ethanol;

the structural formula of the antifouling material B is

The gloss, slip and stain resistance tests conducted on the above examples B1-B5 were conducted to obtain Table 2.

TABLE 2 Performance testing of examples B1-B5 and Prior Art

Description of the drawings:

1. example B1 does not go through steps S4-S5, and although there is a certain performance deficiency with examples B2, B3 and B4, example B1 only uses anti-slip wax to polish to obtain better effect, and has no anti-fouling ability, but under the same cost condition, the performance is excellent, and the cost performance is better.

2. In example B2, step S5 was not performed, antifouling agent B was not used, the effect of the fluorinated silicone-based antifouling liquid was not exhibited, and the water-formable layer of nonslip wax was bonded to the antifouling agent A layer, but the gloss, the nonslip property, and the antifouling ability were all better than those of the conventional nonslip tile. Example B3 does not proceed to step S4, and the antifouling agent B layer is directly coated on the surface of the anti-skid wax layer, because of not enough matching, the overall performance is reduced compared with example S2, the antifouling ability is four-grade, but the overall performance is still better than that of the existing common anti-skid brick.

3. In the embodiment B5, the step S5 is performed first, and then the step S4 is performed; the antifouling agent A is not well filled between the anti-skid wax water forming layer and the antifouling agent B layer, the antifouling capacity is reduced to four levels, the glossiness is 85 degrees, and the friction coefficients are 0.70 (dry method) and 0.62 (wet method); in example B4, the gloss was the best 91 degrees, the friction coefficient was 0.75 (dry method) and 0.65 (wet method), and the antifouling ability was five-grade after the process of steps S1-S5; compared with the existing common anti-skid brick, the glossiness of the anti-skid brick is close to that of the common brick without anti-skid and anti-fouling treatment, and the anti-skid brick has a good mirror effect and excellent anti-skid capacity and anti-fouling capacity.

Example C

Example C1

And S1, cleaning the fired ceramic tile, finely polishing the surface of the ceramic tile to the glossiness of 50 degrees by using a polishing machine, and polishing the edge of the ceramic tile by using an edge grinding machine.

S11, polishing 10 grinding disks (each grinding disk is provided with 10 grinding heads made of soft fiber or wool soft materials) through a polishing machine at the rotating speed of 200 r/min and the pressure of 9MPa to obtain the ultra-clean and ultra-bright nano silicon solution raw material which is thrown on the surface of a brick.

And S2, cleaning the brick surface by using weak base cleaning solution (PH is 8), maintaining the process for about 10 seconds, then washing the brick surface by using a large amount of tap water, and cleaning the polishing waste residue and the cleaning solution which are not reacted in the micropores.

S3, polishing the anti-skid wax water into the capillary holes and the brick surface by 12 grinding discs of a polishing machine (each grinding disc is provided with 12 grinding heads made of soft fiber or wool soft material), wherein the rotating speed is 200 r/min, and the pressure is 12 MPa.

Example C2

And S1, cleaning the fired ceramic tile, finely polishing the surface of the ceramic tile to the glossiness of 50 degrees by using a polishing machine, and polishing the edge of the ceramic tile by using an edge grinding machine.

S11, polishing 10 grinding disks (each grinding disk is provided with 10 grinding heads made of soft fiber or wool soft materials) through a polishing machine at the rotating speed of 200 r/min and the pressure of 9MPa to obtain the ultra-clean and ultra-bright nano silicon solution raw material which is thrown on the surface of a brick.

And S2, cleaning the brick surface by using weak base cleaning solution (PH is 8), maintaining the process for about 10 seconds, then washing the brick surface by using a large amount of tap water, and cleaning the polishing waste residue and the cleaning solution which are not reacted in the micropores.

S3, polishing the anti-skid wax water into the capillary holes and the brick surface by 12 grinding discs of a polishing machine (each grinding disc is provided with 12 grinding heads made of soft fiber or wool soft material), wherein the rotating speed is 200 r/min, and the pressure is 12 MPa.

S4, polishing the brick surface with 5 grinding discs of a polishing machine (each grinding disc is provided with 12 grinding heads made of soft fiber or wool soft material), rotating at 200 r/min and 4MPa to apply the permeable antifouling agent A on the brick surface. The antifouling agent can effectively permeate into crystal gaps to play a role in preventing fouling.

S5, using 3 grinding discs of the waxing machine (each rotary disc is provided with 5 grinding heads which are made of soft sponge or cotton cloth materials), and applying the antifouling agent B on the surface of the brick at the rotating speed of 20 r/min and the pressure of 0.5MPa, wherein the antifouling agent B is silicon fluoride antifouling liquid.

The formulations used in examples C1 and C2 were the same as in example B.

The gloss performance tests of examples C1 and C2 described above were performed and compared to examples B1 and B4 to prepare Table 3.

TABLE 3 gloss contrast of examples C1, C2 with examples B1, B4

Description of the drawings:

comparing the example C1 with the example B1, it can be seen that the example C1 utilizes an ultra-clean and bright polisher to polish the brick surface, and then the original capillary pores on the brick surface are blocked, so that the transparency and the glossiness of the brick surface are improved, and the glossiness is 4 degrees higher than that of the B1; similarly, for example C2 and example B4, the gloss was also 4 degrees higher after example C2 added in step S11, which shows that after step S11, the following antislip wax, antisoiling material a and antisoiling material B are still suitable for step S11 added additionally, without adverse effect, but the gloss is improved, so that the performance of example B4 in the present invention is further improved.

The technical principle of the present invention is described above in connection with specific embodiments. The description is made for the purpose of illustrating the principles of the invention and should not be construed in any way as limiting the scope of the invention. Based on the explanations herein, those skilled in the art will be able to conceive of other embodiments of the present invention without inventive effort, which would fall within the scope of the present invention.