Polymerizable composition for optical material, polymerizable prepolymer composition for optical material, cured product, and method for producing optical material

文档序号：157051 发布日期：2021-10-26 浏览：33次中文

阅读说明：本技术 光学材料用聚合性组合物、光学材料用聚合性预聚物组合物、固化物及光学材料的制造方法 (Polymerizable composition for optical material, polymerizable prepolymer composition for optical material, cured product, and method for producing optical material ) 是由末杉幸治伊藤伸介中野将太郎松井勇辅于 2021-01-27 设计创作，主要内容包括：光学材料用聚合性组合物,其是包含2种以上不同的光学材料用单体、和聚合催化剂的光学材料用聚合性组合物,2种以上不同的光学材料用单体中的至少1种为不具有芳香环的异氰酸酯化合物,相对于2种以上不同的光学材料用单体的合计100质量份而言的、聚合催化剂的含量大于0.05质量份且为2.0质量份以下,所述光学材料用聚合性组合物的用B型粘度计、在25℃、60rpm的条件下测定的粘度为10mPa·s～1000mPa·s。(A polymerizable composition for optical materials, which comprises 2 or more different monomers for optical materials and a polymerization catalyst, wherein at least 1 of the 2 or more different monomers for optical materials is an isocyanate compound having no aromatic ring, and the content of the polymerization catalyst is more than 0.05 part by mass and 2.0 parts by mass or less relative to 100 parts by mass of the total of the 2 or more different monomers for optical materials, and the polymerizable composition for optical materials has a viscosity of 10 to 1000 mPas as measured with a B-type viscometer at 25 ℃ and 60 rpm.)

1. A polymerizable composition for optical materials, which comprises 2 or more different monomers for optical materials and a polymerization catalyst,

at least 1 of the 2 or more different optical material monomers is an isocyanate compound having no aromatic ring,

the content of the polymerization catalyst is more than 0.05 part by mass and 2.0 parts by mass or less relative to 100 parts by mass of the total of the 2 or more different optical material monomers,

the polymerizable composition for optical materials has a viscosity of 10 to 1000 mPas as measured with a B-type viscometer at 25 ℃ and 60 rpm.

2. The polymerizable composition for optical materials as claimed in claim 1, wherein the thixotropic ratio is 1.3 or less.

3. The polymerizable composition for optical materials as claimed in claim 1 or 2, comprising:

2 or more different monomers for optical materials;

a polymerization catalyst; and

a prepolymer having a polymerizable functional group, which is a polymer of the 2 or more different monomers for optical materials.

4. The polymerizable composition for optical materials according to any one of claims 1 to 3, wherein the 2 or more different monomers for optical materials comprise at least 1 active hydrogen compound selected from the group consisting of a polythiol compound having 2 or more mercapto groups, a hydroxythiol compound comprising 1 or more mercapto groups and 1 or more hydroxyl groups, a polyol compound comprising 2 or more hydroxyl groups, and an amine compound.

5. The polymerizable composition for optical materials as claimed in any one of claims 1 to 4, wherein the polymerization catalyst satisfies the following condition 1,

[ Condition 1]

-Ea/R is-7100 or more and-2900 or less,

ea is the reaction rate constant of the 2 or more different optical material monomers at 2 or more different temperatures, and activation energy calculated from Arrhenius plot, and R is the gas constant (8.314J/mol/K).

6. The polymerizable composition for optical materials according to any one of claims 1 to 5, wherein the polymerization catalyst comprises at least 1 selected from the group consisting of a basic catalyst having a pKa value of 4 to 8 and an organometallic catalyst.

7. A polymerizable prepolymer composition for optical materials, comprising: a prepolymer having a polymerizable functional group, which is a polymer of 2 or more different monomers for optical materials; and a polymerization catalyst,

at least 1 of the 2 or more different optical material monomers is an isocyanate compound having no aromatic ring,

the polymerizable prepolymer composition for optical materials has a viscosity of 10 to 2000 mPas as measured with a B-type viscometer at 25 ℃ and 60 rpm.

8. The polymerizable prepolymer composition for optical materials according to claim 7, wherein the content of the polymerization catalyst is 0.1 to 4.0 parts by mass relative to 100 parts by mass of the total amount of the prepolymers.

9. The polymerizable prepolymer composition for optical materials according to claim 7 or 8, wherein the 2 or more different monomers for optical materials comprise at least 1 active hydrogen compound selected from the group consisting of a polythiol compound having 2 or more mercapto groups, a hydroxythiol compound comprising 1 or more mercapto groups and 1 or more hydroxyl groups, a polyol compound comprising 2 or more hydroxyl groups, and an amine compound.

10. The polymerizable prepolymer composition for optical materials according to any one of claims 7 to 9, wherein the polymerization catalyst satisfies the following condition 1,

[ Condition 1]

-Ea/R is-7100 or more and-2900 or less,

11. The polymerizable prepolymer composition for optical materials as claimed in any one of claims 7 to 10, wherein the polymerization catalyst comprises at least 1 selected from the group consisting of a basic catalyst having a pKa value of 4 to 8 and an organometallic catalyst.

12. A cured product of the polymerizable composition for optical materials according to any one of claims 1 to 6 or the polymerizable prepolymer composition for optical materials according to any one of claims 7 to 11.

13. A method for producing an optical material, comprising the steps of:

at least 1 of the 2 or more different optical material monomers is an isocyanate compound having no aromatic ring,

the content of the polymerization catalyst is more than 0.05 parts by mass and 2.0 parts by mass or less with respect to 100 parts by mass of the total of the 2 or more different optical material monomers;

a casting step of adjusting the viscosity of the polymerizable composition for optical materials, measured with a B-type viscometer at 25 ℃ and 60rpm, to 10 to 1000 mPas, and casting the composition into a mold; and

and a curing step of curing the polymerizable composition for optical material by polymerizing the 2 or more different types of monomers for optical material in the polymerizable composition for optical material in the mold.

14. A method for producing an optical material, comprising the steps of:

a preparation step of preparing a total of 100 parts by mass of 2 or more different optical material monomers and 0.010 to 2.0 parts by mass of a polymerization catalyst; and

a pre-polymerization step of mixing a part of the 2 or more different optical material monomers and at least a part of the polymerization catalyst to polymerize at least a part of the 2 or more different optical material monomers to obtain a pre-polymer, thereby obtaining a mixture containing the pre-polymer,

at least 1 of the 2 or more different optical material monomers is an isocyanate compound having no aromatic ring.

15. The method for manufacturing an optical material according to claim 14, further comprising the steps of:

a step of producing a polymerizable composition for optical materials, in which a mixture containing the prepolymer is added with at least the remaining part of the 2 or more different monomers for optical materials, thereby obtaining a polymerizable composition for optical materials containing the 2 or more different monomers for optical materials, the prepolymer, and the polymerization catalyst; and

and a curing step of curing the 2 or more different optical material monomers in the polymerizable composition for optical material to obtain an optical material which is a cured product of the polymerizable composition for optical material.

16. The method for producing an optical material according to any one of claims 13 to 15, wherein the 2 or more different monomers for an optical material comprise at least 1 active hydrogen compound selected from the group consisting of a polythiol compound having 2 or more mercapto groups, a hydroxythiol compound containing 1 or more mercapto groups and 1 or more hydroxyl groups, a polyol compound containing 2 or more hydroxyl groups, and an amine compound.

17. The method for producing an optical material according to any one of claims 13 to 16, wherein the polymerization catalyst satisfies the following condition 1,

[ Condition 1]

-Ea/R is-7100 or more and-2900 or less,

18. The method for producing an optical material according to any one of claims 13 to 17, wherein the polymerization catalyst contains at least 1 selected from the group consisting of a basic catalyst having a pKa value of 4 to 8 and an organometallic catalyst.

19. The method for producing an optical material according to any one of claims 13 to 18, wherein the polymerization catalyst contains at least 1 selected from the group consisting of an amine-based catalyst and an organotin-based catalyst.

20. A cured product of 2 or more different optical monomers, wherein at least 1 of the 2 or more different optical monomers is an isocyanate compound having no aromatic ring, no cord having a length of 1.0mm or more is present within a range of 15mm from the center of the cured product, and the amine content is 0.03 mass% or more and 2.5 mass% or less as measured by gas chromatography-mass spectrometry.

Technical Field

The present disclosure relates to a polymerizable composition for an optical material, a polymerizable prepolymer composition for an optical material, a cured product, and a method for producing an optical material.

Background

Examples of a method for producing a resin that can be used for an optical material for a plastic lens include a cast polymerization method in which a polymerizable composition containing a monomer is injected into a mold (cast mold) and cured by heating.

In the cast polymerization method, an optical material (for example, a lens, a semi-finished blank (semi-finished blank), or the like) is obtained by preparing a polymerizable composition, degassing the composition, injecting the polymerizable composition into a mold (casting mold), heating the composition to cure the composition (polymerization reaction), taking out the product from the mold (mold release), and annealing the product.

In the heat curing, in order to improve the quality of the optical material, the polymerization reaction is generally carried out for several hours to several tens of hours while gradually increasing the temperature by heating, and specifically, it is generally required to be about 20 hours to 48 hours. In addition, it is known that much time in the total time of the manufacturing process (for example, 9 out of the total time) is consumed in the time for polymerization.

In the examples of patent document 1, there are described: the mold into which the polymerizable composition was injected was gradually heated from 10 ℃ to 120 ℃ and polymerized for 20 hours to obtain a molded article.

In addition, in the examples of patent document 2, there are described: the mold into which the polymerizable composition was injected was gradually heated from 25 ℃ to 120 ℃ over 16 hours, and heated at 120 ℃ for 4 hours to obtain a molded article.

Patent document 1: international publication No. 2014/027427

Patent document 2: international publication No. 2014/133111

Disclosure of Invention

Problems to be solved by the invention

As described above, conventionally, in the process of producing an optical material, a polymerization reaction is generally carried out for several hours to several tens of hours (for example, about 20 hours to 48 hours) while gradually raising the temperature by heating.

However, since the optical material is manufactured for a long time, the apparatus for manufacturing needs to be operated for a long time, which causes a large economic burden and impairs the work efficiency.

On the other hand, when an optical material is produced by a conventional method, it is considered that when the polymerization reaction is carried out by shortening the heating polymerization time, the polymerization is insufficient, and thus the optical material is not cured, or a defect such as a streak is generated in the optical material even if the curing is carried out, and the quality of the optical material is degraded.

In view of the above, there is a demand for shortening the manufacturing time of optical materials while maintaining the quality of the optical materials to be obtained in the manufacturing of the optical materials.

An object to be solved by one embodiment of the present disclosure is to provide a method for producing an optical material, which can maintain the quality of the obtained optical material and can shorten the production time of the optical material.

Further, an object to be solved by one embodiment of the present disclosure is to provide a polymerizable composition for an optical material that can be used in a method for producing an optical material, which can maintain the quality of the obtained optical material and can shorten the production time of the optical material.

Means for solving the problems

Specific means for solving the above problems include the following means.

Embodiment 1 of the present disclosure includes the following modes.

[ 1] A polymerizable composition for optical materials, which comprises 2 or more different monomers for optical materials, at least 1 of the 2 or more different monomers for optical materials being an isocyanate compound having no aromatic ring, and a polymerization catalyst, wherein the content of the polymerization catalyst is more than 0.05 parts by mass and 2.0 parts by mass or less relative to 100 parts by mass of the total of the 2 or more different monomers for optical materials, and wherein the polymerizable composition for optical materials has a viscosity of 10 to 1000 mPas as measured with a B-type viscometer at 25 ℃ and 60 rpm.

< 2 > the polymerizable composition for optical materials described in < 1 > has a thixotropic ratio (thixocopy ratio) of 1.3 or less.

The polymerizable composition for optical materials described in < 3 > such as < 1 > or < 2 > comprises: 2 or more different monomers for optical materials; a polymerization catalyst; and a prepolymer having a polymerizable functional group, which is a polymer of the aforementioned 2 or more different monomers for optical materials.

The polymerizable composition for optical materials of any one of < 4 > to < 1 > < 3 >, wherein the 2 or more different monomers for optical materials include at least 1 active hydrogen compound selected from the group consisting of a polythiol compound having 2 or more mercapto groups, a hydroxythiol compound containing 1 or more mercapto groups and 1 or more hydroxyl groups, a polyol compound containing 2 or more hydroxyl groups, and an amine compound.

The polymerizable composition for optical materials of < 5 > to < 1 > -4 > wherein the polymerization catalyst satisfies the following condition 1.

[ Condition 1]

-Ea/R is-7100 or more and-2900 or less.

(Ea is the reaction rate constant of the 2 or more different optical material monomers at 2 or more different temperatures and the activation energy calculated from the Arrhenius plot, and R is the gas constant (8.314J/mol/K).)

The polymerizable composition for optical materials of < 6 > to < 1 > -5 > wherein the polymerization catalyst contains at least 1 kind selected from the group consisting of a basic catalyst having a pKa value of 4 to 8 and an organometallic catalyst.

The polymerizable composition for optical materials of < 6-1 > or < 1 > -6 > wherein the polymerization catalyst contains at least 1 kind selected from the group consisting of amine-based catalysts and organotin-based catalysts.

< 6-2 > the polymerizable composition for optical materials according to any one of < 1 > to < 6-1 >, wherein the polymerization catalyst contains at least 1 selected from the group consisting of 3, 5-lutidine, 2,4, 6-collidine, triethylenediamine, N-dimethylethanolamine, N-ethylmorpholine, dibutyltin dichloride, dimethyltin dichloride, dibutyltin dilaurate and dibutyltin diacetate.

< 7 > a polymerizable prepolymer composition for optical materials comprising: a prepolymer having a polymerizable functional group, which is a polymer of 2 or more different monomers for optical materials; and a polymerization catalyst, wherein at least 1 of the 2 or more different monomers for an optical material is an isocyanate compound having no aromatic ring, and the polymerizable prepolymer composition for an optical material has a viscosity of 10 to 2000 mPas as measured with a B-type viscometer at 25 ℃ and 60 rpm.

< 8 > and < 7 > wherein the content of the polymerization catalyst is 0.1 to 4.0 parts by mass based on 100 parts by mass of the total amount of the prepolymers.

The polymerizable prepolymer composition for optical materials described in < 8-1 > such as < 7 > or < 8 > has a thixotropic ratio of 1.3 or less.

The polymerizable prepolymer composition for optical materials described in any one of < 8-2 > to < 7 > -8-1, wherein the prepolymer contains an isocyanate group.

The polymerizable prepolymer composition for optical materials described in any one of < 8-3 > to < 8-1 >, wherein the prepolymer contains substantially no isocyanate group.

The polymerizable prepolymer composition for optical materials of < 9 > as defined in any one of < 7 > to < 8-3 >, wherein the 2 or more different monomers for optical materials comprise at least 1 active hydrogen compound selected from the group consisting of a polythiol compound having 2 or more mercapto groups, a hydroxythiol compound containing 1 or more mercapto groups and 1 or more hydroxyl groups, a polyol compound containing 2 or more hydroxyl groups, and an amine compound.

The polymerizable prepolymer composition for optical materials, wherein the polymerization catalyst satisfies the following condition 1, as described in any one of < 10 > to < 7 > -9 >.

[ Condition 1]

-Ea/R is-7100 or more and-2900 or less.

The polymerizable prepolymer composition for optical materials, wherein the polymerization catalyst comprises at least 1 kind selected from the group consisting of a basic catalyst having a pKa value of 4 to 8 and an organometallic catalyst, and < 11 > is, for example, < 7 > to < 10 >.

The polymerizable prepolymer composition for optical materials, wherein the polymerization catalyst comprises at least 1 selected from the group consisting of amine catalysts and organotin catalysts, and the composition is < 11-1 > or < 7 > -11 >.

The polymerizable prepolymer composition for optical materials described in any one of < 11-2 > to < 7 > -11-1, wherein a value obtained by subtracting a refractive index B of a prepolymer raw material composition, which is a composition before the formation of the prepolymer and contains the 2 or more different monomers for optical materials and a polymerization catalyst, from a refractive index A of the polymerizable prepolymer composition for optical materials is greater than 0.

A cured product of the polymerizable composition for optical materials described in any one of < 12 > to < 6-2 > or the polymerizable prepolymer composition for optical materials described in any one of < 7 > to < 11-2 >.

A cured product of the polymerizable composition for optical materials described in < 12-1 > or < 12 > wherein the 2 or more different types of monomers for optical materials include at least 1 type of active hydrogen compound selected from the group consisting of a polythiol compound having 2 or more mercapto groups, a hydroxythiol compound having 1 or more mercapto groups and 1 or more hydroxyl groups, a polyol compound having 2 or more hydroxyl groups, and an amine compound.

A cured product of the polymerizable composition for optical materials, wherein the polymerization catalyst satisfies the following condition 1, and < 12-2 > is, for example, < 12 > or < 12-1 >.

[ Condition 1]

-Ea/R is-7100 or more and-2900 or less.

The cured product of any one of the above polymerizable compositions for optical materials < 12-3 > such as < 12 > -12-2 > wherein the polymerization catalyst contains at least 1 kind selected from the group consisting of a basic catalyst having a pKa value of 4 to 8 and an organometallic catalyst.

The cured product of any one of < 12-4 > to < 12-3 >, which is a cured product of the polymerizable composition for optical materials, wherein the polymerization catalyst contains at least 1 selected from the group consisting of an amine-based catalyst and an organotin-based catalyst.

The cured product of any one of the formulas < 12-5 > and < 12-4 > is a cured product of the polymerizable composition for optical materials, wherein the polymerization catalyst contains at least 1 selected from the group consisting of 3, 5-lutidine, 2,4, 6-collidine, triethylenediamine, N-dimethylethanolamine, N-ethylmorpholine, dibutyltin dichloride, dimethyltin dichloride, dibutyltin dilaurate and dibutyltin diacetate.

< 13 > a method for producing an optical material, comprising the steps of:

at least 1 of the 2 or more different optical material monomers is an isocyanate compound having no aromatic ring, and the content of the polymerization catalyst is more than 0.05 parts by mass and 2.0 parts by mass or less with respect to 100 parts by mass of the total of the 2 or more different optical material monomers; and

< 14 > a method for producing an optical material, comprising the steps of:

a preparation step of preparing a total of 100 parts by mass of 2 or more different optical material monomers and 0.010 to 2.0 parts by mass of a polymerization catalyst; and

at least 1 of the 2 or more different optical material monomers is an isocyanate compound having no aromatic ring.

The method for producing an optical material of < 15 > or < 14 > further comprises the steps of:

and a curing step of curing the 2 or more different types of monomers for optical materials in the polymerizable composition for optical materials to obtain an optical material which is a cured product of the polymerizable composition for optical materials.

The method of producing an optical material of any one of < 16 > to < 15 >, wherein the 2 or more different monomers for an optical material include at least 1 active hydrogen compound selected from the group consisting of a polythiol compound having 2 or more mercapto groups, a hydroxythiol compound containing 1 or more mercapto groups and 1 or more hydroxyl groups, a polyol compound containing 2 or more hydroxyl groups, and an amine compound.

The method of producing an optical material as described in any one of < 17 > to < 13 > to < 16 >, wherein the polymerization catalyst satisfies the following condition 1.

[ Condition 1]

-Ea/R is-7100 or more and-2900 or less.

The method for producing an optical material as described in any one of < 18 > to < 13 > to < 17 >, wherein the polymerization catalyst contains at least 1 kind selected from the group consisting of a basic catalyst having a pKa value of 4 to 8 and an organometallic catalyst.

The method for producing an optical material as described in any one of < 19 > to < 13 > wherein the polymerization catalyst contains at least 1 kind selected from the group consisting of an amine-based catalyst and an organotin-based catalyst.

< 20 > a cured product which is a cured product of 2 or more different optical monomers, wherein at least 1 of the 2 or more different optical monomers is an isocyanate compound having no aromatic ring, no rib having a length of 1.0mm or more is present within a range of a radius of 15mm from the center of the cured product, and the amine content as measured by gas chromatography mass spectrometry is 0.03 mass% or more and 2.5 mass% or less.

ADVANTAGEOUS EFFECTS OF INVENTION

According to one embodiment of the present disclosure, a method for producing an optical material can be provided, which can maintain the quality of the obtained optical material and can favorably shorten the production time of the optical material.

In addition, according to another embodiment of the present disclosure, a polymerizable composition for an optical material that can be used in a method for producing an optical material, which can maintain the quality of the obtained optical material and can favorably shorten the production time of the optical material, can be provided.

According to one embodiment of the present disclosure, a method for producing an optical material, which can reduce the time required for producing an optical material while maintaining the quality of the obtained optical material, can be provided.

Further, according to one embodiment of the present disclosure, a polymerizable composition for an optical material that can be used in a method for producing an optical material, which can maintain the quality of the obtained optical material and can shorten the production time of the optical material, can be provided.

According to one embodiment of the present disclosure, a method for producing an optical material, which can suppress striae in the obtained optical material and can shorten the production time of the optical material, can be provided.

Further, according to one embodiment of the present disclosure, a polymerizable composition for an optical material that can be used in a method for producing an optical material, which can suppress striae in the obtained optical material and can shorten the production time of the optical material, can be provided.

Drawings

FIG. 1 is a graph showing the relationship between the elapsed time of the polymerization reaction and the temperature in the heat-insulated container in example 8A.

Detailed Description

In the present disclosure, a numerical range represented by "to" means a range including numerical values described before and after "to" as a lower limit value and an upper limit value.

In the present disclosure, when a plurality of substances belonging to each component are present in the composition, the amount of each component in the composition refers to the total amount of the plurality of substances present in the composition, unless otherwise specified.

In the numerical ranges described in stages in the present disclosure, the upper limit value or the lower limit value described in one numerical range may be replaced with the upper limit value or the lower limit value described in other numerical ranges described in stages. In addition, in the numerical ranges described in the present disclosure, the upper limit value or the lower limit value of the numerical range may be replaced with the values shown in the embodiments.

In the present disclosure, the term "step" is not limited to an independent step, and is also included in the term as long as the desired purpose of the step is achieved even when the step cannot be clearly distinguished from other steps.

The present disclosure includes embodiment 1 and embodiment 2.

Each embodiment will be described.

Implementation E1E

Polymerizable composition for optical Material

The polymerizable composition for optical materials according to embodiment 1 is a polymerizable composition for optical materials comprising 2 or more different monomers for optical materials, at least 1 of the 2 or more different monomers for optical materials being an isocyanate compound having no aromatic ring, and a polymerization catalyst, the content of the polymerization catalyst being more than 0.05 parts by mass and 2.0 parts by mass or less relative to 100 parts by mass of the total of the 2 or more different monomers for optical materials, and the polymerizable composition for optical materials having a viscosity of 10 to 1000mPa · s as measured with a B-type viscometer at 25 ℃ and 60 rpm.

The polymerizable composition for optical materials according to embodiment 1, which includes the above-described configuration, can maintain the quality of the obtained optical material and can favorably shorten the production time of the optical material.

(monomer for optical Material)

The polymerizable composition for optical materials of embodiment 1 includes 2 or more different monomers for optical materials, and at least 1 of the monomers for optical materials is an isocyanate compound having no aromatic ring.

The monomer for an optical material is not particularly limited as long as it is a monomer that can be used for optical applications.

For example, the monomer may be used for producing an optical material having any of the following properties.

The optical material obtained using the monomer for an optical material may have a total light transmittance of 10% or more. The total light transmittance of the optical material may be measured in accordance with JIS K7361-1 (1997).

The haze (i.e., total haze) of the optical material obtained using the monomer for an optical material may be 10% or less, preferably 1% or less, and more preferably 0.5% or less. The haze of the optical material was measured at 25 ℃ in accordance with JIS-K7105 using a haze measuring machine (available from Tokyo electrochromatography, TC-HIII DPK).

The refractive index of the optical material obtained using the monomer for an optical material is preferably 1.58 or more. The refractive index of the optical material obtained using the monomer for an optical material may be 1.80 or less, and may be 1.75 or less. The refractive index of the optical material may be measured according to JIS K7142 (2014).

The shape of the optical material obtained using the optical material monomer is not particularly limited, and may be a plate shape, a cylindrical shape, a rectangular parallelepiped shape, or the like.

Examples of the monomer for an optical material include polymerizable monomers that are polymerized using a polymerization catalyst described later. Specifically, there may be mentioned isocyanate compounds, polythiol compounds having 2 or more mercapto groups, hydroxythiol compounds containing 1 or more mercapto groups and 1 or more hydroxyl groups, polyol compounds containing 2 or more hydroxyl groups, amine compounds and the like.

The 2 or more different optical material monomers preferably include at least 1 active hydrogen compound selected from the group consisting of a polythiol compound having 2 or more mercapto groups, a hydroxythiol compound including 1 or more mercapto groups and 1 or more hydroxyl groups, a polyol compound including 2 or more hydroxyl groups, and an amine compound.

[ isocyanate Compound ]

Examples of the isocyanate compound include aliphatic isocyanate compounds, alicyclic isocyanate compounds, aromatic isocyanate compounds, heterocyclic isocyanate compounds, and the like, and 1 kind or 2 or more kinds thereof may be used in combination. These isocyanate compounds may comprise dimers, trimers, prepolymers. Examples of the isocyanate compound include those exemplified in International publication No. 2011/055540.

Further, as the isocyanate compound, halogen-substituted compounds (for example, chlorine-substituted compounds, bromine-substituted compounds, etc.), alkyl-substituted compounds, alkoxy-substituted compounds, carbodiimide-modified compounds, urea-modified compounds, biuret-modified compounds of the above-mentioned compounds,

prepolymer-type modified products of the above-mentioned compounds with nitro-substituted compounds, polyhydric alcohols and the like,

dimerization or trimerization reaction products of the above compounds, and the like.

These compounds may be used alone or in combination of 2 or more.

In the present disclosure, the alicyclic isocyanate compound refers to an isocyanate compound that includes an alicyclic structure and may include a structure other than the alicyclic structure, such as a heterocyclic structure.

The aromatic isocyanate compound is an isocyanate compound which has an aromatic structure and may have any one of an aliphatic structure, an alicyclic structure and a heterocyclic structure or a combination thereof.

The heterocyclic isocyanate compound is an isocyanate compound having a heterocyclic structure and not having an alicyclic structure or an aromatic structure.

The aliphatic isocyanate compound is an isocyanate compound containing no aromatic structure, no alicyclic structure, and no heterocyclic structure.

The isocyanate compound preferably contains at least 1 selected from the group consisting of an aliphatic isocyanate compound, an alicyclic isocyanate compound, an aromatic isocyanate compound and a heterocyclic isocyanate compound.

At least 1 kind of the optical material monomer in embodiment 1 is an isocyanate compound having no aromatic ring. Specific examples of the isocyanate compound having no aromatic ring include alicyclic isocyanate compounds, heterocyclic isocyanate compounds, and aliphatic isocyanate compounds having no aromatic ring. The alicyclic isocyanate compound, heterocyclic isocyanate compound, and aliphatic isocyanate compound having no aromatic ring are preferable in that the polymerization reaction rate is not too high and the polymerization reaction can be easily controlled, as compared with the isocyanate compound having an aromatic ring.

The monomer for an optical material may contain an isocyanate compound other than an isocyanate compound having no aromatic ring.

When the monomer for an optical material contains an isocyanate compound having no aromatic ring and an isocyanate compound having an aromatic ring, the ratio of the isocyanate compound having no aromatic ring to the isocyanate compound having an aromatic ring is preferably in the range of 7:3 to 10:0, and more preferably in the range of 8:2 to 10:0 in terms of the molar ratio of isocyanate groups, from the viewpoint of controlling the polymerization reaction.

The isocyanate compound other than the isocyanate compound having no aromatic ring is not particularly limited, and examples thereof include isocyanate compounds having an aromatic ring. When the monomer for an optical material contains an isocyanate compound having no aromatic ring and an isocyanate compound having an aromatic ring, the number of moles of isocyanate groups in the isocyanate compound having no aromatic ring is preferably larger than the number of moles of isocyanate groups in the isocyanate compound having an aromatic ring.

In embodiment 1, the isocyanate compound preferably contains at least 1 selected from the group consisting of isophorone diisocyanate, 2, 5-bis (isocyanotomethyl) bicyclo- [2.2.1] -heptane, 2, 6-bis (isocyanotomethyl) bicyclo- [2.2.1] -heptane, m-xylylene diisocyanate, 2, 4-tolylene diisocyanate, 2, 6-tolylene diisocyanate, dicyclohexylmethane diisocyanate, 1, 3-bis (isocyanotomethyl) cyclohexane, 1, 4-bis (isocyanotomethyl) cyclohexane, 1, 6-hexamethylene diisocyanate, and 1, 5-pentamethylene diisocyanate, from the viewpoint of maintaining the quality of the optical material and shortening the production time of the optical material,

more preferably at least 1 selected from the group consisting of isophorone diisocyanate, 2, 5-bis (isocyanatomethyl) bicyclo- [2.2.1] -heptane, 2, 6-bis (isocyanatomethyl) bicyclo- [2.2.1] -heptane, dicyclohexylmethane diisocyanate, and 1, 3-bis (isocyanatomethyl) cyclohexane,

further preferably contains at least 1 selected from the group consisting of 2, 5-bis (isocyanotomethyl) bicyclo- [2.2.1] -heptane, 2, 6-bis (isocyanotomethyl) bicyclo- [2.2.1] -heptane, dicyclohexylmethane diisocyanate, and 1, 3-bis (isocyanotomethyl) cyclohexane.

[ active Hydrogen Compound ]

Examples of the active hydrogen compound include a polythiol compound having 2 or more mercapto groups, a hydroxythiol compound containing 1 or more mercapto groups and 1 or more hydroxyl groups, a polyol compound containing 2 or more hydroxyl groups, and an amine compound.

As the active hydrogen compound, an oligomer of the active hydrogen compound, a halogen-substituted compound of the active hydrogen compound (for example, a chlorine-substituted compound, a bromine-substituted compound, etc.), and the like can be used.

The active hydrogen compounds may be used alone or in combination of 2 or more.

(polythiol compound having 2 or more mercapto groups)

Examples of the polythiol compound having 2 or more mercapto groups include those exemplified in International publication No. 2016/125736.

In embodiment 1, from the viewpoint of maintaining the quality of the optical material and shortening the time required for producing the optical material, the polythiol compound preferably includes a compound selected from the group consisting of 4-mercaptomethyl-1, 8-dimercapto-3, 6-dithiaoctane, 5, 7-dimercaptomethyl-1, 11-dimercapto-3, 6, 9-trithiaundecane, 4, 8-dimercaptomethyl-1, 11-dimercapto-3, 6, 9-trithiaundecane, pentaerythritol tetrakis (3-mercaptopropionate), bis (mercaptoethyl) sulfide, pentaerythritol tetrakis (2-mercaptoacetate), 2, 5-bis (mercaptomethyl) -1, at least 1 of 4-dithian, 1,3, 3-tetra (mercaptomethylthio) propane, 4, 6-bis (mercaptomethylthio) -1, 3-dithian, and 2- (2, 2-bis (mercaptomethylthio) ethyl) -1, 3-dithian,

more preferably at least 1 selected from the group consisting of 4-mercaptomethyl-1, 8-dimercapto-3, 6-dithiaoctane, 5, 7-dimercapto-1, 11-dimercapto-3, 6, 9-trithioundecane, 4, 8-dimercapto-1, 11-dimercapto-3, 6, 9-trithioundecane, pentaerythritol tetrakis (3-mercaptopropionate), pentaerythritol tetrakis (2-mercaptoacetate), and 2, 5-bis (mercaptomethyl) -1, 4-dithiacyclohexane,

further preferably contains at least 1 selected from the group consisting of 4-mercaptomethyl-1, 8-dimercapto-3, 6-dithiaoctane, 5, 7-dimercapto-1, 11-dimercapto-3, 6, 9-trithioundecane, 4, 8-dimercapto-1, 11-dimercapto-3, 6, 9-trithioundecane and pentaerythritol tetrakis (3-mercaptopropionate).

(polythiol compound having 3 or more mercapto groups)

As the active hydrogen compound, there may be mentioned a polythiol compound having 3 or more mercapto groups.

When the polymerizable composition for optical materials of embodiment 1 includes a polythiol compound having 3 or more mercapto groups as an active hydrogen compound, it is preferable to include a compound (also referred to as compound (N1)) obtained by replacing at least 1 mercapto group of 3 or more mercapto groups included in the polythiol compound having 3 or more mercapto groups with a group represented by formula (N1) described below, from the viewpoint of promoting the polymerization reaction.

[ chemical formula 1]

In formula (N1), a indicates a bonding site.

In the polymerizable composition for an optical material according to embodiment 1, when the peak area is measured by high performance liquid chromatography, the peak area of the compound (N1) is preferably 3.0 or less, more preferably 1.5 or less, relative to the peak area 100 of the polythiol compound having 3 or more thiol groups, from the viewpoint of easy adjustment of the polymerization reaction.

In the case of measuring the peak area by high performance liquid chromatography, the peak area of the compound (N1) is preferably 0.01 or more relative to the peak area 100 of the polythiol compound having 3 or more thiol groups, from the viewpoint of promoting the polymerization reaction.

The peak area by high performance liquid chromatography can be measured by the method described in paragraph 0146 and the like of International publication No. 2014/027665.

(hydroxythiol compounds containing 1 or more mercapto groups and 1 or more hydroxyl groups)

Examples of the thiol compound having a hydroxyl group include, but are not limited to, 2-mercaptoethanol, 3-mercapto-1, 2-propanediol, glycerol bis (thioglycolate), 4-mercaptophenol, 2, 3-dimercapto-1-propanol, pentaerythritol tris (3-mercaptopropionate), and pentaerythritol tris (thioglycolate).

(polyol compound containing 2 or more hydroxyl groups)

Examples of the polyol compound include 1 or more kinds of aliphatic or alicyclic alcohols. Specifically, there may be mentioned linear or branched aliphatic alcohols, alicyclic alcohols, alcohols obtained by adding at least 1 kind selected from the group consisting of ethylene oxide, propylene oxide and e-caprolactone to these alcohols, and the like. More specifically, compounds exemplified in International publication No. 2016/125736 are exemplified.

The polyol compound is preferably at least 1 selected from the group consisting of ethylene glycol, diethylene glycol, triethylene glycol, propylene glycol, 1, 3-propanediol, 1, 2-cyclopentanediol, 1, 3-cyclopentanediol, 1, 2-cyclohexanediol, 1, 3-cyclohexanediol, and 1, 4-cyclohexanediol.

(amine Compound)

Examples of the amine compound include: ethylenediamine, 1, 2-or 1, 3-diaminopropane, 1,2-, 1, 3-or 1, 4-diaminobutane, 1, 5-diaminopentane, 1, 6-diaminohexane, 1, 7-diaminoheptane, 1, 8-diaminooctane, 1, 10-diaminodecane, 1,2-, 1, 3-or 1, 4-diaminocyclohexane, o-, m-or p-diaminobenzene, 3, 4-or 4,4 '-diaminobenzophenone, 3, 4-or 4, 4' -diaminodiphenyl ether, 4 '-diaminodiphenylmethane, 4' -diaminodiphenyl sulfide, 3 'or 4, 4' -diaminodiphenyl sulfone, 2, 7-diaminofluorene, 1, 5-), Primary polyamine compounds such as 1, 8-or 2, 3-diaminonaphthalene, 2,3-, 2, 6-or 3, 4-diaminopyridine, 2, 4-or 2, 6-diaminotoluene, m-or p-xylylenediamine, isophoronediamine, diaminomethylcyclohexane, 1, 3-or 1, 4-diaminomethylcyclohexane, 2-or 4-aminopiperidine, 2-or 4-aminomethylpiperidine, 2-or 4-aminoethylpiperidine, N-aminoethylmorpholine and N-aminopropylmorpholine;

monofunctional secondary amine compounds such as diethylamine, dipropylamine, di-N-butylamine, di-sec-butylamine, diisobutylamine, di-N-pentylamine, di-3-pentylamine, dihexylamine, dioctylamine, di (2-ethylhexyl) amine, methylhexylamine, diallylamine, N-methylallylamine, piperidine, pyrrolidine, diphenylamine, N-methylamine, N-ethylamine, dibenzylamine, N-methylbenzylamine, N-ethylbenzylamine, dicyclohexylamine, N-methylaniline, N-ethylaniline, dinaphthylamine, 1-methylpiperazine, morpholine and the like;

n, N '-dimethylethylenediamine, N' -dimethyl-1, 2-diaminopropane, N '-dimethyl-1, 3-diaminopropane, N' -dimethyl-1, 2-diaminobutane, N '-dimethyl-1, 3-diaminobutane, N' -dimethyl-1, 4-diaminobutane, N '-dimethyl-1, 5-diaminopentane, N' -dimethyl-1, 6-diaminohexane, N '-dimethyl-1, 7-diaminoheptane, N' -diethylethylenediamine, N '-diethyl-1, 2-diaminopropane, N' -diethyl-1, 3-diaminopropane, N '-diethyl-1, 2-diaminobutane, N' -diethyl-1, 3-diaminobutane, N '-diethyl-1, 4-diaminobutane, N' -diethyl-1, 5-diaminopentane, N '-diethyl-1, 6-diaminohexane, N' -diethyl-1, 7-diaminoheptane, piperazine, 2-methylpiperazine, 2, 5-dimethylpiperazine, 2, 6-dimethylpiperazine, homopiperazine, 1-bis (4-piperidinyl) methane, 1, 2-bis (4-piperidinyl) ethane, 1, 3-bis (4-piperidinyl) propane, N '-diethyl-1, 4-diaminobutane, N' -diethyl-1, 6-diaminopiperazine, piperazine, 1-bis (4-piperidinyl) methane, 1, 2-bis (4-piperidinyl) ethane, 1, 3-bis (4-piperidinyl) propane, N '-diethyl-1, 3-diaminobutane, N' -diethyl-1, 4-diaminohexane, Secondary polyamine compounds such as 1, 4-bis (4-piperidyl) butane and tetramethylguanidine; and so on.

Among the above, the active hydrogen compound preferably contains a polythiol compound having 2 or more mercapto groups, from the viewpoint of improving heat resistance and refractive index.

The content of the polythiol compound having 2 or more mercapto groups is preferably 60% by mass or more, more preferably 70% by mass or more, and further preferably 80% by mass or more, relative to the total mass of the active hydrogen compound.

In addition, as the active hydrogen compound in embodiment 1, the total content of 4-mercaptomethyl-1, 8-dimercapto-3, 6-dithiaoctane, 5, 7-dimercaptomethyl-1, 11-dimercapto-3, 6, 9-trithiaundecane, 4, 8-dimercaptomethyl-1, 11-dimercapto-3, 6, 9-trithiaundecane, and pentaerythritol tetrakis (3-mercaptopropionate) is preferably 60 mass% or more, more preferably 70 mass% or more, and still more preferably 80 mass% or more, with respect to the total mass of the active hydrogen compound.

In the composition, the molar ratio of the total of the hydroxyl group (OH group) and the mercapto group (SH group) in the active hydrogen compound (NCO group/(OH group + SH group)) to the isocyanate group (NCO group) in the isocyanate compound is preferably 0.8 or more, more preferably 0.85 or more, and still more preferably 0.9 or more.

In the composition, the molar ratio of the total of the hydroxyl group (OH group) and the mercapto group (SH group) in the active hydrogen compound (NCO group/(OH group + SH group)) to the isocyanate group (NCO group) in the isocyanate compound is preferably 1.2 or less, more preferably 1.15 or less, and still more preferably 1.1 or less.

< polymerization catalyst >

The polymerizable composition for optical materials of embodiment 1 contains at least 1 polymerization catalyst.

The polymerization catalyst is not particularly limited, and for example, a basic catalyst, an organometallic catalyst, zinc carbamate, ammonium salt, sulfonic acid, or the like can be used.

The polymerization catalyst may be used alone in 1 kind, or may be used in combination of 2 or more kinds.

(basic catalyst)

Examples of the basic catalyst include amine catalysts (including imidazole catalysts).

Specific examples thereof include tertiary amine catalysts such as triethylenediamine, N-dimethylethanolamine, triethylamine and N-ethylmorpholine; 2-methylpyrazine, pyridine, α -methylpyridine, β -methylpyridine, γ -methylpyridine, 2, 6-dimethylpyridine, 3, 5-dimethylpyridine, 2,4, 6-trimethylpyridine, 3-chloropyridine, N-diethylaniline, N-dimethylaniline, hexamethylenetetramine, quinoline, isoquinoline, N-dimethyl-p-toluidine, N-dimethylpiperazine, quinaldine, 4-methylmorpholine, triallylamine, trioctylamine, 1, 2-dimethylimidazole, 1-benzyl-2-methylimidazole and the like.

Among the above, as the basic catalyst, an amine-based catalyst is preferable.

Examples of the amine-based catalyst include 3, 5-lutidine; 2,4, 6-trimethylpyridine; tertiary amine catalysts such as triethylenediamine, N-dimethylethanolamine, triethylamine, N-ethylmorpholine and the like; and so on.

The amine catalyst preferably contains at least 1 selected from the group consisting of 3, 5-lutidine, 2,4, 6-collidine, triethylenediamine, N-dimethylethanolamine, and N-ethylmorpholine.

The basic catalyst also preferably contains a compound represented by the following general formula (2) and/or a compound represented by the following general formula (3).

[ chemical formula 2]

In the general formula (2), R₁Represents a straight-chain alkyl group having 1 to 20 carbon atoms, a branched chain having 3 to 20 carbon atomsAn alkyl group, a cycloalkyl group having 3 to 20 carbon atoms, or a halogen atom, wherein a plurality of R are present₁May be the same or different. Q represents a carbon atom or a nitrogen atom. m represents an integer of 0 to 5.

[ chemical formula 3]

In the general formula (3), R₂、R₃And R₄Each independently represents a linear alkyl group having 3 to 20 carbon atoms, a branched alkyl group having 3 to 20 carbon atoms, a cycloalkyl group having 3 to 20 carbon atoms, an allyl group, or a hydroxyl group-containing hydrocarbon group.

The pKa value of the basic catalyst is preferably 1 or more, more preferably 3 or more, and still more preferably 4 or more.

The pKa value of the basic catalyst is preferably 9 or less, and more preferably 8 or less.

The pKa value (acid dissociation index) can be measured, for example, by The method described in (a) The Journal of Physical Chemistry vol.68, number6, page1560(1964), (b) a method using an automatic potential difference titrator (AT-610 (trade name) manufactured by Kyoto electronics industries, Ltd.), or by The acid dissociation index described in (c) The chemical review by The Japan chemical society (revised version 3, Showa 59, 6/25 th, issued by Takayasu Co., Ltd.).

(organometallic catalyst)

Examples of the organometallic catalyst include organotin catalysts; organic acid salts of iron, nickel, zinc, and the like; an acetylacetone complex; a catalyst composition comprising a carboxylic acid metal compound and a quaternary ammonium salt compound; a catalyst composition formed from a 2-cyclic tertiary amine compound; metal catalysts in which an alkoxy group, a carboxyl group, or the like is coordinated to titanium or aluminum; and so on.

Among the above, the organic metal-based catalysts are preferably organic tin-based catalysts.

Examples of the organotin catalyst include dibutyltin Dichloride (DBC), dimethyltin Dichloride (DMC), dibutyltin dilaurate (DBTDL), dibutyltin diacetate and the like.

The organotin-based catalyst preferably contains at least 1 selected from the group consisting of dibutyltin dichloride, dimethyltin dichloride, dibutyltin dilaurate and dibutyltin diacetate.

The polymerization catalyst preferably contains at least 1 kind selected from the group consisting of a basic catalyst having a pKa value of 4 to 8 and an organometallic catalyst.

The polymerization catalyst also preferably contains at least 1 selected from the group consisting of amine-based catalysts and organotin-based catalysts.

The polymerization catalyst preferably contains at least 1 selected from the group consisting of 3, 5-lutidine, 2,4, 6-collidine, triethylenediamine, N-dimethylethanolamine, N-ethylmorpholine, dibutyltin dichloride, dimethyltin dichloride, dibutyltin dilaurate and dibutyltin diacetate.

The polymerizable composition for optical materials of embodiment 1 contains the polymerization catalyst in an amount of more than 0.05 parts by mass and 2.0 parts by mass or less based on 100 parts by mass of the total of the 2 or more different optical material monomers.

The content of the polymerization catalyst in embodiment 1 is higher than that in the conventional method for producing an optical material.

Thus, when the optical material monomer in the polymerizable composition for an optical material is polymerized in the curing step, the reaction heat of the polymerizable composition for an optical material (i.e., heat generated by self-heating) can be generated in a short time. Therefore, the polymerization reaction can be favorably accelerated, and as described later, the viscosity of the polymerizable composition can be increased, thermal convection presumably causing striae can be suppressed, and a high-quality optical material can be obtained in a shorter time than in the past.

When the content of the polymerization catalyst is more than 0.05 part by mass relative to 100 parts by mass of the total of the 2 or more different optical material monomers, the polymerization reaction can be favorably accelerated, and thus a high-quality optical material can be obtained in a short time. Further, by favorably promoting the polymerization reaction, the releasability when the cured product is taken out from the mold can be improved.

From the above viewpoint, the content of the polymerization catalyst is preferably 0.08 parts by mass or more, preferably 0.10 parts by mass or more, more preferably 0.13 parts by mass or more, and further preferably 0.17 parts by mass or more, relative to 100 parts by mass of the total of the 2 or more different optical material monomers.

By setting the content of the polymerization catalyst to 2.0 parts by mass or less with respect to 100 parts by mass of the total of the 2 or more different optical material monomers, for example, the workability when injecting the polymerizable composition for an optical material into a mold can be improved.

From the above viewpoint, the content of the polymerization catalyst is preferably 1.8 parts by mass or less, more preferably 1.5 parts by mass or less, further preferably 1.0 parts by mass or less, particularly preferably 0.5 parts by mass or less, and further preferably 0.3 parts by mass or less, relative to 100 parts by mass of the total of the 2 or more different optical material monomers.

The content of the polymerization catalyst may be appropriately set depending on the kind of the polymerization catalyst, the kind and amount of the monomer (isocyanate compound, active hydrogen compound, other component, etc.) used, and the shape of the desired molded article.

The range of the content of the polymerization catalyst may be appropriately changed depending on the types of the monomer for optical materials and the polymerization catalyst.

For example, when the monomer for optical materials contains dicyclohexylmethane diisocyanate and a mixture of 5, 7-dimercaptomethyl-1, 11-dimercapto3, 6, 9-trithioundecane and 4, 8-dimercaptomethyl-1, 11-dimercapto3, 6, 9-trithioundecane, and the polymerization catalyst contains 3, 5-lutidine, it is preferable to use 1.0 part by mass or more of the polymerization catalyst per 100 parts by mass of the monomer for optical materials which is different from 2 or more types, and it is more preferable to use 1.5 parts by mass or more of the polymerization catalyst.

For example, when the monomer for optical materials contains 1, 3-bis (isocyanatomethyl) cyclohexane, pentaerythritol tetrakis (2-mercaptoacetate), and 2, 5-bis (mercaptomethyl) -1, 4-dithiane, and the polymerization catalyst contains 3, 5-lutidine, the polymerization catalyst is preferably used in an amount of 0.03 parts by mass or more, more preferably 0.07 parts by mass or more, per 100 parts by mass of the 2 or more different monomers for optical materials.

The polymerization catalyst preferably satisfies the following condition 1.

[ Condition 1]

-Ea/R is-7100 or more and-2900 or less.

(Ea is the reaction rate constant of 2 or more different optical material monomers at 2 or more different temperatures, activation energy calculated from Arrhenius plot, and R is the gas constant (8.314J/mol/K).)

When the polymerization catalyst satisfies the condition 1, the variation in polymerization rate can be suppressed in the process of polymerizing and curing the polymerizable composition, and as a result, the occurrence of optical strain and striae can be suppressed, and an optical material having excellent appearance can be obtained.

The value of Ea was calculated by the following method.

The value of Ea was calculated by performing the following steps:

a physical property acquisition step of heating a composition 1 containing a polymerization reactive compound and a predetermined amount of a polymerization catalyst to acquire a physical property value 1a of a functional group derived from the polymerization reactive compound before heating and a physical property value 1b of a residual functional group derived from the residual functional group after heating for a predetermined time in the case of heat preservation at a plurality of temperatures;

a residual functional group ratio calculation step of calculating residual functional group ratios 1 at a plurality of temperatures from the physical property values 1a and 1 b;

a reaction rate constant calculation step of calculating reaction rate constants 1 at a plurality of temperatures from the residual functional group ratio 1 based on a reaction rate formula;

and a fitting step of calculating the activation energy Ea1 and the frequency factor A1 from the Arrhenius plot using the reaction rate constants 1 at the plurality of temperatures.

Using the calculated Ea, it is judged whether or not the polymerization catalyst satisfies the condition 1.

The specific embodiment of the method for calculating the value of Ea and the method for determining whether or not the polymerization catalyst satisfies the condition 1 are the same as those described in international publication No. 2020/256057.

(other additives)

The polymerizable composition for optical materials of embodiment 1 may contain optional additives.

Examples of the optional additives include photochromic compounds, internal release agents, bluing agents, and ultraviolet absorbers.

(photochromic Compound)

Photochromic compounds are compounds whose molecular structure reversibly changes upon irradiation with light of a specific wavelength, and the absorption characteristics (absorption spectrum) of the photochromic compounds change accordingly.

Examples of the photochromic compound used in embodiment 1 include compounds whose absorption characteristics (absorption spectrum) change with respect to light having a specific wavelength.

In embodiment 1, the photochromic compound is not particularly limited, and any compound can be appropriately selected from conventionally known compounds that can be used for photochromic lenses. For example, 1 or 2 or more species of spiropyran-based compounds, spirooxazine-based compounds, fulgide-based compounds, naphthopyran-based compounds, bisimidazole compounds, and the like can be used depending on the desired coloring.

(internal mold Release agent)

As the internal mold release agent, acidic phosphate ester is exemplified. The acidic phosphate ester includes a phosphoric monoester and a phosphoric diester, and may be used alone or in a mixture of 2 or more.

(bluing agent)

Examples of the bluing agent include those having an absorption band in the orange to yellow wavelength region in the visible light region and having a function of adjusting the hue of an optical material made of a resin. More specifically, the bluing agent comprises a substance that appears blue to violet.

(ultraviolet absorber)

Examples of usable ultraviolet absorbers include benzophenone-based ultraviolet absorbers such as 2, 2' -dihydroxy-4-methoxybenzophenone, triazine-based ultraviolet absorbers such as 2- [4- [ (2-hydroxy-3-dodecyloxypropyl) oxy ] -2-hydroxyphenyl ]4, 6-bis (2, 4-dimethylphenyl) -1,3, 5-triazine, benzotriazole-based ultraviolet absorbers such as 2- (2H-benzotriazol-2-yl) -4-methylphenol and 2- (2H-benzotriazol-2-yl) -4-tert-octylphenol, and preferably include 2- (2H-benzotriazol-2-yl) -4-tert-octylphenol, n-butyl-ethyl-phenyl-4-tert-octylphenol, n-butyl-ethyl-propyl-phenyl-4-hydroxy-phenyl-1, 3, 5-triazine-based ultraviolet absorbers, and the like, Benzotriazole-based ultraviolet absorbers such as 2- (5-chloro-2H-benzotriazol-2-yl) -4-methyl-6-tert-butylphenol. These ultraviolet absorbers may be used alone or in combination of 2 or more.

(viscosity)

The polymerizable composition for optical materials according to embodiment 1 has a viscosity of 10mPa · s or more, preferably 40mPa · s or more, more preferably 70mPa · s or more, further preferably 80mPa · s or more, particularly preferably 100mPa · s or more, and further preferably 120mPa · s or more, as measured with a B-type viscometer at 25 ℃ and 60rpm, from the viewpoint of suppressing striae.

The polymerizable composition for optical materials according to embodiment 1 has a viscosity of 1000mPa · s or less, preferably 700mPa · s or less, and more preferably 400mPa · s or less, as measured with a B-type viscometer at 25 ℃ and 60rpm, from the viewpoint of maintaining good workability when an optical material is molded into a desired shape.

The viscosity of the polymerizable composition for optical materials according to embodiment 1 can be adjusted depending on the use application of the obtained cured product.

For example, in the case of obtaining a cured product using a mold for convex lenses (plus lenses), the end face (i.e., the inlet) is narrow (e.g., 1mm to 3mm), and therefore, the viscosity is preferably 10mPa · s to 100mPa · s from the viewpoint of suppressing striae in the polymerizable composition for an optical material of embodiment 1.

On the other hand, in the case where a cured product is obtained using a mold for a general lens other than a convex lens, the end face (i.e., the inlet) is wide (for example, 5mm to 15mm), and therefore, in the polymerizable composition for an optical material according to embodiment 1, the viscosity is preferably 10mPa · s to 1000mPa · s, and more preferably 100mPa · s to 1000mPa · s, from the viewpoint of suppressing striae.

By increasing the viscosity of the polymerizable composition for optical materials, when the composition is heated from the outside, thermal convection due to a temperature difference between the inside and the outside of the composition can be suppressed, and striae due to thermal convection can be reduced.

However, when the amount of the catalyst is small, the thickening rate during polymerization is insufficient, and therefore, the maximum temperature difference is not increased to such an extent that thermal convection can be suppressed, and the temperature cannot be rapidly increased in a short time. Further, the time required until the completion of the polymerization also becomes long.

On the other hand, according to the present disclosure, the catalyst amount is increased to the most suitable range in consideration of the reactivity of the isocyanate compound having no aromatic ring, whereby the viscosity of the entire composition can be increased more quickly. This can suppress the unevenness of polymerization and also suppress the thermal convection due to a rapid temperature rise, thereby enabling the polymerization to be carried out in a short time.

(thixotropic ratio)

The thixotropic ratio of the polymerizable composition for optical materials according to embodiment 1 is preferably 1.3 or less, more preferably 1.2 or less, and still more preferably 1.1 or less.

When the thixotropic ratio of the polymerizable composition for optical materials of embodiment 1 is 1.3 or less, the composition can be quickly filled into a polymerization vessel such as a mold described later, and thermal convection during polymerization can be suppressed, and generation of striae and the like in the monomer for optical materials can be further prevented. As a result, the optical material obtained can suppress the occurrence of striae and the like, and can maintain good quality.

The thixotropic ratio of the polymerizable composition for optical materials according to embodiment 1 is preferably 0.9 or more, more preferably 0.95 or more, and still more preferably 1.0 or more.

The thixotropic ratio can be measured by using a type B viscometer at 25 ℃ and at 6rpmConstant viscosity eta₁Divided by the viscosity eta measured at 60rpm₂To calculate.

For example, the thixotropic ratio can be reduced by reducing the molecular weight of 2 or more kinds of monomers for optical materials, suppressing the polymerization degree of the prepolymer to a certain value or less, or reducing the ratio of a structure providing elasticity in the monomer.

The polymerizable composition for optical materials of embodiment 1 preferably includes: 2 or more different monomers for optical materials; a polymerization catalyst; and a prepolymer having a polymerizable functional group, which is a polymer of 2 or more different monomers for optical materials.

The prepolymer is a polymer of 2 or more different monomers for optical materials, and has a polymerizable functional group.

A cured product obtained by polymerizing a prepolymer with 2 or more different optical material monomers can be used as an optical material.

Examples of the prepolymer include: a polymer in which polymerizable functional groups of 2 optical material monomers among the optical material monomers are not polymerized at an equivalent ratio of 1: 1; and polymers obtained by polymerizing 2 kinds of optical material monomers out of the optical material monomers at unbalanced equivalent ratios.

The polymerizable functional group is a functional group polymerizable with other polymerizable functional groups, and specifically includes functional groups having active hydrogen such as isocyanate groups and mercapto groups described later.

The polymerization is carried out at an equivalent ratio of 1:1, and means, for example: when the polymerization is carried out using the isocyanate compound and the polythiol compound, the polymerization is carried out in such an amount that the molar ratio of the isocyanate group of the isocyanate compound to the mercapto group of the polythiol compound becomes 1: 1.

Polymerizable prepolymer composition for optical Material

The polymerizable prepolymer composition for an optical material of embodiment 1 includes: a prepolymer having a polymerizable functional group, which is a polymer of 2 or more different monomers for optical materials; and a polymerization catalyst, wherein at least 1 of the 2 or more different monomers for an optical material is an isocyanate compound having no aromatic ring, and the polymerizable prepolymer composition for an optical material has a viscosity of 10 to 2000 mPas as measured with a B-type viscometer at 25 ℃ and 60 rpm.

It is preferable that the viscosity of the prepolymer composition is not easily changed (i.e., stabilized) with the passage of time. For example, the polymerizable prepolymer composition for optical materials preferably does not contain a component having another polymerizable functional group which is easily polymerized with a polymerizable functional group contained in a prepolymer as described later.

The term "stable viscosity" of the prepolymer composition means that the viscosity of the prepolymer composition changes by 10% or less before and after storage of the prepolymer composition at 20 ℃ for 24 hours.

The specific examples, preferable embodiments and the like of the optical material monomer and the polymerization catalyst of the polymerizable prepolymer composition for optical materials are the same as the specific examples, preferable embodiments and the like of the optical material monomer and the polymerization catalyst described in the above section of the polymerizable composition for optical materials.

The definition of the prepolymer of the polymerizable prepolymer composition for optical materials is the same as that of the prepolymer described in the above section of the polymerizable composition for optical materials.

Specific examples, preferable embodiments, and the like of the isocyanate compound having no aromatic ring and the viscosity included as the optical material monomer in the polymerizable prepolymer composition for optical material are the same as the specific examples, preferable embodiments, and the like described in the above-mentioned section of the polymerizable composition for optical material.

In the polymerizable prepolymer composition for optical materials according to embodiment 1, the content of the polymerization catalyst is preferably 0.1 to 4.0 parts by mass with respect to 100 parts by mass of the total of the 2 or more different optical material monomers.

By setting the content of the polymerization catalyst to 0.1 part by mass or more based on 100 parts by mass of the total of the 2 or more different optical material monomers, the polymerization reaction can be favorably accelerated, and thus a high-quality optical material can be obtained in a short time. Further, by favorably promoting the polymerization reaction, the releasability when the cured product is taken out from the mold can be improved.

From the above viewpoint, the content of the polymerization catalyst is preferably 0.15 parts by mass or more, and more preferably 0.20 parts by mass or more, relative to 100 parts by mass of the total of the 2 or more different optical material monomers.

By setting the content of the polymerization catalyst to 4.0 parts by mass or less with respect to 100 parts by mass of the total of the 2 or more different optical material monomers, for example, the workability when injecting the polymerizable composition for an optical material into a mold can be improved.

From the above viewpoint, the content of the polymerization catalyst is preferably 3.0 parts by mass or less, more preferably 2.0 parts by mass or less, and still more preferably 1.0 part by mass or less, relative to 100 parts by mass of the total of the 2 or more different optical material monomers.

(thixotropic ratio)

The thixotropic ratio of the polymerizable prepolymer composition for optical materials according to embodiment 1 is preferably 1.3 or less, more preferably 1.2 or less, and still more preferably 1.1 or less.

When the thixotropic ratio of the polymerizable prepolymer composition for optical materials of embodiment 1 is 1.3 or less, the composition can be quickly filled into a polymerization vessel such as a mold described later, and thermal convection during polymerization can be suppressed, and generation of striae and the like in the monomer for optical materials can be further prevented. As a result, the optical material obtained can suppress the occurrence of striae and the like, and can maintain good quality.

The thixotropic ratio of the polymerizable composition for optical materials according to embodiment 1 is preferably 0.9 or more, more preferably 0.95 or more, and still more preferably 1.0 or more.

The method of measuring the thixotropic ratio is as described above.

In the polymerizable prepolymer composition for an optical material according to embodiment 1, it is sometimes preferable that the prepolymer contains an isocyanate group from the viewpoint of handling of the composition.

That is, it is preferable that not all of the isocyanate groups of the prepolymer are polymerized but only a part of the isocyanate groups are polymerized, and it is preferable that 85% or more of the isocyanate groups of the isocyanate compound used for producing the prepolymer composition remain without being polymerized.

By including the isocyanate group in the prepolymer, that is, by including the isocyanate compound more than the other optical material monomer polymerizable with the isocyanate compound, the viscosity of the polymerizable prepolymer composition for an optical material can be kept low when the viscosity of the other optical material monomer is high, and the handling of the composition becomes easy.

In the polymerizable prepolymer composition for an optical material according to embodiment 1, it is also preferable that the prepolymer contains substantially no isocyanate group.

The phrase "the prepolymer contains substantially no isocyanate group" means a state in which substantially all of the isocyanate groups are polymerized.

Specifically, the phrase "the prepolymer contains substantially no isocyanate group" means that the content of isocyanate group in the prepolymer is not more than the detection limit when measured by an IR spectrometer.

Since the prepolymer contains substantially no isocyanate group, there is substantially no isocyanate group having high reactivity, and therefore, the stability of the polymerizable prepolymer composition for optical materials can be improved.

In the polymerizable prepolymer composition for optical materials of embodiment 1, a value obtained by subtracting the refractive index B of the prepolymer raw material composition (the prepolymer raw material composition is a composition before the prepolymer is formed and contains the 2 or more different optical material monomers and polymerization catalysts) (also referred to as "refractive index a-refractive index B") from the refractive index a of the polymerizable prepolymer composition for optical materials is preferably greater than 0, more preferably 0.003 or more, and still more preferably 0.010 or more.

The refractive index a is the refractive index of a polymerizable prepolymer composition for optical materials obtained by polymerizing a monomer for optical materials with a polymerization catalyst to obtain a prepolymer, and the refractive index B is the refractive index of a prepolymer raw material composition before polymerizing a monomer for optical materials with a polymerization catalyst to obtain a prepolymer.

When the refractive index a-refractive index B are within the above range, the polymerizable composition for optical materials can be easily adjusted to a predetermined viscosity. In addition, the quality (for example, refractive index, appearance, and the like) of the cured product of the polymerizable composition for optical materials can be easily stabilized.

The refractive index a-refractive index B may be 0.020 or less, or may be 0.018 or less.

When the prepolymer contains an isocyanate group, the refractive index a — refractive index B is preferably 0.005 or more, and more preferably 0.010 or more. Further, it is preferably 0.030 or less, and more preferably 0.020 or less.

On the other hand, when the prepolymer contains substantially no isocyanate group, the refractive index a — refractive index B is preferably 0.003 or more, and more preferably 0.005 or more. Further, it is preferably 0.020 or less, more preferably 0.015 or less.

Curing products

The cured product of embodiment 1 is a cured product of the polymerizable composition for optical materials of embodiment 1 or the polymerizable prepolymer composition for optical materials of embodiment 1.

In the cured product of embodiment 1, when an amine-based catalyst is used as a polymerization catalyst, the content of the amine is preferably 0.03 mass% or more, more preferably 0.05 mass% or more, and still more preferably 0.07 mass% or more, from the viewpoint of reducing striae.

In addition, the content of the amine in the cured product of embodiment 1 is preferably 2.5% by mass or less, more preferably 2.0% by mass or less, and still more preferably 1.5% by mass or less, from the viewpoint of improving the workability of the polymerizable composition for optical materials.

The amine content is measured by gas chromatography mass spectrometry from a methylene chloride composition obtained by dispersing a cured product in methylene chloride and performing ultrasonic extraction.

In the cured product of embodiment 1, when the organotin catalyst is used, the content of tin is preferably 0.05% by mass or more, more preferably 0.1% by mass or more, and still more preferably 0.2% by mass or more, from the viewpoint of reducing the striae.

In addition, the content of tin in the cured product of embodiment 1 is preferably 2.5% by mass or less, more preferably 2.0% by mass or less, and still more preferably 1.5% by mass or less, from the viewpoint of improving the workability of the polymerizable composition for optical materials.

The method of measuring the amine content in the cured product is as follows.

200mg of the solidified product formed into a powdery shape by filing and 3mL of methylene chloride were put into a centrifuge tube (volume: 10mL), and subjected to ultrasonic extraction at room temperature for 10 minutes using an ultrasonic washer (manufactured by IUCHI, U.S. Pat. No. 4), and centrifuged at 4000rpm for 10 minutes using a centrifuge (manufactured by KUBOTA, small bench centrifuge 2410).

The supernatant was collected, and the residue was dispersed again in 3mL of dichloromethane, and subjected to the ultrasonic extraction and centrifugal separation described above to collect the supernatant (hereinafter, also referred to as "residue extraction").

After 2 more extractions of the residue, dichloromethane was added to the obtained supernatant to make the total volume 10 mL.

The obtained 10mL of supernatant was filtered and analyzed by gas chromatography-mass spectrometry (also referred to as GC-MS.) (GC-MS apparatus: 6890GC/5973N MSD, manufactured by Agilent Co., Ltd.; column: CP-Sil 8 CB for Amine (0.25 mmID. times.30 m F.T ═ 0.25 μm)), to obtain a peak area value derived from the Amine. The amine content in the cured product was measured by preparing a calibration curve of the peak area value derived from the amine and the amount of the amine.

The amine is an amine compound that can be used as a polymerization catalyst or an amine compound derived from the amine compound.

In particular, in optical applications requiring light transmittance, the cured product of embodiment 1 preferably has a devitrification degree of less than 50, more preferably less than 35.

The degree of devitrification can be measured by the following method.

Light from a light source (for example, HAYASHI-REPIC CO., manufactured by LTD., Luminar Ace LA-150A) is transmitted through the cured product in a dark place. An image of light transmitted through a cured product is captured by an image processing apparatus (for example, an image processing apparatus manufactured by Ube Information Systems inc.), the captured image is subjected to shading processing, the shading degree of the processed image is digitized for each pixel, and a value calculated as an average value of the numerical values of the shading degrees of the respective pixels is regarded as a degree of devitrification.

In the cured product of embodiment 1, it is preferable that the beads have no length of 1.0mm or more within a range of a radius of 15mm from the center of the cured product, and it is more preferable that the beads have no length of 1.0mm or more within and outside a range of a radius of 15mm from the center of the cured product.

More specifically, the cured product of embodiment 1 may be a cured product of 2 or more different optical monomers, wherein at least 1 of the 2 or more different optical monomers is an isocyanate compound having no aromatic ring, no cord having a length of 1.0mm or more is present within a range of a radius of 15mm from the center of the cured product, and the content of amine measured by gas chromatography mass spectrometry is 0.03 mass% or more and 2.5 mass% or less.

The 2 or more different optical monomers and isocyanate compounds having no aromatic ring are as described above.

In the cured product of the present disclosure, the 2 or more different optical monomers may contain an isocyanate compound other than the isocyanate compound having no aromatic ring.

When the 2 or more different optical monomers include an isocyanate compound having no aromatic ring and an isocyanate compound having an aromatic ring, the ratio of the isocyanate compound having no aromatic ring to the isocyanate compound having an aromatic ring is preferably in the range of 7:3 to 10:0, and more preferably in the range of 8:2 to 10:0 in terms of the molar ratio of isocyanate groups, from the viewpoint of controlling the polymerization reaction.

Method for producing optical Material

The method for producing an optical material according to embodiment 1 includes the following production method a and production method B.

< preparation A >

The preparation method A comprises the following steps:

a preparation step of preparing a polymerizable composition for an optical material, the polymerizable composition for an optical material containing 2 or more different monomers for an optical material; and a polymerization catalyst, wherein at least 1 of the 2 or more different monomers for optical materials is an isocyanate compound having no aromatic ring, and the content of the polymerization catalyst is more than 0.05 parts by mass and 2.0 parts by mass or less with respect to 100 parts by mass of the total of the 2 or more different monomers for optical materials;

The production method a includes the preparation step, the viscosity adjustment step, and the curing step, whereby the quality of the obtained optical material can be maintained and the production time of the optical material can be shortened.

The preparation method a may include the preparation step, the viscosity adjustment step, and the curing step in this order.

The polymerizable composition for optical materials prepared in the preparation step in the preparation method a contains the polymerization catalyst in an amount of more than 0.05 parts by mass and not more than 2.0 parts by mass based on 100 parts by mass of the total of the 2 or more different monomers for optical materials. The content of the polymerization catalyst is higher than that of the conventional method for producing an optical material.

The polymerization reaction of the optical material monomer in the polymerizable composition for an optical material can be accelerated by the reaction heat, and therefore, a high-quality optical material can be obtained in a shorter time than in the conventional case.

Conventionally, polymerization reaction is mainly carried out by heating the polymerizable composition for optical materials, but in the production method a, heating of the polymerizable composition for optical materials is not essential.

In addition, since the production method a also utilizes self-heating of the composition, polymerization can be carried out without excessively depending on heat supply from the outside, and therefore, not only can the viscosity of the composition described later be increased, but also unevenness of heat and convection in the polymerizable composition for optical materials can be suppressed, and generation of striae can be suppressed.

In the present disclosure, the ridge is a state in which the refractive index of a specific portion is different from the normal refractive index of the surrounding portion. In addition, it may also appear that an unfavorable condition occurs in the intended use of the optical material. In optical materials, cord is a defect.

< preparation Process >

The preparation method A comprises the following steps:

The preparation step may be a step of simply preparing a previously produced polymerizable composition for optical materials, or may be a step of producing a polymerizable composition for optical materials.

In the preparation step, the polymerizable composition for optical materials is not particularly limited as long as it contains 2 or more different monomers for optical materials and a polymerization catalyst.

As the polymerizable composition for optical materials, a ready-made product may be used, or at least 2 or more different monomers for optical materials and a polymerization catalyst may be mixed to prepare the composition.

The method of mixing is not particularly limited, and a known method can be used.

The temperature at which the above components are mixed is not particularly limited, but is preferably 30 ℃ or lower, and more preferably room temperature (25 ℃) or lower.

From the viewpoint of the pot life of the prepared polymerizable composition for optical materials, it is sometimes preferable to set the temperature to be lower than 25 ℃. However, when the solubility of the additive such as the internal mold release agent with each of the above components is poor, the above components may be heated in advance to dissolve the additive in each of the above components.

When the above-mentioned components are mixed, it is preferable to carry out the mixing under a dry inert gas in order to prevent mixing of water into the polymerizable composition for optical materials.

The preparation step is preferably a step of mixing the polymerization catalyst in a part of the 2 or more different optical material monomers and then mixing the remaining part of the 2 or more different optical material monomers to produce the polymerizable composition for an optical material.

This prevents the polymerization of the part of the 2 or more different optical material monomers and the remainder of the 2 or more different optical material monomers from occurring before the mixture containing the part of the 2 or more different optical material monomers and the polymerization catalyst and the mixture not containing the polymerization catalyst and containing the remainder of the 2 or more different optical material monomers are mixed.

Therefore, by performing the preparation steps in the above-described order, the timing of starting the polymerization can be adjusted. Therefore, for example, the workability of injecting the polymerizable composition for optical materials into a mold can be improved.

In the preparation step, after the polymerization catalyst is mixed in advance in a part of the 2 or more different optical material monomers, the remaining part of the 2 or more different optical material monomers may be mixed in a single step or may be mixed in multiple steps.

Specific examples of the preparation step include the following.

First, a part of the optical material monomer and an additive (for example, an internal mold release agent) are charged to prepare a mixed solution. The mixed solution was stirred at 25 ℃ for 1 hour to completely dissolve the respective components, and then a part of the remaining part of the optical material monomer was further charged and stirred to prepare a uniform solution. This solution was degassed to obtain a1 st mixed solution.

Next, the remaining part of the monomer for optical material and the catalyst were stirred at 25 ℃ for 30 minutes to completely dissolve them, thereby obtaining a2 nd mixed solution.

Then, the 1 st mixed solution and the 2 nd mixed solution were mixed to obtain a uniform solution, thereby obtaining a polymerizable composition for an optical material.

< casting Process >

The production method B comprises a casting step of adjusting the viscosity of the polymerizable composition for optical materials measured with a type B viscometer at 25 ℃ and 60rpm to 10 mPas to 1000 mPas, and casting the composition into a mold.

By adjusting the viscosity of the polymerizable composition for optical materials to the above range and casting, the viscosity of the polymerizable composition for optical materials produced in the production process of the polymerizable composition for optical materials can be made to fall within an appropriate range from the viewpoint of suppressing striae in the obtained optical materials.

From the above-mentioned viewpoint, the viscosity of the polymerizable composition for optical materials is 10mPa · s or more, preferably 40mPa · s or more, more preferably 70mPa · s or more, further preferably 80mPa · s or more, particularly preferably 100mPa · s or more, and further preferably 120mPa · s or more.

The polymerizable composition for an optical material has a viscosity of 1000mPa · s or less, preferably 700mPa · s or less, and more preferably 400mPa · s or less, from the viewpoint of maintaining good workability when the optical material is molded into a desired shape.

The method for adjusting the viscosity of the polymerizable composition for optical materials is not particularly limited.

For example, the viscosity of the polymerizable composition for optical materials can be adjusted by a method such as addition of a high-viscosity compound, heating, or stirring.

< curing Process >

The preparation method A comprises the following steps:

The process a can produce an optical material by polymerizing the polymerizable composition for an optical material by including a curing step.

In the conventional method, the polymerizable composition for optical materials is heated to cause the polymerization reaction to occur during the polymerization reaction, but the polymerizable composition for optical materials in the production method a can accelerate the polymerization reaction of the monomer for optical materials in the polymerizable composition for optical materials by increasing the reaction heat (i.e., the heat generated by self-heating) associated with the polymerization reaction.

Therefore, in the production method a, heating of the polymerizable composition for optical materials is not essential, but heating may be performed.

That is, in the curing step of the production method a, the polymerizable composition for optical materials is allowed to stand to cure by polymerization.

The environment for performing the curing step is not particularly limited, and the curing may be performed by heating the mold from the outside of the mold, but from the viewpoint of improving the optical quality such as moire and the like and performing the polymerization in a short time, it is preferable to perform the step of curing the polymerizable composition for optical material by leaving the polymerizable composition for optical material in a closed space.

By leaving the polymerizable composition for optical materials in a closed space, it is possible to prevent the release of heat generated by self-heating of the polymerizable composition for optical materials to the outside. This allows heat generated by self-heating to be retained in the closed space, and therefore, the polymerization reaction can be promoted more efficiently, and the optical material can be produced in a shorter time.

Examples of the closed space include a heat insulating environment.

The heat insulating environment is an environment in which heat is retained inside and heat conduction between the inside and the outside is suppressed. The environment in which heat conduction between the inside and the outside is suppressed means the following environment: when the polymerizable composition for optical materials is left to stand in the closed space, the thermal conductivity between the inside and the outside of the closed space is such that the polymerizable composition for optical materials can be cured.

The insulating environment may be formed using an insulating material, for example.

That is, by allowing the polymerizable composition for an optical material to stand in a heat-insulating container made of a heat-insulating material, heat can be retained inside the heat-insulating container, and heat conduction between the inside and the outside can be suppressed.

The thermal conductivity of the heat insulating material is preferably 0.50W/mK or less, more preferably 0.10W/mK or less, and still more preferably 0.05W/mK or less.

The density of the heat insulating material is preferably 10kg/m³Above, more preferably 15kg/m³Above, more preferably 20kg/m³The above.

In the "heat insulation" or "heat insulation environment" in the production method a, it is preferable to perform heating for bringing the heat-insulating reaction tank into a constant temperature state (constant temperature reaction tank) within a range that does not interfere with the polymerization reaction based on the reaction heat of the polymerizable composition for optical material or excessively promotes the polymerization reaction of the polymerizable composition for optical material by heating from the outside.

Accordingly, the ambient temperature in the reaction vessel (constant temperature reaction vessel) in which the mold is left standing can be kept warm or kept at a constant temperature depending on the temperature rise state or the like caused by the self-heating of the optical material monomer, and therefore, the polymerization reaction can be more favorably promoted.

As the heat insulating environment, for example, the heat insulating reaction vessel or the constant temperature reaction vessel described above can be used.

For example, when a mold into which a monomer is injected is left to stand in a vacuum vessel as an adiabatic reaction tank, adiabatic polymerization in an adiabatic environment using an adiabatic reaction tank (isothermal reaction tank) can be performed by the following procedure.

The inner surface of the vacuum vessel is covered with a member having heat insulating and heat retaining properties such as urethane foam or cork, and the mold into which the monomer is injected is covered with a member such as cloth as necessary. Then, the mold into which the monomer was injected was allowed to stand in the vacuum vessel.

The curing step may be a step of curing the polymerizable composition for optical materials by leaving the polymerizable composition for optical materials without heating from the outside.

As described above, in the preparation method a, heating of the polymerizable composition for optical materials is not essential.

In order to heat from the outside, an apparatus may be used, which may increase the economic burden. In the case of the production method A, since the optical material can be produced by a simple method, the economic burden can be reduced.

The curing step is preferably a step of allowing the polymerizable composition for optical materials to stand for 2 to 10 hours to cure the polymerizable composition for optical materials.

According to the conventional method, the polymerization reaction is generally carried out for several hours to several tens of hours (for example, about 20 hours to 48 hours) while gradually increasing the temperature by heating.

When the time for carrying out the polymerization reaction is short, the polymerizable composition for an optical material is not completely cured, and thus an optical material cannot be obtained or the quality of the optical material is degraded.

However, according to the method a, the optical material can be produced in a short time while maintaining the quality of the optical material obtained. Specifically, the optical material can be produced by leaving the polymerizable composition for an optical material for 10 hours or less.

From the above viewpoint, in the curing step, it is more preferable that the polymerizable composition for optical materials is left to stand for 8 hours or less.

In addition, from the viewpoint of carrying out the polymerization reaction and obtaining a well-cured optical material, the polymerizable composition for an optical material is preferably left to stand for 2 hours or more, more preferably 5 hours or more.

In the curing step, a microwave irradiation step of irradiating the polymerizable composition for an optical material with a microwave for a predetermined time may be provided as required.

As one embodiment of the curing step, there is an embodiment including the following steps a and b.

Step a: the polymerizable composition for optical materials is injected (cast) into a mold (into a cavity of a mold).

And a step b: the mold into which the polymerizable composition for optical materials was injected was allowed to stand in a closed space for a predetermined time to carry out adiabatic polymerization.

(Process a)

First, a polymerizable composition is injected into a molding die (mold) held by a gasket, a tape, or the like. In this case, according to the physical properties required for the optical material to be obtained, it is preferable to perform, as necessary, defoaming treatment under reduced pressure, filtration treatment under reduced pressure, or the like.

(Process b)

The polymerization conditions are not limited, and are preferably adjusted as appropriate depending on the composition of the polymerizable composition for optical materials, the kind and amount of the catalyst used, the shape of the mold, and the like.

The mold into which the polymerizable composition for optical materials is injected may be left to stand in a heat insulating environment for 2 to 4 hours to be polymerized.

In the step b, a heating step may be added, if necessary, after a heat-insulating polymerization process in which the mold into which the polymerizable composition for optical material is injected is left for a certain period of time in a heat-insulating environment.

In the step b, the mold into which the polymerizable composition for optical material is injected may be heated continuously or intermittently at a temperature not higher than the self-heating temperature generated by the polymerizable composition for optical material in the adiabatic polymerization process, or the inside of the adiabatic reactor may be heated to keep the ambient temperature in the adiabatic reactor, if necessary, in parallel with the step of leaving the mold into which the polymerizable composition for optical material is injected in the adiabatic environment (adiabatic polymerization).

< annealing Process >

If necessary, the production method a may include an annealing step of annealing the cured polymerizable composition for optical materials.

The annealing is usually carried out at a temperature of 50 to 150 ℃, preferably 90 to 140 ℃, and more preferably 100 to 130 ℃.

< other working procedures >

In the process a, other steps may be provided as necessary.

As another step, for example, in the case of manufacturing an optical material using a mold, an injection step of injecting a polymerizable composition for an optical material into the mold may be mentioned.

< use of optical Material >

The optical material in the production method A can be used for plastic lenses, prisms, optical fibers, information recording substrates, optical filters, light emitting diodes, and the like.

Among the above, the optical material in embodiment 1 can be suitably used for a plastic lens, and can be more suitably used for a plastic lens for spectacles.

< preparation method B >

The preparation method B comprises the following steps:

a preparation step of preparing a total of 100 parts by mass of 2 or more different optical material monomers and 0.010 to 2.0 parts by mass of a polymerization catalyst; and

a prepolymer formation step of mixing a part of the 2 or more different optical material monomers and at least a part of the polymerization catalyst to polymerize at least a part of the 2 or more different optical material monomers to obtain a prepolymer, thereby obtaining a mixture containing the prepolymer;

at least 1 of the 2 or more different optical material monomers is an isocyanate compound having no aromatic ring.

In the method B, the preparation step and the prepolymerization step are included, whereby the striae in the obtained optical material can be suppressed and the time for producing the optical material can be shortened.

In addition to the preparation step and the prepolymerization step described above, the production method B preferably further comprises the following steps:

In the production method B, the preparation step and the prepolymerization step are included, and the production step of the polymerizable composition for an optical material and the curing step are included, whereby the striae in the obtained optical material can be more favorably suppressed, and the production time of the optical material can be more favorably shortened.

The polymerizable composition for optical materials prepared in the preparation step in the preparation method B contains the polymerization catalyst in an amount of 0.010 to 2.0 parts by mass based on 100 parts by mass of the total of 2 or more different monomers for optical materials. In the same manner as in the case of the production method a, the content of the polymerization catalyst is larger than that in the conventional production method of an optical material.

Therefore, as in the case of the production method a, a high-quality optical material in which striae are suppressed can be obtained in a shorter time than in the conventional case.

In the same manner as in the case of the production method a, the production method B does not necessarily require heating of the polymerizable composition for optical materials.

In addition, in the case of the production method B, by including the preparation step, the prepolymerization step, the production step of the polymerizable composition for optical materials, and the curing step, convection in the mold in which the polymerization reaction proceeds can be suppressed, and generation of striae in the obtained cured product can be suppressed.

In addition, in the case of the production method B, the storage stability of the mixture containing the prepolymer (for example, the polymerizable composition for optical materials) can be maintained more favorably than the case where the prepolymerization step is not involved.

For example, when a mixture containing a prepolymer is stored for a certain period of time, the polymerization reaction in the mixture can be suppressed. I.e. a longer storage period can be ensured.

< preparation Process >

The preparation method B comprises the following steps: a preparation step of preparing a total of 100 parts by mass of 2 or more different optical material monomers and 0.010 to 2.0 parts by mass of a polymerization catalyst.

In the preparation step, 100 parts by mass in total of 2 or more different optical material monomers and 0.010 to 2.0 parts by mass of a polymerization catalyst are prepared.

That is, in the production method B, 0.010 to 2.0 parts by mass of a polymerization catalyst is used with respect to 100 parts by mass of the total of 2 or more different optical material monomers.

By using the polymerization catalyst in an amount of 0.010 parts by mass or more per 100 parts by mass of 2 or more different optical material monomers, the polymerization reaction can be favorably accelerated, and thus a high-quality optical material in which striae are suppressed can be obtained in a short time. Further, by favorably promoting the polymerization reaction, the releasability when the cured product is taken out from the mold can be improved.

From the above-mentioned viewpoint, the polymerization catalyst is preferably used in an amount of 0.015 part by mass or more, more preferably 0.038 part by mass or more, still more preferably 0.10 part by mass or more, and particularly preferably 0.17 part by mass or more, based on 100 parts by mass of the 2 or more different optical material monomers.

The range of the content of the polymerization catalyst may be appropriately changed depending on the types of the monomer for optical materials and the polymerization catalyst.

For example, when the monomer for an optical material contains 2,5(6) -bis (isocyanatomethyl) -bicyclo- [2.2.1] -heptane, pentaerythritol tetrakis (3-mercaptopropionate), and 4-mercaptomethyl-1, 8-dimercapto-3, 6-dithiaoctane, and the polymerization catalyst contains 3, 5-lutidine, the polymerization catalyst is preferably used in an amount of 0.10 parts by mass or more, more preferably 0.17 parts by mass or more, per 100 parts by mass of the monomer for an optical material which is different from 2 or more.

By using 2.0 parts by mass or less of a polymerization catalyst per 100 parts by mass of 2 or more different optical material monomers, for example, the workability of injecting the polymerizable composition for an optical material into a mold can be improved.

From the above viewpoint, it is preferable to use 1.5 parts by mass or less of the polymerization catalyst per 100 parts by mass of the 2 or more different optical material monomers.

Depending on the types of the optical material monomer and the polymerization catalyst, the amount of the polymerization catalyst may be 1.0 part by mass or less, 0.3 part by mass or less, or 0.15 part by mass or less per 100 parts by mass of 2 or more different types of the optical material monomer.

The amount of the polymerization catalyst may be appropriately set depending on the kind of the polymerization catalyst, the kind and amount of the monomer (isocyanate compound, active hydrogen compound, other component, etc.) used, and the shape of the desired molded article.

< Process of prepolymerization >

The preparation method B comprises the following steps:

and a pre-polymerization step of mixing a part of the 2 or more different optical material monomers and at least a part of the polymerization catalyst to polymerize at least a part of the 2 or more different optical material monomers to obtain a pre-polymer, thereby obtaining a mixture containing the pre-polymer.

The inventors of the present application considered that convection was generated due to non-uniform temperature distribution in the mold in which the polymerization reaction proceeded, which is one of the causes of generation of striae in the obtained cured product.

Therefore, the inventors of the present application focused on improving the viscosity of the polymerizable composition for optical materials by polymerizing a part of the monomer for optical materials in advance to produce a prepolymer and including the prepolymer in the polymerizable composition for optical materials. This can suppress convection in the mold.

In addition, in the production method B, since the self-heating is not dissipated to the outside, a temperature difference between the inside and the outer periphery of the mold is less likely to occur.

From the above viewpoints, it is presumed that the production method B can suppress the striae of the obtained cured product.

The production method B can obtain a prepolymer having an excellent pot life by including all 1 kind of optical material monomer out of 2 or more different optical material monomers, a part of the other optical material monomer than the 1 kind of optical material monomer, and all or a part of the polymerization catalyst in the prepolymer production process.

The mode of "a part of the monomers for 2 or more different optical materials" is not particularly limited.

For example, the "part of 2 or more different optical material monomers" may be the amount of part of each of 2 or more different optical material monomers.

The "part of the 2 or more different optical material monomers" may be all of 1 or more optical material monomers out of the 2 or more different optical material monomers.

In the prepolymerization step, a part or all of the polymerization catalyst may be used.

When a part of the monomer for optical materials is used as a polymerization catalyst, the mode of "a part of a polymerization catalyst" is not particularly limited, as in "a part of 2 or more different monomers for optical materials".

For example, a "portion of a polymerization catalyst" can be an amount of a portion of a polymerization catalyst.

When a part of the polymerization catalyst is used, the part of the polymerization catalyst is preferably 5 to 80 parts by mass, more preferably 10 to 60 parts by mass, and still more preferably 15 to 50 parts by mass, out of 100 parts by mass of the polymerization catalyst, from the viewpoint of ensuring a long storage life.

From the viewpoint of ensuring a long storage life, a part of the 2 or more different optical material monomers is preferably 5 to 95 parts by mass, more preferably 20 to 80 parts by mass, and even more preferably 30 to 70 parts by mass out of 100 parts by mass of the 2 or more different optical material monomers.

The following shows an example of a specific embodiment of the prepolymerization step, but the prepolymerization step in the production method B is not limited to the embodiment described below.

(mode a)

The prepolymerization step in the embodiment a is a step of mixing a part of 2 or more different optical material monomers and the entire polymerization catalyst, and polymerizing at least a part of the 2 or more different optical material monomers to obtain a prepolymer, thereby obtaining a mixture containing the prepolymer.

In the aspect a, the part of the 2 or more different optical material monomers is preferably formed by all of 1 optical material monomer out of the 2 or more different optical material monomers and part of the other optical material monomers except for the 1 optical material monomer.

(mode b)

The prepolymerization step in embodiment b is a step of mixing a part of 2 or more different optical material monomers and a part of a polymerization catalyst, and polymerizing at least a part of the 2 or more different optical material monomers to obtain a prepolymer, thereby obtaining a mixture containing the prepolymer.

When the preparation method B includes the prepolymerization step of the embodiment B, the later-described polymerizable composition for optical materials production step is a step of adding at least the remaining part of the 2 or more different monomers for optical materials and the remaining part of the polymerization catalyst to a mixture containing a prepolymer to obtain a polymerizable composition for optical materials containing the 2 or more different monomers for optical materials, the prepolymer, and the polymerization catalyst.

In the aspect b, it is preferable that the 2 or more different optical material monomers include an isocyanate compound, a part of the 2 or more different optical material monomers include a part of the isocyanate compound, and the remaining part of the 2 or more different optical material monomers include the remaining part of the isocyanate compound.

< viscosity control Process >

The production method B preferably further comprises a viscosity adjusting step of adjusting the viscosity of the mixture containing the prepolymer to 30 to 2000mPa · s after the prepolymerization step and before the production step of the polymerizable composition for optical materials.

When the viscosity of the mixture containing the prepolymer is within the above range, the viscosity of the polymerizable composition for optical materials produced in the production process of the polymerizable composition for optical materials can be set within an appropriate range from the viewpoint of suppressing striae in the optical materials obtained. As a result, the striae in the obtained optical material can be suppressed.

From the above viewpoint, the viscosity of the mixture containing the prepolymer is preferably 40 to 2000mPa · s, and more preferably 50 to 1800mPa · s.

The viscosity was measured at 25 ℃ and 60rpm (revolutions per minute) using a B-type viscometer.

As a method of adjusting the viscosity of the mixture containing the prepolymer, there is no particular limitation.

For example, the viscosity of the mixture containing the prepolymer can be adjusted by a method of adding a high-viscosity compound, heating, stirring, or the like.

The temperature at which the mixture containing the prepolymer is prepared is not particularly limited, and may be any temperature at which the prepolymer can be obtained by the polymerization reaction. For example, it may be 20 to 50 ℃ and may be 25 to 45 ℃.

The stirring time for preparing the mixture containing the prepolymer is not particularly limited as long as the prepolymer can be obtained by the polymerization reaction. For example, the time may be 30 minutes to 5 hours, or 1 hour to 5 hours.

Specifically, the method for producing a mixture containing a prepolymer may be a method for producing a mixture containing a prepolymer while adjusting the viscosity by stirring at 40 ℃ for 3 hours.

< Process for producing polymerizable composition for optical Material >

The preparation method B comprises the following steps:

a step of producing a polymerizable composition for optical materials, wherein a remaining part of at least 2 or more different monomers for optical materials is added to a mixture containing a prepolymer, thereby obtaining a polymerizable composition for optical materials containing 2 or more different monomers for optical materials, a prepolymer, and a polymerization catalyst.

The step of producing a polymerizable composition for optical materials is a step of adding at least the remaining part of 2 or more different monomers for optical materials to a mixture containing a prepolymer to obtain a polymerizable composition for optical materials containing 2 or more different monomers for optical materials, a prepolymer, and a polymerization catalyst.

This prevents the remaining part of the prepolymer and the 2 or more different optical material monomers from being polymerized before the mixture containing the prepolymer and the remaining part of the 2 or more different optical material monomers are mixed.

Therefore, by performing the step of producing the polymerizable composition for optical materials at an appropriate timing, for example, the workability at the time of injecting the polymerizable composition for optical materials into a mold can be improved.

In the step of producing the polymerizable composition for optical materials, when the remaining part of at least 2 or more different monomers for optical materials is added to the mixture containing the prepolymer, the remaining part of the 2 or more different monomers for optical materials may be mixed in a single step or may be mixed in multiple steps.

The "remaining part of the 2 or more different optical material monomers" means a part of the 2 or more different optical material monomers remaining in the prepolymerization step, out of the 2 or more different optical material monomers.

The "remaining part of the 2 or more different monomers for optical materials" may be the following monomers for optical materials: the optical material monomer has a functional group which is polymerizable with the polymerizable functional group of the prepolymer, and the amount of the functional group which is polymerizable with the polymerizable functional group of the prepolymer is an amount (that is, equivalent) which is polymerizable with substantially all of the polymerizable functional groups of the prepolymer.

From the viewpoint of improving the optical uniformity of the optical material composition, the remaining part of the 2 or more different optical material monomers preferably contains the same kind of monomers as the optical material monomers constituting the prepolymer.

The temperature at which the above components are mixed is not particularly limited, but is preferably 30 ℃ or lower, and more preferably room temperature (25 ℃) or lower.

The temperature at the time of mixing the components may be preferably lower than 25 ℃. However, in the case where the solubility of the additive such as the internal mold release agent with each of the above components is poor, the above components may be heated in advance to dissolve the additive in each of the above components.

Specific examples of the process for producing the polymerizable composition for optical materials include the following processes.

First, an additive (for example, an internal mold release agent) is added to a mixture containing a prepolymer to prepare a mixed solution. The mixture was stirred at 25 ℃ for 1 hour to completely dissolve the components, and then degassed to obtain a1 st mixture.

The remaining part of the monomer for optical material and the remaining part of the polymerization catalyst as needed were stirred at 25 ℃ for 30 minutes to completely dissolve them, thereby obtaining a2 nd mixed solution.

Then, the 1 st mixed solution and the 2 nd mixed solution were mixed, stirred, and degassed to obtain a uniform solution, thereby obtaining a polymerizable composition for an optical material.

< liquid feeding step >

The production method B may further include a liquid feeding step of feeding the polymerizable composition for optical material to a casting mold after the production step of the polymerizable composition for optical material and before the curing step.

The liquid feeding step may be a step of feeding the polymerizable composition for optical materials to the casting mold while remixing the polymerizable composition for optical materials in a static mixer.

This eliminates the unevenness in the distribution of the polymerizable composition for optical materials during the period of conveying the polymerizable composition for optical materials to the mold, and therefore suppresses the striae of the resulting cured product.

< curing Process >

The preparation method B comprises the following steps:

and a curing step of curing 2 or more different optical material monomers in the polymerizable composition for an optical material to obtain an optical material which is a cured product of the polymerizable composition for an optical material.

The specific embodiments, preferable embodiments, and the like of the curing step in the production method B are the same as the specific embodiments, preferable embodiments, and the like described in the item < curing step > in the production method a.

< 2 nd Pre-polymerization Process

The production method B may further comprise, in addition to the preparation step and the prepolymerization step described above, the following steps:

a2 nd prepolymer step of mixing the remaining part of the 2 or more different optical material monomers and the remaining part of the polymerization catalyst to polymerize at least part of the remaining part of the 2 or more different optical material monomers to obtain a2 nd prepolymer, thereby obtaining a mixture containing the 2 nd prepolymer;

a step of producing a polymerizable composition for optical materials, in which a mixture containing the 2 nd prepolymer is added to a mixture containing the prepolymers, thereby obtaining a polymerizable composition for optical materials containing the prepolymers, the 2 nd prepolymer, and the polymerization catalyst; and

and a curing step of curing the prepolymer and the 2 nd prepolymer in the polymerizable composition for an optical material to obtain an optical material which is a cured product of the polymerizable composition for an optical material.

In the production method B, a mixture containing the prepolymer obtained in the prepolymerization step and a mixture containing the 2 nd prepolymer obtained in the 2 nd prepolymerization step can be obtained by including the above-described configuration.

This allows the viscosity of the mixture containing the prepolymer to be close to that of the mixture containing the 2 nd prepolymer, and therefore, the two can be more easily mixed.

In the second prepolymerization step 2, the monomer for optical material, polymerization catalyst, specific embodiment, preferred embodiment, and the like of 2 or more different types are the same as those of the monomer for optical material, polymerization catalyst, specific embodiment, preferred embodiment, and the like of 2 or more different types in the prepolymerization step.

When the production method B includes the 2 nd prepolymerization step, the step of producing the polymerizable composition for optical materials is a step of adding a mixture containing the 2 nd prepolymer to a mixture containing the prepolymer to obtain a polymerizable composition for optical materials containing the prepolymer, the 2 nd prepolymer, and the polymerization catalyst.

In the step of producing the polymerizable composition for optical materials, the specific embodiment, preferred embodiment, and the like of the mixture containing the prepolymer are the same as those in the < step of producing the polymerizable composition for optical materials > described above.

When the production method B includes the 2 nd prepolymerization step, the curing step is a step of curing the prepolymer in the polymerizable composition for optical materials and the 2 nd prepolymer to obtain an optical material which is a cured product of the polymerizable composition for optical materials.

In the above-mentioned curing step, the prepolymer, specific embodiments, preferable embodiments, and the like are the same as those in the < curing step > described above.

< annealing Process >

The production method B may include an annealing step of annealing the cured polymerizable composition for optical materials, if necessary.

Preferred embodiments of the annealing step in the production method B and the like are the same as those of the annealing step in the production method a and the like.

< other working procedures >

In the process B, other steps may be provided as necessary.

Specific embodiments, preferable embodiments, and the like of the other steps in the production method B are the same as those of the other steps in the production method a.

< use of optical Material >

Specific examples, preferable specific examples, and the like of the application of the optical material in the production method B are the same as those of the optical material in the production method a.

Implementation mode 2E

Method for producing optical Material

The method for producing an optical material according to embodiment 2 includes the steps of:

a preparation step of preparing a polymerizable composition for an optical material, the polymerizable composition for an optical material containing 2 or more different monomers for an optical material; and a polymerization catalyst, wherein the content of the polymerization catalyst is 0.1 to 0.3 parts by mass relative to 100 parts by mass of the total of the 2 or more different optical material monomers; and

The method for producing an optical material according to embodiment 2 is similar to the method for producing an optical material according to embodiment 1, except that the content of the polymerization catalyst is 0.1 to 0.3 parts by mass relative to 100 parts by mass of the total of 2 or more different optical material monomers.

In the method for producing an optical material according to embodiment 2, details of specific examples, preferable specific examples, specific embodiments, preferable embodiments, and the like of each component are the same as those of the specific examples, preferable specific examples, specific embodiments, preferable embodiments, and the like of each component in the method for producing an optical material according to embodiment 1.

Embodiment 2 of the present disclosure includes the following modes.

< 2-1 > a method for producing an optical material, comprising the steps of:

a preparation step of preparing a polymerizable composition for an optical material, the polymerizable composition for an optical material containing 2 or more different monomers for an optical material; and a polymerization catalyst, wherein the content of the polymerization catalyst is 0.05 to 2.0 parts by mass relative to 100 parts by mass of the total of the 2 or more different optical material monomers; and

< 2-2 > the method for producing an optical material according to < 2-1 >, wherein the preparation step is a step of mixing the polymerization catalyst in advance with a part of the 2 or more different optical material monomers and then further mixing the remaining part of the 2 or more different optical material monomers to produce the polymerizable composition for an optical material.

The method for producing an optical material as described in < 2-3 > such as < 2-1 > or < 2-2 >, wherein the curing step is a step of curing the polymerizable composition for an optical material by allowing the polymerizable composition for an optical material to stand in a closed space.

The method of producing an optical material as set forth in any one of < 2-4 > such as < 2-1 > -to < 2-3 >, wherein the curing step is a step of curing the polymerizable composition for an optical material by leaving the polymerizable composition for an optical material without heating from the outside.

The method of producing an optical material as set forth in any one of < 2-5 > such as < 2-1 > -to < 2-4 >, wherein the curing step is a step of curing the polymerizable composition for an optical material by leaving the polymerizable composition for an optical material to stand for 2 to 10 hours.

The method of producing an optical material of any one of < 2-6 > such as < 2-1 > - < 2-5 >, wherein the 2 or more different monomers for an optical material comprise an isocyanate compound and at least 1 active hydrogen compound selected from the group consisting of a polythiol compound having 2 or more mercapto groups, a hydroxythiol compound having 1 or more mercapto groups and 1 or more hydroxyl groups, a polyol compound having 2 or more hydroxyl groups, and an amine compound.

< 2-7 > the process for producing an optical material, wherein the isocyanate compound contains an isocyanate compound having no aromatic ring, as < 2-6 >.

The method for producing an optical material as described in any one of < 2-8 > such as < 2-1 > -to < 2-7 >, wherein the polymerization catalyst contains at least 1 kind selected from the group consisting of a basic catalyst having a pKa value of 4 to 8 and an organometallic catalyst.

The method for producing an optical material as described in any one of < 2-9 > such as < 2-1 > - < 2-8 >, wherein the polymerization catalyst contains at least 1 kind selected from the group consisting of an amine-based catalyst and an organotin-based catalyst.

The method for producing an optical material according to any one of < 2-10 > such as < 2-1 > -to < 2-9 >, wherein the polymerization catalyst contains at least 1 selected from the group consisting of 3, 5-lutidine, 2,4, 6-collidine, triethylenediamine, N-dimethylethanolamine, triethylamine, N-ethylmorpholine, dibutyltin dichloride, dimethyltin dichloride, dibutyltin dilaurate and dibutyltin diacetate.

< 2-11 > a polymerizable composition for optical materials, which comprises 2 or more different monomers for optical materials and a polymerization catalyst, and wherein the content of the polymerization catalyst is 0.1 to 0.3 parts by mass relative to 100 parts by mass of the total of the 2 or more different monomers for optical materials.

Examples

The polythiol compound used in this example can be produced by the method described in international publication No. 2014/027665.

< example A >)

Hereinafter, embodiment 1 and embodiment 2 of the present disclosure will be specifically described with reference to example a, but embodiment 1 and embodiment 2 are not limited to these examples.

The viscosity measurement method in example a is the same as the above method.

The molded articles obtained in the respective examples or comparative examples were evaluated as follows.

(degree of devitrification)

The molded article was prepared by transmitting light from a light source (HAYASHI-REPIC CO., manufactured by LTD., Luminar Ace LA-150A) in a dark place. An image of light transmitted through the molded article is collected in an image processing apparatus (manufactured by Ube Information Systems inc.) and the collected image is subjected to shading processing. The degree of shading of the processed image is digitized for each pixel, and the average value of the numerical values of the degrees of shading of the pixels is obtained to determine the degree of devitrification of the molded article.

The obtained devitrification degree was evaluated according to the following criteria.

A: the devitrification degree is less than 35.

B: the degree of devitrification is 35 or more and less than 50.

C: the degree of devitrification is 50 or more and less than 100.

D: the degree of devitrification is 100 or more.

(Reinforcement)

A molded article having a center thickness of 8mm and a diameter of 78mm was projected by an ultrahigh-pressure mercury lamp (light source model OPM-252 HEG: manufactured by USHIO Inc.), and the transmitted image was observed by visual observation and evaluated according to the following criteria.

A: no striae were observed. Specifically, beads having a length of 1.0mm or more were not observed visually within and outside a range of 15mm in radius from the center of the molded article.

B: although beads were observed, they were generally allowable as an article. Specifically, the beads having a length of 1.0mm or more were visually observed outside the range of 15mm in radius from the center of the molded article, but the beads having a length of 1.0mm or more were not visually observed within the range of 15mm in radius from the center of the molded article, and the beads were almost acceptable as a product.

C: ribbing was observed and was not allowed as a product. Specifically, beads having a length of 1.0mm or more were visually observed within and outside a range of 15mm in radius from the center of the molded article.

(releasability)

The releasability of the molded article when the molded article was released from the molding die was evaluated according to the following criteria.

A: peeled off even without application of force.

B: and peeled off when force is applied.

C: although the mold is peeled off when force is applied, there is a possibility that the mold or the lens is broken.

D: the film could not be peeled off even when a force was applied, and thus an article was not obtained.

In examples A and B, — Ea/R of each polymerization catalyst is as follows.

Dibutyltin (II) dichloride-5737

3, 5-dimethylpyridine-3397

2,4, 6-trimethylpyridine-4483

[ example 1A ]

0.1 part by mass of ZelecUN [ internal mold release agent ] manufactured by Stepan corporation, 1.5 parts by mass of 2- (2H-benzotriazol-2-yl) -4-tert-octylphenol [ ultraviolet absorber ], and 40.6 parts by mass of 2,5(6) -bis (isocyanatomethyl) -bicyclo- [2.2.1] -heptane [ monomer for optical material ] were charged to prepare a mixed solution. The mixture was stirred at 25 ℃ for 1 hour to completely dissolve the mixture. Then, 23.9 parts by mass of pentaerythritol tetrakis (3-mercaptopropionate) [ monomer for optical material ] and 25.5 parts by mass of 4-mercaptomethyl-1, 8-dimercapto-3, 6-dithiaoctane [ monomer for optical material ] were charged into the mixture, and the mixture was stirred at 15 ℃ for 5 minutes to prepare a uniform solution. This solution was degassed at 400Pa for 60 minutes to obtain a1 st mixed solution.

10.0 parts by mass of 2,5(6) -bis (isocyanatomethyl) -bicyclo- [2.2.1] -heptane [ the monomer for optical materials ] and 0.3 parts by mass of dibutyltin (II) dichloride [ the polymerization catalyst ] were stirred at 25 ℃ for 30 minutes to completely dissolve them, and a second mixed solution was obtained.

Then, the 1 st mixed solution and the 2 nd mixed solution were mixed at 20 ℃ to obtain a uniform solution, thereby obtaining a polymerizable composition for an optical material. The thixotropic ratio of the polymerizable composition for optical materials is shown in table 1.

This solution was filtered through a1 μm PTFE filter and injected at a rate of 10 g/sec into a cavity of a casting mold composed of a 4-bend (4-curved) glass mold (upper mold) having a diameter of 78mm and a 4-bend (lower mold) having a diameter of 78mm, and having a cavity for lens production with a set center thickness of 8 mm. The cast product was placed in a heat-insulating container at 25 ℃ and allowed to stand for 4 hours to carry out heat-insulating polymerization, and then the cured molded article was released from the casting mold and further subjected to annealing treatment at 120 ℃ for 2 hours to obtain a molded article (lens).

Further, as a result of measuring properties of the obtained molded article, the refractive index (ne) was 1.596, Abbe's number (. nu.e) was 39, and glass transition temperature (Tg) was 113 ℃, and good physical properties were exhibited. The results of the devitrification, striae and releasability are shown in table 1.

[ example 2A ]

A molded article was obtained in the same manner as in example 1A except that the amount of the catalyst was set as described in table 1.

Further, as a result of measuring properties of the obtained molded article, the refractive index (ne) was 1.598, Abbe's number (. nu.e) was 39, glass transition temperature (Tg) was 114 ℃, and good physical properties were exhibited. The results of the devitrification, striae and releasability are shown in table 1.

[ example 3A ]

A molded article was obtained in the same manner as in example 1A except that 0.3 part by mass of dibutyltin dichloride (II) was changed to 0.25 part by mass of 3, 5-dimethylpyridine [ polymerization catalyst ] (pKa value: 6.14).

[ example 4A ]

A molded article was obtained in the same manner as in example 3A except that the amount of the catalyst was set as described in table 1.

Further, as a result of measuring properties of the obtained molded article, the refractive index (ne) was 1.598, Abbe's number (. nu.e) was 39, glass transition temperature (Tg) was 113 ℃ and good physical properties were exhibited. The results of the devitrification, striae and releasability are shown in table 1.

[ example 5A ]

A cured molded article was obtained in the same manner as in example 3A, except that the amount of the catalyst was set as described in table 1.

Further, as a result of measuring properties of the obtained molded article, the refractive index (ne) was 1.597, Abbe's number (. nu.e) was 39, and glass transition temperature (Tg) was 109 ℃. The results of the devitrification, striae and releasability are shown in table 1.

[ example 6A ]

A molded article was obtained in the same manner as in example 1A except that 0.3 part by mass of dibutyltin dichloride (II) was changed to 0.13 part by mass of 2,4, 6-trimethylpyridine [ polymerization catalyst ] (pKa value 7.5).

Further, as a result of measuring properties of the obtained molded article, the refractive index (ne) was 1.598, Abbe's number (. nu.e) was 39, and glass transition temperature (Tg) was 112 ℃, and good physical properties were exhibited. The results of the devitrification, striae and releasability are shown in table 1.

[ example 7A ]

Molded bodies were obtained in the same manner as in example 1A, except that the type and amount of the catalyst were set as described in table 1.

Further, as a result of measuring properties of the obtained molded article, the refractive index (ne) was 1.598, Abbe's number (. nu.e) was 39, glass transition temperature (Tg) was 108 ℃, and good physical properties were exhibited. The results of the devitrification, striae and releasability are shown in table 1.

Comparative example 1A

The same polymerizable composition as in example 1A was prepared and injected into the cavity of a casting mold, except that the amount of the catalyst was set as described in table 1. The casting mold into which the polymerizable composition was injected was put into a polymerization oven, and polymerization was performed by gradually raising the temperature from 20 ℃ to 130 ℃ over 20 hours. After completion of the polymerization, the casting mold was taken out of the oven, the molded article was released from the cavity, and further, annealing treatment was performed at 120 ℃ for 2 hours to obtain a molded article.

Comparative example 2A

Polymerization was carried out in the same manner as in comparative example 1A, except that the cast product was cured by a polymerization procedure (temperature-raising procedure) in which the cast product was cured for 4 hours in comparative example 1A. As a result of taking out the cavity immediately after polymerization, it was confirmed that the polymerizable composition expanded and overflowed from the cavity of the casting mold in the polymerization process. The cured molded article was demolded and further annealed at 120 ℃ for 2 hours to obtain a molded article.

The properties of the molded article thus obtained were measured, and as a result, the refractive index (ne) was 1.596, the Abbe number (. nu.e) was 39, and the glass transition temperature (Tg) was 113 ℃. The results of the devitrification, striae and releasability are shown in table 1.

After annealing, the molded article obtained was observed for appearance (visual observation in the room), and as a result, bubbles were generated in the cured molded article, and a large number of striae were also generated.

Comparative example 3A

Polymerization was carried out in the same manner as in example 1A, except that the type and amount of the catalyst were set as described in table 1, but were not cured. Since the cured product was not cured, the degree of devitrification and the like were not evaluated.

As described above, in the example in which the operation time of the polymerization reaction was short, a lens with good quality was obtained.

On the other hand, in comparative example 1A, although a good quality lens was obtained, the polymerization time was 20 hours, and a long time was required to complete the polymerization.

In comparative example 2A, the polymerization time was set to 4 hours, and the quality of the resulting molded article was poor.

[ example 8A ]

In the case of the example 1A,

changing the 1 st mixed solution to a mixed solution prepared as follows;

changing 0.3 part by mass of dibutyltin (II) dichloride to 0.15 part by mass of dimethyltin (II) Dichloride (DMC); and the number of the first and second groups,

a molded article (lens) was produced in the same manner as in example 1A except that the cast material was placed in a heat-insulating container at 25 ℃ and left to stand for 5 hours, and when heat-insulating polymerization was performed, additional heating was performed at 120 ℃ for 1 hour. In the production of the above-mentioned molded article, a graph showing the relationship between the elapsed time of the polymerization reaction and the temperature in the heat-insulating container is shown in FIG. 1.

Method for producing first mixture solution in embodiment 8A

First, a composition (9.8 parts by mass) containing 2,5(6) -bis (isocyanatomethyl) -bicyclo- [2.2.1] -heptane was dissolved in a master solution, which was a photochromic compound, i.e., reverosacol welley Green (0.036 parts by mass) manufactured by Vivimed, revesacol heat Green (0.060 parts by mass) manufactured by Vivimed, Peacock Blue (0.030 parts by mass) manufactured by Vivimed, Jalapeno Red (0.024 parts by mass) manufactured by Vivimed, and HOSTAVIN PR-25(0.075 parts by mass) as an ultraviolet absorber.

Next, a composition (30.05 parts by mass) containing 2,5(6) -bis (isocyanatomethyl) -bicyclo- [2.2.1] -heptane, the obtained mother liquor (10 parts by mass), ADEKA PLURONIC (registered trademark) L-64(2.52 parts by mass) manufactured by ADEKA Corporation, JP-506H (0.05 parts by mass) manufactured by north-urban chemical industry as an acid phosphate, pentaerythritol tetrakis (3-mercaptopropionate) (19.98 parts by mass), and 4-mercaptomethyl-1, 8-dimercapto-3, 6-dithiaoctane (27.25 parts by mass) were added to prepare a mixed solution, thereby obtaining a polymerizable composition for an optical material. The thixotropic ratio of the polymerizable composition for optical materials was 1.0.

In the production of the molded article according to example 8A, the maximum exothermic temperature in the polymerization process was 132 ℃ and the maximum exothermic duration was 65 minutes. The molded article thus produced was not clouded at all and was excellent in transparency. Further, voids due to bubbles, cracks, and the like are not generated.

< example B >

Hereinafter, the production method B of embodiment 1 will be specifically described by way of example B, but the production method B of embodiment 1 is not limited to these examples.

The viscosity in example B was measured in the same manner as described above.

In example B, the amine content in the cured product was measured by the method described above. Specifically, the peak areas appearing at retention times of 7.0 minutes to 7.3 minutes were summed up, and the amine content was calculated using a calibration curve (y: 0.00018x +6.43364, y: catalyst weight (μ g), x: peak area) prepared in advance.

The molded articles obtained in the respective examples or comparative examples were evaluated as follows.

(Reinforcement)

The molded article was projected by an ultrahigh pressure mercury lamp (model OPM-252 HEG: manufactured by USHIO Inc.), and the transmitted image was observed by visual observation, and evaluated according to the following criteria.

A: no striae were observed. Specifically, beads having a length of 1.0mm or more were not observed visually within and outside a range of 15mm in radius from the center of the molded article.

[ example 1B ]

A mixed solution was prepared by charging 0.1 part by mass of an internal mold release agent [ internal mold release agent ] for MR manufactured by Mitsui chemical corporation, 1.5 parts by mass of Tinuvin329[ ultraviolet absorber ], and 40.6 parts by mass of 2,5(6) -bis (isocyanatomethyl) -bicyclo- [2.2.1] -heptane [ monomer for optical materials ]. The mixture was stirred at 25 ℃ for 1 hour to completely dissolve the mixture. Then, 23.9 parts by mass of pentaerythritol tetrakis (3-mercaptopropionate) [ monomer for optical material ] and 25.5 parts by mass of 4-mercaptomethyl-1, 8-dimercapto-3, 6-dithiaoctane [ monomer for optical material ] were charged into the mixed solution, and the mixture was stirred at 25 ℃ for 5 minutes to prepare a uniform solution. Further, 0.05 part by mass of 3, 5-dimethylpyridine [ polymerization catalyst ] (pKa value 6.14) was charged into the obtained homogeneous solution, and the mixture was stirred for 1 hour while degassing was performed at 400Pa and 25 ℃. The optical material monomer was polymerized while adjusting the viscosity, to obtain a1 st mixed solution as a mixture containing the prepolymer. The viscosity of the prepolymer containing mixture is shown in table 2.

2,5(6) -bis (isocyanatomethyl) -bicyclo- [2.2.1] -heptane [ the monomer for optical materials ]10.0 parts by mass and 3, 5-dimethylpyridine [ the polymerization catalyst ]0.15 part by mass were charged to prepare a mixed solution. The mixture was stirred at 25 ℃ for 15 minutes to obtain a2 nd mixture.

Then, the 1 st mixed solution and the 2 nd mixed solution were mixed at 20 ℃ to obtain a polymerizable composition for an optical material.

Whether or not the prepolymer contains an isocyanate group is shown in table 2.

Table 2 shows a value obtained by subtracting a refractive index B of a prepolymer raw material composition (also referred to as "refractive index a-refractive index B"), which is a composition before forming a prepolymer and contains 2 or more different monomers for an optical material and a polymerization catalyst, from a refractive index a of a polymerizable prepolymer composition for an optical material.

The obtained polymerizable composition for optical materials was transferred to a casting mold (i.e., a casting die) while being remixed in a static mixer.

The viscosity (also referred to as casting viscosity) of the polymerizable composition for an optical material when it was fed to a mold and cast was adjusted to the value shown in table 2.

In the transportation of the polymerizable composition for optical materials, the polymerizable composition for optical materials was filtered through a1 μm ptfe filter and injected at a rate of 10 g/sec into a cavity of a casting mold composed of a 4-bend or 6-bend glass mold (upper mold) having a diameter of 78mm and a 4-bend or 2-bend glass mold (lower mold) having a diameter of 78mm, and having a cavity for lens production having a set center thickness described in table 2.

The cast product was placed in a heat-insulated container at 25 ℃ and allowed to stand for 2 hours to carry out heat-insulated polymerization, and then the cast product was taken out from the heat-insulated container and further subjected to heat polymerization at 120 ℃ for 1 hour.

The cured molded article was released from the casting mold and further subjected to annealing treatment at 120 ℃ for 2 hours to obtain a molded article (lens).

The content of amine in the obtained molded article (i.e., cured product) is shown in table 2.

Example 2B to example 4B

A molded article (lens) was obtained in the same manner as in example 1B except that the amount of the polymerization catalyst and the stirring time of the first mixed solution in the prepolymerization step were changed to values shown in table 2, and the casting viscosity of the polymerizable composition for an optical material was adjusted to the values shown in table 2.

[ example 5B ]

A mixed solution was prepared by charging 0.1 part by mass of an internal mold release agent [ internal mold release agent ] for MR manufactured by Mitsui chemical corporation, 1.5 parts by mass of Tinuvin329[ ultraviolet absorber ], and 50.6 parts by mass of 2,5(6) -bis (isocyanatomethyl) -bicyclo- [2.2.1] -heptane [ monomer for optical materials ]. The mixture was stirred at 25 ℃ for 1 hour to completely dissolve the mixture. Then, to the mixed solution, 1.7 parts by mass of pentaerythritol tetrakis (3-mercaptopropionate) [ monomer for optical materials ] and 1.8 parts by mass of 4-mercaptomethyl-1, 8-dimercapto-3, 6-dithiaoctane [ monomer for optical materials ] were charged, and the mixture was stirred at 25 ℃ for 5 minutes to prepare a uniform solution. Further, 0.2 part by mass of 3, 5-dimethylpyridine [ polymerization catalyst ] was charged into the obtained homogeneous solution, and the mixture was stirred at 40 ℃ for 3 hours to polymerize the monomer for an optical material while adjusting the viscosity, thereby obtaining a mixture containing a prepolymer. The viscosity of the prepolymer containing mixture is shown in table 2.

Then, the mixture containing the prepolymer was degassed at 400Pa and 25 ℃ for 1 hour to obtain a1 st mixed solution.

22.2 parts by mass of pentaerythritol tetrakis (3-mercaptopropionate) [ monomer for optical material ] and 23.7 parts by mass of 4-mercaptomethyl-1, 8-dimercapto-3, 6-dithiaoctane [ monomer for optical material ] were charged to prepare a mixed solution, and the mixed solution was degassed at 400Pa and 25 ℃ for 1 hour to obtain a2 nd mixed solution.

Then, the 1 st mixed solution and the 2 nd mixed solution were mixed at 20 ℃ to obtain a polymerizable composition for an optical material.

The obtained polymerizable composition for optical materials was transferred to a casting mold in the same manner as in example 1B, and the casting viscosity was adjusted to the value shown in table 2.

The cast product was placed in a heat-insulated container at 25 ℃ and allowed to stand for 2 hours to conduct heat-insulated polymerization, and then the cast product was taken out from the heat-insulated container and further subjected to heat polymerization at 120 ℃ for 1 hour.

The cured molded article was released from the casting mold and further subjected to annealing treatment at 120 ℃ for 2 hours to obtain a molded article (lens).

Example 6B to example 7B

A molded article (lens) was obtained in the same manner as in example 5B except that the contents of pentaerythritol tetrakis (3-mercaptopropionate) and 4-mercaptomethyl-1, 8-dimercapto-3, 6-dithiaoctane in the prepolymerization step were changed to values shown in table 2, and the casting viscosity of the polymerizable composition for optical materials was adjusted to the values shown in table 2.

[ example 8B ]

A molded article (lens) was obtained in the same manner as in example 7B, except that the cast article was placed in a heat-insulating container set to 25 ℃, allowed to stand for 3 hours, subjected to heat-insulating polymerization, and then taken out of the heat-insulating container and released from the mold.

[ example 9B ]

A molded body (lens) was obtained in the same manner as in example 7B, except that the cast product was not polymerized in the heat-insulating state, and was polymerized by heating from 30 ℃ to 120 ℃ over time and heating for 3 hours.

Example 10B to example 11B

[ example 12B ]

A molded article (lens) was obtained in the same manner as in example 5B except that the polymerization catalyst was changed from 3, 5-lutidine to dibutyltin dichloride (II), and the contents of pentaerythritol tetrakis (3-mercaptopropionate) and 4-mercaptomethyl-1, 8-dimercapto-3, 6-dithiaoctane, the stirring time in the prepolymerization step, the casting viscosity of the polymerizable composition for an optical material, and the time for adiabatic polymerization in the prepolymerization step were changed to values shown in table 2.

[ example 13B ]

A molded body (lens) was obtained in the same manner as in example 12B, except that the cast product was not polymerized in the heat-insulating state, and was heated from 30 ℃ to 120 ℃ over time and polymerized in the heating state over 3 hours.

The monomer species described in each table are as follows.

a 1: mixtures of 2, 5-bis (isocyanatomethyl) bicyclo- [2.2.1] -heptane and 2, 6-bis (isocyanatomethyl) bicyclo- [2.2.1] -heptane

a 2: dicyclohexylmethane diisocyanate

a 3: 1, 3-bis (isocyanatomethyl) cyclohexane

b 1: 4-mercaptomethyl-1, 8-dimercapto-3, 6-dithiaoctane

b 2: pentaerythritol tetrakis (3-mercaptopropionate)

b 3: mixtures of 5, 7-dimercaptomethyl-1, 11-dimercapto-3, 6, 9-trithiaundecane, 4, 7-dimercaptomethyl-1, 11-dimercapto-3, 6, 9-trithiaundecane, and 4, 8-dimercaptomethyl-1, 11-dimercapto-3, 6, 9-trithiaundecane

b 4: pentaerythritol tetrakis (2-mercaptoacetate)

b 5: 2, 5-bis (mercaptomethyl) -1, 4-dithianes

As shown in table 2, in the examples using the following method for producing an optical material, the optical material produced had suppressed striae and the production time of the optical material was shortened, the method comprising the steps of:

a preparation step of preparing a total of 100 parts by mass of 2 or more different optical material monomers and 0.010 to 2.0 parts by mass of a polymerization catalyst;

a pre-polymerization step of mixing a part of 2 or more different optical material monomers and at least a part of a polymerization catalyst to polymerize at least a part of the 2 or more different optical material monomers to obtain a pre-polymer, thereby obtaining a mixture containing the pre-polymer;

a step of producing a polymerizable composition for optical materials, in which a mixture containing a prepolymer is added with at least the remaining part of 2 or more different monomers for optical materials, thereby obtaining a polymerizable composition for optical materials containing 2 or more different monomers for optical materials, a prepolymer, and a polymerization catalyst; and

In examples, striae were more favorably suppressed in examples 2B to 4B and examples 6B to 11B in which the viscosity of the polymerizable composition for an optical material during casting (i.e., the casting viscosity) was 70mPa · s or more.

[ example 14B ]

58.9 parts by mass of dicyclohexylmethane diisocyanate [ optical material monomer ], 1.5 parts by mass of Tinuvin329[ ultraviolet absorber ], and 0.1 part by mass of internal mold release agent [ internal mold release agent ] for MR manufactured by Mitsui chemical corporation were charged to prepare a mixed solution. The mixture was stirred at 25 ℃ for 1 hour to completely dissolve the mixture. Then, 4.1 parts by mass of a mixture of 5, 7-dimercaptomethyl-1, 11-dimercapto-3, 6, 9-trithiaundecane, 4, 7-dimercaptomethyl-1, 11-dimercapto-3, 6, 9-trithiaundecane, and 4, 8-dimercaptomethyl-1, 11-dimercapto-3, 6, 9-trithiaundecane was charged into the mixture, and the mixture was stirred at 25 ℃ for 5 minutes to prepare a uniform solution. Further, 1.5 parts by mass of 3, 5-dimethylpyridine [ polymerization catalyst ] was charged into the obtained homogeneous solution, and the mixture was stirred at 40 ℃ for 4 hours to polymerize the monomer for an optical material while adjusting the viscosity, thereby obtaining a mixture containing a prepolymer. The viscosity of the prepolymer containing mixture is shown in table 3.

Then, the mixture containing the prepolymer was degassed at 400Pa and 25 ℃ for 1 hour to obtain a1 st mixed solution.

37.0 parts by mass of a mixture of 5, 7-dimercaptomethyl-1, 11-dimercapto-3, 6, 9-trithiaundecane, 4, 7-dimercaptomethyl-1, 11-dimercapto-3, 6, 9-trithiaundecane, and 4, 8-dimercaptomethyl-1, 11-dimercapto-3, 6, 9-trithiaundecane was charged, and the mixture was degassed at 400Pa and 25 ℃ for 1 hour to obtain a2 nd mixture.

Then, the 1 st mixed solution and the 2 nd mixed solution were mixed at 20 ℃ to obtain a polymerizable composition for an optical material.

The obtained polymerizable composition for optical materials was transferred to a casting mold in the same manner as in example 1, and the casting viscosity was adjusted to the value shown in table 3.

The cast product was placed in a heat-insulated container at 25 ℃ and allowed to stand for 3 hours to carry out heat-insulated polymerization, and then the cast product was taken out from the heat-insulated container and further subjected to heat polymerization at 130 ℃ for 2 hours.

The cured molded article was released from the casting mold and further subjected to annealing treatment at 120 ℃ for 2 hours to obtain a molded article (lens).

As shown in table 3, in the examples using the following method for producing an optical material, the optical material produced had suppressed striae and the production time of the optical material was shortened, the method comprising the steps of:

a preparation step of preparing a total of 100 parts by mass of 2 or more different optical material monomers and 0.010 to 2.0 parts by mass of a polymerization catalyst;

[ example 15B ]

A mixed solution was prepared by charging 48 parts by mass of 1, 3-bis (isocyanatomethyl) cyclohexane [ monomer for optical materials ], 1.5 parts by mass of Tinuvin329[ ultraviolet absorber ], and 0.18 part by mass of JP-506H (manufactured by North China chemical Co., Ltd.). The mixture was stirred at 25 ℃ for 1 hour to completely dissolve the mixture. Then, 4.0 parts by mass of pentaerythritol tetrakis (2-mercaptoacetate) and 3.9 parts by weight of 2, 5-bis (mercaptomethyl) -1, 4-dithian cyclohexane were charged into the mixture, and the mixture was stirred at 25 ℃ for 5 minutes to prepare a homogeneous solution. Further, 0.1 part by mass of 3, 5-dimethylpyridine [ polymerization catalyst ] was charged into the obtained homogeneous solution, and the mixture was stirred at 40 ℃ for 3 hours to polymerize the monomer for an optical material while adjusting the viscosity, thereby obtaining a mixture containing a prepolymer. The viscosity of the prepolymer containing mixture is shown in table 5.

Then, the mixture containing the prepolymer was degassed at 400Pa and 25 ℃ for 1 hour to obtain a1 st mixed solution.

22.7 parts by mass of pentaerythritol tetrakis (2-mercaptoacetate) and 22.3 parts by weight of 2, 5-bis (mercaptomethyl) -1, 4-dithian cyclohexane were charged, and the mixture was degassed at 400Pa and 25 ℃ for 1 hour to obtain a2 nd mixture.

Then, the 1 st mixed solution and the 2 nd mixed solution were mixed at 20 ℃ to obtain a polymerizable composition for an optical material.

The cured molded article was released from the casting mold and further subjected to annealing treatment at 120 ℃ for 2 hours to obtain a molded article (lens).

As shown in table 4, in the examples using the following method for producing an optical material, the optical material obtained was suppressed in striae and the production time of the optical material was shortened, the method comprising the steps of:

a preparation step of preparing a total of 100 parts by mass of 2 or more different optical material monomers and 0.010 to 2.0 parts by mass of a polymerization catalyst;

The entire disclosures of Japanese patent application No. 2020-011127 filed on 27/2020 and Japanese patent application No. 2020-194660 filed on 24/11/2020 are incorporated herein by reference.

All documents, patent applications, and technical standards described in the present specification are incorporated by reference into the present specification to the same extent as if each document, patent application, and technical standard was specifically and individually described.

50页详细技术资料下载

上一篇：一种医用注射器针头装配设备

下一篇：具有良好粘附性能的湿固化组合物

Polymerizable composition for optical material, polymerizable prepolymer composition for optical material, cured product, and method for producing optical material

相关技术

网友询问留言