阅读说明：本技术 一种超疏水涤纶丝及其制备方法 (Super-hydrophobic polyester yarn and preparation method thereof ) 是由 徐志林 施锋杰 项兴军 于 2021-07-15 设计创作，主要内容包括：本申请涉及涤纶丝的领域,具体公开了一种超疏水涤纶丝及其制备方法。制备方法包括以下步骤：S1：原料预处理：将聚对苯二甲酸乙二醇酯称量并干燥；S2：熔融纺丝；S3：冷却成型,集束：得到原丝；S4：喷涂粘接层和疏水层：在原丝外表面依次喷涂粘接层和疏水层；S5：冷却干燥：得到涤纶丝；所述粘接层为质量分数为20-60%的聚乙烯醇水溶液；所述疏水层包括微晶石蜡,疏水层用量为原丝重量的40-60%,其具有提高涤纶丝的疏水性的优点,同时可确保疏水效果的稳定持续性。(The application relates to the field of polyester yarns, and particularly discloses a super-hydrophobic polyester yarn and a preparation method thereof. The preparation method comprises the following steps: s1: pretreatment of raw materials: weighing and drying polyethylene terephthalate; s2: melt spinning; s3: cooling and forming, and bundling: obtaining raw silk; s4: spraying an adhesive layer and a hydrophobic layer: sequentially spraying an adhesive layer and a hydrophobic layer on the outer surface of the protofilament; s5: and (3) cooling and drying: obtaining polyester yarns; the adhesive layer is a polyvinyl alcohol aqueous solution with the mass fraction of 20-60%; the hydrophobic layer comprises microcrystalline paraffin, the dosage of the hydrophobic layer is 40-60% of the weight of the raw silk, the hydrophobic effect of the polyester silk is improved, and meanwhile, the stability and the continuity of the hydrophobic effect can be ensured.)

1. The preparation method of the super-hydrophobic polyester yarn is characterized by comprising the following steps:

s1: pretreatment of raw materials: weighing and drying polyethylene terephthalate;

s2: melt spinning;

s3: cooling and forming, and bundling: obtaining raw silk;

s4: spraying an adhesive layer and a hydrophobic layer: sequentially spraying an adhesive layer and a hydrophobic layer on the outer surface of the protofilament;

s5: and (3) cooling and drying: obtaining polyester yarns;

the adhesive layer is a polyvinyl alcohol aqueous solution with the mass fraction of 20-60%;

the hydrophobic layer comprises microcrystalline paraffin, and the dosage of the hydrophobic layer is 40-60% of the weight of the precursor.

2. The preparation method of the super-hydrophobic polyester yarn as claimed in claim 1, wherein the hydrophobic layer further comprises polyethylene, and the mass part ratio of the auxiliary material to the microcrystalline paraffin is 1: (8-15).

3. The method for preparing the super-hydrophobic polyester yarns as claimed in claim 1, wherein the polyvinyl alcohol in the bonding layer is 30-45% of the weight of the yarns.

4. The method as claimed in claim 3, wherein the filament temperature is 100-140 ℃ before the adhesive layer is sprayed in step S4.

5. The method for preparing the super-hydrophobic polyester yarns as claimed in claim 1, wherein in the step S1, the raw material further comprises modified starch, and the modified starch is prepared by the following method:

z1: mixing starch and aqueous hydrogen peroxide, wherein the amount of the hydrogen peroxide is 5-12% of that of the starch; mixing at 40-60 deg.C for 10-30min, filtering, and drying to obtain oxidized starch;

z2: mixing the oxidized starch and glycerol uniformly, and heating to 55-70 deg.C and keeping the temperature for 10-30 min; filtering and drying to obtain the modified starch.

6. The preparation method of the super-hydrophobic polyester yarn as claimed in claim 5, wherein the mass part ratio of the polyethylene terephthalate and the modified starch in the raw materials is 1: (0.04-0.055).

7. The method for preparing super-hydrophobic polyester yarns as claimed in claim 1, wherein the cooling in the step S5 is performed by circular blowing at a temperature of 5-20 ℃.

8. A super-hydrophobic polyester yarn, characterized in that, it is obtained by the method for preparing the super-hydrophobic polyester yarn according to any one of claims 1 to 7.

Technical Field

The application relates to the field of polyester yarns, in particular to super-hydrophobic polyester yarns and a preparation method thereof.

Background

Polyester yarn is an important variety of synthetic fiber, and is a fiber obtained by taking polyethylene terephthalate (PET) as a raw material and performing melt spinning and bundling. Including undrawn, as well as drawn and textured filaments.

The polyester yarn belongs to chemical fiber, and as a fiber for clothes, the polyester has the characteristics of high strength, soft hand feeling, stretch resistance, crease resistance, wear resistance, machine washability and the like. But the defects of single variety and low technical content are shown at present due to rapid amplification of the production scale of the conventional polyester variety. Wherein, the polyester yarn has poor hydrophobicity, which limits the application range.

Disclosure of Invention

In order to improve the hydrophobicity of the polyester yarn, the application provides the super-hydrophobic polyester yarn and the preparation method thereof.

In a first aspect, the present application provides the following technical solutions: a preparation method of super-hydrophobic polyester yarns comprises the following steps:

s1: pretreatment of raw materials: weighing and drying polyethylene terephthalate;

s2: melt spinning;

s3: cooling, forming and bundling; obtaining raw silk;

s4: spraying an adhesive layer and a hydrophobic layer: sequentially spraying an adhesive layer and a hydrophobic layer on the outer surface of the protofilament;

s5: and (3) cooling and drying: obtaining polyester yarns;

the adhesive layer is a polyvinyl alcohol aqueous solution with the mass fraction of 20-60%;

the hydrophobic layer comprises microcrystalline paraffin, and the dosage of the hydrophobic layer is 40-60% of the weight of the precursor.

By adopting the technical scheme, the polyester protofilament, the adhesive layer and the hydrophobic layer are sequentially arranged from inside to outside, and experiments show that the polyester protofilament, the adhesive layer and the hydrophobic layer have excellent hydrophobic effect, are good in weather resistance and are good in stability and continuity of the hydrophobic effect. The adhesive layer adopts a polyvinyl alcohol aqueous solution, so that on one hand, the polyvinyl alcohol can be dissolved at 90-120 ℃, and the energy consumption and the high-temperature contact with the polyester protofilament are reduced; on the other hand, when the adhesive layer is sprayed, the temperature outside the polyester protofilament is higher, water can be evaporated, and the polyvinyl alcohol is transferred to the surface of the protofilament by taking the water as a carrier; the polyvinyl alcohol has adhesiveness in a molten state, so that the connection between the precursor and the hydrophobic layer is realized. After being melted, the microcrystalline paraffin is attached to the surfaces of the bonding layer and the protofilament to form a hydrophobic layer, and the hydrophobic layer plays a role in hydrophobicity.

The bonding layer plays a role in bonding, and can improve the integrity and the overall stability of the super-hydrophobic polyester yarns, so that the hydrophobic stability and the continuity are improved.

Further, the hydrophobic layer also comprises polyethylene, and the mass part ratio of the auxiliary material to the microcrystalline paraffin is 1: (8-15).

By adopting the technical scheme, during mixing, the polyethylene is heated to be molten, then the microcrystalline paraffin is added, and the mixture is uniformly dispersed for later use. It is found from the test that the stability and the durability of the hydrophobic effect can be further improved.

Furthermore, the usage amount of the polyvinyl alcohol in the bonding layer is 30-45% of the weight of the precursor.

By adopting the technical scheme, the polyvinyl alcohol has certain hygroscopicity, so that the polyvinyl alcohol serving as the bonding layer cannot be directly exposed to the outside and contacted with external moisture; otherwise it could easily lead to the destruction of the adhesive layer and thus to an overall hydrophobic property. Limiting the attachment amount of polyvinyl alcohol, wherein the polyvinyl alcohol does not need to completely cover the surface of the protofilament; the polyvinyl alcohol forms a plurality of approximately uniform bonding points on the surface of the protofilament, the hydrophobic layer is fixed, and the polyvinyl alcohol is bonded with the hydrophobic layer material; on the other hand, part of the hydrophobic layer is directly connected with the protofilament. It was found from the test that the hydrophobicity and the weather resistance were balanced and the stable persistence of the hydrophobic effect was achieved.

Further, in the step S4, before the adhesive layer is sprayed, the filament temperature is 100 ℃ to 140 ℃.

By adopting the technical scheme, experiments show that the hydrophobicity can be further improved to a small extent.

Further, in step S1, the raw material further includes a modified starch, and the modified starch is prepared by the following method:

z1: mixing starch and aqueous hydrogen peroxide, wherein the amount of the hydrogen peroxide is 5-12% of that of the starch; mixing at 40-60 deg.C for 10-30min, filtering, and drying to obtain oxidized starch;

z2: mixing the oxidized starch and glycerol uniformly, and heating to 55-70 deg.C and keeping the temperature for 10-30 min; filtering and drying to obtain the modified starch.

By adopting the technical scheme, the modified starch serving as a part of the raw materials has hydrophobicity, so that the polyester protofilament has hydrophobicity; on the other hand, the starch contains a large number of hydroxyl groups, and hydrogen bonds can be generated between the starch and polyvinyl alcohol in the bonding layer, so that the connectivity between the bonding layer and the protofilaments is improved, and the integrity of the super-hydrophobic polyester yarns is improved. Further improving the stability and persistence of the hydrophobic effect.

Further, the weight portion ratio of the polyethylene terephthalate to the modified starch in the raw materials is 1: (0.04-0.055).

By adopting the technical scheme, experiments show that the stability and the continuity of the hydrophobic effect can be further improved by compounding the raw materials in the optimal range. The reasons may be: the compound of the raw materials in the limited range can improve the adhesive strength between the adhesive layer and the protofilament, thereby improving the integrity of the super-hydrophobic polyester yarn.

Further, in the step S5, circular air blowing is adopted for cooling, and the temperature is 5-20 ℃.

By adopting the technical scheme, the original yarns sprayed with the bonding layer and the hydrophobic layer are uniformly cooled and dried by circular blowing, and the super-hydrophobic polyester yarns are obtained.

In a second aspect, the present application provides the following technical solutions: a super-hydrophobic polyester yarn obtained by the method for preparing the super-hydrophobic polyester yarn according to any one of claims 1 to 7.

By adopting the technical scheme, the polyester yarn with excellent hydrophobic property and stable and continuous hydrophobic effect is obtained.

In summary, the present application has the following beneficial effects:

1. because this application adopts the scheme that the protofilament surface sprays adhesive linkage and hydrophobic layer in proper order after the cooling shaping, the dacron silk that obtains has excellent hydrophobic effect, has the weatherability simultaneously, and the stability persistence of hydrophobic effect is good.

2. The application adopts polyethylene and microcrystalline wax, so that the stability and the continuity of the hydrophobic effect can be further improved.

3. As the temperature of the protofilament before the spraying of the bonding layer is limited to 100-140 ℃, the hydrophobicity can be further improved to a small extent.

4. Because this application adopts modified starch and PET as the raw materials, improves super hydrophobic polyester silk's wholeness, further improves the stable persistence of hydrophobic effect.

Detailed Description

Examples

Example 1: a preparation method of super-hydrophobic polyester yarns comprises the following steps:

s1: pretreatment of raw materials: putting 100kg of polyethylene terephthalate (PET) into a drying oven, and drying at 165 ℃ for 4h to obtain dried PET;

s2: melt spinning: putting the dried PET into an extruder for extruding and spinning, wherein the heating section temperatures are 235 ℃, 245 ℃, 255 ℃ and 265 ℃ respectively; the PET spinning temperature is 265 ℃, and the spinning speed is 3000 m/min;

s3: cooling and forming, and bundling: cooling by circular air blowing at the temperature of 22 +/-1 ℃ and the air speed of 0.5m/s until the fiber temperature is 150 ℃, and bundling to obtain 167dtex/48f protofilaments;

s4: spraying an adhesive layer and a hydrophobic layer: respectively enabling the precursor to pass through two annular nozzles (the nozzles face the inside of the ring), and uniformly spraying an adhesive layer and a hydrophobic layer in sequence;

the adhesive layer is 60% polyvinyl alcohol aqueous solution, and the usage amount of the polyvinyl alcohol is 25% of the weight of the protofilament; the preparation method comprises the following steps: putting polyvinyl alcohol and 100kg of water into a stirrer, heating to 95 ℃, and stirring for 30min at a stirring speed of 60r/min to obtain the polyvinyl alcohol-water emulsion; when in use, the bonding layer is insulated to 95 ℃;

the hydrophobic layer is microcrystalline paraffin, and the dosage of the microcrystalline paraffin is 40% of the weight of the precursor; when in use, the microcrystalline paraffin is heated to 90 ℃ to be melted and is kept warm, and is sprayed out through a spray head;

s5: and (3) cooling and drying: cooling by circular blowing at 25 +/-1 ℃ and 0.6m/s to normal temperature to obtain the super-hydrophobic polyester yarn.

Example 2: the preparation method of the super-hydrophobic polyester yarn is different from the preparation method of the example 1 in that:

in step S4, the adhesive layer is a 30% polyvinyl alcohol aqueous solution, and the usage amount of the polyvinyl alcohol is 20% of the weight of the protofilament;

the hydrophobic layer is microcrystalline paraffin, and the dosage of the microcrystalline paraffin is 45% of the weight of the precursor.

Example 3: the preparation method of the super-hydrophobic polyester yarn is different from the preparation method of the example 1 in that:

in step S4, the adhesive layer is 20% polyvinyl alcohol aqueous solution, and the usage amount of the polyvinyl alcohol is 60% of the weight of the protofilament;

the hydrophobic layer is microcrystalline paraffin, and the dosage of the microcrystalline paraffin is 60 percent of the weight of the precursor.

Example 4: the preparation method of the super-hydrophobic polyester yarn is different from the preparation method of the example 2 in that: in step S4, the hydrophobic layer was composed of 5kg of polyethylene and 40kg of microcrystalline wax; the preparation method of the hydrophobic layer comprises the following steps: putting microcrystalline paraffin into a stirrer, heating to 90 ℃ to melt, preserving heat, adding polyethylene, and dispersing for 2min under the condition of 600 r/min; then heated to 100 ℃ and stirred at a stirring speed of 200r/min for 10min to obtain the hydrophobic layer.

Example 5: the preparation method of the super-hydrophobic polyester yarn is different from the embodiment 4 in that: in step S4, the hydrophobic layer was composed of 3.8kg of polyethylene and the balance of microcrystalline wax.

Example 6: the preparation method of the super-hydrophobic polyester yarn is different from the embodiment 4 in that: in step S4, the hydrophobic layer was composed of 2.8125kg of polyethylene and the balance of microcrystalline wax.

Example 7: the preparation method of the super-hydrophobic polyester yarn is different from the embodiment 5 in that: in step S4, polyvinyl alcohol was used in the adhesive layer in an amount of 30% by weight of the raw yarn.

Example 8: the preparation method of the super-hydrophobic polyester yarn is different from the embodiment 5 in that: in step S4, the amount of polyvinyl alcohol used in the adhesive layer was 35% by weight of the raw yarn.

Example 9: the preparation method of the super-hydrophobic polyester yarn is different from the embodiment 5 in that: in step S4, the amount of polyvinyl alcohol used in the adhesive layer was 45% by weight of the raw yarn.

Example 10: the preparation method of the super-hydrophobic polyester yarn is different from the embodiment 8 in that: in step S3, the fiber is cooled by circular air blow to a fiber temperature of 100 ℃ for bundling.

Example 11: the preparation method of the super-hydrophobic polyester yarn is different from the embodiment 8 in that: in step S3, the fiber is cooled by circular air blow to 110 ℃ and bundled.

Example 12: the preparation method of the super-hydrophobic polyester yarn is different from the embodiment 8 in that: in step S3, the fiber is cooled by circular air blow to 140 ℃ and bundled.

Example 13: a method for preparing super-hydrophobic polyester yarns, which is different from the method in example 11 in that:

in step S1, the raw materials are 100kg of pet and 20kg of modified starch, and the modified starch is prepared by the following steps:

z1: 30kg of cassava starch and 10% of aqueous hydrogen peroxide solution by mass are put into a stirrer, and the amount of the hydrogen peroxide is 5% of that of the starch; mixing at 40 deg.C for 30min, filtering with gauze, and spreading in a drying oven at 60 deg.C for drying for 1 hr to obtain oxidized starch;

z2: putting the oxidized starch and glycerol into a stirrer, wherein the glycerol is not oxidized and the starch is obtained; heating to 55 deg.C and maintaining for 30 min; filtering and drying with gauze, and spreading in a drying oven at 60 deg.C for 1 hr to obtain modified starch.

In step S1, the dried PET and the modified starch are added into a stirrer and stirred for 2min at the speed of 800r/min to obtain a mixed raw material.

In step S2, the mixed raw materials are melt-spun.

Example 14: a method for preparing super-hydrophobic polyester yarns, which is different from the method in example 13 in that:

in step S1, the modified starch is prepared by the following steps:

z1: 30kg of cassava starch and 10% of aqueous hydrogen peroxide solution by mass are put into a stirrer, and the amount of the hydrogen peroxide is 12% of that of the starch; mixing at 60 deg.C for 10min, filtering with gauze, and spreading in 60 deg.C drying oven for drying for 1 hr to obtain oxidized starch;

z2: putting the oxidized starch and glycerol into a stirrer, wherein the glycerol is not oxidized and the starch is obtained; heating to 70 deg.C and maintaining for 10 min; filtering and drying with gauze, and spreading in a drying oven at 60 deg.C for 1 hr to obtain modified starch.

Example 15: a method for preparing super-hydrophobic polyester yarns, which is different from the method in example 13 in that: in step S1, the raw materials were 100kg of PET and 4kg of modified starch.

Example 16: a method for preparing super-hydrophobic polyester yarns, which is different from the method in example 13 in that: in step S1, the raw materials were 100kg of PET and 5kg of modified starch.

Example 17: a method for preparing super-hydrophobic polyester yarns, which is different from the method in example 13 in that: in step S1, the raw materials were 100kg of PET and 5.5kg of modified starch.

Example 18: a method for preparing super-hydrophobic polyester yarns, which is different from the method in example 16 in that: in step S5, the temperature of the circular air blowing is 5 + -2 deg.C.

Example 19: a method for preparing super-hydrophobic polyester yarns, which is different from the method in example 16 in that: in step S5, the temperature of the circular air blowing is 20. + -. 2 ℃.

In the above embodiment, the microcrystalline paraffin was purchased from Jinan fengming chemical company, ltd, and the model number is 80 #; polyvinyl alcohol was purchased from Shandong Liang New Material science and technology Co., Ltd under the designation 1788; polyethylene was purchased from plastic big plastics materials Co., Ltd, Dongguan city, under the brand name FN 50100; cassava starch procurement, Henan Xuanfeng Biotech Co., Ltd., cat number 03.

Comparative example

Comparative example 1: the preparation method of the polyester yarn is different from the preparation method of the polyester yarn in example 1 in that: steps S4 and S5 are not performed.

Comparative example 2: the preparation method of the polyester yarn is different from the preparation method of the polyester yarn in example 1 in that: in step S4, a hydrophobic layer is sprayed only on the outer surface of the filament.

Characterization test:

1. test for hydrophobic Effect

Test subjects: the polyester yarns obtained in accordance with examples 1 to 19 and comparative examples 1 to 2 were woven in a plain weave on a textile machine (TOYN Utility Co., Ltd., Dongguan) to obtain fabrics designated as examples 1 to 19 and comparative examples 1 to 2, for a total of 21 test samples.

The test method comprises the following steps: contact angle measurement of water was performed using a contact angle measuring instrument (JC 2000D).

Initial contact angle: cutting 5 × 5cm of cloth on a test sample for testing, drawing a 1 × 1cm test area at the center of the cloth, placing the cloth on a sample platform, aligning the test area with a sample injector, and dripping 50ul of water drops onto the surface of the cloth by the sample injector; and (4) carrying out the main interface of the angulometry according to the angulometry button, measuring contact angles of the left side and the right side of the liquid drop, and calculating an average value.

Contact angle after treatment: placing the cloth in a constant temperature and humidity box, and placing for 24 hours at 25 ℃ in an environment with the humidity of 85%; and then placing the mixture into a drying box, drying the mixture for 10min at the temperature of 35 ℃, and taking out the mixture to perform a contact angle test (the same as the initial contact angle test method). The difference between the post-treatment contact angle and the initial contact angle was calculated and recorded.

And (3) test results: the hydrophobic effect test results are reported in table 1.

Table 1 hydrophobic effect test results records

And (3) data analysis: the larger the contact angle, the better the hydrophobicity; the smaller the difference between before and after the treatment, the better the stability and the durability of the water repellent effect. As can be seen from the data in Table 1, the hydrophobic effects are, in order from good to poor, examples 10 to 19, examples 4 to 9, examples 1 to 3, comparative examples 2 and comparative example 1; comparative sample 1 had a contact angle of less than 90 deg., and was not hydrophobic. The stability and the persistence of the hydrophobic effect were, in order from good to poor, examples 18 to 19, examples 15 to 17, examples 13 to 14, examples 7 to 12, examples 4 to 6, examples 1 to 3, and comparative example 2.

For differences in hydrophobicity.

Compared with the comparative sample 1, the embodiment sample 1 has the advantages that the adhesive layer and the hydrophobic layer are added, and the effect of greatly improving the hydrophobicity is achieved. The adhesive layer adopts a polyvinyl alcohol aqueous solution, so that on one hand, the polyvinyl alcohol can be dissolved at 90-120 ℃, and the energy consumption and the high-temperature contact with the polyester protofilament are reduced; on the other hand, when the adhesive layer is sprayed, the temperature outside the polyester protofilament is higher, water can be evaporated, and the polyvinyl alcohol is transferred to the surface of the protofilament by taking the water as a carrier; the polyvinyl alcohol has adhesiveness in a molten state, so that the connection between the precursor and the hydrophobic layer is realized. After being melted, the microcrystalline paraffin is attached to the surfaces of the bonding layer and the protofilament to form a hydrophobic layer, and the hydrophobic layer plays a role in hydrophobicity.

Examples 4-6 increased the use of polyethylene over example 2, and the hydrophobic effect was improved to a small extent. The reasons may be: the polyethylene has small moisture absorption degree and good ductility while playing a role in bonding, and covers the microcrystalline paraffin for the covered place, and meanwhile, the hydrophobic layer forms a more complete whole, so that the hydrophobic effect is improved.

Examples 10 to 12, in addition to example 8, the temperature of the filaments before the adhesive layer was sprayed was limited, and the hydrophobicity was further increased by a small amount. The reasons may be: controlling the temperature of the protofilament, evaporating water when the bonding layer is sprayed, reducing the water content, improving the adhesion when the polyvinyl alcohol is attached to the outer surface of the protofilament, and preparing for spraying a hydrophobic layer; thereby improving the adhesion rate of the hydrophobic layer and improving the hydrophobic effect.

Stabilizing the difference in persistence against the hydrophobic effect.

Compared with the comparative sample 1, the embodiment sample 1 adopts more adhesive layers, so that the stability and the continuity of the hydrophobic effect are greatly improved; the bonding effect of the protofilament and the hydrophobic layer is realized, the internal and external connection strength is improved, and the integrity of the super-hydrophobic polyester yarn is improved.

In examples 4 to 6, the use of polyethylene in the hydrophobic layer is added on the basis of example 2, so that the stability and the persistence of the hydrophobic effect are further improved. The reasons may be: polyethylene is a high polymer, the melting temperature is 85-110 ℃, microcrystalline paraffin is in a melting state at the temperature, and a hydrophobic layer is obtained after uniform mixing; because the polyethylene has small hygroscopicity and proper melting temperature, on one hand, the polyethylene can be used as one of hydrophobic materials of the hydrophobic layer; on the other hand, polyethylene, polyvinyl alcohol and PET are all high polymers, have similar characteristics, have better bonding and connection effects to improve the connectivity of the hydrophobic layer on the polyester protofilament, improve the wear resistance, thereby improve hydrophobic stability.

Examples 7 to 9 in addition to example 5, the amount of polyvinyl alcohol used was limited, and the amount of polyvinyl alcohol adhering to the surface of the strands was adjusted to improve the stability and durability of the hydrophobic effect while ensuring the hydrophobicity. The polyvinyl alcohol has certain hygroscopicity, so that the polyvinyl alcohol serving as an adhesive layer cannot be directly exposed to the outside and contacted with external moisture; otherwise it could easily lead to the destruction of the adhesive layer and thus to an overall hydrophobic property. Limiting the attachment amount of polyvinyl alcohol, wherein the polyvinyl alcohol does not need to completely cover the surface of the protofilament; the polyvinyl alcohol forms a plurality of approximately uniform bonding points on the surface of the protofilament, the hydrophobic layer is fixed, and the polyvinyl alcohol is bonded with the hydrophobic layer material; on the other hand, part of the hydrophobic layer is directly connected with the protofilament.

In examples 13 to 14, the use of modified starch in the spinning raw material was increased on the basis of example 11, and in examples 15 to 17, the compounding amount of PET and modified starch was limited on the basis of example 13, and the stability and the durability of the hydrophobic effect were further improved. As one part of the raw materials, the modified starch has hydrophobicity, so that the polyester protofilament has hydrophobicity; on the other hand, the starch contains a large amount of hydroxyl groups, and hydrogen bonds can be generated between the starch and polyvinyl alcohol in the bonding layer, so that the connectivity between the bonding layer and the protofilaments is improved, the integrity of the super-hydrophobic polyester yarns is improved, and the stability and the continuity of the hydrophobic effect are improved.

Examples 18 to 19 define the cooling temperature of step S5 on the basis of example 16, and the small amplitude improves the stability and durability of the hydrophobic effect; indicating that the temperature process is more suitable for use with this protocol.

The present embodiment is only for explaining the present application, and it is not limited to the present application, and those skilled in the art can make modifications of the present embodiment without inventive contribution as needed after reading the present specification, but all of them are protected by patent law within the scope of the claims of the present application.