阅读说明：本技术 滑动轴承元件 (Plain bearing element ) 是由 京特·比尔克勒 维尔纳·舒伯特 于 2018-11-20 设计创作，主要内容包括：本发明涉及一种滑动轴承元件(2),特别是用于内燃机中的曲轴或连杆的轴承,其具有：特别是由钢组成的金属支撑层(4)；由无铅的、包括镁和锰的铝基合金组成的轴承金属层(6)；和摩擦层(8),其中,铝基合金包含：0.5-6.0重量％的镁；0.05-2重量％的锰；必要时以下合金成分中的一种或多种：锌、硅、铜、铁、铬、钛、锆、钒、镍、钴,铈和杂质相关的合金成分,其中,杂质相关的合金成分的总含量不超过1重量％；以及剩余铝,并且其中,锌、铜和镍的总含量不超过8重量％,所有合金成分的总含量不超过12重量％。本发明提出,通过在涂覆摩擦层(8)之前对轴承金属层(6)的上侧(12)进行机械喷砂,在轴承金属层(6)中产生厚度为0.5-5μm的富含氧化铝的表面区域(14),并随后将摩擦层(8)涂覆到轴承金属层(6)的喷砂后的表面(12)上,摩擦层(8)是具有聚合物粘合剂的滑动漆层(10)。(The invention relates to a plain bearing element (2), in particular a bearing for a crankshaft or a connecting rod in an internal combustion engine, comprising: a metallic support layer (4), in particular consisting of steel; a bearing metal layer (6) consisting of a lead-free, aluminium-based alloy comprising magnesium and manganese; and a friction layer (8), wherein the aluminum-based alloy comprises: 0.5-6.0 wt.% magnesium; 0.05-2 wt% manganese; if necessary, one or more of the following alloy components: zinc, silicon, copper, iron, chromium, titanium, zirconium, vanadium, nickel, cobalt, cerium and impurity-related alloy constituents, wherein the total impurity-related alloy constituent content does not exceed 1 wt.%; and residual aluminum, and wherein the total content of zinc, copper and nickel does not exceed 8 wt.%, and the total content of all alloying constituents does not exceed 12 wt.%. The invention proposes that an aluminum oxide-rich surface region (14) with a thickness of 0.5 to 5 [ mu ] m is produced in the bearing metal layer (6) by mechanically blasting the upper side (12) of the bearing metal layer (6) before applying the friction layer (8), the friction layer (8) being a sliding paint layer (10) with a polymer binder, and subsequently applying the friction layer (8) to the blasted surface (12) of the bearing metal layer (6).)

1. A plain bearing element (2), in particular a radial plain bearing element or a thrust plate, in particular a bearing for a crankshaft or a connecting rod in an internal combustion engine, the plain bearing element (2) having: a metallic support layer (4), in particular consisting of steel; a bearing metal layer (6) consisting of a lead-free, aluminium-based alloy comprising magnesium and manganese; and a friction layer (8),

wherein the aluminum-based alloy comprises: 0.5-6.0 wt.% magnesium; 0.05-2 wt% manganese; optionally one or more of the following alloy constituents: 0.5-7.5 wt.% zinc, 0.5-6 wt.% silicon, up to 5 wt.% copper, 0.05-0.5 wt.% iron, 0.05-1 wt.% chromium, 0.05-0.5 wt.% titanium, 0.05-0.5 wt.% zirconium, 0.05-0.5 wt.% vanadium, 0.1-3 wt.% nickel, 0.1-1 wt.% cobalt, 0.05-0.5 wt.% cerium, impurity related alloy components, wherein the total content of said impurity related alloy components does not exceed 1 wt.%; and residual aluminum, and wherein the total content of zinc, copper and nickel does not exceed 8 wt.%, and the total content of all alloy constituents does not exceed 12 wt.%,

characterized in that an alumina-rich surface region (14) having a thickness of 0.5 to 5 [ mu ] m is produced in the bearing metal layer (6) by mechanically blasting the upper side (12) of the bearing metal layer (6) before applying the friction layer (8), and the friction layer (8) is subsequently applied to the blasted surface (12) of the bearing metal layer (6), the friction layer (8) being a sliding paint layer (10) with a polymer binder.

2. A plain bearing element according to claim 1, characterized in that the polymer binder of the sliding paint layer is PAI, PI or epoxy.

3. A plain bearing element according to claim 1 or 2, characterized in that the upper side (12) of the bearing metal layer (6) of metal is blasted before the friction layer (8) is applied in such a way that it has a so-called falling valley height S of 0.5-1.5 μm_VKAnd 0.06-0.16 μm³/μm²So-called valley volume V_VV(S_VK、V_VVDetermined according to DIN EN ISO 25178, part 2 of 2012; v_VVDetermined under the condition that the material ratio p is 80%).

4. A plain bearing element (2) according to claim 3, characterized in that the blasted upper side (12) of the metallic bearing metal layer (6) has a so-called falling valley height S_VKIs at least 0.7 μm, in particularAt least 0.9 μm and at most 1.5 μm, in particular at most 1.4 μm, in particular at most 1.3 μm, and a so-called valley volume V_VVIs at least 0.08 μm³/μm²In particular at least 0.09 μm³/μm²And up to 0.16 μm³/μm²In particular up to 0.15 μm³/μm²In particular up to 0.14 μm³/μm²。

5. A plain bearing element according to any one or more of the preceding claims, characterized in that the aluminium-based alloy contains no copper or at most 0.5-5 wt.% copper.

6. A plain bearing element according to any one or more of the preceding claims, characterised in that the aluminium-based alloy contains 3-5.5 wt.% magnesium.

7. A sliding bearing element according to any one or more of the preceding claims, characterised in that the aluminium-based alloy contains 0.2-1.0 wt.% manganese.

8. The plain bearing element (2) according to one or more of the preceding claims, characterized in that the layer thickness of the friction layer (8) is 2-25 μm, in particular 4-20 μm.

9. An intermediate product in the manufacture of a sliding bearing element according to the preamble of claim 1, characterized in that the friction layer (8) is applied to the intermediate product thus obtained in a subsequent method step by mechanically blasting the upper side (12) of the bearing metal layer (6) before applying the friction layer (8) to produce an alumina-rich surface region (14) of a thickness of 0.5-5 μm in the bearing metal layer (6) before applying the friction layer (8) to the bearing metal layer (6).

10. Intermediate product according to claim 9, characterized in that it is prepared in such a way thatThe upper side (12) of the bearing metal layer (6) of the metal of the intermediate product is blasted, i.e. has a so-called falling valley height S of 0.5-1.5 μm_VKAnd 0.06-0.16 μm³/μm²So-called valley volume V_VVWherein the intermediate product has been formed into the shape of the plain bearing element (2) to be manufactured.

11. A method for manufacturing a sliding bearing element according to one or more of claims 1 to 8, characterized in that a composite consisting of a metal support layer (4) and a bearing metal layer (6) is formed into the shape of the sliding bearing element (2) to be manufactured, whereafter the upper side (12) of the metallic bearing metal layer (6) is sandblasted before the application of the friction layer (8) so as to produce an alumina-rich surface region (14) with a thickness of 0.5-5 μm in the bearing metal layer (6), and that a layer (10) of a sliding paint with a polymer binder as the friction layer (8) is applied onto the sandblasted upper side (12) of the bearing metal layer (6).

12. Method according to claim 11, characterized in that a so-called falling valley height S of 0.5-1.5 μm is produced by sand blasting_VKAnd 0.06-0.16 μm³/μm²So-called valley volume V_VV。

13. Method according to claim 11 or 12, characterized in that the sliding paint layer (10) is sprayed, rolled or extruded onto the treated upper side of the bearing metal layer.

14. The method according to one or more of claims 11-13, characterized in that the bearing metal layer (6) is blasted with a blasting pressure of 1.0-1.5 bar.

15. The method according to any one or more of claims 11 to 14, wherein the maximum dimension of the cross-section of the blasting nozzle at the outlet is 10 to 14mm, in particular 11 to 13mm, in particular 12 mm.

16. The method as claimed in any one or more of claims 11 to 15, characterized in that the distance of the outlet of the blasting nozzle (16) from the upper side (12) of the bearing metal layer (6) of the plain bearing element to be blasted is 80-120mm, in particular 90-110mm, in particular 100 mm.

17. A method according to one or more of claims 11-16, characterised in that one, two or three blasting devices with corresponding blasting nozzles (16) are used, which blasting devices are arranged one after the other in the circumferential direction of the plain bearing element.

18. The method according to any one or more of claims 11 to 17, characterized in that the feed speed of the blasting nozzle (16) in the axial direction of the plain bearing element is 5 to 60mm/s, in particular 10 to 50 mm/s.

19. Method according to one or more of claims 11-18, characterized in that the bearing metal layer (6) is blasted with a grit, in particular diamond, having a particle size of at most 100 μm, wherein at least 60 mass-% of the grit has a particle size of at least 45 μm.

Technical Field

The invention relates to a plain bearing element, in particular a radial plain bearing element or a thrust plate, in particular a bearing for a crankshaft or a connecting rod in an internal combustion engine, having: a metallic support layer, in particular consisting of steel; a bearing metal layer comprised of a lead-free, aluminum-based alloy containing magnesium and manganese; and a friction layer, wherein the aluminum-based alloy preferably contains: 0.5-6.0 wt.% magnesium; 0.05-2 wt% manganese; optionally, one or more of the following alloy compositions: 0.5-7.5 wt.% zinc, 0.5-6 wt.% silicon, up to 5 wt.% copper, 0.05-0.5 wt.% iron, 0.05-1 wt.% chromium, 0.05-0.5 wt.% titanium, 0.05-0.5 wt.% zirconium, 0.05-0.5 wt.% vanadium, 0.1-3 wt.% nickel, 0.1-1 wt.% cobalt, 0.05-0.5 wt.% cerium and impurity related alloy constituents, wherein the total content of impurity related alloy constituents does not exceed 1 wt.%; and residual aluminum, and wherein the total content of zinc, copper and nickel does not exceed 8 wt.%, and the total content of all alloy constituents does not exceed 12 wt.%,

background

Such plain bearing elements are known from EP 2985358B 1. By heat-treating the composite consisting of the support layer and the bearing metal layer at a temperature between 280 ℃ and 350 ℃ for 2 to 10 hours, a brinell hardness of 50 to 80HB 1/5/30 can be achieved in the bearing metal layer. The friction layer, which is in contact with the sliding partner, interacts with the friction layer, so that a plain bearing element is obtained which has proven to have a very high load capacity and also a fatigue resistance and a wear resistance and is therefore suitable for internal combustion engine-related applications in modern motor vehicle technology. A plating layer or a sputtered layer may be used as the friction layer.

Disclosure of Invention

The object of the invention is to provide a plain bearing element, in particular a bearing for crankshafts and connecting rods in internal combustion engines, which is also capable of high load capacity and which can be produced in a more economical manner than the known plain bearing elements.

In a plain bearing element of the above-mentioned type, this object is achieved according to the invention in that an aluminum oxide-rich surface region with a thickness of 0.5 to 5 μm is produced in the bearing metal layer by mechanical blasting of the upper side of the bearing metal layer before the application of a friction layer, which is a sliding paint layer with a polymer binder, and subsequently the blasted surface of the bearing metal layer is coated with the friction layer.

By blasting the upper side of the bearing metal layer according to the invention, a certain surface roughness can be achieved in a sliding layer of moderate hardness made of an aluminum-based alloy, which essentially achieves the application and adequate adhesion of a polymer-based sliding paint layer (Verklammerung). In the case of softer tin-containing aluminum alloys, the sliding paint layer was applied earlier as a friction layer, but only moderate loads could be exposed in these tin-containing aluminum alloys. In the case of the high-load-bearing plain bearing with the bearing metal layer of the claimed composition discussed here, it is assumed that it is possible to work only with an electroplated friction layer or sputtered layer. Mechanical blasting of the upper side of the bearing metal layer not only produces roughness and surface topography of the three-dimensional structure, but also the metallic aluminum of the aluminum-based alloy exposed during blasting is directly converted to an aluminum oxide coating of only a few nanometers in thickness by contact with oxygen. The alumina is then machined into the crevice surfaces of the bearing metal layer by grit blasting to form an alumina-rich surface region relative to the deeper regions of the bearing metal layer. Since the aluminum oxide particles are very wear-resistant, the bearing metal layer in this surface region is particularly wear-resistant, which has proven to be advantageous in the case of peeling-off of a relatively thin sliding paint layer. In the tribologically effective region facing the friction counterpart, the plain bearing element has a high wear resistance as a result of the sandblasting and the coating with a sliding paint layer, but nevertheless has good tribological properties, since the polymer-based sliding paint is accommodated by the valleys and depressions of the roughness formed on the upper side of the bearing metal layer.

It has also proven advantageous if the polymer binder of the sliding paint layer is PAI, PI or epoxy. In addition, it has also proven advantageous for the sliding paint layer to comprise a solid lubricant, preferably graphite, a metal sulfide (e.g. MoS), which is accommodated in the form of a matrix by a polymer binder₂、WS₂) Or hexagonal boron nitride.

Although in the above mentioned EP 2985358B 1 the applicant considers manganese as an alternative alloying element, it is recognized in the present application that manganese proves advantageous because it can increase the tensile strength and yield strength and improve the corrosion resistance.

In addition, it has also proven advantageous to sand-blast the upper side of the metallic bearing metal layer before the application of the friction layer in such a way that it has a so-called falling valley height S of 0.5 to 1.5 μm_VK(reduzierte Talh6heS_VK) And 0.06-0.16 μm³/μm²So-called valley volume V_VV(leeres Volumen derV_VV)(S_VK、V_VVDetermined according to DIN EN ISO 25178, part 2 of 2012; v_VVDetermined under the condition that the material ratio p is 80%).

In particular, it has also been found that during the transition from static friction to sliding friction at engine start-up, considerable shear forces are generated in the contact area between the shaft and the friction layer. In vehicles equipped with Start-stop operation (Start-stop-Betrieb), this has a crucial role due to the higher frequency of the Start-up. In this mode of operation, the wear resistance of the friction layer is not only dependent on its material and layer parameters, but also, in terms of wear resistance, the engagement of the friction layer with the bearing metal layer is very important for absorbing shear forces. It has now been further determined that these two parameters (i.e. the falling valley height and the valley volume) are the necessary upper side or surface parameters in order to achieve a proven advantageous adhesion of the friction layer on the upper side of the bearing metal layer according to DIN EN ISO 25178 part 2 of 2012. It has been found that an increase in the valleys (i.e. an increase in their depth and in the volume that can be filled) can lead to an increase and improvement in wear resistance. Furthermore, in this respect it was established that the problem of increased roughness or increased functional roughening, which is the case with increasing two parameters, usually occurs in the form of a reduction in the occlusion load (freslast). The increase in roughness leads to a reduction in the compliance and prevents good hydrodynamic development, since the applied friction layer simulates the roughness of the bearing metal layer relatively well, i.e. it is maintained and largely uncompensated. However, in the bite test (Fresstest), this leads to an increase in the proportion of mixed friction and consequently to an increase in the frictional heat, which cannot be dissipated sufficiently quickly due to increased roughness and poor fluid dynamics. This conflict of goals is recognized by the invention and a functional upper-side design of the bearing metal layer has proven to be advantageous, which allows good adhesion of the friction layer to the bearing metal layer and, due to the blasting, forms an alumina-rich surface region, which improves the wear resistance and thus proves to be advantageous in start-stop operation. At each start, it further causes a transition from static friction to sliding friction and thus the described emergency situation. However, these emergencies can be alleviated by better adhesion of the friction layer to the bearing metal layer and an increase in the wear resistance of the upper side of the bearing metal layer.

It has been recognized that the falling valley height S_VKAnd the volume of the valley V_VVIs representative of a functional roughness parameter, which also allowsConclusions are drawn about the lubricating properties of the upper side topography. An increase in these functional roughness parameters therefore means, on the one hand, a better adhesion of the friction layer and an improvement in the wear resistance and, on the other hand, a reduction in the adaptability to the problems that follow. Based on this knowledge, the parameter ranges for which these parameters are claimed are determined.

Fig. 3 and 4 show the falling valley height S_VKAnd the volume of the valley V_VVThe parameter (c) of (c). Falling valley height S_VKRefers to the average height of the valleys protruding below the so-called core on the upper side.

As shown in fig. 3, the falling valley height S_VKIs defined according to the second section of DINENISO 25178. To this end, the core or core height Sk of the topography is first determined by means of a secant on the curve, which secant represents the flat material proportion X of the surface as a function of the height or thickness Y, as follows: starting from the maximum thickness or height Y (i.e. corresponding to a material proportion X of zero), a secant 1 is marked, from which to a corresponding value on the curve (corresponding to the curve being equal to) where the material proportion X is 40%. This secant crossing 40% of the material proportion then moves towards a higher material proportion until its slope/gradient takes a minimum, and then becomes steeper again with further movement. This position of the cutting line is indicated by reference numeral 2 in fig. 3. In this position, the secant 2 extends to a straight line 3. The intersection with the Y coordinate axis indicates the core or core height Sk of the topography when X is 0% and X is 100%. In this present case, the falling valley height S_VKRefers to the height or depth of the protrusion below the core or the height or depth of the downwardly extending valleys. Part 2 of code No. 5.3, S according to DIN EN ISO 25178 of 2012_VKDetermined as the height S of the right triangle A2_VKThe right triangle a2 is configured such that it has the same area as the "valley region", i.e., the total area of the valleys under the core in fig. 3. Thus, the triangle A2 has a value (100% -Smr2) as the base length and S_VKAs the height.

In fig. 4 the valley volume V is shown_VVI.e. as the shown region V_VVOf (a) of total area ratio ofThe material proportion of 80% X has the meaning of part 2 based on the standard DIN EN ISO 25178. Here, the material proportion of 80% refers to a position orthogonal to the upper side in the thickness direction, which corresponds to the Y coordinate direction in fig. 3, 4, and if a plane or a cross section is taken into consideration in the Y value or the Y coordinate in the thickness direction, the projected area of the valley (equivalent to no material) is 20%, and the material proportion is 80%. V according to the provisions in section 2 of the 2012 Standard DIN EN ISO 25178_VVThe void volume of the valley is now the material free volume (based on area units) below this level or cross section.

It has also proven to be advantageous if, in the finished plain bearing element, the sliding paint layer can be separated again using a suitable solvent, so that, after separation, the upper side of the subsequently developed structured sandblasted bearing metal layer can be detected and evaluated using the relevant measuring method (generally optical methods).

It has also proven advantageous if the blasted upper side of the metallic bearing metal layer has a so-called falling valley height S_VKAt least 0.7 μm, in particular at least 0.9 μm and at most 1.5 μm, in particular at most 1.4 μm, in particular at most 1.3 μm, and a so-called valley volume V_VVIs at least 0.08 μm³/μm²In particular at least 0.09 μm³/μm²And up to 0.16 μm³/μm²In particular up to 0.15 μm³/μm²In particular up to 0.14 μm³/μm²。

It is also proposed that the aluminium-based alloy contains no copper or 0.5-5 wt.%, in particular 0.5-3 wt.%, copper.

It is also proposed that the aluminium-based alloy contains 3-5.5 wt.% magnesium.

It is also proposed that the aluminium-based alloy contains 0.2-1.0 wt.% manganese.

Preferably, the aluminum-based alloy consists of the alloy composition of claim 1.

The sliding paint layer is sprayed, rolled or extruded onto the treated upper side of the bearing metal layer.

The invention also provides that the layer thickness of the friction layer is 2 to 25 μm, in particular 4 to 20 μm.

The invention also claims an intermediate product having the features of claims 9 and 10 and a method for producing a plain bearing element or an intermediate product having the features of claims 11 to 19.

In this case, it has also proven advantageous to sand-blast the bearing metal layer with a blasting pressure of 1.0 to 1.5 bar. It is not the pressure exerted by the blasting particles on the impact surface, but the pressure at which the blasting nozzle comes out of the interior of the blasting apparatus.

It has also proven advantageous if the maximum dimension of the cross-section of the blasting nozzle at the outlet is 10 to 14mm, in particular 11 to 13mm, in particular 12 mm.

It has also proven advantageous if the outlet of the blasting nozzle is at a distance of 80 to 120mm, in particular 90 to 110mm, in particular 100mm, from the upper side of the bearing metal layer of the plain bearing element to be blasted.

It has also proven advantageous to use one, two or three blasting devices with corresponding blasting nozzles, which are arranged one behind the other in the circumferential direction of the plain bearing element.

The feed speed of the blasting nozzle is 5mm/s to 60mm/s, in particular 10mm/s to 50mm/s, wherein the feed speed is oriented in the axial direction (i.e. in the direction of the width of the bearing element) during the blasting of the radial plain bearing element, in particular the plain bearing shell.

Finally, it has also proven advantageous to use a shot with a particle size of up to 100 μm, in particular diamond (Al)₂O₃) Blasting the bearing metal layer, wherein at least 60 mass% of the blasting has a particle size of at least 45 μm. In this case, no reject was obtained when sieving with a sieve having a mesh size of 100 μm, whereas at least 60% by weight of reject was obtained when sieving with a sieve having a mesh size of 45 μm. In addition, it has proven advantageous if the spray material has a mohs hardness of at least 8, in particular 9. It preferably comprises angular particle shapes rather than spherical or agglomerate round particle shapes. Suitable spray materials are available from Kuhmichel under the trade name Edelkorund EKF 220.

Drawings

Further details, features and advantages of the invention can be taken from the following description and the accompanying drawings of embodiments of the invention and the appended claims. Wherein:

FIG. 1 is a schematic view of a radial bearing shell according to the present invention;

FIG. 2 is a schematic view of an exemplary arrangement of grit blasting nozzles during manufacture of a radial bearing shell according to the present invention;

FIG. 3 is a schematic illustration of the upper side topography of a bearing metal layer after grit blasting to clarify and determine the falling valley height S_VK；

FIG. 4 is a schematic representation of the upper side topography of a bearing metal layer blasted according to the invention to illustrate the valley volume V at a material proportion of 80%_VV。

Detailed Description

Fig. 1 shows a plain bearing element 2 according to the invention in the form of a schematically illustrated radial bearing shell for a bearing of a crankshaft in an internal combustion engine. In the case of the example, a radial bearing housing, which is not illustrated to scale, for example comprises: a metallic carrier layer 4 made of steel, a bearing metal layer 6 (based on an aluminum-magnesium-manganese base of the type mentioned at the outset) applied thereon, and a friction layer 8 applied thereon, wherein the friction layer is a sliding paint layer 10 based on a polymer binder with fillers.

The Al-Mg-Mn alloy forming the bearing metal layer 6 may be plated on an intermediate layer, wherein the intermediate layer is previously coated on the support layer 4 and consists of pure aluminum or an aluminum alloy or nickel; preferably, however, the Al-Mg-Mn alloy is plated directly onto the support layer consisting of steel.

Then, the composite composed of the support layer 4 and the bearing metal layer 6 is preferably heat-treated at a temperature of between 280 ℃ and 350 ℃ for 2 to 10 hours. In this process, the bearing metal layer 6 can reach a brinell hardness of 50 to 80HB 1/5/30, which has proven to be advantageous for later use.

Subsequently, the composite consisting of the support layer 4 and the bearing metal layer 6 is changed into the shape of the plain bearing element 2 to be produced, in particular during bending.

Before the application of the friction layer 8 to the upper side 12 of the bearing metal layer 6 facing the sliding partner, i.e. away from the carrier layer 4, this upper side 12 is grit-blasted in the manner according to the invention, so that an alumina-rich surface region 14 is produced as described at the outset (see fig. 1).

Preferably, the surface topography is produced by sandblasting, which has a so-called falling valley height S of 0.5 to 1.5 μm_VKOr 0.06-0.16 μm³/μm²So-called valley volume V_VV(S_VKAnd V_VVDetermined according to DIN EN ISO 25178, part 2 of 2012; v_VVDetermined under the condition that the material ratio p is 80%). The surface topography of the bearing metal layer 6 produced by the blasting process is not shown in fig. 1, since it is a microstructure. Subsequently, a friction layer 8 is applied to the surface 14 of the bearing metal layer 6 thus treated.

Fig. 2 also shows schematically a preferred arrangement of the blasting nozzles 16 during the blasting of the upper side 12 of the bearing metal layer 6 of the radial bearing housing. In the case shown, the blasting nozzle 16 is fed in the axial direction of the radial bearing shell (i.e. perpendicular to the surface in the figure).

In the context of the present invention, the composition of the sandblasted bearing metal layer 6 and the support layer 4 forms an intermediate product according to the invention in the course of the manufacture of the plain bearing element 2.

Finally, the sliding paint layer 10 is sprayed, rolled or extruded.