阅读说明：本技术 一种含有活性云母的组合物及其生物发酵制备方法 (Composition containing active mica and biological fermentation preparation method thereof ) 是由 王希峰 金东喆 于 2019-09-25 设计创作，主要内容包括：本发明涉及硅酸盐类矿物利用及生物工程,具体涉及一种含有活性云母的组合物及其生物发酵制备方法。一种含有活性云母的组合物,按重量份计,其制备原料包括：2～6份硅酸盐类矿物、3～8份溶剂、0.5～2份梅果。本发明利用生物发酵制备得到的含有活性云母的组合物不含多种有害成分,富含有效活性组分,能够降解谷物、果蔬中农药和化肥的残留物,降解生活用品中的有毒有害物质,用于制药时可利用其中的有机锗来治疗癌症等多种疾病。此外,还能得到具有多种作用的古曼石,可用作防锈漆的颜料,用于制造耐火材料、石英玻璃、光导纤维、电子工业的重要部件等,用于制备防晒品,对人体无害,用作消毒剂,去除有害物质,用作空气净化剂,保护环境。(The invention relates to utilization of silicate minerals and bioengineering, in particular to a composition containing active mica and a biological fermentation preparation method thereof. The composition containing the active mica comprises the following preparation raw materials in parts by weight: 2-6 parts of silicate minerals, 3-8 parts of solvents and 0.5-2 parts of plum fruits. The composition containing the active mica prepared by biological fermentation does not contain various harmful components, is rich in effective active components, can degrade residues of pesticides and fertilizers in grains, fruits and vegetables and toxic and harmful substances in living goods, and can be used for treating various diseases such as cancers by using organic germanium in the composition during pharmacy. In addition, it can also obtain the Guman stone with various functions, can be used as the pigment of antirust paint, can be used for manufacturing refractory materials, quartz glass, optical fibers, important parts of electronic industry and the like, can be used for preparing sun-screening products, is harmless to human bodies, can be used as a disinfectant, can remove harmful substances, can be used as an air purifying agent, and can protect the environment.)

1. The composition containing the active mica is characterized by comprising the following preparation raw materials in parts by weight: 2-6 parts of silicate minerals, 3-8 parts of solvents and 0.5-2 parts of plum fruits;

the solvent is at least one selected from water, alcohol solvents and ether solvents.

2. The composition of claim 1, wherein said silicate mineral is selected from at least one of granite, perlite, mullite, metamorphic rock, and basalt.

3. The composition according to claim 1, wherein said alcoholic solvent is at least one selected from the group consisting of methanol, ethanol, n-propanol, n-butanol, isoamyl alcohol, ethyl hexanol, ethylene glycol and propylene glycol.

4. The composition containing activated mica according to claim 1, wherein said ether solvent is at least one selected from the group consisting of methyl ether, ethyl ether, propyl ether, isopropyl ether, butyl ether, amyl ether, isoamyl ether, hexyl ether, ethyl butyl ether, methyl t-butyl ether, ethyl vinyl ether, and butyl vinyl ether.

5. The composition of claim 1, wherein said plum is at least one selected from the group consisting of ume, and prune.

6. The composition containing active mica according to claim 1, wherein the weight ratio of the silicate mineral, the solvent and the plum is (3-5): (4-6): 1.

7. a process for the biological fermentative preparation of a composition comprising active mica according to any one of claims 1 to 6, comprising at least the following steps:

(1) crushing and cleaning silicate minerals; removing cores from mume fructus;

(2) adding silicate minerals, a solvent and plum fruits into a fermentation tank, mixing and fermenting for 130-150 days in total to obtain a mixture;

(3) and filtering the mixture to obtain filtrate, namely the composition containing the active mica.

8. The process according to claim 7, wherein the silicate mineral has a particle size of 0.5 to 0.8cm after being pulverized.

9. The process for the biofermentation preparation of a composition containing active mica according to claim 7, wherein the fermentation temperature is 1 to 100 ℃.

10. The process according to claim 7, wherein the mixing is a circulating pump type, and the time interval of the circulation is 7-9 h.

Technical Field

The invention relates to the technical field of silicate mineral utilization and bioengineering, in particular to a composition containing active mica and a biological fermentation preparation method thereof.

Background

Silicate minerals are important non-metallic mineral resources, are also main components of various soils and sediments, are widely distributed, diversified and abundant in nature, and have wide application in many production practice fields. Magnesium in silicate minerals can be used for preparing magnesium-containing compounds such as magnesium carbonate, magnesium oxide, magnesium silicate and the like, and iron in the magnesium-containing compounds can be used for preparing iron-containing compounds such as ferrous oxalate, high-purity iron oxide, iron-based industrial pigments and the like. Magnesium carbonate, magnesium oxide, magnesium silicate, ferrous oxalate and high-purity ferric oxide have high additional value, but have limited market demand and are not suitable for large-scale production; although the iron-based industrial pigment has certain market demand, a large amount of waste water is generated in the preparation process, and the environment is easily polluted.

Biological fermentation is the foundation of bioengineering, modern biotechnology and industrialization, and with the progress of bioengineering technology, the production scale of fermentation industry is continuously enlarged, and the utilization rate of silicate minerals can be improved by using the biological fermentation technology. However, the biological fermentation mechanism is very complex, and the process is difficult to control, so that the product often contains harmful components, and effective active components cannot be obtained, and the expected effect cannot be achieved.

Disclosure of Invention

In order to solve the above problems, the first aspect of the present invention provides a composition containing active mica, which is prepared from the following raw materials in parts by weight: 2-6 parts of silicate minerals, 3-8 parts of solvents and 0.5-2 parts of plum fruits;

the solvent is at least one selected from water, alcohol solvents and ether solvents.

In a preferred embodiment of the present invention, the silicate mineral is at least one selected from granite, perlite, mullite, metamorphic rock, and basalt.

In a preferred embodiment of the present invention, the alcohol solvent is at least one selected from methanol, ethanol, n-propanol, n-butanol, isoamyl alcohol, ethylhexanol, ethylene glycol, and propylene glycol.

In a preferred embodiment of the present invention, the ether solvent is at least one selected from the group consisting of methyl ether, ethyl ether, propyl ether, isopropyl ether, butyl ether, pentyl ether, isopentyl ether, hexyl ether, ethylbutyl ether, methyl tert-butyl ether, ethyl vinyl ether, and butyl vinyl ether.

In a preferred embodiment of the present invention, the plum is at least one selected from the group consisting of green plum, dark plum and prune.

According to a preferable technical scheme of the invention, the weight ratio of the silicate mineral, the solvent and the plum is (3-5): (4-6): 1.

in a second aspect, the invention provides a process for the biological fermentative preparation of a composition comprising activated mica, comprising at least the following steps:

(1) crushing and cleaning silicate minerals; removing cores from mume fructus;

(2) adding silicate minerals, a solvent and plum fruits into a fermentation tank, mixing and fermenting for 130-150 days in total to obtain a mixture;

(3) and filtering the mixture to obtain filtrate, namely the composition containing the active mica.

In a preferred embodiment of the present invention, the silicate mineral has a particle size of 0.5 to 0.8cm after being pulverized.

As a preferable technical scheme, the fermentation temperature is 1-100 ℃.

As a preferable technical scheme of the invention, the mixing mode is a circulating pump type, and the time interval of one circulation is 7-9 h.

Has the advantages that: according to the invention, the composition containing the active mica is prepared by biological fermentation, and by adopting special components and processes, on one hand, the capability of the biological fermentation process is improved, so that the original functions and effects of silicate minerals and mica monomers are greatly improved; on the other hand, the composition does not contain various harmful components, is rich in effective active components, can degrade organic pollutants, red algae (green algae), replace hormones and antibiotics, degrade residues of pesticides and fertilizers in grains, fruits and vegetables, degrade toxic and harmful substances in living goods (such as children toys), can treat various diseases such as cancers by using organic germanium in the composition when the composition is used for preparing medicines, and also has the effects of health care and the like. In addition, the obtained gulmanite has multiple functions, can be used as a pigment of antirust paint, has excellent antirust performance, and can replace red lead; used as a polishing agent for precision instruments and a raw material for manufacturing ferrite elements of magnetic materials; for the manufacture of glass, quartz glass, water glass, optical fibers, important parts of the electronics industry, optical instruments and artware, etc.; for the manufacture of fire-resistant materials, reactive dyes, etc.; used for preparing sunscreen product, and is harmless to human body; used as disinfectant to remove harmful substances; it is used as air purifying agent to protect environment.

The term "active mica" in the present invention means an active organic substance containing various metal ions and metal compounds.

The term "guamanite" in the present invention means a residue obtained by filtering a mixture in the process of preparing a composition containing active mica by biological fermentation, that is, the guamanite.

Detailed Description

The technical features of the technical solutions provided by the present invention are further clearly and completely described below with reference to the specific embodiments, and the scope of protection is not limited thereto. Unless defined otherwise, all technical and scientific terms used herein have the same meaning as commonly understood by one of ordinary skill in the art to which this invention belongs. In case of conflict, the present specification, including definitions, will control.

The words "preferred," "more preferred," "most preferred," and the like in this disclosure mean embodiments of the invention that may, in some instances, provide some benefit. However, other embodiments may be preferred, under the same or other circumstances. Furthermore, the recitation of one or more preferred embodiments does not imply that other embodiments are not useful, nor is it intended to exclude other embodiments from the scope of the invention.

In order to solve the above problems, the first aspect of the present invention provides a composition containing active mica, which is prepared from the following raw materials in parts by weight: 2-6 parts of silicate minerals, 3-8 parts of solvents and 0.5-2 parts of plum fruits.

In a preferred embodiment, the raw materials for preparation comprise, by weight: 4 parts of silicate minerals, 5 parts of solvent and 1 part of plum fruit.

Silicate mineral

The silicate mineral of the invention contains Silicate (SiO)₄ ^4-) General names of minerals (also including other silicon-containing salts, e.g. metasilicates, wollastonite, CaSiO)₃An example). Can be regarded as SiO₂In combination with other oxides, mostly metal oxides.

In a preferred embodiment, the silicate mineral of the invention is at least one selected from granite, perlite, mullite, metamorphic rock, and basalt.

The Granite (Granite) of the invention, the language source is Granum of Latin, which means that grains or granules belong to acidity (SiO)₂>66%) of the rock pulp rock, the invaded rock is generally light flesh red, light gray, gray white and the like. Medium coarse grain, fine grain structure, block structure. Some are mottled structures, spherical structures, flaked structures, etc. The main minerals are quartz, potash feldspar and acidic plagioclase feldspar, and the secondary minerals are biotite, amphibole and sometimes a small amount of pyroxene. The secondary minerals are of various types, and commonly include magnetite, sphene, zircon, apatite, tourmaline, fluorite and the like. The quartz content is the highest of all kinds of rock magma, and can be from 20 to 50%, and a few can reach 50 to 60%. The content of the potassium feldspar is generally higher than that of the plagioclase feldspar, the proportion of the potassium feldspar to the plagioclase feldspar is usually two thirds of the total amount of the potassium feldspar, one third of the plagioclase feldspar, and the potassium feldspar in granite is generally light reddish-fleshy and also grey. The off-white potassium feldspar and plagioclase feldspar are often not easily distinguished on the hand specimen. At this time, we need to carefully observe the twinned features of the two kinds of feldspar, because plagioclase has a poly-lamellar twinkle, regular light and dark poly-lamellar on the plagioclase crystal can be seen when rotating the hand specimen, and the potassium feldspar is a cassette twinkle and appears as two semi-crystals with different brightness degrees.

The Perlite (Perlite) is acid lava sprayed by volcano, is vitreous rock formed by rapid cooling, and is named after the Perlite (Perlite) has a pearl fracture structure. The oxidation and melting temperatures of perlite are: the initial shrinkage temperature was 1025 ℃, the softening temperature was 1175 ℃, and the melting temperature was greater than 1500 ℃. The perlite begins to shrink at a temperature 120 ℃ lower than feldspar, the softening temperature is 75 ℃ lower, and the softening range is widened to 95 ℃. Because of these characteristics, perlite can greatly reduce firing temperature and improve the quality of sintering in the firing of ceramic products. Through further intensive research, perlite has the characteristic that mullite crystals are formed earlier in a ceramic body containing perlite, so that the sintering process is facilitated to be developed. Therefore, the perlite-containing green body has the same process characteristics as the feldspar-quartz-clay (kaolin mineral) ternary system green body formula, can reduce the firing temperature (from 1280 ℃ to 1180 ℃ -1160 ℃) and has good thermal stability.

The Muscovite (also called mica stone) is a sheet ore of silicate mineral Muscovite, which is collected from granite and pegmatite, mainly contains hydrous aluminum potassium silicate, and is produced in inner Mongolia, Liaoning, Jilin, Hebei, Shandong, Yunnan, Zhejiang, Jiangsu, Anhui, Jiangxi and other places, and ancient times can be used as furniture such as screens. The pearl-like or glass-like luster is irregular and flaky, and is different in size, colorless, transparent or white and has a pearl-like or glass-like luster when a plurality of layers are laminated together. The product is tough, can be peeled into thin sheets layer by layer, and the thin sheets are smooth, transparent and elastic.

Metamorphic rock (Metamorphic rock) is rock formed by metamorphism, and is formed by rock pulp rock or sedimentary rock formed in the crust firstly, and mineral components, chemical components and structural structures are changed under the influence of change of environmental conditions. Its lithologic characteristics are controlled by the original rock, and have a certain inheritance, and because it is undergone the process of different metamorphic actions, it also has new nature (for example, it contains metamorphic minerals and directional structure). In general, metamorphic rocks formed from metamorphic rocks by metamorphic action are called "positive metamorphic rocks", and metamorphic rocks formed from metamorphic rocks by metamorphic action are called "secondary metamorphic rocks".

The Basalt (Basalt) is a basic extrusive rock, the chemical composition of which is similar to gabbro rock or gabbro rock, SiO₂The content is changed between 45 percent and 52 percent, K₂O and Na₂The content of O is slightly higher than that of the invaded rock, CaO and Fe₂O₃And the FeO and MgO contents are slightly lower than those of the invaded rock. The mineral components mainly comprise basic feldspar and pyroxene, the secondary minerals comprise olivine, amphibole, biotite and the like, and the rocks are dark, generally black, and sometimes grayish green, dark purple and the like. Is in spot-shaped structure. Stomata configurations and almond configurations are common.

In a more preferred embodiment, the silicate mineral of the invention is granite.

Solvent(s)

The Solvent (Solvent) of the present invention is a liquid that can dissolve solid, liquid or gaseous solute and then become a solution. The most common solvent in daily life is water. The organic solvent is an organic compound containing carbon atoms. Solvents generally possess a relatively low boiling point and are readily volatile.

In a preferred embodiment, the solvent according to the present invention is at least one selected from the group consisting of water, alcohol solvents, and ether solvents.

In a preferred embodiment, the alcoholic solvent of the present invention is at least one selected from methanol, ethanol, n-propanol, n-butanol, isoamyl alcohol, ethylhexanol, ethylene glycol, and propylene glycol.

In a preferred embodiment, the ether solvent according to the present invention is at least one selected from the group consisting of methyl ether, ethyl ether, propyl ether, isopropyl ether, butyl ether, pentyl ether, isopentyl ether, hexyl ether, ethylbutyl ether, methyl tert-butyl ether, ethylvinyl ether, and butylvinyl ether.

In a more preferred embodiment, the solvent of the present invention is water.

Plum fruit

The plum fruit is also called plum, is a general name of plant fruits, is sweet in taste, large in fruit, thin in peel, glossy, thick in meat, small in kernel, crisp and fine in texture, rich in juice, high in acidity, rich in various amino acids needed by a human body, and has sour and sweet fragrance, especially because of being rich in fruit acid and vitamin C.

In a preferred embodiment, the plum fruit of the present invention is at least one selected from the group consisting of green plum, dark plum and prune.

The green plum (scientific name: Vaticangachapoi Blanco) is a tree of the genus Vaticangachapoi of the family Dipterocarpaceae, and the tree height is about 20 m. The small branches are villi in star shape. The leaf is leather, is in a shape of a long circle to a long circle, is in a needle shape, the tip of the leaf is gradually sharp or short, the base of the leaf is circular or wedge-shaped, the two sides of the leaf are both protruded, the net vein is obvious, and the petiole is densely covered with grayish yellow short villi. The conifer is terminal or axillary, the sepals of the calyx are arranged in a pincerlike manner, the ovate shape is in a needle shape or an oblong shape, and the two sides of the ovate shape are closely covered by stellate hair or scaly hair; the petals are white, are light yellow or light red sometimes, are aromatic, are in a long round shape or a linear spoon shape, are short in filaments, are long in anther, are spherical in ovaries, are densely covered with short villi, and are spherical in fruits; 12-1 month flowering period, 4-5 month fruit period. Distributed in Hainan China. It is grown in hills and sloping fields with elevation below 700 m. Vietnam, Thailand, Philippines, Indonesia, etc. are distributed.

The mume fructus has effects of promoting appetite, dredging gallbladder, promoting fluid production, and quenching thirst. Flowers bloom in winter and ripe in summer. Therefore, it is most sour and enters gallbladder and ear. Four orifices are under the tongue of human. The two orifices can dredge gallbladder liquid. When eaten, it can dredge gallbladder. To let the liquid go out. The like feeling is also obtained. And (5) primarily recovering acid. Therefore, they are mainly used for the treatment of acid-induced diseases. Such as this meridian is full of heat-removing herbs. Ease heart and relieve pain in limbs. However, it is better to store for a long time. If the herb is Qing Mei, it congeals and astringes qi. It is also suitable for diseases such as hemiplegia and malnutrition. The species of plum are many. But mu lan Mei is the most superior. The sworn and the sworn of the palm tree are expressed in Wu-Fu-Shu-Mei branches and branches of the fax. We can do this. The fruit is bloomed. It is from taihe mountains, zhou. I.e. one of the elms. It is as plum as apricot. And the crunchiness is abnormal. Therefore, it is known as Xiaomei. Appetite stimulating and body fluid generating. Refreshing and sleeping. Is also the nature of the hammer tree. However, it can also congeal blood and stagnate qi when eaten more often. Can be eaten after being carefully examined.

The dark plum, also called plum fruit, smoked plum, orange plum pulp, plum and spring plum, is a dried nearly mature fruit of plum prunus me (Sieh.) sieb. Collected in summer when the fruits are nearly ripe, and dried at low temperature and then sealed until the color becomes black. Is ring-like or oblate spherical, and the aperture is 1.5-3 cm. The surface is dark black or brownish black, the fruit is not flat, and the base part has round fruit stalk marks. The fruit stones are hard, oval, brown yellow and have pits on the surfaces; the seeds are flat ovoid and yellowish. Light smell, extremely sour taste. Astringe lung, astringe intestine, promote fluid production and relieve ascaris. Can be used for treating lung deficiency, chronic cough, chronic dysentery, intestine dryness, asthenia heat, diabetes, ascariasis, emesis, abdominal pain, and biliary ascariasis.

The prune (scientific name: Prunusdomestica L.), also known as California prune, European plum, French black date, is like apricot plum, when the plum is mature, the surface prune skin is dark purple, and the pulp is amber. The beverage is rich in citric acid, malic acid and succinic acid, and has effects of lowering blood pressure, improving sleep, clearing away heat, and promoting fluid production. The prunus mume has effects of strengthening liver function and relieving fatigue. The mume fructus is an alkaline food, and has effects of purifying blood, promoting natural discharge of toxin, and removing toxic substances of food, water and blood. It contains abundant nutrients including cellulose, vitamin A, minerals, trace elements, etc.

In a more preferred embodiment, the plum fruit of the present invention is a green plum.

In a preferred embodiment, the silicate mineral, the solvent and the plum fruit of the present invention are present in a weight ratio of (3 to 5): (4-6): 1.

in a more preferred embodiment, the silicate mineral, the solvent and the plum fruit of the present invention are present in a weight ratio of 4: 5: 1.

since silicate minerals are rich in various elements, among them, in addition to Si and O, which are essential for silicate formation, ions of mainly inert gas type (such as Na) exist as metal cations⁺、K⁺、Mg²⁺、Ca²⁺、Ba²⁺、Al³⁺Etc.) and partially transitional ions (e.g., Fe)²⁺、Fe³⁺、Mn²⁺、Mn³⁺、Cr³⁺、Ti³⁺Etc.) and also small amounts of copper type ions (e.g., Cu)⁺、Zn^{2 +}、Pb²⁺、Sn⁴⁺Etc.); the mume fructus contains large amount of protein, fat (fatty oil), carbohydrate, various inorganic salts, and organic acids, and adopts biological fermentation technology, and utilizes specific functions of fungi, enzyme and bacteria to dissolve minerals and release the mineralsSilicon, potassium and other elements, thereby improving the utilization rate of silicate minerals.

However, the inventors of the present application have unexpectedly found that when granite is selected as a silicate mineral, green plum is selected as a plum, and the weight ratio of the silicate mineral, a solvent and the plum is controlled to be (3-5): (4-6): 1, the content of calcium, zinc and potassium in the active mica composition can be obviously improved. Probably because the green plums are rich in chemical components such as acids, polyphenols, sugars and glycosides, mushrooms, lipids, sterols, alkaloids and the like, and can also generate a plurality of different microorganisms, the granite has a compact structure and low availability, so that the competition among the microorganisms is intensified. Under specific conditions, chemical substances in the green plums and generated various microorganisms and granite act together through mutual synergy and combined action and with the help of small molecules of a proper amount of solvent, so that various mechanisms of erosion, complexation, dissolution and redox in a system play a role together, and the content of calcium, potassium and zinc in the active mica composition is improved.

In a second aspect, the invention provides a process for the biological fermentative preparation of a composition comprising activated mica, comprising at least the following steps:

(1) crushing and cleaning silicate minerals; removing cores from mume fructus;

(2) adding silicate minerals, a solvent and plum fruits into a fermentation tank, mixing and fermenting for 130-150 days in total to obtain a mixture;

(3) and filtering the mixture to obtain filtrate, namely the composition containing the active mica.

In a preferred embodiment, the silicate mineral of the present invention has a particle size of 0.5 to 0.8cm after being pulverized.

The method for judging the particle size comprises the following steps: separating the crushed silicate minerals by using a sieve with the aperture of 0.8cm, taking small particles falling out of the holes, separating the small particles by using a sieve with the aperture of 0.5cm, and taking powder particles left on the sieve, wherein the particle size of the particles is 0.5-0.8 cm.

In a preferred embodiment, the mixing mode of the present invention is a circulation pump type, and the time interval of one circulation is 7 to 9 hours.

The time interval of one circulation is 7-9 h, which means that a circulation pump is used for one circulation every 7-9 h in the fermentation process.

In a preferred embodiment, the fermentation temperature is 1-100 ℃.

The present invention will now be described in detail by way of examples, and the starting materials used are commercially available unless otherwise specified.