Harmful organism active heterocycles derivative is killed with sulfur-bearing substituent group
阅读说明：本技术 具有含硫取代基的杀有害生物活性杂环衍生物 (Harmful organism active heterocycles derivative is killed with sulfur-bearing substituent group ) 是由 O·F·胡特 A·埃德蒙兹 A·杰恩格纳特 P·J·M·容 A·布驰赫尔兹 M·米尔巴赫 于 2015-12-10 设计创作，主要内容包括：具有化学式I的化合物<Image he="352" wi="700" file="DDA0002178491160000011.GIF" imgContent="drawing" imgFormat="GIF" orientation="portrait" inline="no"></Image>其中这些取代基是如在权利要求1中所定义的,以及那些化合物的农用化学上可接受的盐、立体异构体、对映异构体、互变异构体和N-氧化物,可以用作杀虫剂并且可按照本身已知的方法制备。(Compound with Formula I Wherein these substituent groups are as claimed in claim 1, and acceptable salt, stereoisomer, enantiomter, tautomer and N- oxide in the agrochemicals of those compounds, it may be used as insecticide and can be prepared according to method known per se.)
1. a kind of compound with Formula I
Wherein
A indicates CH or N；
Q is attached to 3 or 4；It and is C3-C6Naphthenic base or by substituent group selected from the group below is monosubstituted or polysubstituted C3-C6 Naphthenic base, the group consisting of: halogen, cyano, C1-C4Alkyl, C1-C4Halogenated alkyl, C3-C6Naphthenic base ,-C (O) OH、-C(O)NH2, phenyl and can by substituent group selected from the group below monosubstituted or polysubstituted phenyl, the group is by the following terms Composition: halogen, cyano, C1-C4Alkyl, C1-C4Halogenated alkyl, C1-C4Halogenated alkoxy, C1-C4Alkoxy, C1-C4Halogenated alkyl Sulfanyl, C1-C4Alkylsulfinyl, C1-C4Halogenated alkyl sulfonyl and-C (O) C1-C4Halogenated alkyl；
X is S, SO or SO2；
R1It is C1-C4Alkyl, C1-C4Halogenated alkyl, C3-C6Naphthenic base, C3-C6Naphthenic base-C1-C4Alkyl is taken by selected from the group below For base is monosubstituted or polysubstituted C3-C6Naphthenic base, the group consisting of: halogen, cyano and C1-C4Alkyl；Or
R1It is by substituent group selected from the group below is monosubstituted or polysubstituted C3-C6Naphthenic base-C1-C4Alkyl, the group is by the following terms Composition: halogen, cyano and C1-C4Alkyl；Or
R1It is C2-C6Alkenyl, C2-C6Halogenated alkenyl or C2-C6Alkynyl；
R2It is halogen, cyano, C1-C6Halogenated alkyl or the C replaced by one or two substituent group selected from the group below1-C6Alkyl halide Base, the group consisting of: hydroxyl, methoxyl group and cyano；Or
R2It is C1-C4Halogenated alkyl sulfanyl, C1-C4Alkylsulfinyl, C1-C4Halogenated alkyl sulfonyl, O (C1-C4Halogen Substituted alkyl) or-C (O) C1-C4Halogenated alkyl；Or
R2Be can by substituent group selected from the group below monosubstituted or polysubstituted C3-C6Naphthenic base, the group consisting of: Halogen, cyano and C1-C4Alkyl；
X1It is O, S or NR3, wherein R3It is hydrogen, C1-C4Alkyl, C2-C6Alkenyl, C2-C6Alkynyl, C1-C4Alkoxy -C1-C4Alkyl or C3-C6Naphthenic base；And acceptable salt, stereoisomer, enantiomerism in the agrochemicals of the compound with Formula I Body, tautomer and N- oxide.
2. the compound according to claim 1 with Formula I is indicated by the compound with Formula I -1
Wherein R2It is as defined under Formula I in claim 1 with Q；
Xa1It is S, SO or SO2；And
Ra1It is methyl, ethyl, n-propyl, isopropyl or Cvclopropvlmethvl.
3. the compound according to claim 1 with Formula I is indicated by the compound with Formula I -2
Wherein R2It is as defined under Formula I in claim 1 with Q；
Xa1It is S, SO or SO2；And
Ra1It is methyl, ethyl, n-propyl, isopropyl or Cvclopropvlmethvl.
4. the compound according to claim 1 with Formula I is indicated by the compound with Formula I -3
Wherein R2It is as defined under Formula I in claim 1 with Q；
Xa1It is S, SO or SO2；And
Ra1It is methyl, ethyl, n-propyl, isopropyl or Cvclopropvlmethvl.
5. the compound according to claim 1 with Formula I is indicated by the compound with Formula Ia -1
Wherein
A is CH or N；
X2It is S or SO2；
X3It is N- (C1-C4Alkyl)；
R4It is C1-C4Alkyl；
R5It is C1-C4Halogenated alkyl or C1-C4Halogenated alkyl sulfanyl；And
QaIt is C3-C6Naphthenic base or by substituent group selected from the group below is monosubstituted or polysubstituted C3-C6Naphthenic base, the group is by following Item composition: halogen, cyano, C1-C4Alkyl, C1-C4Halogenated alkyl ,-C (O) OH and-C (O) NH2。
6. the compound according to claim 1 with Formula I is indicated by the compound with Formula Ia -2
Wherein
A is CH or N；
X4It is N- (C1-C4Alkyl)；
R6It is C1-C4Halogenated alkyl or C1-C4Halogenated alkyl sulfanyl；And
QbIt is C3-C6Naphthenic base or by the mono-substituted C of substituent group selected from the group below3-C6Naphthenic base, the group consisting of: Cyano ,-C (O) OH and-C (O) NH2。
7. the compound according to claim 1 with Formula I is indicated by the compound with Formula Ia -3
Wherein
A is CH or N；
X2pIt is S or SO2；
X3pIt is N- (C1-C4Alkyl)；
R4pIt is C1-C4Alkyl；
R5pIt is C1-C4Halogenated alkyl or C1-C4Halogenated alkyl sulfanyl；And
QapIt is C3-C6Naphthenic base or by substituent group selected from the group below is monosubstituted or polysubstituted C3-C6Naphthenic base, the group is by following Items composition: halogen, cyano, C1-C4Alkyl, C1-C4Halogenated alkyl ,-C (O) OH ,-C (O) NH2And phenyl.
8. the compound according to claim 1 with Formula I is indicated by the compound with Formula Ia -4
Wherein
A is CH or N；
X4pIt is N- (C1-C4Alkyl)；
R6pIt is C1-C4Halogenated alkyl or C1-C4Halogenated alkyl sulfanyl；And
QbpIt is C3-C6Naphthenic base or by the mono-substituted C of substituent group selected from the group below3-C6Naphthenic base, the group consisting of: Cyano ,-C (O) OH and-C (O) NH2。
9. a kind of compound with chemical formula VI-a
Wherein
A、Q、X1And R2It is as defined under Formula I in claim 1；And
Xb30It is halogen.
10. a kind of compound with chemical formula XV-int
Wherein
R1、R2、R3, X and A be as defined under Formula I in claim 1；And
Q is group
Wherein R0002It is cyano.
11. one kind kills pest composition, it includes at least one according to claim 1 that this, which kills pest composition, Compound with Formula I or it is appropriate when its tautomer as active constituent and at least one auxiliary agent, the compound In all cases it is free form or is available salt form in agrochemicals.
12. a kind of method for controlling harmful organism, this method includes applying composition according to claim 11 In these harmful organisms or its environment, be used to handle the method for human or animal body except through operation or therapy and in people or Except the diagnostic method implemented on animal body.
13. a kind of method for protecting plant propagation material to attack from harmful organism, this method include being wanted with according to right The place that the propagation material of compositions-treated described in asking 11 or the propagation material are planted.
14. the plant propagation material of the processing of method described in 3 according to claim 1.
- 上一篇：一种医用注射器针头装配设备
- 下一篇：用于激酶抑制的杂芳基化合物