Coating composition, method of making and method of using the same
阅读说明：本技术 涂料组合物及其制造方法和使用方法 (Coating composition, method of making and method of using the same ) 是由 B·A·查特 H·史密斯 于 2018-04-03 设计创作，主要内容包括：本公开提供一种包含果胶和非甘油糖醇的涂料组合物。所述果胶按重量计可以以至少30.0％和至多50.0％的量存在。所述非甘油糖醇按重量计可以以至少10.0％和至多40.0％的量存在。所述果胶相对于所述非甘油糖醇以至少1∶1且至多5∶1的比例存在。本公开还提供了与所述涂料组合物有关的涂料悬浮液、涂层和经涂覆的底物。本公开还提供了制备和使用所述涂料组合物的方法。(The present disclosure provides a coating composition comprising pectin and a non-glycerol sugar alcohol. The pectin may be present in an amount of at least 30.0% and at most 50.0% by weight. The non-glycerol sugar alcohol may be present in an amount of at least 10.0% and at most 40.0% by weight. The pectin is present in a ratio of at least 1:1 and at most 5:1 relative to the non-glycerol sugar alcohol. The present disclosure also provides coating suspensions, coatings and coated substrates related to the coating compositions. The present disclosure also provides methods of making and using the coating compositions.)
1. A coating composition comprising:
pectin in an amount of at least 30.0% and at most 50.0% by weight; and
a non-glycerol sugar alcohol in an amount of at least 10.0% and at most 40.0% by weight.
2. A coating composition comprising:
pectin, and
a non-glycerol sugar alcohol;
wherein the pectin is present in a ratio of at least 1:1 and at most 5:1 relative to the non-glycerol sugar alcohol.
3. A coating composition according to claim 1 or 2, wherein the pectin has a degree of methyl esterification of more than 50.
4. A coating composition according to any one of the preceding claims, wherein the pectin has a molecular weight of at least 60,000 g/mol.
5. A coating composition according to any one of the preceding claims, wherein the pectin has a molecular weight of at least 75,000 g/mol.
6. A coating composition according to any one of the preceding claims, wherein the pectin has a molecular weight of at least 100,000 g/mol.
7. A coating composition according to any one of the preceding claims, wherein the pectin is present in an amount of at least 35.0% and at most 45.0% by weight.
8. A coating composition according to any one of the preceding claims, wherein the pectin is present in an amount of at least 37.5% and at most 42.5% by weight.
9. A coating composition as claimed in any one of the preceding claims, wherein the non-glycerol sugar alcohol is sorbitol.
10. A coating composition as claimed in any one of the preceding claims, wherein the non-glycerol sugar alcohol is present in an amount of at least 15.0% and at most 25.0% by weight.
11. A coating composition as claimed in any one of the preceding claims, wherein the non-glycerol sugar alcohol is present in an amount of at least 17.5% and at most 22.5% by weight.
12. A coating composition according to any one of the preceding claims, wherein the coating composition is substantially free of divalent cations.
13. A coating composition as set forth in any preceding claim wherein said coating composition is substantially free of calcium and magnesium.
14. A coating composition according to any one of the preceding claims, wherein the coating composition is substantially free of calcium.
15. A coating composition according to any one of the preceding claims, wherein the coating composition is substantially free of genetically modified organisms or products thereof.
16. The coating composition of any one of the preceding claims, further comprising glycerol in an amount of at least 0.01% and at most 20.0% by weight.
17. The coating composition of any of the preceding claims, further comprising an oil-based plasticizer in an amount of at least 0.01% and at most 15.0% by weight.
18. The coating composition of claim 17, wherein the oil-based plasticizer is selected from the group consisting of acetylated monoglycerides, medium chain triglycerides, propylene glycol dicaprylate/dicaprate, fatty acid-based plasticizers, and combinations thereof.
19. The coating composition of claim 18, wherein the oil-based plasticizer comprises a medium chain triglyceride.
20. The coating composition of any one of the preceding claims, further comprising a film former in an amount of at least 0.01% and at most 15.0% by weight.
21. The coating composition of claim 20, wherein the film forming agent is hydroxypropyl cellulose, hydroxypropyl methylcellulose, or a combination thereof.
22. The coating composition of any one of the preceding claims, further comprising an opacifier in an amount of at least 0.01% and at most 20.0% by weight.
23. The coating composition of any of the preceding claims, further comprising a wax in an amount of at least 0.01% and at most 5.0% by weight.
24. The coating composition of claim 23, wherein the wax is carnauba wax, beeswax, or a combination thereof.
25. The coating composition of claim 24, wherein the wax is carnauba wax.
26. A coating composition as set forth in any preceding claim further comprising a non-sugar alcohol sweetener in an amount of at least 0.01% and at most 10.0% by weight.
27. A coating composition according to claim 26, wherein the sweetener comprises an artificial sweetener in an amount of at least 0.01% and at most 2.0% by weight of the coating composition.
28. The coating composition of claim 27, wherein the artificial sweetener is sucralose.
29. The coating composition of claim 26, wherein the sweetener is sugar.
30. The coating composition of any one of the preceding claims, further comprising an adjuvant.
31. The coating composition of any one of the preceding claims, further comprising a spray-dried flavor, a dried crystalline flavor, a particulate flavor, or a combination thereof in an amount of at least 3.0% and at most 15.0% by weight.
32. The coating composition of claim 31, wherein the spray dried flavor, dried crystalline flavor, particulate flavor, or combination thereof comprises a synthetic flavor, an artificial flavor, a natural flavor, or a combination thereof.
33. The coating composition of claim 31 or 32, wherein the spray dried flavor, dried crystalline flavor, particulate flavor, or combination thereof provides a flavor selected from the group consisting of: almond, almond-flavoured spirit, apple, green apple, apple-cherry-berry, apple-honey, apricot, bacon, banana, barbecue, beef, roast beef, beefsteak, berry, blueberry, birch beer, spruce beer, blackberry, bloody mary, blueberry, boysenberry, brandy, bubble gum, butter, cream walnut, buttermilk, butterscotch, candy corn, hami melon lime, caramel, carrot, cassia seed, caviar, celery, cereal, champagne, cherry cola, wine-soaked cherry, malted cherry, black cherry, red cherry, cherry-cola, chicken, chocolate, almond, cinnamon flavour, citrus mix, orange-strawberry, clam, cocoa, coconut, roasted coconut, coffee almond, cola-vanilla, biscuit and cream, biscuit, butter, chocolate and cream, chocolate, etc, Marshmallow, cranberry-raspberry, cheese soda, dairy cream, mint essential oil, cucumber, blackberry, milk caramel sauce, egg yolk milk, pork fat, non-pork fat, anchovy, herring, sardine, frankfurter, fried garlic, gin, ginger juice, ginger beer, greham biscuit, grape, grapefruit-lemon, grapefruit-lime, pomegranate juice, grilled fish, babassu, guava, hazelnut, honey roast honey, ice cream, mexican pepper, lime, kiwi-banana, kiwi-lemon-lime, kiwi-strawberry, champagne, fatty pig, lemon cream jelly, lemon water, pink lemon water, lemon-lime, lemon water, lemon-lime water, lemon water, lime water, Malt, malt milk, mango-pineapple, maple, margarite, marshmallow, meat, condensed milk, cooked milk, mint, botanical flavors, mocha powder, molasses, mushrooms, stir-fried mushrooms, melon, nectarine, narcole ice cream, shallot, stir-fried onion, orange juice, orange fondant, orange cream, orange peach mango, orange strawberry banana, butter orange, mandarin, passion fruit-guava, orange-pineapple, papaya, passion fruit, peach mango, peanut, roasted nut, pear, walnut cookie, pecan candy, pepper, mint, allspice, pineapple juice rum/coconut, pineapple, pistachio, pizza, pomegranate, roasted potato, prune, panfun, cherry fruit wine, plum, panfun, plum wine, panfun, and apple, Grape punch, raspberry, black raspberry, blue raspberry, red raspberry, raspberry-blackberry, raspberry-ginger beer, raspberry-lime, root beer, rum, sang gri wine, mexican china, sassafras, sausage pizza, seafood, shrimp, pecan tobacco, legume bush tobacco, sour cream and onion, spearmint, strawberry margarite, jam strawberry, strawberry-kiwi, coke, tallow, fruits of tamarind, citrus-lime, citrus, tea, tequila, taffy, orange peel wine, tropical fruit mix, turkey, assorted confection, vanilla cream, vanilla egg custard, french vanilla, vegetables, wormwood wine, vinegar, balsam vinegar, watermelon, whiskey, wild berry, wine, yogurt, and combinations thereof.
34. The coating composition of any one of the preceding claims, further comprising a liquid flavoring in an amount of at least 0.1% and at most 9.0% by weight.
35. The coating composition of claim 34, wherein the liquid flavorant comprises synthetic flavorant, artificial flavorant, natural flavorant, or a combination thereof.
36. A coating composition according to claim 34 or 35, wherein the liquid flavouring provides a flavour selected from the group consisting of: almond, almond-flavoured spirit, apple, green apple, apple-cherry-berry, apple-honey, apricot, bacon, banana, barbecue, beef, roast beef, beefsteak, berry, blueberry, birch beer, spruce beer, blackberry, bloody mary, blueberry, boysenberry, brandy, bubble gum, butter, butternut, buttermilk, butterscotch, candy corn, hami melon lime, caramel, carrot, cassia seed, caviar, celery, cereal, champagne, cherry-cola, wine-soaked cherry, malted cherry, black cherry, red cherry, cherry cola, chicken, chocolate, almond, cinnamon flavour, citrus mix, citrus strawberry, clam, cocoa, coconut, roasted coconut, coffee, almond, cola, vanilla, biscuit and cream, marshmallow, sugar, apricot, peanut butter, black cherry, chocolate, cranberry, cranberry-raspberry, cheese soda, dairy cream, mint essential oil, cucumber, blackberry, milk caramel sauce, egg yolk milk, pork fat, non-pork fat, anchovy, herring, sardine, frankfurter, fried garlic, gin, ginger juice, ginger beer, greige biscuit, grape, grapefruit-lemon, grapefruit-lime, pomegranate juice, roasted fleshfish, guava, hazelnut, honey, roasted honey, egg roll ice cream, mexican pepper, mexican lime, kiwi-banana, kiwi-lemon-lime, kiwi-strawberry, cola champagne, fatty pig, lemon cream jelly, lemonade, pink lemon water, lemon-lime, malt, lemon, lime, malt milk, mango-pineapple, maple, margarite, marshmallow, meat, condensed milk, boiled milk, mint, botanical flavors, mocha powder, molasses, mushroom, stir-fried mushroom, melon, nectarine, narcole ice cream, shallot, stir-fried onion, orange juice, fudge, orange cream, orange peach and mango, orange banana, butter orange, mandarin, passion fruit-guava, orange-pineapple, papaya, passion fruit, peach and mango, peanut, roasted nut, pear, pecan cookie, mountain nut candy, pepper, mint, allspice, pineapple juice rum/pineapple coconut, pineapple orange, pistachio, pizza, potato, roasted, prune, panfun, pomegranate, panfun, cherry, panfun, pineapple, orange, panfun, plum, panfun, and the like, Grape punch, raspberry, black raspberry, blue raspberry, red raspberry, raspberry-blackberry, raspberry-ginger beer, raspberry-lime, root beer, rum, sang gri wine, mexican china, sassafras, sausage pizza, seafood, shrimp, pecan tobacco, legume bush tobacco, sour cream and onion, spearmint, strawberry margarite, jam strawberry, strawberry-kiwi, coke, tallow, fruits of tamarind, citrus-lime, citrus, tea, tequila, taffy, orange peel wine, tropical fruit mix, turkey, assorted confection, vanilla cream, vanilla egg custard, french vanilla, vegetables, wormwood wine, vinegar, balsam vinegar, watermelon, whiskey, wild berry, wine, yogurt, and combinations thereof.
37. The coating composition of any of the preceding claims, further comprising a spray-dried sensate, a dried crystalline sensate, a particulate sensate, or a combination thereof in an amount of at least 3.0% and at most 15.0% by weight.
38. The coating composition of claim 37, wherein the spray-dried sensate, dried crystalline sensate, granular sensate, or combination thereof provides a hot sensation, a cool sensation, a tingling sensation, or combination thereof.
39. The coating composition of any one of the preceding claims, further comprising a liquid sensate in an amount of at least 0.1% and at most 9.0% by weight.
40. The coating composition of claim 39, wherein the liquid sensate provides a hot sensation, a cool sensation, a tingling sensation, or a combination thereof.
41. The coating composition of any one of the preceding claims, further comprising a combination of a flavoring agent and a sensate.
42. The coating composition of any one of the preceding claims, further comprising a taste-masking agent in an amount of at least 0.1% and at most 9.0% by weight.
43. The coating composition of any one of the preceding claims, further comprising a colorant in an amount of at least 0.01% and at most 20.0% by weight.
44. A coating composition according to claim 43, wherein the colorant is a pigment.
45. A coating composition according to claim 43 or 44, wherein the colourant is a pearlescent pigment.
46. A coating composition according to claim 43, wherein the tinting agent is a dye.
47. The coating composition of any one of the preceding claims, further comprising an acidulant in an amount of at least 0.01% and at most 1.0% by weight.
48. A coating composition according to claim 47, wherein the acidulant is citric acid.
49. A coating suspension comprising the coating composition of any one of the preceding claims and a solvent.
50. The coating suspension of claim 49, wherein the coating suspension has a solids content of at least 8.0% and at most 13.0%.
51. The coating suspension of claim 50, wherein the solids content is at least 9.0%.
52. The coating suspension of claim 51, wherein the solids content is at least 10.0%.
53. The coating suspension of claim 52, wherein the solids content is at least 11.0%.
54. A coating suspension according to any one of claims 49 to 53, wherein the solids content is at most 12.0%.
55. The coating suspension of claim 54, wherein the solids content is at most 11.0%.
56. The coating suspension of any one of claims 49-55, wherein the solvent is selected from the group consisting of water, an alcohol, and combinations thereof.
57. A method of using the coating suspension of any one of claims 49-56, comprising applying the coating suspension to a substrate.
58. The method of claim 57, further comprising applying a powder binder to the substrate prior to applying the coating suspension to the substrate.
59. A method of making the composition of any one of claims 1-48, comprising combining the ingredients of the coating composition.
60. A coating comprising the non-volatile components of the coating composition of any one of claims 1-48 or the non-volatile components of the coating suspension of any one of claims 49-56.
61. A coated substrate comprising a substrate and the coating of claim 60.
62. The coated substrate of claim 61, wherein the substrate is a colloidal nutrient.
63. The coated substrate of claim 61, wherein the substrate is a gummy candy.
64. A coated substrate according to claim 61 wherein the substrate is a cereal.
65. A coated substrate according to claim 61 wherein the substrate comprises a probiotic.
Summary of The Invention
In one aspect, the present disclosure provides a coating composition. The coating composition may comprise pectin and a non-glycerol sugar alcohol. The pectin may be present in an amount of at least 30.0% and at most 50.0% by weight. The non-glycerol sugar alcohol may be present in an amount of at least 10.0% and at most 40.0% by weight. The pectin may be present in a ratio of at least 1:1 and at most 5:1 relative to the non-glycerol sugar alcohol.
In another aspect, the present disclosure provides a coating suspension. The coating suspension includes a coating composition described herein and a solvent.
In another aspect, the present disclosure provides a method of using the coating suspension. The method includes applying the coating suspension to a substrate.
In another aspect, the present disclosure provides a method of making a coating composition described herein. The method includes combining the components of the coating composition.
In another aspect, the present disclosure provides a coating. The coating comprises the non-volatile components of the coating composition described herein and/or the non-volatile components of the coating suspension.
In another aspect, the present disclosure provides a coated substrate. The coated substrate includes a substrate and a coating as described herein.
Detailed Description
Before the present invention is described in further detail, it is to be understood that this invention is not limited to particular embodiments described. It is also to be understood that the terminology used herein is for the purpose of describing particular embodiments only and is not intended to be limiting. The scope of the invention is limited only by the claims. As used herein, the singular forms "a", "an" and "the" include plural embodiments unless the context clearly dictates otherwise.
It will be apparent to those skilled in the art that many more modifications besides those already described are possible without departing from the inventive concepts herein. In interpreting the disclosure, all terms should be interpreted in the broadest possible manner consistent with the context. The terms "comprises" and "comprising" should be interpreted as referring to elements, components, or steps in a non-exclusive manner, such that the referenced elements, components, or steps may be combined with other elements, components, or steps that are not expressly referenced. Embodiments referred to as "comprising," including, "or" having "certain elements are also considered to" consist essentially of and "consist of the element(s)" unless the context clearly dictates otherwise. It should be understood that some aspects of the disclosure described with respect to the system apply to the method, and vice versa, unless the context clearly dictates otherwise.
The numerical ranges disclosed herein include their endpoints. For example, a numerical range of 1 to 10 includes the values 1 and 10. When a range of numerical ranges is disclosed for a given value, this disclosure expressly contemplates ranges that include all combinations of the upper and lower limits of those ranges. For example, a numerical range of 1 to 10 or 2 to 9 is intended to include numerical ranges of 1 to 9 and 2 to 10.
The present disclosure provides a coating composition. The coating composition comprises pectin and a non-glycerol sugar alcohol.
The pectin may have a molecular weight of at least 60 kg/mol, at least 65 kg/mol, at least 70 kg/mol, at least 75 kg/mol, at least 80 kg/mol, at least 85 kg/mol, at least 90 kg/mol, at least 95 kg/mol or at least 100 kg/mol. The pectin has a degree of methyl esterification of greater than 50. Suitable pectins are available from CP Kelco, Atlanta, GA, of Atlanta, Georgia.
The pectin may be present in the coating composition in an amount of at least 30.0%, at least 31.0%, at least 32.0%, at least 33.0%, at least 34.0%, at least 35.0%, at least 36.0%, at least 37.0%, at least 37.5%, at least 38.0%, at least 39.0%, or at least 39.5% by weight. The pectin may be present in the coating composition in an amount of at most 50.0%, at most 49.0%, at most 48.0%, at most 47.0%, at most 46.0%, at most 45.0%, at most 44.0%, at most 43.0%, at most 42.5%, at most 42.0%, at most 41.0% or at most 40.5% by weight.
The non-glycerol sugar alcohol may be selected from sorbitol, mannitol, xylitol, isomalt, hydrogenated starch hydrolysates, and combinations thereof. The non-glycerol sugar alcohol may be sorbitol. The non-glycerol sugar alcohol may be a non-GMO non-glycerol sugar alcohol. The sorbitol may be non-GMO sorbitol.
The non-glycerol sugar alcohol may be present in the coating composition in an amount of at least 10.0%, at least 11.0%, at least 12.0%, at least 13.0%, at least 14.0%, at least 15.0%, at least 16.0%, at least 17.0%, at least 17.5%, at least 18.0%, at least 18.5%, at least 19.0%, at least 19.5% or at least 20.0% by weight. The non-glycerol sugar alcohol may be present in the coating composition in an amount of at most 40.0%, at most 39.0%, at most 37.5%, at most 35.0%, at most 32.5%, at most 30.0%, at most 29.0%, at most 28.0%, at most 27.0%, at most 26.0%, at most 25.0%, at most 24.5%, at most 24.0%, at most 23.5%, at most 23.0%, at most 22.5%, at most 22.0%, at most 21.5%, at most 21.0%, at most 20.5% or at most 20.0% by weight.
The coating composition may optionally include a plasticizer, such as glycerol. It is understood that glycerol may perform some of the functions of non-glycerol sugar alcohols, but is identified herein as a separate component due to its inclusion of additional properties that may be realized. The plasticizer may be present in an amount of at least 0.01%, at least 0.1%, at least 0.5%, at least 1.0%, at least 2.0%, at least 2.5%, at least 3.0%, at least 4.0%, or at least 5.0% by weight. The plasticizer may be present in an amount of up to 10.0%, up to 9.0%, up to 8.0%, up to 7.5%, up to 7.0%, up to 6.0%, or up to 5.0% by weight.
The coating composition may optionally include an oil-based plasticizer. The oil-based plasticizer may be present in the coating composition in an amount of at least 0.01%, at least 0.1%, at least 0.5%, at least 1.0%, at least 2.0%, at least 3.0%, at least 4.0%, at least 5.0%, at least 6.0%, at least 7.0%, or at least 8.0% by weight. The oil-based plasticizer may be present in an amount of up to 15.0%, up to 14.0%, up to 13.0%, up to 12.5%, up to 12.0%, up to 11.5%, up to 11.0%, up to 10.5%, up to 10.0%, up to 9.5%, up to 9.0%, up to 8.5%, or up to 8.0% by weight.
The oil-based plasticizer may be selected from the group consisting of acetylated monoglycerides, Medium Chain Triglycerides (MCT), propylene glycol dicaprylate/dicaprate (e.g.,
The coating composition may comprise a film-forming agent. The film forming agent may be present in the coating composition in an amount of at least 0.01%, at least 0.1%, at least 0.5%, at least 1.0%, at least 2.0%, at least 3.0%, at least 4.0%, at least 5.0%, at least 6.0%, at least 7.0%, or at least 8.0% by weight. The film forming agent may be present in an amount of at most 15.0%, at most 14.0%, at most 13.0%, at most 12.5%, at most 12.0%, at most 11.5%, at most 11.0%, at most 10.5%, at most 10.0%, at most 9.5%, at most 9.0%, at most 8.5%, or at most 8.0% by weight.
The film forming agent, which functions as a binder and may also be referred to herein as a binder, may be hydroxypropyl cellulose (HPC), hydroxypropyl methylcellulose (HPMC), or a combination thereof. In some cases, the HPC and/or HPMC may be low molecular weight HPC and/or HMPC. In some cases, the film former has a viscosity of 2.0 to 6.0 cP. In some cases, the viscosity of the HPC is 2.0 to 5.9cP, including 2.0 to 2.9cP and 3.0 to 5.9 cP. In some cases, the HPMC is HPMC3 cp.
The coating composition may comprise a wax. The wax may be present in the coating composition in an amount of at least 0.01%, at least 0.1%, at least 0.5%, at least 1.0%, at least 2.0%, at least 3.0%, at least 4.0% by weight. The wax may be present in the coating composition in an amount of up to 5.0%, up to 4.5%, up to 4.0%, up to 3.5%, up to 3.0%, or up to 2.5% by weight. In some cases, the wax may be present in an amount within 5%, 10%, 15%, 20%, or 25% of the oil content of the coating composition, which allows for the formation of a waxy emulsion during stirring, which may improve the smoothness (slip) of the substrate during application.
The wax may be selected from carnauba wax, beeswax, a vegetable based wax, and combinations thereof. The wax may be carnauba wax.
The coating composition may optionally include an opacifier. The sunscreen may be present in the coating composition in an amount of at least 10.0%, at least 10.5%, at least 11.0%, at least 11.5%, at least 12.0%, at least 12.5%, at least 13.0%, at least 13.5%, at least 14.0%, at least 14.5% or at least 15.0% by weight. The sunscreen agent may be present in the coating composition in an amount of up to 20.0%, up to 19.5%, up to 19.0%, up to 18.5%, up to 18.0%, up to 17.5%, up to 17.0%, up to 16.5%, up to 16.0%, up to 15.5% or up to 15.0% by weight.
The opacifier may be selected from titanium dioxide, calcium carbonate,AvalancheTM(available from sensitive Colors LLC, st. louis, MO), microcrystalline cellulose, other components that exhibit opacifying properties, and combinations thereof.
The coating composition may optionally comprise a non-sugar alcohol sweetener. The non-sugar alcohol sweetener may be present in the coating composition in an amount of at least 0.01%, at least 0.1%, at least 0.5%, at least 1.0%, at least 2.0%, at least 2.5%, at least 3.0%, at least 3.5%, at least 4.0%, at least 4.5%, at least 5.0%, at least 6.0%, at least 7.0%, or at least 8.0% by weight. The non-sugar alcohol sweetener may be present in the coating composition in an amount of up to 10.0%, up to 9.5%, up to 9.0%, up to 8.5%, up to 8.0%, up to 7.5%, up to 7.0%, up to 6.0%, up to 5.0%, up to 4.0%, up to 3.0%, or up to 2.5% by weight.
The non-sugar alcohol sweetener may be selected from artificial sweeteners, natural sweeteners, e.g., erythritol, stevia (stevia), sugars and combinations thereof.
The natural sweetener may be present in the coating composition in an amount of at least 0.01%, at least 0.1%, at least 0.5%, at least 1.0%, or at least 1.5% by weight. The natural sweetener may be present in the coating composition in an amount of up to 2.0%, up to 1.5%, up to 1.0%, or up to 0.5% by weight.
The artificial sweetener may be selected from sucralose, acesulfame, aspartame, and combinations thereof. The artificial sweetener may be present in the coating composition in an amount of at least 0.01%, at least 0.1%, at least 0.5%, at least 1.0%, or at least 1.5% by weight. The artificial sweetener may be present in the coating composition in an amount of up to 2.0%, up to 1.5%, up to 1.0%, or up to 0.5% by weight.
The sugar may be selected from sucrose, fructose and combinations thereof.
The coating composition may comprise an adjuvant. An adjuvant as used herein refers to an additive that has some complementary benefit to the existing benefit of the substrate being coated. Examples of suitable adjuvants include, but are not limited to, vitamins (e.g., vitamin C (ascorbic acid), vitamin D2 (ergocalciferol), vitamin D3 (cholecalciferol), vitamin K1 (phylloquinone), and vitamin K2 (menadione, vitamin K2)); thiamine; riboflavin; nicotinic acid (niacin); nicotinic acid (nicotinic acid); pantothenic acid; vitamin B6; vitamin H; folic acid; a folate; cyanocobalamin; methylcobalamin, and the like. Using vitamin C as a specific non-limiting example, vitamin C may be applied within a powder coating (see below) to help support the immune system (immune system). Applying vitamin C to the exterior of a substrate, such as gum, can help maintain the shelf life of the vitamin C and can also achieve color integrity. In many cases, vitamin C will oxidize, turning the orange color to brown. The use of vitamin C as an adjuvant in the powder base can reduce this effect.
The coating composition may comprise a flavoring or sensate agent (sensate). The flavoring agent may be a spray-dried flavoring agent, a dried crystalline flavoring agent, a particulate flavoring agent, a liquid flavoring agent, or a combination thereof. The spray-dried flavor, dried crystalline flavor, particulate flavor, liquid flavor, or a combination thereof may comprise synthetic flavors, artificial flavors, natural flavors, or a combination thereof. The spray-dried flavor, dried crystalline flavor, particulate flavor, liquid flavor, or a combination thereof can provide a flavor selected from the group consisting of: almond, almond-flavoured spirit, apple, green apple, apple-cherry-berry, apple-honey, apricot, bacon, banana, barbecue, beef, roast beef, beefsteak, berry, blueberry, birch beer, spruce beer, blackberry, bloody mary, blueberry, boysenberry, brandy, bubble gum, butter, butternut, buttermilk, butterscotch, confectionary corn, hami melon lime, caramel, carrot, cassia seed, caviar, celery, cereal, champagne, cherry cola, wine-soaked cherry, malted cherry, black cherry, red cherry, cherry-cola, chicken, chocolate, almond, cinnamon flavour, citrus mix, citrus strawberry, clam, cocoa, coconut, roasted coconut, coffee, almond, cola-vanilla, biscuit and cream, biscuit, milk, chocolate, soy, Marshmallow, cranberry-raspberry, cheese soda, dairy cream, mint essential oil, cucumber, blackberry, milk caramel sauce, egg yolk milk, pork fat, non-pork fat, anchovy, herring, sardine, frankfurter, fried garlic, gin, ginger juice, ginger beer, greige biscuit type, grape, grapefruit-lemon, grapefruit-sourOrange, pomegranate juice, roasted meat fish, guava, hazelnut, honey, roasted honey, ice cream, mexican pepper, mexican lime, kiwi-banana, kiwi-lemon-lime, kiwi-strawberry, cola champagne, fatty pig, lemon mousse, lemonade, pink lemon water, lemon-lime, malt milk, mango-pineapple, maple, margarite, marshmallow, meat, condensed milk, boiled milk, mint, spice, mocha powder, molasses, mushroom, roasted mushroom, melon, nectarine, Napbus ice cream, shallot, roasted onion, orange juice, orange jelly, orange cream, orange peach, orange strawberry, butter orange, mandarin, banana, honey orange, honey lemon, melon, honey pear, nectar, nectarine, avocado, onion, roasted ice cream, orange strawberry, butterscotch, honey orange, honey, Passion flower-guava, orange-pineapple, papaya, passion fruit, peach-mango, peanut, roasted nut, pear, pecan cookie (pecan danish), pecan praline, pepper, mint, allspice, pineapple juice rum (pina colada), pineapple juice rum/pineapple coconut, pineapple orange, pistachio, pizza, pomegranate, roasted potato, prune, panzelle, citrus panzelle, tropical panzelle, cherry panzelle, grape panzelle, raspberry, blueraspberry, raspberry-blackberry, raspberry-ginger juice beer, raspberry-lime, root beer, mornings, smilax mexicana, sassafras, sausage, pizza, seafood, shrimp, pecan tobacco, shrub tobacco, sour onion, sour cream and onion, Spearmint, strawberry margarite, jam-type strawberry, strawberry-kiwi, coke, tallow, fruit of tamarind, citrus-lime, citrus, tea, agave, taffy, orange peel, tropical fruit mix, turkey, assorted preserves, vanilla cream, vanilla custard, french vanilla, vegetables, wormwood wine, vinegar, balsamic vinegar, watermelon, whisky, wildberry, wine, yogurt and combinations thereof. The flavors described herein can be used alone or in combination with the sensates described herein to experience a perception of cooling, hot and tingling, e.g., with
The spray-dried flavor, dried crystalline flavor, particulate flavor, or combination thereof may be present in the coating composition in an amount of at least 0.1%, at least 1.0%, at least 2%, at least 3.0%, at least 4.0%, at least 5.0%, at least 6.0%, at least 7.0%, at least 8.0%, at least 9.0%, at least 10.0%, at least 11.0%, at least 12.0%, or at least 12.5% by weight. The spray-dried flavor, dried crystalline flavor, particulate flavor, or combination thereof may be present in the coating composition in an amount of up to 15.0%, up to 14.0%, up to 13.0%, up to 12.0%, up to 11.0%, up to 10.0%, up to 9.0%, up to 8.0%, up to 7.0%, up to 6.0%, or up to 5.0% by weight.
The liquid flavorant may be present in the coating composition in an amount of at least 0.1%, at least 0.5%, at least 1.0%, at least 2.0%, at least 2.5%, at least 3.0%, at least 3.5%, at least 4.0%, at least 4.5%, at least 5.0%, at least 6.0%, at least 7.0%, or at least 8.0% by weight. The liquid flavorant may be present in the coating composition in an amount of up to 9.0%, up to 8.0%, up to 7.0%, up to 6.0%, up to 5.0%, up to 4.0%, up to 3.0%, up to 2.0%, or up to 1.0% by weight.
The coating composition may include a sensate. The sensate may be a spray-dried sensate, a dried crystalline sensate, a granular sensate, a liquid sensate, or a combination thereof. The spray-dried sensate, dried crystalline sensate, particulate sensate, liquid sensate, or combinations thereof may provide a hot (hot) sensation, a cool sensation, a tingling sensation, or combinations thereof. In some cases, the sensate can be combined with a flavoring agent to provide a combination of flavoring and sensate that combines the flavors and sensations disclosed herein. In the case of combining a flavoring agent with a sensate, the combination of flavoring and sensate should be present in an amount equal to the amount described herein with respect to the flavoring and sensate.
The spray-dried sensate, dried crystalline feel, particulate feel, or combination thereof may be present in the coating composition in an amount of at least 1%, at least 2%, at least 3.0%, at least 4.0%, at least 5.0%, at least 6.0%, at least 7.0%, at least 8.0%, at least 9.0%, at least 10.0%, at least 11.0%, at least 12.0%, or at least 12.5% by weight. The spray-dried sensate, dried crystalline sensate, particulate sensate, or combination thereof may be present in the coating composition in an amount of up to 15.0%, up to 14.0%, up to 13.0%, up to 12.0%, up to 11.0%, up to 10.0%, up to 9.0%, up to 8.0%, up to 7.0%, up to 6.0%, or up to 5.0% by weight.
The liquid sensate may be present in the coating composition in an amount of at least 0.1%, at least 0.5%, at least 1.0%, at least 2.0%, at least 2.5%, at least 3.0%, at least 3.5%, at least 4.0%, at least 4.5%, at least 5.0%, at least 6.0%, at least 7.0%, or at least 8.0% by weight. The liquid sensate may be present in the coating composition in an amount of up to 9.0%, up to 8.0%, up to 7.0%, up to 6.0%, up to 5.0%, up to 4.0%, up to 3.0%, up to 2.0% or up to 1.0% by weight.
The coating composition may comprise a taste masking agent. The taste-masking agent may be selected from
The coating composition may comprise a colorant. The colorant may be selected from pigments, dyes, non-test colorants (an exemplar colorants) (i.e., colorants from natural sources or (certified) organic bases), and combinations thereof. The colorant may be present in an amount of at least 0.01%, at least 0.1%, at least 0.5%, at least 1.0%, at least 2.0%, at least 2.5%, at least 3.0%, at least 3.5%, at least 4.0%, at least 4.5%, at least 5.0%, at least 6.0%, at least 7.0%, or at least 8.0% by weight. The colorant may be present in an amount of up to 20.0%, up to 17.5%, up to 15.0%, up to 12.5%, or up to 10.0% by weight.
In some cases, the colorant can be provided in the form of a colorant liquid and/or emulsion. In these cases, the colorant, in liquid and/or emulsion form, may be added directly to the coating suspension described elsewhere herein. In some cases, the amount of the colorant may be determined based on the above percentages and the portion by weight of the liquid and/or emulsion colorant is separated. When added directly to the coating suspension, the colorant in liquid and/or emulsion form may be present in the suspension in an amount of at least 0.01%, at least 0.1%, at least 0.5%, at least 1.0%, at least 2.0%, at least 2.5%, at least 3.0%, at least 3.5%, at least 4.0%, at least 4.5%, at least 5.0%, at least 6.0%, at least 7.0%, or at least 8.0% by weight. When added directly to the coating suspension, the colorant in liquid and/or emulsion form may be present in an amount of up to 20.0%, up to 17.5%, up to 15.0%, up to 14.0%, up to 13.0%, up to 12.5%, up to 12.0%, up to 11.0%, or up to 10.0% by weight.
The coating composition may comprise an acidulant. The acidulant may be selected from the group consisting of citric acid, malic acid, ascorbic acid and combinations thereof. The acidulant may be present in the coating composition in an amount of at least 0.01%, at least 0.1%, at least 0.25% or at least 0.5% by weight. The acidulant may be present in the coating composition in an amount of up to 1.0%, up to 0.9%, up to 0.75%, or up to 0.5% by weight.
The coating composition may be substantially free of the various components typically used with pectin. The coating composition may be substantially free of divalent cations, such as calcium or magnesium ions, especially calcium ions.
The coating composition may be substantially free of genetically modified organisms or products thereof.
The present disclosure provides a powder base. The powder base may be applied to the substrate prior to application of the coating composition and/or coating suspension. The powder base may be added to a substrate and is particularly useful when added to a tacky substrate in a weight gain of at least 0.5%, at least 1.0%, at least 1.5%, at least 2.0%, at least 2.5%, or at least 3.0%. The powder base may be subsequently coated with a coating composition and/or a coating suspension after application. The powder base may comprise polymers such as maltodextrin, tapioca dextrin, high amylose starch or other cellulosic materials and the like. The powder base may contain additional flavoring agents, adjuvants, sweeteners, opacifiers, probiotics, masking agents, and the like. These components may be present in the context of the coating composition in the amounts described elsewhere herein or in amounts that would be understood to be beneficial by one of ordinary skill in the art.
As an example of this decision, a two-step decision process may include the steps of step 1-using a coating composition/suspension to form a non-slip surface? if yes, coating with the coating composition/suspension, if not, proceeding to step 2. step 2-using the powder base to add other ingredients (e.g., adjuvants, probiotics/prebiotics, other flavors, taste masking, colorants, or other excipients) to the surface of a substrate (e.g., gum).
The present disclosure provides a coating suspension. The coating suspension may comprise a solvent and a coating composition as described elsewhere herein. The solvent may be selected from the group consisting of water, alcohols (e.g., methanol, ethanol, isopropanol, butanol), and combinations thereof.
The coating suspension may have a solids content of at least 6.0%, at least 6.5%, at least 7.0%, at least 7.5%, 8.0%, at least 8.5%, at least 9.0%, at least 9.5%, a solids content of at least 10.0%, at least 10.5%, or at least 11.0%. The coating suspension may have a solids content of at most 13.0%, at most 12.5%, at most 12.0%, at most 11.5%, at most 11.0%, at most 10.5%, or at most 10.0%.
In some cases, the coating suspension has a viscosity of at least 1150cP at 10% solids content when mechanically agitated by a multi-action agitating blade at 900rpm (revolutions per minute) to 1200 rpm. The viscosity decreases under high shear agitation at 4000rpm to 6000 rpm.
The present disclosure provides a coating. The coating is the result of applying the foregoing coating suspension to an article according to the method described herein. As understood by one of ordinary skill in the art, the coating may comprise the same or substantially similar components as described in connection with the coating compositions described elsewhere herein, but does not comprise any volatile components removed in the coating process.
The present disclosure provides a coated substrate. The coated substrate is the result of applying the coating suspension to the substrate according to the methods described herein. The coated substrate comprises a substrate and a coating as described elsewhere herein. Although the properties of the coating composition are described with respect to coating a particular substrate in a particular manner (as described herein), the composition can be used to coat a variety of substrates, including but not limited to food products.
In some cases, the substrate may be a nutraceutical, including a gummy nutraceutical, a probiotic-containing nutraceutical, or the like, a cereal, a candy (including gummy candies, lozenges, chewing gum, or the like).
The present disclosure provides a method of preparing a coating composition and/or suspension.
The method of preparing the coating composition may include combining and/or milling the various components of the coating composition. In some cases, the dry ingredients are first mixed and then the wet ingredients are added while stirring.
The method of preparing the coating suspension may include: 1) stirring a desired amount of solvent, optionally at a level sufficient to create vortexing; 2) adding a desired amount of the coating composition; 3) mix until a suspension is formed.
The present disclosure provides a method of using the coating composition and/or suspension.
Where the coating composition is a starting material, a method of using the coating composition can include preparing a coating suspension having a solids content, as described elsewhere herein. The process is then continued by the method described below with respect to the coating suspension.
Where the coating suspension is a starting material, a method of using the coating suspension may include applying the coating suspension to a plurality of uncoated substrates. The application may conform to the parameters outlined in table 1 below. In some cases, the coating suspension may be agitated at a speed and/or heated to a temperature at which pectin "entangles" (i.e., individual pectin molecules become loosened/denatured or separated from other pectin molecules and/or non-glycerolic sugar alcohol molecules) prior to application of the coating suspension. In these cases, the method involves cooling the coated substrate to "recombine" the pectin (i.e., individual pectin molecules recoil/renature or recombine with other pectin molecules and/or non-glycerol sugar alcohol molecules). In some cases, this entanglement can be determined by thinning or reducing the viscosity of the suspension.
TABLE 1
Substrates coated with the compositions herein in the coating methods herein may have certain advantageous properties. These improved properties are described in terms of exposure to predetermined conditions for a predetermined length of time. The predetermined condition may be a predetermined temperature and/or a predetermined relative humidity. In some cases, the predetermined temperature may be 25 ℃, 30 ℃, 35 ℃, 40 ℃, 45 ℃ or 50 ℃. In some cases, the predetermined relative humidity may be 50%, 55%, 60%, 65%, 70%, 75%, 80%, or 85%. The predetermined length of time may be 6 hours, 12 hours, 24 hours or 1 day, 2 days, 3 days, 5 days, 7 days or 1 week, 10 days, 14 days or 2 weeks, 17 days, 25 days, 28 days or 4 weeks, 56 days or 8 weeks, 84 days or 16 weeks, or 168 days or 32 weeks.
Some specific conditions were used in the experiments described herein, but these conditions are merely exemplary and are not intended to be limiting. As used herein, "H2" refers to a predetermined temperature of 25 ℃ and a predetermined relative humidity of 60%. As used herein, "H4" refers to a predetermined temperature of 40 ℃ and a predetermined relative humidity of 75%.
In certain instances, the coating compositions described herein can impart improved structural integrity to the applied substrate. One method for measuring this improved structural integrity includes applying a coating composition to a substrate that undergoes a bulk-packed volume reduction under predetermined conditions without application of the coating. To test the structural integrity, a predetermined amount of substrate can be loosely packed in a container (e.g., adding a predetermined amount of substrate to a beaker or jar, gently shaking the beaker or jar to ensure there is no blockage that prevents the loose packing configuration) and exposed to predetermined conditions. It is evident that the substrate itself lacks some structural integrity without being coated in order to provide improved structural integrity. Therefore, in order to make thisThe test is meaningful, on which the uncoated substrate must fail. In some cases, the test may be on an off-the-shelf Gummy bear (e.g., Great Value Gummy bearings chewy candy, Black Forest Gummy bearings candy, or
In some cases, the coating compositions described herein can impart improved adhesion resistance to an applied substrate in the event of easy adhesion between substrates that are not coated with the coating composition. To test this improved resistance to adhesion, a predetermined amount of substrate may be loosely packed in a container and exposed to predetermined conditions, as described above. After exposure to the predetermined conditions, a predetermined amount of the substrate is removed from the container by pouring. The removed substrate was fanned out into a monolayer by applying light pressure by hand. If the substrates coalesce to form no monolayer, the test fails (i.e., adhesion is determined). The test passes if monolayers are formed and if at least 50%, at least 60%, at least 70%, at least 80% or at least 90% of the individual substrates are lifted from the surface of the formed monolayer without co-lifting (co-lifting) while the remaining substrates adhere to these individual substrates. Clearly, to demonstrate improved adhesion resistance, some adhesion had to be made to the substrate itself without coating. Thus, in order for the test to be meaningful, the uncoated substrate must fail the test.
In some cases, the coating compositions described herein can impart substantially unchanged optical properties to an applied substrate. In other words, the coating composition can provide a substantially transparent coating and/or the coating composition can provide a coating having a substantially unchanged color value of the underlying substrate. Such a substantially transparent and/or unchanged color value is recoverable after exposure to predetermined conditions for a predetermined length of time.
In some instances, the coating compositions described herein can reduce or prevent the exudation of certain components of the substrate or the exudation of the liquid filling in the gum after application. As a non-limiting example, an uncoated gummy bear is soaked in various oils upon exposure to predetermined conditions (e.g., H4 conditions), but coating the gummy bear with the coating composition described herein can reduce or eliminate the exudation of these oils. One test for this property is to weigh the substrate before exposure and the substrate after exposure. If the weight is reduced, one or more components of the substrate have left the substrate. Another test of this property is to remove the substrate from a container in which it is stored under predetermined conditions and analyze the contents of the container (using standard analytical techniques, such as chromatography and/or mass spectrometry) to determine whether any components of the substrate are "left behind" in the container. In certain instances, the coating compositions described herein can reduce the exudation of a component of a substrate by at least 10%, at least 20%, at least 25%, at least 30%, at least 40%, at least 50%, at least 60%, at least 70%, at least 75%, at least 80%, at least 85%, at least 90%, or at least 95%.
In some instances, the coating compositions described herein may improve resistance to melting and/or deformation at elevated temperatures. One test to determine these properties is to place the uncoated substrate (e.g., gelatin candy) and the coated substrate in an oven at an initial temperature (e.g., 30 ℃) with 1 hour interval and 5 ℃ temperature increase per hour. The uncoated gelatine candy started to soften at 40 ℃ and completely melted/deformed at 45 ℃. The coated gummy candy retains its original shape integrity at a temperature of at least 55 ℃ or 60 ℃.
Examples
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