Semiconductor device and method for manufacturing the same

文档序号:193959 发布日期:2021-11-02 浏览:77次 中文

阅读说明:本技术 半导体器件及其制造方法 (Semiconductor device and method for manufacturing the same ) 是由 杨丰诚 林孟汉 贾汉中 王圣祯 林仲德 于 2020-12-08 设计创作,主要内容包括:提供了一种半导体器件及其制造方法。在实施例中,通过在不同且独立的工艺过程中制造字线的部分来形成存储器阵列,从而允许首先形成的部分在之后的工艺过程中用作结构支撑,否则将对结构造成不期望的损坏。(A semiconductor device and a method of manufacturing the same are provided. In an embodiment, the memory array is formed by fabricating portions of the word lines in different and independent processes, allowing the first-formed portions to serve as structural support during later processes that would otherwise cause undesired damage to the structure.)

1. A method of manufacturing a semiconductor device, the method comprising:

etching a first trench in a multilayer stack, the multilayer stack comprising alternating dielectric layers and sacrificial layers;

depositing a first conductive material within the first trench;

filling the remaining portion of the first trench with a first dielectric material;

etching a second trench in the multilayer stack after filling the remaining portion of the first trench;

depositing a second conductive material within the second trench;

filling the remaining portion of the second trench with a second dielectric material;

etching the first conductive material and the second conductive material; and

after etching the first and second conductive materials, a channel material is deposited in the first trench.

2. The method of claim 1, further comprising:

planarizing the second dielectric material with portions of the dielectric layer after filling the remaining portions of the second trench; and

removing the portion of the dielectric layer prior to etching the first conductive material.

3. The method of claim 2, wherein removing the portion of the dielectric layer forms an "H" shaped structure.

4. The method of claim 1, wherein the first conductive material comprises a first adhesive layer, and wherein depositing the second conductive material deposits a second adhesive layer in physical contact with the first adhesive layer.

5. The method of claim 1, further comprising recessing the sacrificial layer prior to depositing the first conductive material.

6. The method of claim 1, further comprising planarizing the first dielectric material and the first conductive material prior to etching the second trench.

7. The method of claim 1, further comprising depositing a ferroelectric material in the first trench.

8. A method of manufacturing a semiconductor device, the method comprising:

forming an alternating stack of a first dielectric material and a sacrificial material;

forming a first portion of a first word line within the alternating stack, the forming the first portion of the first word line comprising:

etching a first trench in the alternating stack;

forming a first groove by recessing a first portion of the sacrificial material within the first trench;

depositing a first conductive material in the first recess; and

depositing a second dielectric material to fill the remaining portion of the first trench; and

forming a second portion of the first word line in the alternating stack, the forming the second portion of the first word line comprising:

etching a second trench in the alternating stack;

forming a second recess by removing a second portion of the sacrificial material exposed within the second trench;

depositing a second conductive material in the second recess; and

depositing a third dielectric material to fill the remaining portion of the second trench.

9. The method of claim 8, further comprising removing a top layer of the first dielectric material after depositing the third dielectric material.

10. A semiconductor device, comprising:

a ferroelectric material extending away from the substrate;

a channel material on a first side of the ferroelectric material;

a first dielectric material extending away from a second side of the ferroelectric material opposite the first side;

a second dielectric material extending away from the second side of the ferroelectric material;

a first conductive material extending away from the second side of the ferroelectric material between the first and second dielectric materials, the first conductive material comprising a first bulk material and a first adhesive layer; and

a second conductive material, keep away from first dielectric material with between the second dielectric material first conductive material extends, second conductive material includes second bulk material and second viscose layer, the second viscose layer with first viscose layer physical contact.

Technical Field

Embodiments of the present application relate to a semiconductor device and a method of manufacturing the same.

Background

Semiconductor memories are used in integrated circuits for electronic applications including radios, televisions, cell phones, and personal computing devices. Semiconductor memories include two main categories. One is a volatile memory; the other is a non-volatile memory. Volatile memory includes Random Access Memory (RAM), which can be further divided into two subcategories, Static Random Access Memory (SRAM) and Dynamic Random Access Memory (DRAM). Both SRAM and DRAM are volatile because they lose stored information when power is removed.

On the other hand, the nonvolatile memory may store data thereon. One type of nonvolatile semiconductor memory is ferroelectric random access memory (FeRAM or FRAM). Advantages of FeRAM include its faster write/read speed and smaller size.

Disclosure of Invention

Some embodiments of the present application provide a method of manufacturing a semiconductor device, the method comprising: etching a first trench in a multilayer stack, the multilayer stack comprising alternating dielectric layers and sacrificial layers; depositing a first conductive material within the first trench; filling the remaining portion of the first trench with a first dielectric material; etching a second trench in the multilayer stack after filling the remaining portion of the first trench; depositing a second conductive material within the second trench; filling the remaining portion of the second trench with a second dielectric material; etching the first conductive material and the second conductive material; and depositing a channel material in the first trench after etching the first and second conductive materials.

Further embodiments of the present application provide a method of manufacturing a semiconductor device, the method including: forming an alternating stack of a first dielectric material and a sacrificial material; forming a first portion of a first word line within the alternating stack, the forming the first portion of the first word line comprising: etching a first trench in the alternating stack; forming a first groove by recessing a first portion of the sacrificial material within the first trench; depositing a first conductive material in the first recess; and depositing a second dielectric material to fill the remaining portion of the first trench; and forming a second portion of the first word line in the alternating stack, the forming the second portion of the first word line comprising: etching a second trench in the alternating stack; forming a second recess by removing a second portion of the sacrificial material exposed within the second trench; depositing a second conductive material in the second recess; and depositing a third dielectric material to fill the remaining portion of the second trench.

Still further embodiments of the present application provide a semiconductor device including: a ferroelectric material extending away from the substrate; a channel material on a first side of the ferroelectric material; a first dielectric material extending away from a second side of the ferroelectric material opposite the first side; a second dielectric material extending away from the second side of the ferroelectric material; a first conductive material extending away from the second side of the ferroelectric material between the first and second dielectric materials, the first conductive material comprising a first bulk material and a first adhesive layer; and a second conductive material, which is far away from the first dielectric material and extends from the first conductive material between the second dielectric material, wherein the second conductive material comprises a second block material and a second adhesive layer, and the second adhesive layer is in physical contact with the first adhesive layer.

Drawings

Aspects of the invention are best understood from the following detailed description when read with the accompanying drawing figures. It should be noted that, in accordance with standard practice in the industry, various components are not drawn to scale. In fact, the dimensions of the various elements may be arbitrarily increased or decreased for clarity of discussion.

FIG. 1 is a block diagram of a random access memory according to some embodiments.

Fig. 2A and 2B are various views of a memory array according to some embodiments.

Figures 3A-15B are various views of intermediate stages in the manufacture of a memory array, according to some embodiments.

Fig. 16A and 16B are various views of a memory array according to some embodiments.

Fig. 17A and 17B are various views of a memory array according to some embodiments.

18A and 18B are various views of a memory array according to some embodiments.

Fig. 19A-19B are various views of intermediate stages in the manufacture of a memory array, according to some embodiments.

Fig. 20A-22B are various views of intermediate stages in the manufacture of a memory array, according to some embodiments.

Detailed Description

The following disclosure provides many different embodiments, or examples, for implementing different features of the invention. Specific examples of components and arrangements are described below to simplify the present disclosure. These are, of course, merely examples and are not intended to limit the invention. For example, in the following description, forming a first feature over or on a second feature may include embodiments in which the first and second features are formed in direct contact, and may also include embodiments in which additional features may be formed between the first and second features, such that the first and second features may not be in direct contact. Moreover, the present disclosure may repeat reference numerals and/or characters in the various examples. This repetition is for the purpose of simplicity and clarity and does not in itself dictate a relationship between the various embodiments and/or configurations discussed.

Also, spatially relative terms, such as "below …," "below …," "lower," "above …," "upper," and the like, may be used herein for ease of description to describe one element or component's relationship to another (or other) element or component as illustrated. Spatially relative terms are intended to encompass different orientations of the device in use or operation in addition to the orientation depicted in the figures. The device may be otherwise oriented (rotated 90 degrees or at other orientations) and the spatially relative descriptors used herein interpreted accordingly.

According to various embodiments, the word lines of the memory array are formed by a multiple patterning process, wherein a first portion of the word lines and a first subset of the transistors of the memory array are formed in a first patterning process, and wherein a second portion of the word lines and a second subset of the transistors of the memory array are subsequently formed in a second patterning process. Thus, the aspect ratio of the columns of the memory array can be increased while avoiding twisting or collapse of the features during formation.

FIG. 1 is a block diagram of a random access memory 50 according to some embodiments. The random access memory 50 includes a memory array 52, a row decoder 54, and a column decoder 56. Each of memory array 52, row decoder 54, and column decoder 56 may be part of the same semiconductor die or may be part of different semiconductor dies. For example, memory array 52 may be part of a first semiconductor die, while row decoder 54 and column decoder 56 may be part of a second semiconductor die.

Memory array 52 includes memory cells 58, word lines 62, and bit lines 64. The memory cells 58 are arranged in rows and columns. Word line 62 and bit line 64 are electrically connected to memory cell 58. Word lines 62 are conductive lines that extend along rows of memory cells 58. Bit line 64 is a conductive line that extends along a column of memory cells 58.

The row decoder 54 may be, for example, a static Complementary Metal Oxide Semiconductor (CMOS) decoder, a pseudo N-type metal oxide semiconductor (NMOS) decoder, or the like. During operation, row decoder 54 selects a desired memory cell 58 in a row of memory array 52 by activating the word line 62 of the row. The column decoder 56 may be, for example, a static CMOS decoder, a pseudo NMOS decoder, etc., and may include write drivers, sense amplifiers, combinations thereof, etc. During operation, column decoder 56 selects a bit line 64 for a desired memory cell 58 from a column of memory array 52 in a selected row and uses bit line 64 to read data from or write data to the selected memory cell 58.

Fig. 2A and 2B are various views of a memory array 52 according to some embodiments. Fig. 2A is a circuit diagram of the memory array 52. Fig. 2B is a three-dimensional view of a portion of memory array 52.

The memory array 52 is a flash memory array such as a NOR gate (NOR) flash memory array; high speed memory arrays such as DRAM or SRAM; nonvolatile memories such as resistive ram (rram) or magnetic ram (mram), and the like. Each memory cell 58 is a flash memory cell that includes a Thin Film Transistor (TFT) 68. The gate of each TFT 68 is electrically connected to a respective word line 62, a first source/drain region of each TFT 68 is electrically connected to a respective bit line 64, and a second source/drain region of the TFT 68 is electrically connected to a respective source line 66 (which is electrically grounded). Memory cells 58 in the same row of memory array 52 share a common word line 62, while memory cells in the same column of memory array 52 share a common bit line 64 and a common source line 66.

The memory array 52 includes multiple arrangements of conductive lines (e.g., word lines 62), with a dielectric layer 72 between adjacent ones of the word lines 62. Word lines 62 are in a first direction D parallel to the major surface of the underlying substrate1An upper extension (not shown in fig. 2B, but discussed in more detail below with reference to fig. 3A-21B). The word lines 62 may have a staircase arrangement such that the lower word lines 62 are longer than the upper word lines 62 and extend laterally beyond the ends of the upper word lines 62. For example, in FIG. 2B, multiple stacked layers of word lines 62 are shown, with the topmost word line 62A being the shortest line and the bottommost word line 62B being the longest line. The length of the respective word line 62 increases in a direction extending toward the underlying substrate. In this manner, a portion of each word line 62 may be accessed from above the memory array 52So that a conductive contact can be formed to the exposed portion of each word line 62.

The memory array 52 also includes multiple arrangements of conductive lines, such as bit lines 64 and source lines 66. The bit line 64 and the source line 66 are perpendicular to a first direction D1And a second direction D of the main surface of the underlying substrate2And an upper extension. A dielectric layer 74 is disposed between and separates adjacent ones of the bit line 64 and source line 66. The boundaries of each memory cell 58 are defined by pairs of bit lines 64 and source lines 66 and intersecting word lines 62. Dielectric plugs 76 are disposed between and isolate adjacent pairs of bit lines 64 and source lines 66. Although fig. 2A and 2B show a particular position of the bit line 64 relative to the source line 66, it should be noted that in other embodiments, the position of the bit line 64 and the source line 66 may be reversed.

The memory array 52 also includes ferroelectric stripes 84 and semiconductor stripes 82. The ferroelectric strip 84 contacts the word line 62. Semiconductor strips 82 are disposed between ferroelectric strips 84 and dielectric layer 74.

The semiconductor strips 82 provide channel regions for the TFTs 68 of the memory cells 58. For example, when an appropriate voltage (e.g., above the corresponding threshold voltage (V) of the corresponding TFT 68) is applied through the corresponding word line 62th) In turn, the area where the semiconductor strip 82 intersects the word line 62 may allow current to flow from the bit line 64 to the source line 66 (e.g., at D)1In the direction).

Ferroelectric strips 84 are the data storage layers that can be polarized in one of two different directions by applying an appropriate voltage difference across ferroelectric strips 84. Depending on the polarization direction of a particular region of the ferroelectric strip 84, the threshold voltage of the corresponding TFT 68 changes and a digital value (e.g., 0 or 1) may be stored. For example, when the region of the ferroelectric strip 84 has a first electrical polarization direction, the corresponding TFT 68 may have a relatively low threshold voltage, and when the region of the ferroelectric strip 84 has a second electrical polarization direction, the corresponding TFT 68 may have a relatively high threshold voltage. The difference between the two threshold voltages may be referred to as a threshold voltage shift. A larger threshold voltage shift may make it easier (e.g., less prone to error) to read the digital value stored in the corresponding memory cell 58. Accordingly, the memory array 52 may also be referred to as a ferroelectric random access memory (FERAM) array.

To perform a write operation on a particular memory cell 58, a write voltage may be applied to the area of ferroelectric stripe 84 corresponding to memory cell 58. For example, the write voltage may be applied by applying appropriate voltages to the word line 62, bit line 64, and source line 66 corresponding to the memory cell 58. The direction of polarization of a region of the ferroelectric strip 84 can be changed by applying a write voltage across the region of the ferroelectric strip 84. Accordingly, the respective threshold voltage of the respective TFT 68 may be switched from a low threshold voltage to a high threshold voltage (or vice versa) such that a digital value may be stored in the memory cell 58. Because word lines 62 and bit lines 64 intersect in memory array 52, a single memory cell 58 can be selected and written.

To perform a read operation on a particular memory cell 58, a read voltage (a voltage between the low and high threshold voltages) is applied to the word line 62 corresponding to the memory cell 58. The TFT 68 of the memory cell 58 may or may not be turned on depending on the polarization direction of the corresponding region of the ferroelectric strip 84. Thus, bit line 64 may or may not discharge (e.g., ground) through source line 66, thereby determining the digital value stored in memory cell 58. Because word lines 62 and bit lines 64 intersect in memory array 52, a single memory cell 58 may be selected and read from a single memory cell 58.

Fig. 3A-15B are various views of intermediate stages in the manufacture of memory array 52, according to some embodiments. A portion of a memory array 52 is shown. For clarity of illustration, some features are not shown, such as a staircase arrangement of word lines (see fig. 2B). Fig. 3A, 4A, 5A, 6A, 7A, 8A, 9A, 10A, 11A, 12A, 13A, 14A, and 15A are three-dimensional views of the memory array 52. Fig. 3B, 4B, 5B, 6B, 7B, 8B, 9B, 10B, 11B, 12B, 13B, 14B, and 15B are sectional views shown along a reference section B-B in fig. 13A.

In fig. 3A and 3B, a substrate 102 is provided. The substrate 102 may be a semiconductor substrate, such as a bulk semiconductor, a semiconductor-on-insulator (SOI) substrate, or the like, which may be doped (e.g., doped with a dopant of p-type or n-type) or undoped. The substrate 102 may be a wafer, such as a silicon wafer. In general, an SOI substrate is a layer of semiconductor material formed on an insulator layer. The insulator layer may be, for example, a Buried Oxide (BOX) layer, a silicon oxide layer, or the like. The insulator layer is disposed on a substrate, typically a silicon or glass substrate. Other substrates, such as multilayer or gradient substrates, may also be used. In some embodiments, the semiconductor material of the substrate 102 may include silicon; germanium; a compound semiconductor containing silicon carbide, gallium arsenide, gallium phosphide, indium arsenide, and/or indium antimonide; an alloy semiconductor containing silicon germanium, gallium arsenide phosphide, aluminum indium arsenide, aluminum gallium arsenide, gallium indium phosphide, and/or gallium indium arsenide phosphide; or a combination thereof. The substrate 102 may comprise a dielectric material. For example, the substrate 102 may be a dielectric substrate or may include a dielectric layer on a semiconductor substrate. Acceptable dielectric materials for the dielectric substrate include oxides such as silicon oxide; nitrides such as silicon nitride and the like; carbides such as silicon carbide and the like; and the like; or combinations thereof such as silicon oxynitride, silicon oxycarbide, silicon carbonitride, and the like. In some embodiments, substrate 102 is formed of silicon carbide.

A multilayer stack 104 is formed over the substrate 102. The multilayer stack 104 includes alternating first and second dielectric layers 104A and 104B. The first dielectric layer 104A is formed of a first dielectric material and the second dielectric layer 104B is formed of a second dielectric material. The dielectric materials may each be selected from candidate dielectric materials for the substrate 102. In some particular embodiments, the first dielectric layer 104A may be any suitable material as long as the material of the first dielectric layer 104A is etched at a slower etch rate than the material of the second dielectric layer 104B in subsequent processing (described further below) during removal of the material of the second dielectric layer 104B.

In the illustrated embodiment, the multilayer stack 104 includes five first dielectric layers 104A and four second dielectric layers 104B. It should be noted that the multilayer stack 104 may include any number of first dielectric layers 104A and any number of second dielectric layers 104B.

The multilayer stack 104 will be patterned in subsequent processing. As such, the dielectric material of the first dielectric layer 104A and the dielectric material of the second dielectric layer 104B both have a high etch selectivity compared to the etching of the substrate 102. The patterned first dielectric layer 104A will be used to isolate the subsequently formed TFTs. The patterned second dielectric layer 104B is a sacrificial layer (or dummy layer) which will be removed in a subsequent process and replaced by a word line of the TFT. As such, the second dielectric material of the second dielectric layer 104B also has a high etch selectivity compared to the etching of the first dielectric material of the first dielectric layer 104A. In embodiments where the substrate 102 is formed of silicon carbide, the first dielectric layer 104A may be formed of an oxide, such as silicon oxide, and the second dielectric layer 104B may be formed of a nitride, such as silicon nitride. Other combinations of dielectric materials with acceptable etch selectivity with respect to each other may also be used.

Each layer of multilayer stack 104 can be formed by an acceptable deposition process, such as Chemical Vapor Deposition (CVD), Atomic Layer Deposition (ALD), and the like. The thickness of each layer may range from about 15nm to about 90 nm. In some embodiments, the first dielectric layer 104A is formed to a different thickness than the second dielectric layer 104B. For example, the first dielectric layer 104A may be formed to have a first thickness t1And the second dielectric layer 104B may be formed to have a second thickness T2A second thickness T2Is greater than the first thickness T1Small [ big/small ]]From about 0% to about 100%. Further, multilayer stack 104 can have any suitable number of pairs of first dielectric layer 104A and second dielectric layer 104B, such as more than 20 pairs, and multilayer stack 104 can have an overall height H in a range of about 1000nm to about 10000nm (such as about 2000nm)1

As will be discussed in more detail below, fig. 4A-14B illustrate a process in which trenches are patterned in multilayer stack 104 and TFTs are formed in the trenches. Specifically, the TFT is formed using a multiple patterning process. The multiple patterning process may be a double patterning process, a quadruple patterning process, or the like. Fig. 4A to 14B illustrate a double patterning process. In the double patterning process, a first trench 106 is patterned in the multilayer stack 104 using a first etching process (see fig. 4A and 4B), and a first subset of elements of the TFT are formed in the first trench 106. Then, a second trench 120 is patterned in the multilayer stack 104 using a second etching process (see fig. 8A and 8B), and a second subset of TFTs is formed in the second trench 120. Forming TFTs using multiple patterning processes allows for each patterning process to be performed at a low pattern density, which may help reduce defects while still allowing the memory array 52 to have sufficient memory cell density, while also helping to prevent the problem of the aspect ratio becoming too high and causing structural instability.

In fig. 4A and 4B, a first trench 106 is formed in the multilayer stack 104. In the illustrated embodiment, the first trench 106 extends through the multilayer stack 104 and exposes the substrate 102. In another embodiment, the first trench 106 extends through some, but not all, of the layers of the multilayer stack 104. The first trench 106 may be formed using acceptable photolithography and etching techniques, such as with an etch process that is selective to the multilayer stack 104 (e.g., a process that etches the dielectric material of the first dielectric layer 104A and the dielectric material of the second dielectric layer 104B at a faster rate than the material of the substrate 102). The etching may be any acceptable etching process, such as reactive ion etching (PIE), neutral atomic beam etching (NBE), or the like, or a combination thereof. The etching may be anisotropic. In embodiments where the substrate 102 is formed of silicon carbide, the first dielectric layer 104A is formed of silicon oxide, and the second dielectric layer 104B is formed of silicon nitride, the first trench 106 may be formed by using hydrogen (H) with hydrogen2) Or oxygen (O)2) Gas-mixed fluorine-based gases (e.g. C)4F6) And dry etching.

A portion of the multilayer stack 104 is disposed between each pair of first trenches 106. Each portion of multilayer stack 104 may have a width W that is about three times greater than the desired final width of the word line1Such as in the range of about 50nm to about 500nm (such as about 240nm), and has a height H as described with reference to fig. 3A and 3B1. Moreover, each portion of the multilayer stack 104 is separated by a separation distance S1The separation distance S1May be in the range of about 50nm to about 200nm, such as about 80nm. The Aspect Ratio (AR) of each portion of the multilayer stack 104 is the height H1The ratio to the width of the narrowest part of the portion of multilayer stack 104, which is the width W in that processing step1. According to some embodiments, when forming the first trench 106, the aspect ratio of each portion of the multilayer stack 104 is in a range of about 5 to about 15. Forming each portion of multilayer stack 104 with an aspect ratio less than about 5 may not allow memory array 52 to have a sufficient memory cell density. Forming each portion of the multilayer stack 104 with an aspect ratio greater than about 15 may cause distortion or collapse of the multilayer stack 104 during subsequent processing.

In fig. 5A and 5B, the first trench 106 is expanded to form a first sidewall recess 110. Specifically, the portion of the sidewalls of the second dielectric layer 104B exposed by the first trench 106 is recessed to form a first sidewall recess 110. Although the sidewalls of the second dielectric layer 104B are shown as being linear, the sidewalls may be concave or convex. The first sidewall recess 110 may be formed by an acceptable etch process, such as an etch process that is selective to the material of the second dielectric layer 104B (e.g., a process that selectively etches the material of the second dielectric layer 104B at a faster rate than the material of the first dielectric layer 104A and the material of the substrate 102). The etching may be isotropic. In embodiments where the substrate 102 is formed of silicon carbide, the first dielectric layer 104A is formed of silicon oxide, and the second dielectric layer 104B is formed of silicon nitride, the first trench 106 may be formed by using phosphoric acid (H)3PO4) Is used to spread. However, any other suitable etching process, such as dry selective etching, may also be employed.

After formation, the first sidewall recess 110 has a depth D that extends beyond the sidewalls of the first dielectric layer 104A3. To a desired depth D in the first sidewall recess 1103Thereafter, the etching of the first sidewall recess 110 may be stopped using a timed etch process. For example, when phosphoric acid is used to etch the second dielectric layer 104B, the etch may be performed for a time sufficient to cause the first sidewall recesses 110 to have a depth D in the range of about 10nm to about 60nm (such as about 40nm)3. Forming a first sidewall recess 110The width of the second dielectric layer 104B is reduced. Continuing with the previous example, after etching, the second dielectric layer 104B may have a width W in the range of about 50nm to about 450nm (such as about 160nm)2. As described above, the Aspect Ratio (AR) of each portion of the multilayer stack 104 is the height H1The ratio to the width of the narrowest part of the portion of multilayer stack 104, which is the width W in that processing step2. Thus, forming the first sidewall recesses 110 increases the aspect ratio of each portion of the multilayer stack 104. According to some embodiments, the aspect ratio of each portion of the multilayer stack 104 remains within the range described above, e.g., within the range of about 5 to about 15, after the first sidewall recesses 110 are formed. Thus, the advantages of such aspect ratios (as described above) may still be realized.

In fig. 6A and 6B, the first conductive part 112A is formed in the first sidewall recess 110, thus completing the process of replacing the first portion of the second dielectric layer 104B. First conductive features 112A may each include one or more layers, such as glue layers, barrier layers, diffusion layers, and fill layers, among others. In some embodiments, first conductive components 112A each include an adhesive layer 112AGAnd a main layer 112AMAlthough in other embodiments adhesive layer 112AGMay be omitted. Each adhesive layer 112AGAlong the corresponding main layer 112A located in the first sidewall groove 110MExtend from three sides (e.g., the top surface, the sidewalls, and the bottom surface) of the material. Adhesive layer 112AGFormed of a first conductive material such as titanium, titanium nitride, tantalum nitride, molybdenum, ruthenium, rhodium, hafnium, iridium, niobium, rhenium, tungsten, combinations thereof, oxides thereof, and the like. Main layer 112AMMay be formed of a second conductive material such as a metal, e.g., tungsten, cobalt, aluminum, nickel, copper, silver, gold, molybdenum, ruthenium, molybdenum nitride, alloys thereof, and the like. Adhesive layer 112AGIs a material having good adhesion to the material of the first dielectric layer 104A, and the main layer 112AMIs made of a material of a counter adhesive layer 112AGThe material of (2) has good adhesion. In embodiments where the first dielectric layer 104A is formed of an oxide, such as silicon oxide, glue is usedLayer 112AGMay be formed of titanium nitride, the main layer 112AMMay be formed of tungsten. Adhesive layer 112AGAnd a main layer 112AMEach may be formed by an acceptable deposition process such as Chemical Vapor Deposition (CVD), Atomic Layer Deposition (ALD), and the like.

In fig. 7A and 7B, the remaining portion of the first trench 106 is filled and/or overfilled with the first dielectric material 108 without etching back the material of the first conductive feature 112A. In an embodiment, the first dielectric material 108 may be a material deposited using a chemical vapor deposition process, an atomic layer deposition process, a physical vapor deposition process, combinations thereof, or the like, such as silicon oxide, silicon nitride, silicon oxynitride, combinations thereof, or the like. In some embodiments, the first dielectric material 108 may be a similar material to that of the first dielectric layer 104A, although in other embodiments the material may be different. Any suitable material and deposition method may be used.

Once the dielectric material 108 has been deposited to fill and/or overfill the first trench 106, the first dielectric material 108 may be planarized to remove excess material outside the first trench 106. In one embodiment, the first dielectric material 108 may be planarized using, for example, a Chemical Mechanical Planarization (CMP) process. However, any suitable planarization process, such as a grinding process, may also be employed.

In one embodiment, the first dielectric material 108 and the first dielectric layer 104A are planarized to be planar. As such, the portion of the first conductive feature 112A outside the first trench 106 is also removed and planarized to be planar with the first dielectric layer 104A and the first dielectric material 108. As such, the planar first surface includes the first dielectric layer 104A, the first conductive feature 112A, and the first dielectric material 108.

In fig. 8A and 8B, a second trench 120 is formed in the multilayer stack 104. In the illustrated embodiment, the second trench 120 extends through the multilayer stack 104 and exposes the substrate 102. In another embodiment, second trench 120 extends through some, but not all, of the layers in multilayer stack 104. The second trench 120 may be formed using acceptable photolithography and etching techniques, such as with an etch process that is selective to the multilayer stack 104 (e.g., a process that etches the dielectric material of the first dielectric layer 104A and the dielectric material of the second dielectric layer 104B at a faster rate than the material of the substrate 102). The etch may be any acceptable etch process and, in some embodiments, may be similar to the etch used to form the first trench 106 described with reference to fig. 4A and 4B.

A portion of multilayer stack 104 is disposed between each second trench 120 and each first trench 106. Each portion of multilayer stack 104 can have a width W in the range of about 50nm to about 500nm3And has a height H as described with reference to FIGS. 3A and 3B1. Moreover, each portion of the multilayer stack 104 is separated by a separation distance S2The separation distance S2And may range from about 50nm to about 200 nm. The Aspect Ratio (AR) of each portion of the multilayer stack 104 is the height H1The ratio to the width of the narrowest part of the portion of multilayer stack 104, which is the width W in that processing step3. According to some embodiments, when forming second trench 120, the aspect ratio of each portion of multilayer stack 104 is in a range of about 5 to about 15. Forming each portion of multilayer stack 104 with an aspect ratio less than about 5 may not allow memory array 52 to have a sufficient memory cell density. Forming each portion of the multilayer stack 104 with an aspect ratio greater than about 15 may cause distortion or collapse of the multilayer stack 104 during subsequent processing.

In fig. 9A and 9B, the second trench 120 is expanded to form a second sidewall recess 124. Specifically, the remaining portion of the second dielectric layer 104B is removed to form the second sidewall recesses 124. Thus, the second sidewall recess 124 exposes a portion of the first conductive component 112A, such as the adhesive layer 112AG. The second sidewall recesses 124 may be formed by an acceptable etch process, such as an etch process that is selective to the material of the second dielectric layer 104B (e.g., a process that selectively etches the material of the second dielectric layer 104B at a faster rate than the material of the first dielectric layer 104A and the material of the substrate 102). The etch may be any acceptable etch process and, in some embodiments, may be similar toThe etch used to form the first sidewall recess 110 described with reference to fig. 5A and 5B. After formation, the second sidewall recess 124 has a depth D that extends beyond the sidewalls of the first dielectric layer 104A4. In some embodiments, depth D4Depth D similar to that described with reference to FIGS. 5A and 5B3. In another embodiment, the depth D4Different (greater or less) than the depth D described with reference to fig. 5A and 5B3

However, by forming the first conductive feature 112A and the second dielectric material 122 prior to etching the second trench 120 and forming the second sidewall recess 124, the first conductive feature 112A is present during the etching of the second trench 120 and the second sidewall recess 124. As such, the unremoved first conductive feature 112A and the unremoved second dielectric material 122 may act as pillars to provide structural support during high stress relief. The additional support allows for avoiding problems that may occur during the removal process (e.g., word line wiggling or word line collapse).

In fig. 10A and 10B, the first conductive part 112A is formed in the second sidewall recess 124, thus completing the process of replacing the second portion of the second dielectric layer 104B. The second conductive features 112B may be formed of a material selected from the same set of candidate materials for the first conductive features 112A, and may be formed using a method selected from the same set of candidate methods for forming the material of the first conductive features 112A. First and second conductive components 112A and 112B may be formed of the same material, or may comprise different materials. In some embodiments, second conductive components 112A each include an adhesive layer 112BGAnd a main layer 112BMAlthough in other embodiments adhesive layer 112BGMay be omitted. Adhesive layer 112B of second conductive member 112BGAnd a main layer 112BMMay have adhesive layers 112A with the first conductive members 112A, respectivelyGAnd a main layer 112AMSimilar thickness. In some embodiments, adhesive layer 112AGAnd adhesive layer 112BGFormed of a similar material, in this case adhesive layer 112AGAnd adhesive layer 112BGCan fuse during formation such that there is no discernable interface between them. In addition toIn one embodiment (discussed further below), adhesive layer 112AGAnd adhesive layer 112BGFormed of a different material, in this case adhesive layer 112AGAnd adhesive layer 112BGIt is not possible to fuse during formation so that there is a discernible interface between them.

The first and second conductive features 112A and 112B are collectively referred to as word lines 112 of the memory array 52. Adjacent pairs of first and second conductive members 112A and 112B are in physical contact with each other and are electrically coupled to each other. Thus, each pair of first and second conductive features 112A and 112B functions as a single word line 112.

Fig. 10A to 10B also show: once the second conductive component 112B has been deposited into the second trench 120, a second dielectric material 122 may be deposited over the second conductive component 112B in order to fill and/or overfill the remaining portions of the second trench 120 prior to any etch-back of the second conductive component 112B. In one embodiment, the second dielectric material 122 may be a material similar to the material of the first dielectric material 108 deposited within the first trench 106, and may also be similar to the first dielectric layer 104A, and may be deposited in a manner similar to the material of the first dielectric material 108. However, any suitable material and any suitable deposition method may be employed.

Once the dielectric material 122 has been deposited to fill and/or overfill the first trench 120, the second dielectric material 122 may be planarized to remove excess material outside the second trench 120. In an embodiment, the second dielectric material 122 may be planarized using, for example, a chemical mechanical planarization process, although any suitable process may be employed. In addition, the planarization process may also remove any material of the second conductive features 112B outside the second trenches 120, thereby forming a planar surface including the first dielectric layer 104A, the first conductive features 112A, the second conductive features 112B, the first dielectric material 108, and the second dielectric material 122.

Fig. 11A to 11B illustrate removal of: the top layer of the first dielectric layer 104A (the exposed first dielectric layer 104A) and the first dielectric material 108 within the first trench 106 and the second dielectric material 122 within the second trench 120. In embodiments, the removal may be performed using one or more chemical dry etching processes, wet etching processes, combinations thereof, and the like. For example, in embodiments where the material of the first dielectric layer 104A is the same as the material of the first dielectric material 108 and the second dielectric material 122, a single etch process using an etchant that is selective to the material of the first dielectric layer 104A, the first dielectric material 108, and the second dielectric material 122 may be used. In other embodiments where the materials of the first dielectric layer 104A, the first dielectric material 108, and the second dielectric material 122 are different, multiple etching processes may be employed in order to sequentially remove these different materials. Any suitable removal process may be employed.

In addition, as best seen in FIG. 11B, removing the topmost first dielectric layer 104A leaves a first conductive component 112A and a second conductive component 112B (which have been fused into one single conductive structure) having a "U" shaped configuration with sidewalls that include the first and second conductive components 112A and 112B. In this manner, the remaining portion of the first conductive component 112A and the remaining portion of the second conductive component 112B form an "H" shaped configuration (highlighted in FIG. 11B by the dashed circle labeled 126) with the adhesive layer 112Ag and the adhesive layer 112Bg between the remaining portion of the first conductive component 112A and the remaining portion of the second conductive component 112B.

Fig. 12A-12B illustrate an etch back process to remove excess portions of the first conductive feature 112A and the second conductive feature 112B and expose the underlying first dielectric layer 104A. In an embodiment, the etch back process may be performed using, for example, an anisotropic etch process, such as reactive ion etching. However, any suitable etching process may be employed.

In an embodiment, an etch-back process is performed until the material of the first conductive component 112A and the material of the second conductive component 112B that are located within the first trench 106 and the second trench 120 but not in the first sidewall recesses 110 and the second sidewall recesses 124 and that are not covered by the next first dielectric layer 104A have been removed. As such, the remaining material of first conductive features 112A and the remaining material of second conductive features 112B have a similar width (e.g., 80nm) as the remaining portions of second dielectric layer 104B. However, any suitable dimensions may be used.

Fig. 13A to 13B show a TFT thin film stack formed in the first trench 106 and the second trench 120. Specifically, two ferroelectric strips 114, a semiconductor strip 116, and a dielectric layer 118 are formed in each first trench 106 and each second trench 120. In this embodiment, no other layer is formed in the first trench 106 and the second trench 120. In another embodiment (discussed further below), additional layers are formed in the first trench 106 and the second trench 120.

The ferroelectric stripe 114 used to store digital values is a data storage stripe formed of an acceptable ferroelectric material, such as hafnium zirconium oxide (HfZrO); zirconium oxide (ZrO); hafnium oxide (HfO) doped with lanthanum (La), silicon (Si), aluminum (Al), or the like; undoped hafnium oxide (HfO), and the like. The material of the ferroelectric strip 114 may be formed by an acceptable deposition process such as ALD, CVD, Physical Vapor Deposition (PVD), and the like.

The semiconductor strips 116 used to provide the channel regions of the TFTs are formed of acceptable semiconductor materials, such as Indium Gallium Zinc Oxide (IGZO), Indium Tin Oxide (ITO), Indium Gallium Zinc Tin Oxide (IGZTO), zinc oxide (ZnO), polysilicon, amorphous silicon, and the like. The material of the semiconductor strips 116 may be formed by an acceptable deposition process such as ALD, CVD, PVD, and the like.

The dielectric layer 118 is formed of a dielectric material. Acceptable dielectric materials include oxides such as silicon oxide or aluminum oxide; nitrides such as silicon nitride and the like; carbides such as silicon carbide; and the like; or combinations thereof such as silicon oxynitride, silicon oxycarbide, silicon carbonitride, and the like. The material of the dielectric layer 118 may be formed by an acceptable deposition process such as ALD, CVD, flowable CVD (fcvd), and the like.

The ferroelectric strips 114, semiconductor strips 116, and dielectric layer 118 may be formed by a combination of deposition, etching, and planarization. For example, a ferroelectric layer can be conformally deposited on multilayer stack 104 and in first trench 106 and second trench 120 (e.g., on sidewalls of first conductive feature 112A and sidewalls of first dielectric layer 104A). Then, a semiconductor layer can be conformally deposited on the ferroelectric layer. The semiconductor layer may then be anisotropically etched to remove horizontal portions of the semiconductor layer, thereby exposing the ferroelectric layer. A dielectric layer may then be conformally deposited on the remaining vertical portion of the semiconductor layer and on the exposed portion of the ferroelectric layer. A planarization process is then applied to the layers to remove excess material over the multilayer stack 104. The planarization process may be a Chemical Mechanical Polishing (CMP), an etch back process, a combination thereof, or the like. The portion of the ferroelectric layer, the portion of the semiconductor layer, and the portion of the dielectric layer remaining in the first trench 106 form a ferroelectric stripe 114, a semiconductor stripe 116, and a dielectric layer 118, respectively. The planarization process exposes multilayer stack 104 such that the top surface of multilayer stack 104, the top surface of ferroelectric strip 114, the top surface of semiconductor strip 116, and the top surface of dielectric layer 118 are coplanar (within process variations) after the planarization process.

In fig. 14A and 14B, dielectric plugs 132 are formed through the dielectric layer 118 and the semiconductor strips 116. The dielectric plugs 132 are spacer pillars to be disposed between adjacent TFTs and to physically and electrically separate the adjacent TFTs. In the illustrated embodiment, the dielectric plugs 132 do not extend through the ferroelectric strip 114. Different regions of the ferroelectric strip 114 can be individually polarized, so the ferroelectric strip 114 can be used to store values even if adjacent regions are not physically and electrically separated. In another embodiment, dielectric plugs 132 are also formed through ferroelectric strip 114. The dielectric plugs 132 extend further through the first dielectric layer 104A.

As an example of forming the dielectric plug 132, an opening of the dielectric plug 132 may be formed through the dielectric layer 118 and the semiconductor strip 116. These openings can be formed by using acceptable photolithography and etching techniques. One or more dielectric materials are then formed in these openings. Acceptable dielectric materials include oxides such as silicon oxide; nitrides such as silicon nitride and the like; carbides such as silicon carbide; and the like; or combinations thereof such as silicon oxynitride, silicon oxycarbide, silicon carbonitride, and the like. The dielectric material may be formed by an acceptable deposition process such as ALD, CVD, and the like. In some embodiments, silicon oxide or silicon nitride is deposited in these openings. A planarization process is then applied to the layers to remove excess dielectric material over the remaining topmost first dielectric layer 104A. The planarization process may be a Chemical Mechanical Polishing (CMP), an etch back process, a combination thereof, or the like. The remaining dielectric material forms dielectric plugs 132 in the openings.

Fig. 14A and 14B also show that bit lines 134 and source lines 136 formed through the dielectric layer 118 the bit lines 134 and source lines 136 extend further through the first dielectric layer 104A. The bit line 134 and source line 136 serve as source/drain regions of the TFT. The bit lines 134 and source lines 136 are conductive columns formed in pairs, with each semiconductor stripe 116 contacting a respective bit line 134 and a respective source line 136. Each TFT includes a bit line 134, a source line 136, a word line 112, and regions where the semiconductor strips 116 and ferroelectric strips 114 intersect the word line 112. Each dielectric plug 132 is disposed between a bit line 134 of a TFT and a source line 136 of another TFT. In other words, the bit line 134 and the source line 136 are disposed at opposite sides of each dielectric plug 132. Thus, each dielectric plug 132 physically and electrically separates adjacent TFTs.

As an example of forming the bit line 134 and the source line 136, openings for the bit line 134 and the source line 136 may be formed through the dielectric layer 118. These openings can be formed by using acceptable photolithography and etching techniques. Specifically, these openings are formed on opposite sides of the dielectric plug 132. One or more conductive materials, such as an adhesive layer and bulk conductive material, are then formed in these openings, acceptable conductive materials including metals such as tungsten, cobalt, aluminum, nickel, copper, silver, gold, alloys thereof, and the like. The conductive material may be formed by an acceptable deposition process such as ALD or CVD, an acceptable plating process such as electroplating or electroless plating, or the like. In some embodiments, tungsten is deposited in the opening. A planarization process is then applied to the layers to remove excess conductive material over the topmost first dielectric layer 104A. The planarization process may be a Chemical Mechanical Polishing (CMP), an etch back process, a combination thereof, or the like. The remaining conductive material forms bit lines 134 and source lines 136 in the openings.

In fig. 15A and 15B, an interconnect structure 140 is formed over the intermediate structure. For clarity of illustration, only some components of interconnect structure 140 are shown in fig. 15A. The interconnect structure 140 may include a metallization pattern 142, for example, in a dielectric material 144. The dielectric material 144 may include one or more dielectric layers, such as one or more layers of low dielectric constant (LK) or ultra low dielectric constant (ELK) dielectric material. Metallization pattern 142 may be metal interconnects (e.g., metal lines and vias) formed in one or more dielectric layers. The interconnect structure 140 may be formed by a damascene process, such as a single damascene process, a dual damascene process, and the like.

Metallization pattern 142 of interconnect structure 140 is electrically coupled to bit line 134 and source line 136. For example, metallization pattern 142 includes bit line interconnect 142B (which is electrically coupled to bit line 134) and source line interconnect 142S (which is electrically coupled to source line 136). Adjacent bit lines 134 are connected to different bit line interconnects 142B, which helps to avoid shorting of adjacent bit lines 134 when their common word line 112 is activated. Likewise, adjacent source lines 136 are connected to different source line interconnects 142S, which helps to avoid shorting of adjacent source lines 136 when common word lines 112 of these adjacent source lines 136 are activated.

In this embodiment, the bit lines 134 and the source lines 136 are formed in a staggered layout, with adjacent bit lines 134 and adjacent source lines 136 along the first direction D1(see fig. 2B) are laterally offset from each other. Thus, each word line 112 is disposed laterally between a dielectric plug 132 and a bit line 134 or between a dielectric plug 132 and a source line 136. The bit line interconnect 142B and the source line interconnect 142S are each in the second direction D2(see fig. 2B), for example, along columns of the memory array 52. Bit line interconnect 142B is connected to alternate ones of bit lines 134 along columns of memory array 52. Source line interconnect 142B is connected to alternate ones of source lines 136 along a column of memory array 52. Laterally offset bit lines 134 and source lines 136 eliminate the need for lateral interconnects along columns of memory array 52, thus allowing bit line interconnects 142B and source line interconnects 142S to be interconnect structures that may be present140 at the lowest level. In another embodiment (discussed below), the bit lines 134 and source lines 136 are not formed in a staggered layout, but rather lateral interconnects are implemented in the interconnect structure 140.

Fig. 16A and 16B are various views of a memory array 52 according to some other embodiments. A portion of a memory array 52 is shown. For clarity of illustration, some features are not shown, such as a staircase arrangement of word lines (see fig. 2B). Fig. 16A is a three-dimensional view of the memory array 52, and fig. 16B is a sectional view showing a section similar to the reference section B-B in fig. 13A.

In this embodiment, the ferroelectric stripe 114 is omitted and replaced by a plurality of dielectric layers 150, the plurality of dielectric layers 150 being data memory stripes, thereby turning the memory cells into flash-like storage elements, thereby permitting the creation of, for example, a NOR flash memory array. Specifically, a first dielectric layer 150A is formed on the substrate 102 and in contact with sidewalls of the word lines 112. A second dielectric layer 150B is formed on the first dielectric layer 150A. A third dielectric layer 150C is formed on the second dielectric layer 150B. The first dielectric layer 150A, the second dielectric layer 150B, and the third dielectric layer 150C are each formed of a dielectric material. Acceptable dielectric materials include oxides such as silicon oxide; nitrides such as silicon nitride and the like; carbides such as silicon carbide; and the like; or combinations thereof such as silicon oxynitride, silicon oxycarbide, silicon carbonitride, and the like. In some embodiments, the first and third dielectric layers 150A, 150C are formed of a first dielectric material (e.g., an oxide such as silicon oxide) and the second dielectric layer 150B is formed of a second, different dielectric material (e.g., a nitride such as silicon nitride). The dielectric material may be formed by an acceptable deposition process such as ALD, CVD, and the like. For example, the first dielectric layer 150A, the second dielectric layer 150B, and the third dielectric layer 150C may be formed by a combination of deposition, etching, and planarization in a manner similar to that described above with reference to the ferroelectric strip 114.

Fig. 17A and 17B are various views of a memory array 52 according to some other embodiments. A portion of a memory array 52 is shown. For clarity of illustration, some features are not shown, such as a staircase arrangement of word lines (see fig. 2B). Fig. 17A is a three-dimensional view of the memory array 52, and fig. 17B is a sectional view showing a section similar to the reference section B-B in fig. 13A.

In this embodiment, conductive strips 160 are formed between ferroelectric strips 114 and semiconductor strips 116. The formation of conductive strips 160 helps to avoid or reduce the formation of interlayer oxides on the ferroelectric strips 114 during the formation of the semiconductor strips 116. Avoiding or reducing the formation of interlayer oxide may increase the lifetime of the memory array 52.

Conductive strips 160 may be formed of a metal such as ruthenium, tungsten, titanium nitride, tantalum nitride, molybdenum, and the like. The conductive material of the conductive strip 160 may be formed by an acceptable deposition process such as ALD or CVD, an acceptable plating process such as electroplating or electroless plating, or the like. The thickness of conductive strip 160 may be in the range of about 1nm to about 20 nm. The conductive strips 160 may be formed in a similar manner as the semiconductor strips 116 and may be formed during the formation of the semiconductor strips 116. Dielectric plug 132 may (or may not) be formed through conductive strip 160.

Fig. 18A and 18B are various views of a memory array 52 according to some other embodiments. A portion of a memory array 52 is shown. For clarity of illustration, some features are not shown, such as a staircase arrangement of word lines (see fig. 2B). Fig. 18A is a three-dimensional view of the memory array 52, and fig. 18B is a sectional view showing a section similar to the reference section B-B in fig. 13A.

In this embodiment, adhesive layer 112AGAnd adhesive layer 112BGFormed of different materials to help reduce overall resistivity. For example, adhesive layer 112AGCan be formed of a first adhesive material (e.g., titanium nitride), adhesive layer 112BGMay be formed of a second glue material (e.g., tantalum nitride) having a different resistivity. Thus, the adhesive layer 112AGAnd adhesive layer 112BGMay not fuse during formation such that they are independent and distinct from each other.

Fig. 19A and 19B are various views of a memory array 52 according to some other embodiments. A portion of a memory array 52 is shown. For clarity of illustration, some features are not shown, such as a staircase arrangement of word lines (see fig. 2B). Fig. 19A is a three-dimensional view of the memory array 52, and fig. 19B is a cross-sectional view shown along a reference section B-B in fig. 19A.

In this embodiment, the metallization pattern 142 of the interconnect structure 140 includes only the source line interconnect 142S. Another interconnect structure 170 is formed on a side of the substrate 102 opposite the interconnect structure 140. Interconnect structure 170 may be formed in a similar manner as interconnect structure 140. The interconnect structure 170 may include, for example, a metallization pattern 172 in a dielectric material 174. Conductive vias 180 may be formed through the substrate 102 and the ferroelectric strip 114 to electrically couple the metallization pattern 172 to the bit lines 134 and/or the source lines 136. For example, metallization pattern 172 includes bit line interconnect 172B (which is electrically coupled to source line 136 through conductive via 180).

Also, in this embodiment, the bit lines 134 and the source lines 136 are not formed in a staggered layout, and thus the adjacent bit lines 134 and the adjacent source lines 136 are along the first direction D1(see fig. 2B) are laterally aligned with each other. Thus, each word line 112 is laterally disposed between a pair of bit lines 134 or between a pair of source lines 136. Because bit lines 134 and source lines 136 are not formed in a staggered layout, lateral interconnections to a subset of source line interconnects 142S are implemented in interconnect structure 140, while lateral interconnections to a subset of bit line interconnects 172B are implemented in interconnect structure 170. For example, the source line interconnect 142S is a straight conductive segment formed at an intermediate level of the interconnect structure 140. Lateral interconnects 146 between the first subset of source line interconnects 142S and the first subset of source lines 136 are formed at a lower level of the interconnect structure 140 than the source line interconnects 142S. Straight line interconnects 148 between the second subset of source line interconnects 142S and the second subset of source lines 136 are formed at a lower level of the interconnect structure 140 than the source line interconnects 142S. Likewise, bit line interconnect 172B is a straight conductive segment formed at an intermediate level of interconnect structure 170. Lateral interconnects 176 between the first subset of bit line interconnects 172B and the first subset of bit lines 134 are formed at a lower level of the interconnect structure 170 than the bit line interconnects 172B. Bit line interconnect 172B is compared to bit line interconnectStraight line interconnects 178 between the second subset of the connections 172B and the second subset of the bit lines 134 are formed at a lower level of the interconnect structure 170.

It should be noted that in other embodiments, the layout of the interconnect structures 140, 170 may be reversed. For example, metallization pattern 142 of interconnect structure 140 may include bit line interconnects, and metallization pattern 172 of interconnect structure 170 may include source line interconnects.

Fig. 20A-22B are various views of intermediate stages in the manufacture of a memory array 52, according to some other embodiments. A portion of a memory array 52 is shown. For clarity of illustration, some features are not shown, such as a staircase arrangement of word lines (see fig. 2B). Fig. 20A and 21A are three-dimensional views of the memory array 52. Fig. 20B and 21B are sectional views shown along a reference section B-B in fig. 21A. Fig. 22A and 22B are top views of a portion of the memory array 52.

In fig. 20A and 20B, a structure similar to that described with reference to fig. 13A and 13B is obtained, but the ferroelectric stripe 114, the semiconductor stripe 116, and the dielectric layer 118 are not formed in this processing step. In contrast, the first trench 106 (see fig. 4A and 4B) and the second trench 120 (see fig. 8A and 8B) are each filled with a dielectric layer 192. The dielectric layer 192 is formed of a dielectric material. Acceptable dielectric materials include oxides such as silicon oxide; nitrides such as silicon nitride and the like; carbides such as silicon carbide; and the like; or combinations thereof such as silicon oxynitride, silicon oxycarbide, silicon carbonitride, and the like. The dielectric material may be formed by an acceptable deposition process such as ALD, CVD, and the like. In some embodiments, silicon oxide is deposited in the first trench 106 and the second trench 120. A planarization process may be applied to the layers to remove excess dielectric material over the topmost first dielectric layer 104A. The planarization process may be a Chemical Mechanical Polishing (CMP), an etch back process, a combination thereof, or the like. For example, a first planarization process may be performed after filling the first trench 106 to form the dielectric layer 192, and a second planarization process may be performed after filling the second trench 120 to form the dielectric layer 192.

In fig. 21A and 21B, a TFT thin film stack is formed extending through the dielectric layer 192. The TFT thin film stacks each include a ferroelectric stripe 114, a semiconductor stripe 116, and a dielectric layer 118. Bit line 134 and source line 136 are then formed at least through dielectric layer 118.

The ferroelectric strips 114, semiconductor strips 116, and dielectric layer 118 may be formed by a combination of deposition, etching, and planarization. For example, an opening may be formed through the dielectric layer 192. These openings can be formed by using acceptable photolithography and etching techniques. The ferroelectric layer may be conformally deposited in the openings through dielectric layer 192. Then, a semiconductor layer can be conformally deposited on the ferroelectric layer. The semiconductor layer may then be anisotropically etched to remove horizontal portions of the semiconductor layer, thereby exposing the ferroelectric layer. A dielectric layer may then be conformally deposited on the remaining vertical portion of the semiconductor layer and on the exposed portion of the ferroelectric layer. A planarization process is then applied to the layers to remove excess material over the topmost first dielectric layer 104A. The planarization process may be a Chemical Mechanical Polishing (CMP), an etch back process, a combination thereof, or the like. The portion of the ferroelectric layer, the portion of the semiconductor layer, and the portion of the dielectric layer remaining in the opening through dielectric layer 192 form ferroelectric stripe 114, semiconductor stripe 116, and dielectric layer 118, respectively. The planarization process exposes the topmost first dielectric layer 104A such that, after the planarization process, the top surface of the topmost first dielectric layer 104A, the top surface of the ferroelectric strip 114, the top surface of the semiconductor strip 116, and the top surface of the dielectric layer 118 are coplanar (within process variations).

As an example of forming the bit line 134 and the source line 136, an opening for the bit line 134 and an opening for the source line 136 may be formed through the dielectric layer 118, and optionally also through the ferroelectric bar 114 and the semiconductor bar 116. These openings can be formed by using acceptable photolithography and etching techniques. Specifically, these openings are formed such that they are opposite the sides of the remaining portion of the dielectric layer 118. In some embodiments, the openings extend only through the dielectric layer 118, such that the bit lines 134 and source lines 136 extend only through the dielectric layer 118 (as shown in FIG. 22A). In some embodiments, the openings also extend through the ferroelectric and semiconductor strips 114, 116, such that the bit lines 134 and source lines 136 also extend through the ferroelectric and semiconductor strips 114, 116. One or more dielectric materials are then formed in these openings. Acceptable conductive materials include metals such as tungsten, cobalt, aluminum, nickel, copper, silver, gold, alloys thereof, and the like. The conductive material may be formed by an acceptable deposition process such as ALD or CVD, an acceptable plating process such as electroplating or electroless plating, or the like. In some embodiments, tungsten is deposited in the opening. A planarization process is then applied to the layers to remove excess conductive material over the topmost first dielectric layer 104A. The planarization process may be a Chemical Mechanical Polishing (CMP), an etch back process, a combination thereof, or the like. The remaining conductive material forms bit lines 134 and source lines 136 in the openings. Then, similar techniques as described above may be used to form interconnects above (or below) bit lines 134 and above (or below) source lines 136, such that bit lines 134 and source lines 136 may be coupled to the bit line interconnects and the source line interconnects, respectively.

However, by forming the first conductive feature 112A and the second dielectric material 122 prior to etching the second trench 120 and forming the second sidewall recess 124, the first conductive feature 112A and the second dielectric material 122 are present during subsequent etching processes, such as during etching of the second trench 120 and the second sidewall recess 124. As such, these unremoved structures may provide structural support during subsequent processing, thereby helping to prevent problems such as word line wiggling or even word line collapse. Avoiding these problems allows smaller devices to be fabricated with fewer defects, thereby increasing overall yield.

According to an embodiment, a method of manufacturing a semiconductor device includes: etching a first trench in a multilayer stack, the multilayer stack comprising alternating dielectric layers and sacrificial layers; depositing a first conductive material within the first trench; filling the remaining portion of the first trench with a first dielectric material; etching a second trench in the multilayer stack after filling the remaining portion of the first trench; depositing a second conductive material within the second trench; filling the remaining portion of the second trench with a second dielectric material; etching the first conductive material and the second conductive material; and depositing a channel material in the first trench after etching the first conductive material and the second conductive material. In an embodiment, the method further comprises: planarizing the second dielectric material with a portion of the dielectric layer after filling the remaining portion of the second trench; and removing the portion of the dielectric layer prior to etching the first conductive material. In an embodiment, removing the portion of the dielectric layer forms an "H" shaped structure. In an embodiment, the first conductive material comprises a first adhesive layer, and wherein depositing the second conductive material may deposit a second adhesive layer in physical contact with the first adhesive layer. In an embodiment, the method further comprises recessing the sacrificial layer prior to depositing the first conductive material. In an embodiment, the method further comprises planarizing the first dielectric material and the first conductive material prior to etching the second trench. In an embodiment, the method further comprises depositing a ferroelectric material in the first trench.

According to another embodiment, a method of manufacturing a semiconductor device includes: forming an alternating stack of a first dielectric material and a sacrificial material; forming a first portion of a first word line in the alternating stack, the forming the first portion of the first word line comprising: etching first trenches in the alternating stack; forming a first recess by recessing a first portion of the sacrificial material exposed within the first trench; depositing a first conductive material in the first recess; and depositing a second dielectric material to fill the remaining portion of the first trench; and forming a second portion of the first word line within the alternating stack, the forming the second portion of the first word line comprising: etching second trenches in the alternating stack; forming a second recess by removing a second portion of the sacrificial material exposed within the second trench; depositing a second conductive material in the second recess; and depositing a third dielectric material to fill the remaining portion of the second trench. In an embodiment, the method further comprises removing the top layer of the first dielectric material after depositing the third dielectric material. In an embodiment, removing the top layer of the first dielectric material leaves a "U" shaped opening, wherein the sidewalls of the "U" shaped opening comprise the first conductive material and the second conductive material. In an embodiment, removing the second portion of the sacrificial material may expose a portion of the first conductive material. In an embodiment, the method further comprises planarizing the third dielectric material after depositing the third dielectric material. In an embodiment, the third dielectric material is different from the second dielectric material. In an embodiment, the method further comprises: removing the second dielectric material and the third dielectric material; etching the first conductive material and the second conductive material; depositing a ferroelectric material adjacent to the first conductive material and the second conductive material; and depositing a channel material adjacent to the ferroelectric material.

According to still another embodiment, a semiconductor device includes: a ferroelectric material extending away from the substrate; a channel material on a first side of the ferroelectric material; a first dielectric material extending away from a second side of the ferroelectric material opposite the first side; a second dielectric material extending away from the second side of the ferroelectric material; a first conductive material extending away from a second side of the ferroelectric material between the first dielectric material and the second dielectric material, the first conductive material comprising a bulk material and a first adhesive layer; and a second conductive material extending away from the first conductive material between the first dielectric material and the second dielectric material, the second conductive material comprising a second bulk material and a second adhesive layer, the second adhesive layer in physical contact with the first adhesive layer. In an embodiment, the semiconductor device further comprises a second ferroelectric material in physical contact with the second conductive material. In an embodiment, the semiconductor device further comprises: a third dielectric material extending away from the second side of the ferroelectric material; a third conductive material extending away from a second side of the ferroelectric material between the third dielectric material and the second dielectric material, the second conductive material comprising a third bulk material and a third adhesive layer; and a fourth conductive material extending away from the third conductive material between the third dielectric material and the second dielectric material, the fourth conductive material comprising a fourth bulk material and a fourth adhesive layer, the fourth adhesive layer in physical contact with the third adhesive layer. In an embodiment, the first conductive material and the second conductive material collectively have a width of about 80 nm. In an embodiment, the first conductive material and the second conductive material form a word line of the memory cell. In an embodiment, the memory cell is part of a three-dimensional memory array.

The foregoing has outlined features of several embodiments so that those skilled in the art may better understand the aspects of the present invention. Those skilled in the art should appreciate that they may readily use the present disclosure as a basis for designing or modifying other processes and structures for carrying out the same purposes and/or achieving the same advantages of the embodiments introduced herein. Those skilled in the art should also realize that such equivalent constructions do not depart from the spirit and scope of the present disclosure, and that they may make various changes, substitutions, and alterations herein without departing from the spirit and scope of the present disclosure.

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