阅读说明：本技术 用于汽油催化转化多产btx的催化剂及其制备方法 (Catalyst for gasoline catalytic conversion and high yield of BTX and preparation method thereof ) 是由 王丽霞 林伟 田辉平 严加松 孙敏 于 2019-09-30 设计创作，主要内容包括：本发明涉及石油化工领域,公开了一种用于汽油催化转化多产BTX的催化剂及其制备方法以及汽油催化转化的方法,该催化剂包括天然矿物质、无机氧化物、FAU结构分子筛和贵金属,以所述催化剂的总重量为基准,天然矿物质的含量为15-70wt％,无机氧化物的含量为5-60wt％,FAU结构分子筛的含量为10-70wt％,以元素计,贵金属的含量为0.01-10wt％。所述汽油催化转化的方法包括：将汽油、二氧化碳以及任选的稀释气与上述催化剂接触反应。采用本发明提供的催化剂可以在温和条件下实现汽油的催化转化和CO-2的有效利用,具有较高低碳烯烃产率,能够多产BTX。(The invention relates to the field of petrochemical industry, and discloses a catalyst for gasoline catalytic conversion and high yield of BTX, a preparation method thereof and a gasoline catalytic conversion methodThe catalyst comprises noble metal, wherein the content of natural mineral substances is 15-70 wt%, the content of inorganic oxides is 5-60 wt%, the content of FAU structure molecular sieve is 10-70 wt%, and the content of noble metal is 0.01-10 wt% calculated by elements. The method for catalytically converting gasoline comprises the following steps: gasoline, carbon dioxide and optional diluent gas are contacted with the catalyst for reaction. The catalyst provided by the invention can realize the catalytic conversion and CO of gasoline under mild conditions 2 The method has the advantages of effective utilization, high yield of low-carbon olefin and capability of producing more BTX.)

1. The catalyst for catalytic conversion of gasoline to produce BTX in high yield is characterized by comprising natural minerals, inorganic oxides, FAU-structure molecular sieves and noble metals, wherein the content of the natural minerals is 15-70 wt%, the content of the inorganic oxides is 5-60 wt%, the content of the FAU-structure molecular sieves is 10-70 wt%, and the content of the noble metals is 0.01-10 wt% calculated by elements.

2. The catalyst according to claim 1, wherein the natural mineral content is 20-60 wt%, the inorganic oxide content is 8-50 wt%, the FAU structure molecular sieve content is 10-55 wt%, and the noble metal content is 0.1-5 wt% calculated by element, based on the total weight of the catalyst;

preferably, the content of the natural mineral matter is 20-55 wt%, the content of the inorganic oxide is 10-45 wt%, the content of the FAU structure molecular sieve is 30-40 wt%, and the content of the noble metal is 1-3 wt% calculated by element based on the total weight of the catalyst.

3. Catalyst according to claim 1 or 2, wherein the noble metal is selected from one or more of Au, Ag, Ru, Rh, Pd, Pt, Ir and Os, preferably from one or more of Au, Rh, Pd, Pt and Ir, more preferably from one or more of Au, Pd and Ru.

4. The catalyst of any of claims 1-3, wherein the FAU structure molecular sieve is a Y molecular sieve.

5. The catalyst of any one of claims 1 to 4, wherein the natural mineral is selected from one or more of kaolin, montmorillonite, diatomaceous earth, attapulgite, sepiolite, halloysite, hydrotalcite, bentonite and rectorite;

preferably, the inorganic oxide is selected from one or more of silicon oxide, aluminum oxide-silicon oxide, zirconium oxide, titanium oxide, boron oxide, amorphous silicon aluminum, aluminum phosphate, tungsten oxide-zirconium oxide, molybdenum oxide-zirconium oxide, molybdenum oxide-titanium oxide, tungsten oxide-titanium oxide, tin oxide, zinc oxide, copper oxide, nickel oxide, cobalt oxide, vanadium oxide and niobium oxide.

6. The catalyst according to any one of claims 1 to 5, wherein the catalyst further comprises an auxiliary selected from one or more of group IIA, group IIIA, group IVA, group VA, lanthanides, Sc, Y, Hf, Ta, Cr, Mn, Re, Fe and Cd, preferably from one or more of Ca, Fe, Ga, In, Bi, La and Mn;

preferably, the content of the auxiliary agent is 0.5-10 wt% in terms of oxide based on the total weight of the catalyst.

7. A method for preparing the catalyst for gasoline catalytic conversion and high BTX yield according to any one of claims 1 to 6, which comprises: mixing and pulping noble metal salt and/or supported noble metal, FAU structure molecular sieve, natural mineral, inorganic oxide and/or inorganic oxide precursor, spray drying, and roasting;

preferably, the process further comprises introducing a promoter to the catalyst;

preferably, the introduction manner of the auxiliary agent comprises: mixing and pulping an auxiliary agent precursor, a noble metal salt and/or a supported noble metal, a FAU structure molecular sieve, a natural mineral substance, an inorganic oxide and/or an inorganic oxide precursor, and/or

Mixing and pulping the supported noble metal containing the auxiliary agent, the FAU structure molecular sieve, the natural mineral substance, the inorganic oxide and/or the inorganic oxide precursor.

8. A method for preparing the catalyst for gasoline catalytic conversion and high BTX yield according to any one of claims 1 to 6, which comprises:

(1) mixing noble metal salt and/or supported noble metal, partial natural mineral substance and partial inorganic oxide and/or inorganic oxide precursor, pulping, and spray drying to obtain a solid product I;

(2) mixing, pulping and spray-drying the FAU structure molecular sieve, the rest of natural mineral substances, the rest of inorganic oxide and/or inorganic oxide precursor to obtain a solid product II;

(3) mixing the solid product I and the solid product II, and then roasting;

preferably, the natural minerals in the step (1) account for 1-15% of the total weight of the natural minerals in the step (1) and the step (2);

preferably, the inorganic oxide and/or inorganic oxide precursor of step (1) comprises 1-20% of the total weight of the inorganic oxide and/or inorganic oxide precursor of step (1) and step (2);

preferably, the process further comprises introducing a promoter to the catalyst in step (1);

preferably, step (1) comprises: mixing and pulping the auxiliary agent precursor, the noble metal salt and/or the supported noble metal, part of the natural mineral substance and part of the inorganic oxide and/or the inorganic oxide precursor, and/or

Mixing and pulping the supported noble metal containing the auxiliary agent, partial natural mineral substances and partial inorganic oxide and/or inorganic oxide precursor.

9. The method according to claim 7 or 8, wherein the supported noble metal comprises a support and a noble metal supported on the support; preferably, the support is selected from one or more of alumina, silica, alumina-silica, zirconia, tungsten oxide-zirconia, molybdenum oxide-zirconia, titania, molybdenum oxide-titania, tungsten oxide-titania, tin oxide, zinc oxide, copper oxide, nickel oxide, cobalt oxide, vanadium oxide and niobium oxide, preferably at least one of alumina, alumina-silica and tungsten oxide-zirconia;

preferably, the content of the noble metal is 0.5-20% by element based on the total weight of the supported noble metal.

10. A method for preparing the catalyst for gasoline catalytic conversion and high BTX yield according to any one of claims 1 to 6, which comprises:

1) loading noble metal on the FAU structure molecular sieve to obtain the FAU structure molecular sieve containing the noble metal;

2) mixing and pulping the noble metal-containing FAU structure molecular sieve, natural mineral substances and inorganic oxide and/or inorganic oxide precursor, spray drying, and then roasting;

preferably, the process further comprises introducing a promoter to the catalyst;

preferably, the process further comprises introducing an auxiliary agent to the catalyst in step 1), further preferably step 1) comprises: and loading the noble metal and the auxiliary agent on the FAU structure molecular sieve to obtain the FAU structure molecular sieve containing the noble metal and the auxiliary agent.

11. A method for preparing the catalyst for gasoline catalytic conversion and high BTX yield according to any one of claims 1 to 6, which comprises:

(I) mixing, pulping and spray-drying a FAU structure molecular sieve, natural minerals and inorganic oxide precursors and/or inorganic oxide precursors to obtain a solid product a;

(II) loading a noble metal on the solid product a, and then roasting;

preferably, the process further comprises introducing a promoter to the catalyst;

preferably, the process further comprises introducing an adjunct to the catalyst in step (II), further preferably step (II) comprises: and loading the noble metal and the auxiliary agent on the solid product a.

12. The method of any of claims 7-11, wherein the firing conditions comprise: the roasting atmosphere is air atmosphere, inert atmosphere or steam atmosphere, the roasting temperature is 400-800 ℃, and the roasting time is 0.5-8 hours.

13. A catalyst for gasoline catalytic conversion yielding BTX produced by the method of any one of claims 7-12.

14. A process for the catalytic conversion of gasoline, the process comprising: contacting gasoline, carbon dioxide and a catalyst and optionally a diluent gas for reaction, wherein the catalyst comprises the catalyst for catalytic conversion of gasoline and high yield of BTX in any one of claims 1 to 6 and 13;

preferably, the conditions of the contact reaction include: the temperature is 350-: 1, the mass airspeed of the gasoline is 0.3-10h^-1；

More preferably, the conditions of the contact reaction include: the temperature is 500-650 ℃, the pressure is 0.1-0.3MPa, and the weight ratio of the carbon dioxide to the gasoline is 0.2-2: 1, the mass airspeed of the gasoline is 0.5-5h^-1。

Technical Field

The invention relates to the field of petrochemical industry, in particular to a catalyst for gasoline catalytic conversion and high yield of BTX, a preparation method thereof and a gasoline catalytic conversion method.

Background

Low carbon olefin and BTX are indispensable chemical raw materials. The lower olefins include ethylene, propylene, butylene, and BTX is benzene, toluene, and xylene. Wherein, ethylene is mainly used for producing polyethylene, ethylene oxide, dichloroethane and the like, propylene is mainly used for producing polypropylene, acrylonitrile, propylene oxide and other products, BTX is mainly used as a solvent of paint, dye, resin and the like, and for preparing medicines, pesticides and the like.

In recent years, the demand of low-carbon olefins and BTX is rapidly increased, and the productivity is continuously improved. Currently, the main ways for producing light olefins and BTX are steam cracking, catalytic cracking, propane dehydrogenation, MTO, catalytic reforming, and the like. Wherein, the proportion of the products of the low-carbon olefin produced by adopting a steam cracking mode can not be flexibly adjusted, the reaction temperature is up to 840-860 ℃, and the energy consumption is about 40 percent of the energy consumption of the petrochemical industry. Therefore, the method for increasing the yields of light olefins and BTX in large quantities by catalytic cracking is an efficient way for meeting the demand increase, wherein the catalytic cracking of gasoline fractions such as naphtha is promising because of the advantages of low reaction temperature, flexible and easily adjustable product distribution, small product pollution, and environmental protection. However, from the current results, further improvements and enhancements in process and catalyst performance are still needed.

As is well known, CO₂Is an important greenhouse gas, the greenhouse effect of the greenhouse gas causes a series of problems such as land desertification, aggravation of plant diseases and insect pests, climate change, glacier melting and the like, and therefore, the international society calls for CO₂And (5) emission reduction. But on the other hand, CO₂It is also a cheap and rich C1 resource, which can react with hydrogen to produce CO, methanol, dimethyl ether, low carbon hydrocarbon, gasoline, etc., and can react with methane to produce synthetic gas and ethane to produce ethylene, etc. However, these reactions generally need to be carried out under high pressure, and the reaction conditions are relatively severe.

Disclosure of Invention

The invention aims to overcome the reaction conditions of gasoline catalytic conversion and CO in the prior art₂The defect of harsh conditions is utilized to provide a catalyst for gasoline catalytic conversion and high yield of BTX, a preparation method thereof and a gasoline catalytic conversion method. The catalyst provided by the invention can realize the catalytic conversion and CO of gasoline under mild conditions₂The yield of the products (the low-carbon olefin and the BTX) is further improved.

In order to achieve the above object, the first aspect of the present invention provides a catalyst for catalytic conversion of gasoline with high BTX yield, which comprises natural minerals, inorganic oxides, FAU-structured molecular sieves, and noble metals, wherein the natural minerals are 15 to 70 wt%, the inorganic oxides are 5 to 60 wt%, the FAU-structured molecular sieves are 10 to 70 wt%, and the noble metals are 0.01 to 10 wt% calculated on elements, based on the total weight of the catalyst.

In a second aspect, the present invention provides a method for preparing the above catalyst for catalytic conversion of gasoline with high BTX yield, which comprises: mixing noble metal salt and/or supported noble metal, FAU structure molecular sieve, natural mineral, inorganic oxide and/or inorganic oxide precursor, pulping, spray drying, and roasting.

Preferably, the process further comprises introducing a promoter to the catalyst.

Preferably, the introduction manner of the auxiliary agent comprises: mixing and pulping an auxiliary agent precursor, a noble metal salt and/or a supported noble metal, a FAU structure molecular sieve, a natural mineral substance, an inorganic oxide and/or an inorganic oxide precursor, and/or

Mixing and pulping the supported noble metal containing the auxiliary agent, the FAU structure molecular sieve, the natural mineral substance, the inorganic oxide and/or the inorganic oxide precursor.

In a third aspect, the present invention provides a method for preparing the above catalyst for catalytic conversion of gasoline with high BTX yield, which comprises:

(1) mixing noble metal salt and/or supported noble metal, partial natural mineral substance and partial inorganic oxide and/or inorganic oxide precursor, pulping, and spray drying to obtain a solid product I;

(2) mixing, pulping and spray-drying the FAU structure molecular sieve, the rest of natural mineral substances, the rest of inorganic oxide and/or inorganic oxide precursor to obtain a solid product II;

(3) and mixing the solid product I and the solid product II, and then roasting.

Preferably, the process further comprises introducing a promoter to the catalyst in step (1).

Preferably, step (1) comprises: mixing and pulping the auxiliary agent precursor, the noble metal salt and/or the supported noble metal, part of the natural mineral substance and part of the inorganic oxide and/or the inorganic oxide precursor, and/or

Mixing and pulping the supported noble metal containing the auxiliary agent, partial natural mineral substances and partial inorganic oxide and/or inorganic oxide precursor.

The fourth aspect of the present invention provides a method for preparing the above catalyst for catalytic conversion of gasoline with high BTX yield, which comprises:

1) loading noble metal on the FAU structure molecular sieve to obtain the FAU structure molecular sieve containing the noble metal;

2) mixing and pulping the noble metal-containing FAU structure molecular sieve, natural minerals and inorganic oxides and/or inorganic oxide precursors, spray drying, and then roasting.

Preferably, the process further comprises introducing a promoter to the catalyst.

Preferably, the process further comprises introducing an auxiliary agent to the catalyst in step 1), further preferably step 1) comprises: and loading the noble metal and the auxiliary agent on the FAU structure molecular sieve to obtain the FAU structure molecular sieve containing the noble metal and the auxiliary agent.

The fifth aspect of the present invention provides a method for preparing the above catalyst for catalytic conversion of gasoline with high BTX yield, which comprises:

(I) mixing, pulping and spray-drying a FAU structure molecular sieve, natural minerals and inorganic oxide precursors and/or inorganic oxide precursors to obtain a solid product a;

(II) loading a noble metal on the solid product a, and then calcining.

Preferably, the process further comprises introducing a promoter to the catalyst.

Preferably, the process further comprises introducing an adjunct to the catalyst in step (II), further preferably step (II) comprises: and loading the noble metal and the auxiliary agent on the solid product a.

The sixth aspect of the present invention provides a catalyst for gasoline catalytic conversion with high BTX yield, prepared by the above method.

The seventh aspect of the present invention provides a method for catalytic conversion of gasoline, the method comprising: contacting gasoline, carbon dioxide and a catalyst and optionally a diluent gas for reaction, wherein the catalyst comprises the catalyst for catalytic conversion of the gasoline and high yield of BTX;

preferably, the conditions of the contact reaction include: the temperature is 350-: 1, the mass airspeed of the gasoline is 0.3-10h^-1；

More preferably, the conditions of the contact reaction include: the temperature is 500 ℃ and 650 ℃ and the pressure is0.1-0.3MPa, and the weight ratio of carbon dioxide to gasoline is 0.2-2: 1, the mass airspeed of the gasoline is 0.5-5h^-1。

The invention can realize the catalytic conversion of gasoline under mild conditions by adopting the catalyst containing natural minerals, inorganic oxides, noble metals and FAU structure molecular sieves. The catalyst provided by the invention is used in the catalytic conversion process of gasoline, carbon dioxide and diluent gas are in contact reaction with the catalyst, and CO is utilized₂The weak oxidation performance of the catalyst can be coupled with the catalytic cracking/thermal cracking reaction of the gasoline fraction, so that the yield of the low-carbon olefin can be improved in the normal pressure or lower pressure range, and particularly, the BTX can be produced in a large amount. In addition, the method for catalytically converting the gasoline can also make full use of CO₂Resources, reduces the problems caused by greenhouse gases, and has very good economic value and industrial application value.

Detailed Description

The endpoints of the ranges and any values disclosed herein are not limited to the precise range or value, and such ranges or values should be understood to encompass values close to those ranges or values. For ranges of values, between the endpoints of each of the ranges and the individual points, and between the individual points may be combined with each other to give one or more new ranges of values, and these ranges of values should be considered as specifically disclosed herein.

The invention provides a catalyst for catalytic conversion of gasoline and high yield of BTX, which comprises natural minerals, inorganic oxides, FAU structure molecular sieves and noble metals, wherein the content of the natural minerals is 15-70 wt%, the content of the inorganic oxides is 5-60 wt%, the content of the FAU structure molecular sieves is 10-70 wt%, and the content of the noble metals is 0.01-10 wt% calculated by elements;

preferably, the content of the natural mineral matter is 20-60 wt%, the content of the inorganic oxide is 8-50 wt%, the content of the FAU structure molecular sieve is 10-55 wt%, and the content of the noble metal is 0.1-5 wt% calculated by element based on the total weight of the catalyst.

More preferably, the content of natural minerals is 20-55 wt%, the content of inorganic oxides is 10-45 wt%, the content of FAU structure molecular sieves is 30-40 wt%, and the content of noble metals is 1-3 wt% calculated on elements, based on the total weight of the catalyst.

In the present invention, the noble metal is preferably selected from one or more of Au, Ag, Ru, Rh, Pd, Pt, Ir, and Os; more preferably one or more selected from Au, Rh, Pd, Pt and Ir; further preferred is one or more of Au, Pd and Ru.

The catalyst for gasoline catalytic conversion and high yield of BTX is used in the gasoline catalytic conversion process, and has higher BTX yield.

In the invention, the molecular sieve is a molecular sieve with an FAU structure, wherein the structure type FAU refers to a molecular sieve structure named by International molecular sieve Association (IZA) and is used for describing a spatial topological structure of a pore channel in the molecular sieve. Preferably, the FAU molecular sieve is preferably a Y molecular sieve. The adoption of the Y molecular sieve is more beneficial to improving the yield of the target product.

In the present invention, the FAU molecular sieve may be obtained commercially or may be prepared according to a conventional method in the art, and the present invention is not particularly limited thereto.

In the present invention, the natural mineral may be selected conventionally in the art, and preferably, the natural mineral is selected from one or more of kaolin, montmorillonite, diatomaceous earth, attapulgite, sepiolite, halloysite, hydrotalcite, bentonite and rectorite; more preferably, the natural mineral is selected from one or more of kaolin, halloysite, rectorite and montmorillonite.

In the present invention, the inorganic oxide may be conventionally selected in the art, and preferably, the inorganic oxide is selected from one or more of silicon oxide, aluminum oxide-silicon oxide, zirconium oxide, titanium oxide, boron oxide, amorphous silica-alumina, aluminum phosphate, tungsten oxide-zirconium oxide, molybdenum oxide-zirconium oxide, molybdenum oxide-titanium oxide, tungsten oxide-titanium oxide, tin oxide, zinc oxide, copper oxide, nickel oxide, cobalt oxide, vanadium oxide, and niobium oxide; more preferably, the inorganic oxide is selected from one or more of alumina, silica and alumina-silica.

In the invention, preferably, the catalyst also contains an auxiliary agent; the promoter may be present in the catalyst in the form of an oxide. The auxiliary agent is preferably selected from one or more of group IIA, group IIIA, group IVA, group VA, lanthanoid, Sc, Y, Hf, Ta, Cr, Mn, Re, Fe and Cd, more preferably selected from one or more of Ca, Fe, Ga, In, Bi, La and Mn, and still more preferably Ga.

In the present invention, the content of the promoter is preferably 0.5 to 10 wt% in terms of oxide, based on the total weight of the catalyst. In the examples of the present invention, the example of 1.1% by weight is given as an example, and the present invention is not limited thereto.

The present invention provides a method for producing the catalyst, which is not particularly limited as long as the catalyst having the above composition can be produced, and a method for producing the catalyst is provided to further improve the catalytic performance of the catalyst.

In a second aspect, the present invention provides a method (denoted as method a) for preparing the above catalyst for catalytic conversion of gasoline with high BTX yield, the method comprising: mixing noble metal salt and/or supported noble metal, FAU structure molecular sieve, natural mineral, inorganic oxide and/or inorganic oxide precursor, pulping, spray drying, and roasting.

In the method provided by the invention, the noble metal can be introduced in the form of a noble metal salt or in the form of a supported noble metal.

In the present invention, the noble metal salt may be a water-soluble noble metal salt, such as a nitrate and/or chloride of a noble metal, and the noble metal salt is preferably a chloride of a noble metal.

In the method provided by the invention, preferably, the supported noble metal comprises a carrier and a noble metal supported on the carrier; preferably, the support is selected from one or more of alumina, silica, alumina-silica, zirconia, tungsten oxide-zirconia, molybdenum oxide-zirconia, titania, molybdenum oxide-titania, tungsten oxide-titania, tin oxide, zinc oxide, copper oxide, nickel oxide, cobalt oxide, vanadium oxide and niobium oxide, more preferably alumina.

In the method provided by the invention, the content of the noble metal is preferably 0.5-20% by element, and more preferably 5-20% by element based on the total weight of the supported noble metal.

The supported noble metal of the present invention may be prepared by a method conventionally used in the art, for example, by an impregnation method, and specifically, the support may be impregnated with a solution containing a noble metal salt, followed by drying and calcination. The drying and calcining conditions may be carried out according to conventional conditions, and the present invention will not be described herein.

In the preparation method of the catalyst of the present invention, unless otherwise specified, when the noble metal is mixed and beaten with other raw materials in the form of a supported noble metal, the weight content of the carrier of the supported noble metal is taken into account in the content of the inorganic oxide.

In the present invention, the inorganic oxide precursor may be a substance that can be converted into an inorganic oxide in a subsequent process (e.g., firing) of the method provided by the present invention, and the inorganic oxide precursor can be properly selected by those skilled in the art based on the disclosure of the present invention. Specifically, the inorganic oxide precursor may be a sol of an inorganic oxide, for example, at least one of a silica sol, an aluminum sol, a peptized pseudo-boehmite, a silica-alumina sol, and a phosphorus-containing aluminum sol.

In the present invention, preferably, the method a further comprises introducing an auxiliary agent into the catalyst, wherein the kind of the auxiliary agent is as described above and is not described herein again.

Further preferably, the introduction manner of the auxiliary agent comprises: mixing and pulping an auxiliary agent precursor, a noble metal salt and/or a supported noble metal, a FAU structure molecular sieve, a natural mineral substance, an inorganic oxide and/or an inorganic oxide precursor; and/or

Mixing and pulping the supported noble metal containing the auxiliary agent, the FAU structure molecular sieve, the natural mineral substance, the inorganic oxide and/or the inorganic oxide precursor.

The auxiliary agent can be introduced in a form of mixing and pulping with other materials in the form of an auxiliary agent precursor, or can be introduced in a form of loading the auxiliary agent and the noble metal on a carrier together and then mixing and pulping with other materials.

In the present invention, the promoter precursor may be an oxide of a promoter element or a substance that can be converted into a promoter oxide in a subsequent process (e.g., firing) of the method provided by the present invention, and those skilled in the art can select the promoter precursor correctly based on the disclosure of the present invention. May be an oxide of an auxiliary element or a water-soluble salt of said auxiliary, for example a nitrate and/or chloride of the auxiliary.

The invention has no special limitation on the preparation method, the assistant and the noble metal can be introduced onto the carrier by adopting an impregnation method, the assistant precursor and the noble metal salt can be introduced onto the carrier together (co-impregnation) or introduced onto the carrier step by step (step-by-step impregnation), and when the assistant precursor and the noble metal salt are introduced onto the carrier step by step, the invention has no special limitation on the introduction sequence of the assistant precursor and the noble metal salt.

According to the method A provided by the invention, preferably, the method comprises the steps of adding water into the inorganic oxide and/or the inorganic oxide precursor and the natural mineral substance, mixing, adding the FAU structure molecular sieve and the noble metal salt and/or the supported noble metal, mixing, pulping, spray drying and roasting.

According to a preferred embodiment of the invention: mixing inorganic oxide and/or inorganic oxide precursor, natural mineral and water, and stirring; adding a FAU structure molecular sieve and noble metal salt and/or supported noble metal into the mixture after 0.5 to 2 hours, and stirring the mixture to obtain catalyst slurry with the solid content of 30 to 40 weight percent; spray drying to obtain microsphere catalyst; then the microspherical catalyst is roasted.

In a third aspect, the present invention provides a method (denoted as method B) for preparing the above catalyst for catalytic conversion of gasoline with high BTX production, the method comprising:

(1) mixing noble metal salt and/or supported noble metal, partial natural mineral substance and partial inorganic oxide and/or inorganic oxide precursor, pulping, and spray drying to obtain a solid product I;

(2) mixing, pulping and spray-drying the FAU structure molecular sieve, the rest of natural mineral substances, the rest of inorganic oxide and/or inorganic oxide precursor to obtain a solid product II;

(3) and mixing the solid product I and the solid product II, and then roasting.

According to the method B provided by the invention, preferably, the natural mineral substance in the step (1) accounts for 1-15% of the total weight of the natural mineral substances in the step (1) and the step (2).

According to the method B provided by the present invention, preferably, the inorganic oxide and/or inorganic oxide precursor in the step (1) accounts for 1 to 20% of the total weight of the inorganic oxide and/or inorganic oxide precursor in the step (1) and the step (2).

According to the method B provided by the present invention, preferably, the method further comprises introducing an auxiliary agent into the catalyst in step (1), wherein the kind of the auxiliary agent is as described above and is not described herein again; further preferably, step (1) comprises: mixing and pulping an auxiliary agent precursor, a noble metal salt and/or a supported noble metal, a part of natural mineral substances and a part of inorganic oxide and/or inorganic oxide precursor; and/or the presence of a gas in the gas,

the step (1) comprises the following steps: mixing and pulping the supported noble metal containing the auxiliary agent, partial natural mineral substances and partial inorganic oxide and/or inorganic oxide precursor.

The introduction of the auxiliaries is as described in method a, and is not described herein again.

According to the method B provided by the invention, the solid content of the slurry obtained by mixing and beating in the step (1) is preferably 30-40 wt%.

According to the method B provided by the invention, the solid content of the slurry obtained by mixing and beating in the step (2) is preferably 30-40 wt%.

In a fourth aspect, the present invention provides another method (denoted as method C) for preparing the above catalyst for catalytic conversion of gasoline with high BTX production, the method comprising:

1) loading noble metal on the FAU structure molecular sieve to obtain the FAU structure molecular sieve containing the noble metal;

2) mixing and pulping the noble metal-containing FAU structure molecular sieve, natural minerals and inorganic oxides and/or inorganic oxide precursors, spray drying, and then roasting.

In step 1) of the present invention, the noble metal may be loaded on the FAU-structured molecular sieve by a conventional method in the art, and specifically, one of an impregnation method, an ion exchange method, a chemical deposition method and a plasma method may be used. The examples of the present invention are illustrated in part by the dipping method and the present invention is not limited thereto.

According to an embodiment of the present invention, step 1) may be carried out by impregnating the FAU-structured molecular sieve with a solution containing a noble metal salt, followed by drying and calcination. The drying and calcining conditions may be carried out according to conventional conditions, and the present invention will not be described herein. The noble metal salt is as described above.

In the present invention, preferably, the method further comprises introducing an auxiliary agent into the catalyst, wherein the kind of the auxiliary agent is as described above and is not described herein again; further preferably, the method further comprises introducing an auxiliary agent into the catalyst in step 1); still further preferably, step 1) comprises: and loading the noble metal and the auxiliary agent on the FAU structure molecular sieve to obtain the FAU structure molecular sieve containing the noble metal and the auxiliary agent. Specifically, the method C includes:

1) loading the noble metal and the auxiliary agent on the FAU structure molecular sieve to obtain the FAU structure molecular sieve containing the noble metal and the auxiliary agent;

2) mixing the FAU structure molecular sieve containing the noble metal and the auxiliary agent, natural mineral substances and inorganic oxide and/or inorganic oxide precursor, pulping, spray drying, washing sodium, and roasting.

The invention can adopt an impregnation method to load the auxiliary agent and the noble metal on the FAU structure molecular sieve, the auxiliary agent precursor and the noble metal salt can be jointly impregnated on the FAU structure molecular sieve (co-impregnation) or can be impregnated on the FAU structure molecular sieve step by step (step-by-step impregnation), and when the auxiliary agent precursor and the noble metal salt are impregnated on the FAU structure molecular sieve step by step, the invention has no special limitation on the introduction sequence of the auxiliary agent precursor and the noble metal salt.

According to the method C provided by the invention, the solid content of the slurry obtained by mixing and beating in the step 2) is preferably 30-40 wt%.

A fifth aspect of the present invention provides a method (denoted as method D) for preparing the above catalyst for catalytic conversion of gasoline with high BTX production, comprising:

(I) mixing, pulping and spray-drying a FAU structure molecular sieve, natural minerals and inorganic oxide precursors and/or inorganic oxide precursors to obtain a solid product a;

(II) loading a noble metal on the solid product a, and then calcining.

According to the method D provided by the invention, the solid content of the slurry obtained by mixing and beating in the step (I) is preferably 30-40 wt%.

According to an embodiment of the present invention, step (II) may impregnate the solid product a with a solution containing a noble metal salt, followed by drying and calcination. The drying and calcining conditions may be carried out according to conventional conditions, and the present invention will not be described herein. The noble metal salt is as described above.

According to the method D provided by the present invention, preferably, the method further comprises introducing an auxiliary agent into the catalyst, wherein the kind of the auxiliary agent is as described above and is not described herein again; further preferably, the process further comprises introducing a promoter to the catalyst in step (II); still further preferably, step (II) comprises: and loading the noble metal and the auxiliary agent on the solid product a.

In the step (II) of the present invention, the noble metal may be supported on the solid product a by a conventional method in the art, and specifically, one of an impregnation method, an ion exchange method, a chemical deposition method and a plasma method may be used. The examples of the present invention are illustrated in part by the dipping method and the present invention is not limited thereto.

Specifically, the solid product a may be loaded with an auxiliary agent and a noble metal by an impregnation method, the auxiliary agent precursor and the noble metal salt may be impregnated together with the solid product a (co-impregnation) or may be impregnated stepwise into the solid product a (stepwise impregnation), and when the auxiliary agent precursor and the noble metal salt are impregnated stepwise into the solid product a, the order of introduction of the auxiliary agent precursor and the noble metal salt is not particularly limited in the present invention.

The spray drying in the above-mentioned method of the present invention is not particularly limited, and may be carried out according to a conventional technique in the art, and the spray drying conditions in the above-mentioned methods may be the same or different. Preferably the spray drying conditions are such that the spray dried particles have an average particle size of from 60 to 80 μm and a particle size distribution predominantly in the range of from 40 to 100. mu.m, and more preferably the spray drying conditions are such that more than 50% of the particles having a particle size of from 60 to 80 μm are present in the spray dried particles.

In the above method of the present invention, preferably, the roasting further comprises a step of washing sodium, which means that the catalyst particles obtained by spray drying are contacted with an ammonium salt solution to wash off sodium in the catalyst, wherein the ammonium salt may be an ammonium salt commonly used in the art, and is preferably one or more of ammonium chloride, ammonium sulfate, ammonium carbonate, ammonium bicarbonate, ammonium acetate and ammonium nitrate.

In the present invention, the calcination conditions may be calcination conditions conventional in the art, and preferably, the calcination conditions in each of the above methods independently include: the roasting atmosphere is air atmosphere, inert atmosphere or steam atmosphere, the roasting temperature is 400-800 ℃, preferably 400-600 ℃, and the roasting time is 0.5-8 hours, preferably 1-5 hours. According to a preferred embodiment of the invention, the calcination is carried out in an air atmosphere.

In the present invention, the inert atmosphere may be provided by at least one of nitrogen, argon, helium and neon, preferably nitrogen.

The sixth aspect of the invention also provides a catalyst prepared by the method for catalytic conversion of gasoline and capable of producing BTX in high yield.

The seventh aspect of the present invention provides a method for catalytic conversion of gasoline, wherein gasoline, carbon dioxide and catalyst, and optionally diluent gas are contacted and reacted, and the catalyst comprises the above catalyst for catalytic conversion of gasoline with high yield of BTX.

According to an embodiment of the present invention, the catalyst may be subjected to hydrothermal aging treatment before being used for catalytic conversion of gasoline. In the present invention, the conditions of the hydrothermal aging treatment are not particularly limited, and the hydrothermal aging treatment can be performed according to a conventional technique in the art. The hydrothermal aging treatment is more favorable for improving the stability of the catalyst. In the examples of the present invention, the aging is performed for 17 hours at 800 ℃ under 100% water vapor, but the present invention is not limited thereto.

In the present invention, preferably, the conditions of the contact reaction include: the temperature is 350-: 1, the mass airspeed of the gasoline is 0.3-10h^-1(ii) a More preferably, the conditions of the contact reaction include: the temperature is 500-650 ℃, the pressure is 0.1-0.3MPa, and the weight ratio of the carbon dioxide to the gasoline is 0.2-2: 1, the mass airspeed of the gasoline is 0.5-5h^-1。

In the invention, the gasoline mainly comprises aliphatic hydrocarbons and naphthenic hydrocarbons of C5-C12, and also comprises a certain amount of aromatic hydrocarbons, and specifically comprises one or more of catalytic cracking gasoline, coker gasoline, straight run gasoline, reformed gasoline, laminated gasoline and alkyl gasoline.

In the present invention, the diluent gas may be N₂、H₂O、O₂Air, N₂O、NO₂、NO、 H₂And SO₂Preferably N, is preferably N₂。

According to the present invention, it is preferable that the carbon dioxide is contained in an amount of 10 to 100% by volume, based on the total volume of the carbon dioxide and the diluent gas.

The present invention will be described in detail below by way of examples.

In the following examples:

the various parameters of the gasoline used are shown in table 1 below:

TABLE 1

Parameter(s)	Parameter value
		Density (20 ℃ C.), g/cm3	0.7494
Vapor pressure/kPa	21.9
		Alkane/wt.%	58.6
Cycloalkane/wt%	31.1
		Aromatic hydrocarbon/wt%	10.3
C/wt％	85.50
		H/wt％	14.48
S/wt％	102
		N/wt％	0.64

Kaolin (purchased from suzhou china kaolin, having a solids content of 75% by weight);

rectorite (75 wt% solid content from Zhongxiang rectorite in Hubei province);

montmorillonite (obtained from red rock bentonite, Gekko city, Kogyo, Liaoning, with a solid content of 75 wt%);

alumina sol (available from zilu catalyst division, alumina content 22.5 wt%);

silica sol (purchased from Qingdao ocean chemical Co., Ltd., silica content of 25.5 wt%, pH 3.0);

y molecular sieve (purchased from zilu catalyst works);

the contents of the components in the following catalysts are calculated by the feeding amount.

Example 1

This example illustrates the catalyst of the present invention, its preparation and the process for catalytic conversion of gasoline.

Preparing a catalyst:

mixing 66.7g of alumina sol and 66.8g of kaolin, preparing the mixture into slurry by using decationized water, and uniformly stirring; after 1 hour, 32.9g of Y molecular sieve and 3.1g of AuCl were added₃Stirring to form a catalyst slurry (solid content 32 wt%); continuously stirring, and spray drying to obtain microsphere catalyst (average particle diameter is 65 μm, particle with particle diameter of 60-80 μm accounts for 60%, the same below); and (3) carrying out sodium washing exchange on the microspherical catalyst and ammonium bicarbonate, and roasting the obtained solid product at 450 ℃ for 1.5 hours to obtain the catalyst C-1. The results of the contents of the components in the catalyst are shown in Table 2.

Catalytic conversion of gasoline:

aging the prepared catalyst at 800 deg.C under 100% steam for 17 hr, and oxidizing with gasoline, carbon dioxide and the catalyst at 580 deg.C under 0.11MPaThe weight ratio of carbon to gasoline is 0.2: 1, the mass space velocity of the gasoline is 0.6h^-1The catalytic conversion product of the gasoline is obtained by the contact reaction under the condition of (1). The yields of each product were tested and the results are shown in table 3.

Example 2

This example illustrates the catalyst of the present invention, its preparation and the process for catalytic conversion of gasoline.

Preparing a catalyst:

1) will contain 1.6g of AuCl₃The aqueous solution is dipped into 40.0g of Y molecular sieve, and then dried for 2h at 100 ℃ and roasted for 4h at 300 ℃ to obtain the Y molecular sieve containing noble metal;

2) preparing the Y molecular sieve containing noble metal, 66.7g of alumina sol and 58.7g of montmorillonite into slurry with the solid content of 32 weight percent by using decationized water; continuously stirring, and then spray-drying to prepare a microspherical catalyst; and (3) carrying out sodium washing exchange on the microspherical catalyst and ammonium bicarbonate, and roasting the microspherical catalyst for 2 hours at 450 ℃ to obtain the catalyst C-2. The results of the contents of the components in the catalyst are shown in Table 2.

Catalytic conversion of gasoline:

the procedure is as in example 1. The yields of each product were tested and the results are shown in table 3.

Example 3

This example illustrates the catalyst of the present invention, its preparation and the process for catalytic conversion of gasoline.

Preparing a catalyst:

(1) preparing slurry with the solid content of 30 weight percent by using decationized water for 66.7g of alumina sol, 69.3g of kaolin and 30.0g of Y molecular sieve, uniformly stirring, and carrying out spray drying on the slurry to prepare a microspherical catalyst;

(2) with an AuCl containing 4.6g₃The microsphere catalyst is soaked in the aqueous solution, and then the aqueous solution is dried for 2 hours at 100 ℃ and roasted for 4 hours at 450 ℃;

(3) and (3) performing sodium washing exchange on the roasted product obtained in the step (2) and ammonium bicarbonate, and then drying for 2 hours at 100 ℃ to obtain a catalyst C-3. The results of the contents of the components in the catalyst are shown in Table 2.

Catalytic conversion of gasoline:

the procedure is as in example 1. The yields of each product were tested and the results are shown in table 3.

Example 4

This example illustrates the catalyst of the present invention, its preparation and the process for catalytic conversion of gasoline.

Preparing a catalyst:

mixing 66.7g of alumina sol and 66.0g of montmorillonite, preparing the mixture into slurry by using decationized water, and uniformly stirring; after 1 hour 35.0g of Y molecular sieves and 0.8g of PdCl were added₂To form a catalyst slurry (solids content 32 wt%); continuously stirring, and then spray-drying to prepare a microspherical catalyst; and (3) carrying out sodium washing exchange on the microspherical catalyst and ammonium bicarbonate, and then roasting the microspherical catalyst for 1.5 hours at the temperature of 450 ℃ to obtain a catalyst C-4. The results of the contents of the components in the catalyst are shown in Table 2.

Catalytic conversion of gasoline:

the procedure is as in example 1. The yields of each product were tested and the results are shown in table 3.

Example 5

This example illustrates the catalyst of the present invention, its preparation and the process for catalytic conversion of gasoline.

Preparing a catalyst:

(1) 2.8g of AuCl₃5.3g of rectorite and 6.3g of silica sol are prepared into slurry with the solid content of 32 weight percent by using decationized water; and continuously stirring, and then carrying out spray drying to obtain a solid product I.

(2) Preparing 25.0g of Y molecular sieve, 38.9g of rectorite and 150.6g of silica sol into slurry with the solid content of 32 weight percent by using decationized water; and continuously stirring, and then carrying out spray drying to obtain a solid product II.

(3) And mixing the solid product I and the solid product II, performing sodium washing exchange by using ammonium bicarbonate, and roasting at 360 ℃ for 1.5 hours to obtain the catalyst C-5. The results of the contents of the components in the catalyst are shown in Table 2.

Catalytic conversion of gasoline:

the procedure is as in example 1. The yields of each product were tested and the results are shown in table 2.

Example 6

This example illustrates the catalyst of the present invention, its preparation and the process for catalytic conversion of gasoline.

Preparing a catalyst:

mixing 71.1g of alumina sol and 48.0g of kaolin, preparing the mixture into slurry by using decationized water, and uniformly stirring; after 2 hours 37.0 g of Y molecular sieve and 1.1g of Ga are added₂O₃And 10.0g of Ru (15% by weight)/Al₂O₃To form a catalyst slurry (35% solids by weight); continuously stirring, and then spray-drying to prepare a microspherical catalyst; and (3) carrying out sodium washing exchange on the microspherical catalyst and ammonium bicarbonate, and roasting the microspherical catalyst for 2 hours at 480 ℃ to obtain the catalyst C-6. The results of the contents of the components in the catalyst are shown in Table 2.

Catalytic conversion of gasoline:

the procedure is as in example 1. The yields of each product were tested and the results are shown in table 3.

Example 7

The process of example 1 was followed except that carbon dioxide gas was not introduced during the catalytic conversion of gasoline. The yields of each product were tested and the results are shown in table 3.

Comparative example 1

This comparative example serves to illustrate a comparative catalyst and a method of making the same, as well as a method of catalytic conversion of gasoline.

Catalyst preparation and gasoline catalytic conversion the same as in example 1, except that no AuCl was added₃(i.e., no noble metal is added).

The catalyst obtained was designated D-1. The results of the contents of the components in the catalyst are shown in Table 2. The results of yields of the various products obtained from gasoline catalytic conversion are shown in table 3.

Comparative example 2

This comparative example serves to illustrate a comparative catalyst and a method of making the same, as well as a method of catalytic conversion of gasoline.

Catalyst preparation and gasoline catalytic conversion the same as in example 1 except that no Y molecular sieve was added. The content of noble metal in the catalyst was calculated from the total weight and the amount of the catalyst to be added, and the results are shown in Table 2.

The catalyst obtained was designated D-2. The results of the contents of the components in the catalyst are shown in Table 2. The results of yields of the various products obtained from gasoline catalytic conversion are shown in table 3.

TABLE 2

Note: the noble metal is calculated by element, the inorganic oxide is calculated by oxide, and the auxiliary oxide is calculated by oxide.

TABLE 3

Product yield (%)	Ethylene	Propylene (PA)	BTX	Coke	Diesel oil and oil slurry	Gasoline (gasoline)	Liquefied gas	Dry gas
									Example 1	6.8	13.6	19.8	5.4	10.5	32.0	35.0	17.1
Example 2	6.7	13.2	18.8	6.2	12.3	29.9	34.8	16.8
									Example 3	7.0	13.7	20.4	5.8	10.1	32.7	34.2	17.2
Example 4	6.2	12.3	18.3	5.6	11.2	31.5	34.6	17.1
									Example 5	6.4	12.6	17.6	4.9	9.0	35.2	33.0	17.9
Example 6	7.1	14.3	20.7	5.3	10.1	30.4	36.6	17.6
									Example 7	6.1	13.0	18.4	5.5	11.5	31.8	34.2	17.0
Comparative example 1	3.6	8.7	14.6	4.9	9.2	48.8	27.3	9.8
									Comparative example 2	0.9	1.8	5.8	7.3	5.1	82.2	4.2	1.2

As can be seen from the data results in Table 3, the catalyst and CO provided by the present invention can be used₂The catalyst is used in the catalytic conversion process of the gasoline in a matching way, can realize the effective catalytic conversion of the gasoline under mild conditions, has higher low-carbon olefin yield, can produce BTX in a high yield, and realizes CO₂The effective utilization of the water is realized.

The preferred embodiments of the present invention have been described above in detail, but the present invention is not limited thereto. Within the scope of the technical idea of the invention, many simple modifications can be made to the technical solution of the invention, including combinations of various technical features in any other suitable way, and these simple modifications and combinations should also be regarded as the disclosure of the invention, and all fall within the scope of the invention.