阅读说明：本技术 一种复合磁性材料及其制作方法 (Composite magnetic material and manufacturing method thereof ) 是由 黄玉攀 于昊龙 鲍承林 黄玉冬 于 2019-10-25 设计创作，主要内容包括：本发明提供一种复合磁性材料及其制作方法,涉及磁性材料技术领域。该复合磁性材料及其制作方法,所述复合磁性材料由以下重量份成分组成：铁60-80份、钴5-6份、镍3-4份、钆4-6份、氧化钻1-2份、碳化硅1-1.2份、三氧化二锰0.8-1份、二硼化钛0.6-0.8份、螯合剂1-2份、添加剂0.8-1.6份,所述螯合剂包括铬、磷、铜、锌与钾,所述铬、磷、铜、锌与钾的质量比为1:0.8:1.2:0.9:1.1,所述添加剂二氧化锆、三氧化二铋与二氧化铈,所述二氧化锆、三氧化二铋与二氧化铈的质量比为2:1.5:1.7。通过合理的选取原材料,以及在熔烧过程中加入螯合剂与添加剂,使得制作出的复合磁性材料性能大大提升,复合磁性材料的磁导率不易受到外界因素的影响,且复合磁性材料的使用范围更加广泛。(The invention provides a composite magnetic material and a manufacturing method thereof, and relates to the technical field of magnetic materials. The composite magnetic material comprises the following components in parts by weight: 60-80 parts of iron, 5-6 parts of cobalt, 3-4 parts of nickel, 4-6 parts of gadolinium, 1-2 parts of diamond oxide, 1-1.2 parts of silicon carbide, 0.8-1 part of manganese sesquioxide, 0.6-0.8 part of titanium diboride, 1-2 parts of chelating agent and 0.8-1.6 parts of additive, wherein the chelating agent comprises chromium, phosphorus, copper, zinc and potassium, the mass ratio of the chromium, the phosphorus, the copper, the zinc and the potassium is 1:0.8:1.2:0.9:1.1, the additive comprises zirconium dioxide, bismuth trioxide and cerium dioxide, and the mass ratio of the zirconium dioxide, the bismuth trioxide and the cerium dioxide is 2:1.5: 1.7. Through reasonable selection of raw materials and addition of a chelating agent and an additive in the process of sintering, the performance of the manufactured composite magnetic material is greatly improved, the magnetic conductivity of the composite magnetic material is not easily affected by external factors, and the application range of the composite magnetic material is wider.)

1. A composite magnetic material, characterized by: the composite magnetic material comprises the following components in parts by weight: 60-80 parts of iron, 5-6 parts of cobalt, 3-4 parts of nickel, 4-6 parts of gadolinium, 1-2 parts of diamond oxide, 1-1.2 parts of silicon carbide, 0.8-1 part of manganese sesquioxide, 0.6-0.8 part of titanium diboride, 1-2 parts of chelating agent and 0.8-1.6 parts of additive.

2. A composite magnetic material as claimed in claim 1, wherein: the composite magnetic material comprises the following components in percentage by weight: 60 parts of iron, 5 parts of cobalt, 3 parts of nickel, 4 parts of gadolinium, 1 part of cobalt oxide, 1 part of silicon carbide, 0.8 part of manganese sesquioxide, 0.6 part of titanium diboride, 1 part of chelating agent and 0.8 part of additive.

3. A composite magnetic material as claimed in claim 1, wherein: the composite magnetic material comprises the following components in percentage by weight: 70 parts of iron, 5.5 parts of cobalt, 3.5 parts of nickel, 5 parts of gadolinium, 1.5 parts of diamond oxide, 1.1 parts of silicon carbide, 0.9 part of manganese sesquioxide, 0.7 part of titanium diboride, 1.5 parts of chelating agent and 1.2 parts of additive.

4. A composite magnetic material as claimed in claim 1, wherein: the composite magnetic material comprises the following components in percentage by weight: 80 parts of iron, 6 parts of cobalt, 4 parts of nickel, 6 parts of gadolinium, 2 parts of cobalt oxide, 1.2 parts of silicon carbide, 1 part of manganese sesquioxide, 0.8 part of titanium diboride, 2 parts of chelating agent and 1.6 parts of additive.

5. A composite magnetic material as claimed in claim 1, wherein: the chelating agent comprises chromium, phosphorus, copper, zinc and potassium, wherein the mass ratio of the chromium to the phosphorus to the copper to the zinc to the potassium is 1:0.8:1.2:0.9: 1.1.

6. A composite magnetic material as claimed in claim 1, wherein: the additive comprises zirconium dioxide, bismuth trioxide and cerium dioxide, and the mass ratio of the zirconium dioxide to the bismuth trioxide to the cerium dioxide is 2:1.5: 1.7.

7. A composite magnetic material as claimed in claim 1, wherein: the preparation method of the chelating agent comprises the following steps:

s1, preparing chromium, phosphorus, copper, zinc and potassium according to a mass ratio, and fully and uniformly mixing the chromium, the phosphorus, the copper, the zinc and the potassium;

s2, placing the mixture in a vacuum sintering furnace, introducing a proper amount of nitrogen into the vacuum sintering furnace, and sintering the mixture at the temperature of 500-800 ℃ for 1-2 hours;

s3, placing the sintered material in a mold, carrying out extrusion forming, cooling under natural conditions, and obtaining a block after cooling;

and S4, crushing the blocks to obtain a powdery chelating agent, wherein the granularity of the crushed chelating agent is 10-50 meshes.

8. A method for manufacturing a composite magnetic material is characterized by comprising the following steps: the method comprises the following steps:

s1, preparing raw materials of iron, cobalt, nickel, gadolinium, oxide diamond, silicon carbide, manganese trioxide and titanium diboride according to a weight ratio, and fully and uniformly stirring the iron, the cobalt, the nickel, the gadolinium, the oxide diamond, the silicon carbide, the manganese trioxide and the titanium diboride by using stirring equipment to obtain a mixed material A;

s2, placing the mixed material A in a vacuum melting furnace, introducing a proper amount of rare gas into the vacuum melting furnace, and adjusting the temperature in the vacuum melting furnace to 1500-2000 ℃;

s3, after the mixed material A is sintered for 30-60min in a vacuum melting furnace, adding a chelating agent into the vacuum melting furnace, continuing to sinter for 15-30min, adding an additive, then adjusting the temperature in the vacuum melting furnace to 1000-1200 ℃, and continuing to sinter for 30-45 min;

s4, placing the melt in the vacuum melting furnace into a mold, taking out the melt after molding, and performing water cooling to obtain a preliminary block;

s5, feeding the preliminary block into a sintering furnace for calcining at the temperature of 600-800 ℃ for 1-2 hours, and then taking out and cooling in a vacuum environment;

and S6, crushing the cooled block, putting a proper amount of powder into a forging die, and forging the powder into blocks to obtain the final molded composite magnetic material.

Technical Field

The invention relates to the technical field of magnetic materials, in particular to a composite magnetic material and a manufacturing method thereof.

Background

The magnetic material has a magnetically ordered ferromagnetic substance, and broadly includes weak magnetic and anti-ferromagnetic substances capable of applying the magnetism and magnetic effect thereof, the magnetism is a basic attribute of the substance, the substance can be divided into diamagnetic, paramagnetic, ferromagnetic, anti-ferromagnetic and ferrimagnetic substances according to the internal structure and the property thereof in an external magnetic field, the ferromagnetic and ferrimagnetic substances are ferromagnetic substances, the diamagnetic and paramagnetic substances are weak magnetic substances, the magnetic material is divided into two types of metal and nonmetal according to the property, the former mainly comprises electric steel, nickel-based alloy, rare earth alloy and the like, and the latter mainly comprises ferrite material, and is divided into soft magnetic material, permanent magnetic material and functional magnetic material according to the use.

At present, with the development of science and technology, the use of composite magnetic materials is more and more extensive, and although there are a lot of current composite magnetic material types, most of composite magnetic materials's composition is comparatively simple, and composite magnetic material's magnetic permeability receives external factor's influence easily, and its self application range has received certain limitation.

Disclosure of Invention

Technical problem to be solved

Aiming at the defects of the prior art, the invention provides a composite magnetic material and a manufacturing method thereof, and solves the problems that the magnetic conductivity of the composite magnetic material is easily influenced by external factors, and the application range of the composite magnetic material is limited.

(II) technical scheme

In order to achieve the purpose, the invention is realized by the following technical scheme: a composite magnetic material is composed of the following components in parts by weight: 60-80 parts of iron, 5-6 parts of cobalt, 3-4 parts of nickel, 4-6 parts of gadolinium, 1-2 parts of diamond oxide, 1-1.2 parts of silicon carbide, 0.8-1 part of manganese sesquioxide, 0.6-0.8 part of titanium diboride, 1-2 parts of chelating agent and 0.8-1.6 parts of additive.

Preferably, the composite magnetic material comprises the following components in percentage by weight: 60 parts of iron, 5 parts of cobalt, 3 parts of nickel, 4 parts of gadolinium, 1 part of cobalt oxide, 1 part of silicon carbide, 0.8 part of manganese sesquioxide, 0.6 part of titanium diboride, 1 part of chelating agent and 0.8 part of additive.

Preferably, the composite magnetic material comprises the following components in percentage by weight: 70 parts of iron, 5.5 parts of cobalt, 3.5 parts of nickel, 5 parts of gadolinium, 1.5 parts of diamond oxide, 1.1 parts of silicon carbide, 0.9 part of manganese sesquioxide, 0.7 part of titanium diboride, 1.5 parts of chelating agent and 1.2 parts of additive.

Preferably, the composite magnetic material comprises the following components in percentage by weight: 80 parts of iron, 6 parts of cobalt, 4 parts of nickel, 6 parts of gadolinium, 2 parts of cobalt oxide, 1.2 parts of silicon carbide, 1 part of manganese sesquioxide, 0.8 part of titanium diboride, 2 parts of chelating agent and 1.6 parts of additive.

Preferably, the chelating agent comprises chromium, phosphorus, copper, zinc and potassium, and the mass ratio of the chromium to the phosphorus to the copper to the zinc to the potassium is 1:0.8:1.2:0.9: 1.1.

Preferably, the additive comprises zirconium dioxide, bismuth trioxide and cerium dioxide, and the mass ratio of the zirconium dioxide to the bismuth trioxide to the cerium dioxide is 2:1.5: 1.7.

Preferably, the preparation method of the chelating agent is as follows:

s1, preparing chromium, phosphorus, copper, zinc and potassium according to a mass ratio, and fully and uniformly mixing the chromium, the phosphorus, the copper, the zinc and the potassium;

s2, placing the mixture in a vacuum sintering furnace, introducing a proper amount of nitrogen into the vacuum sintering furnace, and sintering the mixture at the temperature of 500-800 ℃ for 1-2 hours;

s3, placing the sintered material in a mold, carrying out extrusion forming, cooling under natural conditions, and obtaining a block after cooling;

and S4, crushing the blocks to obtain a powdery chelating agent, wherein the granularity of the crushed chelating agent is 10-50 meshes.

A method for manufacturing a composite magnetic material comprises the following steps:

s1, preparing raw materials of iron, cobalt, nickel, gadolinium, oxide diamond, silicon carbide, manganese trioxide and titanium diboride according to a weight ratio, and fully and uniformly stirring the iron, the cobalt, the nickel, the gadolinium, the oxide diamond, the silicon carbide, the manganese trioxide and the titanium diboride by using stirring equipment to obtain a mixed material A;

s2, placing the mixed material A in a vacuum melting furnace, introducing a proper amount of rare gas into the vacuum melting furnace, and adjusting the temperature in the vacuum melting furnace to 1500-2000 ℃;

s3, after the mixed material A is sintered for 30-60min in a vacuum melting furnace, adding a chelating agent into the vacuum melting furnace, continuing to sinter for 15-30min, adding an additive, then adjusting the temperature in the vacuum melting furnace to 1000-1200 ℃, and continuing to sinter for 30-45 min;

s4, placing the melt in the vacuum melting furnace into a mold, taking out the melt after molding, and performing water cooling to obtain a preliminary block;

s5, feeding the preliminary block into a sintering furnace for calcining at the temperature of 600-800 ℃ for 1-2 hours, and then taking out and cooling in a vacuum environment;

and S6, crushing the cooled block, putting a proper amount of powder into a forging die, and forging the powder into blocks to obtain the final molded composite magnetic material.

(III) advantageous effects

The invention provides a composite magnetic material and a manufacturing method thereof. The method has the following beneficial effects:

1. according to the composite magnetic material and the manufacturing method thereof, the raw materials are reasonably selected, and the chelating agent and the additive are added in the sintering process, so that the performance of the manufactured composite magnetic material is greatly improved, the magnetic conductivity of the composite magnetic material is not easily influenced by external factors, and the application range of the composite magnetic material is wider.

2. According to the composite magnetic material and the manufacturing method thereof, the mechanical property of the composite magnetic material is improved and the service life of the composite magnetic material is further prolonged by optimizing the manufacturing process of the composite magnetic material.

Detailed Description

The following will clearly and completely describe the technical solutions in the embodiments of the present invention, and it is obvious that the described embodiments are only a part of the embodiments of the present invention, and not all embodiments. All other embodiments, which can be derived by a person skilled in the art from the embodiments given herein without making any creative effort, shall fall within the protection scope of the present invention.