阅读说明：本技术 一种基于离子注入的铌酸锂或钽酸锂晶圆黑化方法 (Lithium niobate or lithium tantalate wafer blackening method based on ion implantation ) 是由 欧欣 孙嘉良 游天桂 林家杰 于 2020-06-29 设计创作，主要内容包括：本申请提供一种基于离子注入的铌酸锂或钽酸锂晶圆黑化方法,包括以下步骤：获取晶圆,所述晶圆为铌酸锂晶圆或钽酸锂晶圆；对所述晶圆进行还原性离子注入处理,获得注入还原性离子的晶圆；将所述注入还原性离子的晶圆进行退火处理。该方法基于离子注入进行晶圆黑化,能够在不影响材料压电性能的情况下,获得高质量黑化晶圆。该方法利用离子注入技术,将Fe2+等还原性离子注入到铌酸锂或钽酸锂晶圆,Fe2+等的注入会占据晶格中原本更高价态离子的格点,增加铌酸锂或钽酸锂晶体中的氧空位浓度,使晶圆内的载流子浓度提升,进而提高晶圆的电导率,降低电阻率,随后对晶圆进行退火修复,能够有效降低晶体的热释电效应。(The application provides a method for blackening a lithium niobate or lithium tantalate wafer based on ion implantation, which comprises the following steps: obtaining a wafer, wherein the wafer is a lithium niobate wafer or a lithium tantalate wafer; performing reductive ion implantation treatment on the wafer to obtain the wafer implanted with reductive ions; and annealing the wafer implanted with the reducing ions. The method carries out wafer blackening based on ion implantation, and can obtain a high-quality blackened wafer under the condition of not influencing the piezoelectric performance of the material. According to the method, reductive ions such as Fe2+ are injected into a lithium niobate or lithium tantalate wafer by using an ion injection technology, the injected ions such as Fe2+ occupy lattice points of original ions with higher valence states in a crystal lattice, the oxygen vacancy concentration in the lithium niobate or lithium tantalate crystal is increased, the carrier concentration in the wafer is increased, the conductivity of the wafer is further improved, the resistivity is reduced, then the wafer is annealed and repaired, and the pyroelectric effect of the crystal can be effectively reduced.)

1. A method for blackening a lithium niobate or lithium tantalate wafer based on ion implantation is characterized by comprising the following steps:

obtaining a wafer, wherein the wafer is a lithium niobate wafer or a lithium tantalate wafer;

performing reductive ion implantation treatment on the wafer to obtain the wafer implanted with reductive ions;

and annealing the wafer implanted with the reducing ions.

2. The method of claim 1, wherein the reducing ions comprise Fe²⁺。

3. The method of claim 1, wherein the reductive ion implantation has an implantation energy of 0.5 to 3 Mev.

4. The method of claim 1, wherein the reductive ion implantation is performed at an implantation dose of 0.5-5 x 10¹⁵/cm²。

5. The method for blackening the lithium niobate or lithium tantalate wafer based on ion implantation as claimed in claim 1, wherein the annealing process comprises a temperature raising process, a temperature holding process and a cooling process in sequence.

6. The method for blackening the lithium niobate or lithium tantalate wafer based on ion implantation according to claim 5, wherein the temperature rise rate of the temperature rise process is 5-10 ℃/min.

7. The method as claimed in claim 5, wherein the temperature of the thermal process is 350-550 ℃.

8. The method for blackening the lithium niobate or lithium tantalate wafer based on ion implantation according to claim 5, wherein the holding time of the holding process is 10-15 h.

9. The method of claim 1, wherein the subjecting the wafer to a reductive ion implantation process comprises:

carrying out surface mounting processing on the wafer;

and placing the wafer after the chip mounting into an ion implanter for reductive ion implantation.

10. The method of claim 1, wherein the annealing the wafer implanted with reducing ions comprises:

and placing the wafer implanted with the reducing ions into a high-temperature annealing furnace for annealing treatment.

Technical Field

The application relates to the technical field of crystal material post-processing, in particular to a method for blackening a lithium niobate or lithium tantalate wafer based on ion implantation.

Background

Lithium niobate (LiNbO)₃LN) and lithium tantalate (LiTaO)₃LT) crystal belongs to a very typical multifunctional crystal, and is widely used in the fields of surface acoustic wave devices (SAW), optical communication, optoelectronics, and the like at present because of its excellent properties such as ferroelectric, piezoelectric, pyroelectric, acousto-optic, electro-optic, photorefractive, and nonlinear properties. The surface acoustic wave filter is one of the very important application directions of LN and LT crystals, and due to the fact that the color of the crystal after cutting and polishing is close to transparent, the crystal has high optical transmittance, and the intrinsic pyroelectric effect of the crystal, the preparation of SAW devices still has many inconveniences.

First, lithium niobate and lithium tantalate crystals have very high pyroelectric coefficients, up to 4 × 10^-5C/m²K and 23X 10^-5C/m²K, due to its higher resistivity (10)¹³Ωcm-10¹⁵Omega cm), during the production process of the device, along with the change of temperature, a large amount of static charges are easily accumulated on the surface of the wafer, and although the static charges can be spontaneously released between the metal interdigital electrodes and between the wafers, the releasing process is very slow, so that the metal interdigital electrodes are easily burnt and even the wafer is cracked, thereby reducing the yield of the device manufacture and greatly increasing the production cost. Secondly, due to the high transmittance of the substrate, the light is reflected strongly from the back surface after passing through the substrate, which affects the resolution of the surface lithography and reduces the lithography precision.

In order to solve the above two problems, the prior art generally adopts a blackening technique to reduce the pyroelectric effect of LN and LT crystals and improve the electrical conductivity. The blackening method is developed to date and mainly comprises the steps of 1, treating the wafer by using reducing gases such as hydrogen, carbon monoxide and the like, 2, performing alternate stacking contact treatment on the wafer after deep blackening and without blackening to obtain black pieces, and 3, treating the wafer by using carbonate and hydride to obtain the black pieces. However, the above methods all have some problems, reducing gases such as carbon monoxide and hydrogen are easy to explode during heating treatment, which has great potential safety hazard, wafer contact blackening treatment may cause different degrees of blackening and uneven color of the wafer, reduction by carbonate and hydride is not enough in reducing property, which results in long treatment time, and some potential disadvantages of other methods include influence of adsorbed particles on the surface of the wafer on the quality of the wafer and difficulty in demand for corresponding equipment.

Disclosure of Invention

In order to solve the technical problem, the embodiment of the application discloses a method for blackening a lithium niobate or lithium tantalate wafer based on ion implantation, which comprises the following steps:

obtaining a wafer, wherein the wafer is a lithium niobate wafer or a lithium tantalate wafer;

performing reductive ion implantation treatment on the wafer to obtain the wafer implanted with reductive ions;

and annealing the wafer implanted with the reducing ions.

Further, the reducing ions include Fe²⁺。

Further, the implantation energy of the reductive ion implantation is 0.5-3 Mev.

Further, the implantation dosage of the reductive ion implantation is 0.5-5 × 10¹⁵/cm²。

Further, the annealing treatment process sequentially comprises a heating process, a heat preservation process and a cooling process.

Further, the temperature rise rate in the temperature rise process is 5-10 ℃/min.

Further, the heat preservation temperature in the heat preservation process is 350-550 ℃.

Further, the heat preservation time in the heat preservation process is 10-15 h.

Further, the performing a reductive ion implantation process on the wafer includes:

carrying out surface mounting processing on the wafer;

and placing the wafer after the chip mounting into an ion implanter for reductive ion implantation.

Further, the annealing the wafer implanted with the reducing ions includes:

and placing the wafer implanted with the reducing ions into a high-temperature annealing furnace for annealing treatment.

By adopting the technical scheme, the application has the following beneficial effects:

the blackening method of the lithium niobate or lithium tantalate wafer based on ion implantation can carry out blackening based on ion implantation, and obtains a high-quality blackened wafer under the condition that the piezoelectric performance of a material is not influenced. According to the method, reductive ions such as Fe2+ are injected into a lithium niobate or lithium tantalate wafer by using an ion injection technology, the injected ions such as Fe2+ occupy lattice points of original ions with higher valence states in a crystal lattice, the oxygen vacancy concentration in the lithium niobate or lithium tantalate crystal is increased, the carrier concentration in the wafer is increased, the conductivity of the wafer is further improved, the resistivity is reduced, then the wafer is annealed and repaired, and the pyroelectric effect of the crystal can be effectively reduced.

Drawings

In order to more clearly illustrate the technical solutions in the embodiments of the present invention, the drawings needed to be used in the description of the embodiments will be briefly introduced below, and it is obvious that the drawings in the following description are only some embodiments of the present invention, and it is obvious for those skilled in the art to obtain other drawings based on these drawings without creative efforts.

Fig. 1 is a schematic flow chart of a method for blackening a lithium niobate or lithium tantalate wafer based on ion implantation according to an embodiment of the present disclosure.

Detailed Description

The technical solutions in the embodiments of the present application will be clearly and completely described below with reference to the drawings in the embodiments of the present application. It is to be understood that the embodiments described are only a few embodiments of the present application and not all embodiments. All other embodiments, which can be derived by a person skilled in the art from the embodiments given herein without making any creative effort, shall fall within the protection scope of the present application.

Reference herein to "one embodiment" or "an embodiment" means that a particular feature, structure, or characteristic may be included in at least one implementation of the present application. In the description of the embodiments of the present application, it is to be understood that the terms "upper", "lower", "top", "bottom", and the like, indicate orientations or positional relationships based on the orientations or positional relationships shown in the drawings, are only for convenience in describing the present application and simplifying the description, and do not indicate or imply that the referred devices or elements must have a specific orientation, be constructed in a specific orientation, and be operated, and thus, should not be construed as limiting the present application. Furthermore, the terms "first", "second" and "first" are used for descriptive purposes only and are not to be construed as indicating or implying relative importance or implicitly indicating the number of technical features indicated. Thus, a feature defined as "first" or "second" may explicitly or implicitly include one or more of that feature. Moreover, the terms "first," "second," and the like are used for distinguishing between similar elements and not necessarily for describing a particular sequential or chronological order. It is to be understood that the data so used is interchangeable under appropriate circumstances such that the embodiments of the application described herein are capable of operation in sequences other than those illustrated or described herein.

Referring to fig. 1, fig. 1 is a schematic flow chart of a method for blackening a lithium niobate or lithium tantalate wafer based on ion implantation according to an embodiment of the present application, including the following steps:

s1, obtaining a wafer, wherein the wafer is a lithium niobate wafer or a lithium tantalate wafer;

s2, performing reductive ion implantation treatment on the wafer to obtain a wafer implanted with reductive ions;

in the examples of the present application, the reducing ions include, but are not limited to, Fe²⁺(ii) a The injection energy of the reductive ion injection is 0.5-3 Mev; the implantation dosage of the reductive ion implantation is 0.5-5 × 10¹⁵/cm²。

In an embodiment of the present application, the performing a reductive ion implantation process on the wafer includes:

carrying out surface mounting processing on the wafer; and placing the wafer after the chip mounting into an ion implanter for reductive ion implantation.

And S3, annealing the wafer implanted with the reducing ions.

The annealing treatment process sequentially comprises a heating process, a heat preservation process and a cooling process; firstly, heating at a certain rate in the annealing process, then preserving heat for a period of time, and finally naturally cooling to room temperature; and taking out the blackened wafer when the annealing furnace is cooled to the room temperature.

Wherein the heating rate in the heating process is 5-10 ℃/min; the heat preservation temperature in the heat preservation process is 350-550 ℃; the heat preservation time in the heat preservation process is 10-15 h.

In the embodiment of the present application, the wafer implanted with the reducing ions may be placed in a high temperature annealing furnace for annealing.

The blackening method of the lithium niobate or lithium tantalate wafer based on ion implantation can carry out blackening based on ion implantation, and obtains a high-quality blackened wafer under the condition that the piezoelectric performance of a material is not influenced. According to the method, an ion implantation technology is utilized, reducing ions such as Fe2+ are implanted into a lithium niobate or lithium tantalate wafer, the implantation of Fe2+ and the like can occupy lattice points of original ions with higher valence states in a crystal lattice, an F + color center is formed, the wafer is blackened, the oxygen vacancy concentration in the lithium niobate or lithium tantalate crystal is increased, the carrier concentration in the wafer is increased, the electric conductivity of the wafer is further improved, the resistivity is reduced, then annealing repair is carried out on the wafer, and the pyroelectric effect of the crystal can be effectively reduced.

The present invention is not intended to be limited to the particular embodiments shown and described, but is to be accorded the widest scope consistent with the principles and novel features herein disclosed.