阅读说明：本技术 一种改善热喷涂陶瓷涂层自润滑性能的方法 (Method for improving self-lubricating property of thermal spraying ceramic coating ) 是由 邓雯 唐霖 齐慧 于 2020-06-01 设计创作，主要内容包括：本发明涉及表面改性技术领域,具体涉及一种改善热喷涂陶瓷涂层自润滑性能的方法。其既能保留陶瓷涂层的原有性能,又能有效改善其摩擦磨损性能。本发明采用的方法步骤为：步骤一：采用大气等离子喷涂设备在金属基材上沉积制备ZrO<Sub>2</Sub>基陶瓷涂层；步骤二：采用真空浸渍工艺将反应溶液渗入到ZrO<Sub>2</Sub>基陶瓷涂层内部的孔隙中；步骤三：将样品置于反应釜的底部,将反应釜放入烘箱中加热,以2℃/min分别升温至180℃和220℃,对应保温6h和48h进行反应,即可实现在ZrO<Sub>2</Sub>基陶瓷涂层的孔隙中原位合成C/MoS<Sub>2</Sub>复合润滑剂,获得具有优异室温润滑性能的陶瓷基复合涂层。(The invention relates to the technical field of surface modification, in particular to a method for improving the self-lubricating property of a thermal spraying ceramic coating. The original performance of the ceramic coating can be kept, and the frictional wear performance of the ceramic coating can be effectively improved. The method adopted by the invention comprises the following steps: the method comprises the following steps: preparation of ZrO by deposition on metal substrate by using atmospheric plasma spraying equipment 2 A base ceramic coating; step two: the reaction solution is infiltrated into ZrO by adopting a vacuum impregnation process 2 In the pores inside the base ceramic coating; step three: placing the sample at the bottom of a reaction kettle, placing the reaction kettle in an oven for heating, respectively heating to 180 ℃ and 220 ℃ at the speed of 2 ℃/min, correspondingly preserving heat for 6h and 48h for reaction, and then obtaining the ZrO 2 In-situ synthesis of C/MoS in pores of base ceramic coatings 2 Composite lubricant with excellent room temperature wettabilityA ceramic matrix composite coating with slip properties.)

1. A method for improving the self-lubricating property of a thermal spraying ceramic coating is characterized by comprising the following steps:

the method comprises the following steps: preparation of ZrO by deposition on metal substrate by using atmospheric plasma spraying equipment₂A coating layer of a base ceramic, wherein,

step two: the reaction solution is infiltrated into ZrO by adopting a vacuum impregnation process₂In the pores inside the base ceramic coating,

step three: placing the sample at the bottom of a reaction kettle, placing the reaction kettle in an oven for heating, respectively heating to 180 ℃ and 220 ℃ at the speed of 2 ℃/min, correspondingly preserving heat for 6h and 48h for reaction, and then obtaining the ZrO₂In-situ synthesis of C/MoS in pores of base ceramic coatings₂Compounding the lubricant to obtain the ceramic matrix composite coating with excellent room temperature lubricating performance.

2. The method of improving the self-lubricating properties of a thermally sprayed ceramic coating of claim 1, wherein: the reagent needed by the synthesis of C is glucose, and the purity of the glucose is more than or equal to 99.0%.

3. A method of improving the self-lubricating properties of a thermally sprayed ceramic coating according to claim 1 or 2, characterised in that: the synthetic MoS₂The required reagents are sodium molybdate and thiourea, and the purity of the reagents is more than or equal to 99.0 percent.

Technical Field

The invention relates to the technical field of surface modification, in particular to a method for improving the self-lubricating property of a thermal spraying ceramic coating.

Background

The continuous improvement of the comprehensive performance requirements of materials and the continuous deterioration of the working conditions and environments of related parts result in the serious abrasion of metal materials and the premature failure of equipment, and the failure of mechanical parts at key parts can cause catastrophic results, so that the problems of lubrication and abrasion resistance of moving parts under extreme working conditions become bottlenecks affecting the reliability and the service life of mechanical systems.

At present, the requirements of a large amount of advanced technical equipment on the performances of high precision, high efficiency, high reliability, long service life and the like are greatly improved, the requirements on self-lubricating wear-resistant materials and preparation technologies for breaking through the original performance limit are urgent, and the research on special lubricating wear-resistant materials with excellent performance is more and more focused. Ceramics are receiving increasing attention as protective coatings for mechanical parts, but the inherent brittleness and lack of lubricity of ceramic coatings severely limit the wide application of such coatings to frictional parts.

In the preparation technology of various ceramic coatings, the central temperature of the jet flow of the plasma spraying (APS) process is up to 10000 ℃, all materials with physical melting points can be melted, and the preparation method has outstanding advantages in the aspect of spraying ceramic coatings.

However, the prior art has the following problems:

first, pores and microcracks inevitably exist in ceramic coatings prepared by atmospheric plasma spraying technology, and the porous structural defects not only affect the mechanical properties of the coatings, but also affect the frictional wear properties of the coatings.

Second, the flame temperature of the atmospheric plasma spraying process is high, graphite and MoS₂When the traditional lubricant is easy to oxidize and decompose, after the metal coating or the metal lubricant is adopted, the metal and the ceramic have larger performance difference (such as wettability, expansion coefficient, cooling rate and the like), and the prepared coating has more defects, so that the mechanical performance is reduced.

The invention content is as follows:

in view of the above, the present invention provides a method for improving the self-lubricating performance of a thermal spray ceramic coating, which can not only retain the original performance of the ceramic coating, but also effectively improve the frictional wear performance of the ceramic coating.

In order to solve the problems in the prior art, the technical scheme of the invention is as follows: a method for improving the self-lubricating property of a thermal spraying ceramic coating is characterized by comprising the following steps:

the method comprises the following steps: preparation of ZrO by deposition on metal substrate by using atmospheric plasma spraying equipment₂A coating layer of a base ceramic, wherein,

step two: the reaction solution is infiltrated into ZrO by adopting a vacuum impregnation process₂In the pores inside the base ceramic coating,

step three: placing the sample at the bottom of a reaction kettle, placing the reaction kettle in an oven for heating, respectively heating to 180 ℃ and 220 ℃ at the speed of 2 ℃/min, correspondingly preserving heat for 6h and 48h for reaction, and then obtaining the ZrO₂In-situ synthesis of C/MoS in pores of base ceramic coatings₂Compounding the lubricant to obtain the ceramic matrix composite coating with excellent room temperature lubricating performance.

Furthermore, the reagent needed for synthesizing C is glucose, and the purity of the glucose is more than or equal to 99.0%.

Further, MoS was synthesized₂The required reagents are sodium molybdate and thiourea, and the purity of the reagents is more than or equal to 99.0 percent.

Compared with the prior art, the invention has the following advantages:

1. the invention synthesizes the lubricant in situ in the defects of pores, microcracks and the like of the coating on the premise of not changing the original performance of the thermal spraying ceramic coating, and improves the compactness of the coating;

2. the self-lubricating ceramic matrix composite coating can show excellent tribological performance under the working condition of room temperature;

3. the reactants of the hydrothermal reaction are dissolved in the aqueous solution in a molecular or ionic form and can enter a tiny space for reaction;

4. after the lubricant in the pores of the coating is synthesized, the compactness of the coating can be improved, and the hardness of the coating is further increased;

5. the invention synthesizes high-performance C/MoS₂After the lubricant is compounded, a continuous lubricating film with a self-repairing function can be formed in the friction process, so that the wear-resisting life of the coating is prolonged.

Drawings

FIG. 1 is a FESEM topography of a coating cross-section before (a) and after (b) the synthesis of a lubricant;

FIG. 2 is a graph of coefficient of friction (a) and wear rate (b) for the coating;

FIG. 3 is a FESEM topography of the wear surface of the coating before (a) and after (b) the synthesis of the lubricant.

The specific implementation mode is as follows:

in order to make the objects, technical solutions and advantages of the present invention more apparent, the present invention is described in further detail below with reference to the accompanying drawings and embodiments. It should be understood that the specific embodiments described herein are merely illustrative of the invention and are not intended to limit the invention.

Referring to FIGS. 1-3, thermally sprayed ZrO₂The base coating has more irregular pores and cracks, and the composite coating has some attachments, such as C and MoS, in the cross section after the lubricant is synthesized₂Uniformly adhered to the ZrO₂A surface of a base coat defect; the composite coating shows very excellent frictional wear performance due to the synergistic effect of the lubricant; ZrO (ZrO)₂The grinding mark surface of the base ceramic coating is very rough and has more abrasive dust, while the grinding mark surface of the composite coating is smooth and has only slight abrasive wear.

The method comprises the following steps: the metal substrate is subjected to sand blasting treatment to roughen the surfaceUltrasonically cleaning in acetone for 20min to remove residual fine sand particles, grease and other impurities in the sand blasting process; spraying a NiCrAlY transition layer with the thickness of about 80 mu m on the surface of the metal base material after sand blasting treatment, and then spraying ZrO₂The thickness of the base coating is controlled to be 250-300 μm.

Step two: 8.0g of glucose was dissolved in 80mL of deionized water, stirred uniformly, and then polished ZrO was added₂The base coating is flatly placed in a glucose solution (with the purity being more than or equal to 99.0 percent) which is uniformly stirred (the coating faces upwards), and the base coating is placed in a vacuum drying oven and is soaked for 60min under the pressure of-0.08 MPa, so that the glucose solution is soaked into the bottom of the coating as deep as possible.

Step three: after completion of the immersion, the sample was allowed to stand to 150mLPouring the solution into the bottom of a hydrothermal reaction kettle, heating to 180 ℃ at a speed of 2 ℃/min, carrying out heat preservation reaction for 6 hours, naturally cooling to room temperature after the reaction is finished, taking out a sample, cleaning, slightly polishing, and removing C powder adhered to the surface of the sample to obtain ZrO₂-C composite coating.

Step four: dissolving 2.77g of thiourea (the purity is more than or equal to 99.0%) and 1.87g of sodium molybdate (the purity is more than or equal to 99.0%) into 80mL of deionized water, magnetically stirring for 30min to fully dissolve the thiourea and the sodium molybdate, and dissolving ZrO₂the-C composite coating was laid flat in the solution (coating side up) and sonicated for 10min, then placed in a vacuum drying oven and immersed for 60min at-0.08 MPa pressure to immerse the solution as deep as possible into the bottom of the coating.

Step five: taking out the sample after the impregnation is finished, flatly placing the sample to the bottom of a 150mL polytetrafluoroethylene lining, pouring the solution, placing the sample into a high-pressure reaction kettle for sealing, placing the sealed reaction kettle into an oven, heating to 220 ℃ at a speed of 2 ℃/min, preserving heat for 48 hours, naturally cooling to room temperature after the reaction is finished, taking out the sample, cleaning, slightly polishing, and removing MoS adhered to the surface of the sample₂Powder to obtain ZrO₂-C/MoS₂And (4) composite coating.

Step six: ZrO treated by CSM friction tester₂And (3) testing and analyzing the tribological properties of the base coating and the prepared composite coating. All tests were carried out at room temperature (temperature 25. + -. 5 ℃ C., humidity 30. + -. 5%) and the test speed, amplitude and sliding distance were 10 cm. multidot.s, respectively^-12.5mm and 200m, a load of 8N, 6mm diameter Al for the dual ball₂O₃The abrasion volume of the ceramic ball and the coating is measured by a non-contact three-dimensional profilometer. The test results are shown in Table 1.

TABLE 1 Friction and wear Properties of self-lubricating ceramic-based coating at Room temperature

On the basis of ensuring the original performance of the ceramic coating, the invention introduces the lubricant into the coating by interdisciplinary fusion and utilizing the defects of the ceramic coating and adopting an in-situ synthesis mode to obtain the self-lubricating ceramic matrix composite coating. The performance test shows that after the lubricant is introduced into the coating, a continuous lubricating film with a self-repairing function can be formed in the friction process, the room-temperature tribological performance of the thermal spraying ceramic coating is obviously improved, and meanwhile, the ceramic coating can be endowed with more excellent comprehensive mechanical work-leading performance. The preparation technology provides a new way for preparing the self-lubricating ceramic matrix composite coating with the temperature-sensitive solid lubricant.