Semiconductor layer structure with thick buffer layer
阅读说明:本技术 具有厚缓冲层的半导体层结构 (Semiconductor layer structure with thick buffer layer ) 是由 L.范 于 2019-06-28 设计创作,主要内容包括:一种半导体层结构,可以包括衬底、形成在衬底上的缓冲层,以及形成在缓冲层上的一组外延层。所述缓冲层可以具有大于2微米(μm)的厚度。所述一组外延层包括量子阱层。量子阱混合区域可以与所述量子阱层和从半导体层结构的表面的区域扩散的材料相关联地形成。(A semiconductor layer structure may include a substrate, a buffer layer formed on the substrate, and a set of epitaxial layers formed on the buffer layer. The buffer layer may have a thickness greater than 2 micrometers (μm). The set of epitaxial layers includes a quantum well layer. The quantum well intermixed region can be formed in association with the quantum well layer and a material diffused from a region of a surface of the semiconductor layer structure.)
1. A semiconductor layer structure, comprising:
a substrate;
a buffer layer formed on the substrate; and
a set of epitaxial layers formed on the buffer layer;
wherein the buffer layer has a thickness greater than 2 micrometers (μm),
wherein the set of epitaxial layers includes a quantum well layer, an
Wherein a quantum well intermixed region is formed in association with the quantum well layer and a material diffused from a region of a surface of the semiconductor layer structure.
2. The semiconductor layer structure of claim 1, wherein the semiconductor layer structure is included in a laser device.
3. The semiconductor layer structure of claim 2, wherein the laser device has a laser wavelength in the Infrared (IR) or near-infrared range.
4. The semiconductor layer structure of claim 3 wherein the laser wavelength is substantially independent of a slicing position or a number of slices from the substrate of the ingot.
5. The semiconductor layer structure of claim 1, wherein the buffer layer comprises the same material as the substrate.
6. The semiconductor layer structure of claim 1, wherein the buffer layer has a thickness in a range of 2 μ ι η to 5 μ ι η.
7. A semiconductor laser comprising:
a substrate;
a buffer layer formed on the substrate; and
a set of epitaxial layers formed on the buffer layer;
wherein the buffer layer has a thickness in a range of 2 micrometers (μm) to 5 μm,
wherein the set of epitaxial layers includes a quantum well layer, an
Wherein a quantum well intermixing region is formed within the quantum well layer using a quantum well intermixing material diffused through a region from a surface of the semiconductor layer structure.
8. The semiconductor laser of claim 7, wherein the semiconductor laser and another semiconductor laser formed using another substrate of the same boule as the substrate have a laser wavelength variation of less than 20 nanometers (nm).
9. The semiconductor laser of claim 8, wherein the lasing wavelength of the semiconductor laser and the lasing wavelength of the another semiconductor laser are measured under the same operating conditions.
10. The semiconductor laser of claim 8, wherein the lasing wavelengths corresponding to the semiconductor laser and the another semiconductor laser are in the Infrared (IR) or near-infrared range.
11. The semiconductor laser of claim 10, wherein lasing wavelengths corresponding to the semiconductor laser and the another semiconductor laser occur when the semiconductor laser and the another semiconductor laser lase at room temperature.
12. The semiconductor laser of claim 7, wherein the buffer layer is an n-doped buffer layer.
13. The semiconductor laser of claim 12, wherein an n-doped cap layer of the set of epitaxial layers is formed on an n-doped buffer layer,
wherein the quantum well layer is formed on the n-doped cladding layer.
14. The semiconductor laser of claim 7, wherein the thickness averages 4 μ ι η across the buffer layer.
15. An optical device, comprising:
a substrate;
a buffer layer formed on the substrate; and
a set of epitaxial layers formed on the buffer layer;
wherein the buffer layer has an average thickness of 4 micrometers (μm) across the buffer layer,
wherein the set of epitaxial layers includes a quantum well layer, an
Wherein the quantum well intermixed region is formed within the quantum well layer by diffusion of a material from a region of the surface of the semiconductor layer structure using quantum well intermixing,
wherein the cover layer is formed on the buffer layer.
16. The optical device of claim 15, wherein the buffer layer is an n-doped buffer layer.
17. The optical device of claim 15, wherein the buffer layer is a gallium arsenide (GaAs) buffer layer.
18. The optical device of claim 15, wherein a difference between a laser wavelength of the optical device and another laser wavelength of another optical device is less than 20 μm,
wherein the substrate of the optical device and the further substrate of the further optical device are associated with the same ingot.
19. The optical apparatus of claim 18, wherein the laser wavelength and the another laser wavelength are in the Infrared (IR) or near-infrared range.
20. The optical apparatus of claim 18, wherein the laser wavelength and the further laser wavelength are at an operating current (I)op) And occurs during lasing at room temperature.
Technical Field
The present disclosure relates to emitter arrays, and more particularly to semiconductor layer structures having thick buffer layers.
Background
Semiconductor lasers are formed from various epitaxial layers. Various epitaxial layers are grown on the substrate. When supplied with electric current, the semiconductor laser emits laser light. The semiconductor laser may comprise an edge emitting laser or a vertical emitting laser, such as a Vertical Cavity Surface Emitting Laser (VCSEL).
Disclosure of Invention
According to some embodiments, a semiconductor layer structure may include: a substrate; a buffer layer formed on the substrate; and a set of epitaxial layers formed on the buffer layer, wherein the buffer layer has a thickness greater than 2 micrometers (μm), wherein the set of epitaxial layers includes a quantum well layer, and wherein a quantum well intermixed region is formed in association with the quantum well layer and a material diffused from a region of a surface of a semiconductor layer structure.
According to some embodiments, a semiconductor laser may include: a substrate; a buffer layer formed on the substrate; and a set of epitaxial layers formed on the buffer layer, wherein the buffer layer has a thickness in a range of 3 micrometers (μm) to 5 μm, wherein the set of epitaxial layers includes a quantum well layer, and wherein a quantum well intermixed region is formed within the quantum well layer by material diffused from a region of a surface of the semiconductor layer structure using quantum well intermixing.
According to some embodiments, an optical device may include: a substrate; a buffer layer formed on the substrate; and a set of epitaxial layers formed on the buffer layer; wherein the buffer layer has a thickness of 4 micrometers (μm) on average across the buffer layer, wherein the set of epitaxial layers comprises a quantum well layer, and wherein a quantum well intermixed region is formed within the quantum well layer using quantum well intermixing through material diffused from a region of a surface of a semiconductor layer structure, wherein a capping layer is formed on the buffer layer.
According to some embodiments, a method may comprise: providing a substrate; forming a buffer layer on the substrate, wherein the buffer layer has a thickness greater than 2 micrometers (μm); and forming a set of epitaxial layers on the buffer layer, wherein the set of epitaxial layers includes a quantum well layer, and wherein a quantum well intermixed region is formed in association with the quantum well layer and a material diffused from a region of a surface of the semiconductor layer structure.
Drawings
Fig. 1 is a graph depicting the relationship between the laser wavelength and the number of slices of an ingot (boule) of a conventional semiconductor layer structure.
Fig. 2 is a diagram depicting an example embodiment of a semiconductor layer structure having a thick buffer layer as described herein.
Fig. 3 and 4 are diagrams depicting one or more graphs comparing various thicknesses of a buffer layer and the correspondence between the number of slices and the laser wavelength for various thickness ingots.
Fig. 5 is a flow chart depicting an example process for forming a semiconductor layer structure having a thick buffer layer as described herein.
Detailed Description
The following detailed description of example embodiments refers to the accompanying drawings. The same reference numbers in different drawings may identify the same or similar elements.
Impurity-induced disorder (Impurity-induced disorder) can be used to produce high power diode lasers. During this process, the wafer is placed in a high temperature environment until the quantum wells (quantum wells) are mixed. However, quantum well intermixing occurs not only in the region where quantum well intermixing is expected to occur, but also in the active region of the semiconductor layer structure of the diode laser where it is detrimental. The result of this process is a significant difference in laser wavelength between different wafers, which can result in low yield for a given wavelength specification. Significant wavelength variation has been observed as the number of substrate slices from the same ingot varies (e.g., wafers from the same ingot may experience a wavelength variation of 30 nanometers (nm) or greater depending on the number of slices of wafers from the ingot). For example, the laser wavelength for wafers with low substrate slice numbers (e.g., in the range of 850nm to 865 nm) is typically much shorter than the laser wavelength for wafers with high substrate slice numbers (e.g., in the range of 875nm to 895 nm) in the same growth run. During the growth process and other wafer thermal treatments, particularly during impurity-induced disordering process steps, impurities or point defects (e.g., holes, where atoms are absent in the crystal lattice) are present in the substrate and tend to migrate toward the epitaxial layers of the semiconductor layer structure. This migration of impurities or point defects promotes quantum well intermixing, causing the laser wavelength to deviate from the design wavelength.
A barrier layer between the substrate and the epitaxial layer is required to block and/or reduce such migration. The buffer layer separating the epitaxial layer from the substrate plays a key role in epitaxial growth quality. The buffer layer facilitates a smooth interface for epitaxial growth since even the most careful substrate preparation does not provide an atomically smooth surface, which becomes more rough during the initial "oxide blow-off". After growing a thin GaAs buffer layer, the epitaxial structure of the near-infrared semiconductor laser is typically grown on a GaAs substrate. In the above semiconductor layer structure, the thickness of the buffer layer is generally about 0.4 micrometers (μm) (or about 400 nm).
Some embodiments described herein provide a semiconductor layer structure (e.g., for a semiconductor diode laser) that includes a thick buffer layer. For example, the thick buffer layer may separate the substrate of the semiconductor layer structure and various epitaxial layers of the semiconductor layer structure (e.g., when the semiconductor layer structure is included in a semiconductor laser, the various epitaxial layers may be associated with excitation light). The thick buffer layer may have a thickness of multiple micrometers (μm) that prevents or impedes migration of impurities or point defects from the substrate into the respective epitaxial layers. This provides improved control of the laser wavelength between semiconductor lasers generated from different wafers by reducing or eliminating quantum well intermixing in unintended regions of the semiconductor layer structure, thereby reducing or eliminating wavelength variability between different semiconductor lasers, and/or reducing the likelihood that the wavelength of a semiconductor laser formed from the semiconductor layer structure has a laser wavelength outside of the design wavelength range. Improved control of the laser wavelength improves the yield of semiconductor lasers produced from an ingot by providing improved control of the laser wavelength over a range of wavelengths across different semiconductor lasers formed from different wafers of the ingot. The improved yield reduces cost and eliminates waste that would otherwise occur through the use of a semiconductor layer structure that does not include a thick buffer layer.
Fig. 1 is a
As described above, fig. 1 is provided as an example. Other examples may differ from the example described with reference to fig. 1.
Fig. 2 is a diagram depicting an example embodiment of a
As shown in fig. 2, the semiconductor layer structure may include a
As further shown in fig. 2, the semiconductor layer structure may include a
Various epitaxial layers may be formed on the
As further shown in fig. 2, the semiconductor layer structure may include a second waveguide layer 260 (e.g., a p-waveguide layer) formed on the
The semiconductor layer structure shown in fig. 2 and described with reference thereto may be used to form various types of devices. For example, the semiconductor layer structure may be used to form a semiconductor laser (e.g., a semiconductor diode laser), a light emitting device, and the like. In some embodiments, the laser wavelength of the device can be in the Infrared (IR) or near-infrared (nir)A range (e.g., in the range of 700nm to 1000 nm). By including a thick buffer layer, the semiconductor layer structure shown in fig. 2 provides improved control of laser wavelength variability between different devices formed from
In this manner, some embodiments described herein provide a semiconductor layer structure that includes a thick buffer layer. The thick buffer layer may reduce or eliminate migration of defects from the
As described above, fig. 2 is provided as an example. Other examples may differ from the example described with reference to fig. 2.
Fig. 3 is a
As described above, fig. 3 depicts one or more examples. Other examples may differ from the example described in the opening fig. 3.
FIG. 4 is a
As noted above, fig. 4 is provided as an example only. Other examples may differ from the example described in connection with fig. 4.
Fig. 5 is a flow diagram depicting an
As shown in fig. 5, the
As further shown in fig. 5,
As further shown in fig. 5, the
In some embodiments, the semiconductor layer structure is included in a laser device. In some embodiments, the laser device has a wavelength in the Infrared (IR) or near-infrared range. In some embodiments, the laser wavelength of the laser device is substantially independent of the slicing position of the substrate from the ingot.
In some embodiments, the buffer layer comprises the same material as the substrate. In some embodiments, the buffer layer has a thickness in the range of 2 μm to 5 μm. In some embodiments, the thickness averages 4 μm across the buffer layer. In some embodiments, the buffer layer is an n-doped buffer layer. In some embodiments, the n-doped cap layer of the set of epitaxial layers is formed on the n-doped buffer layer. In some embodiments, the quantum well layer is formed on the n-doped cladding layer.
Although fig. 5 shows example blocks of the
The foregoing disclosure provides illustration and description, but is not intended to be exhaustive or to limit the embodiments to the precise form disclosed. Modifications and variations are possible in light of the above disclosure or may be acquired from practice.
As used herein, the term "layer" is intended to be construed broadly as one or more layers and includes layers that are oriented horizontally, vertically, or at other angles.
Some embodiments are described herein in connection with a threshold.
As used herein, meeting a threshold may refer to a value being greater than the threshold, greater than or equal to the threshold, less than or equal to the threshold, and the like, depending on the context.
Although particular combinations of features are recited in the claims and/or disclosed in the specification, these combinations are not intended to limit the disclosure of the various embodiments. Indeed, many of these features may be combined in ways not specifically recited in the claims and/or disclosed in the specification. Although each dependent claim listed may directly depend on only one claim, the disclosure of the various embodiments includes each dependent claim with every other claim in the set of claims.
No element, act, or instruction used herein should be construed as critical or essential unless explicitly described as such. In addition, as used herein, the articles "a" and "an" are intended to include one or more items, and may be used interchangeably with "one or more". Further, as used herein, the article "the" is intended to include one or more items that are referenced in association with the article "the" and may be used interchangeably with "one or more.
Further, as used herein, the term "group" is intended to include one or more items (e.g., related items, unrelated items, combinations of related and unrelated items, etc.) and may be used interchangeably with "one or more. In the case of only one item, the phrase "only one" or similar language is used. Further, as used herein, the term "having" and the like are intended to be open-ended terms. Further, the phrase "based on" is intended to mean "based, at least in part, on" unless explicitly stated otherwise. Further, as used herein, the term "or" when used in succession is intended to be inclusive and may be used interchangeably with "and/or" unless specifically stated otherwise (e.g., if used in combination with "either" or "only one").
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