阅读说明：本技术 锂合金靶材及其制备方法与应用 (Lithium alloy target material and preparation method and application thereof ) 是由 张艳芳 谭志 虞文韬 于 2020-03-30 设计创作，主要内容包括：本发明涉及一种锂合金靶材及其制备方法与应用,该锂合金靶材的制备方法中,通过在靶管的外壁设置凹陷部或纹路可增加靶管表面与熔融反应液的接触面积,并使得混合液冷却收缩时的应力释放首先出现在凹处部分,从而使混合液在冷却过程中与靶管能够紧密贴合,得到品质优异的锂合金靶材。该锂合金靶材能对电极材料进行有效的补锂,从而解决锂离子电池体积膨胀的问题,并提高锂离子电池的循环使用寿命。(The invention relates to a lithium alloy target material and a preparation method and application thereof. The lithium alloy target material can effectively supplement lithium for the electrode material, thereby solving the problem of volume expansion of the lithium ion battery and prolonging the cycle service life of the lithium ion battery.)

1. The preparation method of the lithium alloy target is characterized by comprising the following steps:

providing a mold and a target tube, arranging the target tube in the mold, and forming a forming cavity for forming between the target tube and the inner wall of the mold; the outer wall of the target tube is provided with a concave part, and/or the outer wall of the target tube is provided with grains;

mixing the first simple substance and the second simple substance, and heating to obtain a mixed solution;

pouring the mixed solution into the molding cavity for cooling and molding;

removing the die to obtain a lithium alloy target material;

the first simple substance is molten lithium, and the second simple substance is any one selected from boron powder, silicon powder and molten sulfur.

2. The method for preparing a lithium alloy target according to claim 1, wherein the second simple substance is selected from boron powder, and the molar ratio of the molten lithium to the boron powder is (2-8): 1-9.

3. The method for preparing a lithium alloy target according to claim 1, wherein the second simple substance is selected from silicon powder, and the molar ratio of the molten lithium to the silicon powder is (2-8): 1-9.

4. The method for preparing a lithium alloy target according to claim 1, wherein the second element is selected from molten sulfur, and the molar ratio of the molten lithium to the molten sulfur is (1-9): (1-9).

5. The method for preparing a lithium alloy target according to claim 1, wherein the heating temperature is 190 ℃ to 1000 ℃.

6. The method for preparing a lithium alloy target according to any one of claims 1 to 5, wherein the depth of the recess is 1mm to 10mm, the width of the recess is 1mm to 20cm, and the slope of the recess is 5 ° to 85 °.

7. The method for preparing a lithium alloy target according to any one of claims 1 to 5, wherein the texture is a convex texture or a concave texture.

8. The method for preparing a lithium alloy target according to any one of claims 1 to 5, wherein the target tube is a cylindrical target tube having a diameter of 30mm to 200mm and a length of 100mm to 5000 mm.

9. The method for preparing a lithium alloy target according to any one of claims 1 to 5, wherein a metal foil is coated on the inner wall of the mold, and the metal foil is selected from any one of aluminum foil, copper foil, iron foil, graphite foil and stainless steel foil.

10. The lithium alloy target is characterized by comprising a target tube and a lithium alloy material coated on the target tube, wherein the outer wall of the target tube is provided with a concave part and/or the outer wall of the target tube is provided with grains, and the lithium alloy material is lithium boride, lithium silicide or lithium sulfide.

11. The lithium alloy target according to claim 10, wherein the lithium alloy target is a magnetron sputtering target.

12. The lithium alloy target according to claim 11, wherein the target tube has a hollow portion, a first magnetic pole and two second magnetic poles respectively disposed on two opposite sides of the first magnetic pole are disposed in the hollow portion of the target tube, one of the first magnetic pole and the second magnetic pole is an S magnetic pole, and the other is an N magnetic pole.

13. Use of a lithium alloy target material prepared by the method of preparing a lithium alloy target material according to any one of claims 1 to 9 or a lithium alloy target material according to any one of claims 10 to 12 for the preparation of a lithium battery.

Technical Field

The invention relates to the technical field of lithium ion batteries, in particular to a lithium alloy target material and a preparation method and application thereof.

Background

Research shows that when silicon is used as a negative electrode material of a lithium ion battery, the theoretical specific capacity of the battery is up to 4200mAh/g, which is much higher than that of a commercial graphite negative electrode lithium ion battery (the theoretical specific capacity is up to 372mAh/g), so that the silicon is widely concerned by technical researchers. However, the elementary silicon is accompanied by huge volume change (up to 300%) in the charging and discharging process, which causes the active particles of the negative electrode to fall off from the surface of the current collector after being crushed and pulverized, thereby losing electric contact, and also aggravates the side reaction between the electrode active material and the electrolyte, finally causing the electrode performance to be sharply reduced, and the problem greatly limits the development and practical application of silicon as the negative electrode material of the lithium ion battery. Furthermore, researchers find that when the silicon monoxide is also used as a negative electrode material of a battery, the silicon monoxide also has higher specific capacity, and compared with simple substance silicon, the volume change of the silicon monoxide in the charge and discharge process is smaller; however, the poor electronic and ionic conductivity of the silica material greatly affects the electrochemical performance, and compared with the simple substance silicon, the volume expansion of the silica material is relieved, but the problem that the active material cracks due to stress concentration caused by volume change still exists.

In order to solve the above problems, researchers have supplemented lithium in the negative electrode material/positive electrode material to solve the problem of battery volume expansion and improve the first efficiency. The silicon-carbon negative electrode lithium supplementing process is characterized in that a layer of lithium metal is pre-coated on the surface of a silicon-carbon negative electrode, the coating is in close contact with the negative electrode, the coating reacts with the negative electrode after electrolyte is filled, the coating is embedded into negative electrode particles, and a part of lithium ions are pre-stored in the negative electrode, so that the lithium (Li) ions which are consumed by forming or repairing an SEI film in the first charge-discharge or circulation process are compensated.

In the conventional technology, there are many methods for pre-replenishing lithium, among which, the physical deposition (PVD) method for pre-replenishing lithium is a commonly used method for replenishing lithium, and vacuum evaporation is a method for depositing a metal film on the surface of a material by heating metal lithium under a high vacuum condition to melt and evaporate the metal lithium, however, vacuum evaporation is not suitable for lithium replenishing materials with high boiling points, and the process conditions are too severe.

The lithium metal layer plated by magnetron sputtering has good adhesiveness, and heating is not needed in the film plating process, so the method is a very efficient lithium supplement method. However, when magnetron sputtering is adopted, the lithium supplement material cannot be directly placed in the PVD lithium supplement device, and it is necessary to first combine the lithium supplement material with the target tube to form a lithium target material, and then place the lithium target material in the lithium supplement device to sputter the target material to supplement lithium for the lithium ion battery cathode/anode material. However, when the lithium target is prepared by the conventional technology, the problems that the target source material cannot be tightly attached to the target tube due to local foaming and bulging caused by internal stress when the target source material mixed solution is cooled and shrunk are solved, so that the quality of the lithium alloy target material is affected, the structure of the magnetron sputtering coating is not compact and uniform, the problem of volume expansion of the lithium ion battery cathode material cannot be completely solved by the prepared lithium target material, and the cycle service life of the lithium ion battery is short.

Disclosure of Invention

Based on the lithium alloy target material, the preparation method and the application thereof, the prepared lithium target material is applied to the lithium battery, and the problem of battery volume expansion can be effectively solved, so that the cycle service life of the lithium battery is prolonged.

The technical scheme of the invention is as follows.

The invention provides a preparation method of a lithium alloy target material on one hand, which comprises the following steps:

providing a mold and a target tube, arranging the target tube in the mold, and forming a forming cavity for forming between the target tube and the inner wall of the mold; the outer wall of the target tube is provided with a concave part and/or the outer wall of the target tube is provided with grains;

mixing the first simple substance and the second simple substance, and heating to obtain a mixed solution;

pouring the mixed solution into the molding cavity for cooling and molding;

removing the die to obtain a lithium alloy target;

the first simple substance is molten lithium, and the second simple substance is any one selected from boron powder, silicon powder and molten sulfur.

The contact area between the surface of the target tube and the molten reaction liquid can be increased by arranging the concave parts or the grains on the outer wall of the target tube, and the stress release when the mixed liquid is cooled and contracted is firstly released at the concave part, so that the mixed liquid can be tightly attached to the target tube in the cooling process, and the lithium alloy target with excellent quality is obtained. When the lithium ion battery is prepared, the physical deposition (PVD) is carried out on the lithium alloy target material, a uniform lithium alloy thin layer can be deposited on the surface of an electrode material, and the expected lithium supplement effect is achieved, so that the problem of volume expansion of the lithium ion battery is solved, and the cycle service life of the lithium ion battery is prolonged.

In the preparation method of the lithium alloy target, the second simple substance is selected from boron powder, and the molar ratio of the molten lithium to the boron powder is (2-8) to (1-9).

In the preparation method of the lithium alloy target, the second simple substance is selected from silicon powder, and the molar ratio of the molten lithium to the silicon powder is (2-8) to (1-9).

In some embodiments, the second element is selected from molten sulfur, and the molar ratio of the molten lithium to the molten sulfur is (1-9): 1-9.

In some of these embodiments, the heating is carried out at a temperature of 190 ℃ to 1000 ℃.

In some embodiments, the depth of the recess is 1mm to 10mm, the width of the recess is 1mm to 20cm, and the slope of the recess is 5 ° to 85 °.

In some embodiments, the texture is an outward convex texture or an inward concave texture.

In some of these embodiments, the target tube is a cylindrical target tube having a diameter of 30mm to 200mm and a length of 100mm to 5000 mm.

In some embodiments, the inner wall of the mold is covered with a metal foil selected from any one of aluminum foil, copper foil, iron foil, graphite foil, and stainless steel foil.

In some embodiments, the present invention provides a lithium alloy target material, including a target tube and a lithium alloy material coated on the target tube, wherein the outer wall of the target tube has a recess and/or the outer wall of the target tube has a texture, and the lithium alloy material is lithium boride, lithium silicide or lithium sulfide.

In some of these embodiments, the lithium alloy target is a magnetron sputtering target

In some embodiments, the target tube has a hollow portion, a first magnetic pole and two second magnetic poles respectively disposed on two opposite sides of the first magnetic pole are disposed in the hollow portion of the target tube, one of the first magnetic pole and the second magnetic pole is an S magnetic pole, and the other is an N magnetic pole.

The invention provides a lithium alloy target material prepared by the preparation method of the lithium alloy target material or an application of the lithium alloy target material in preparation of a lithium battery.

Drawings

Fig. 1 is a schematic view of a casting step in a method for preparing a lithium alloy target according to an embodiment of the present invention;

fig. 2 is a schematic view of a target tube used in the method for preparing a lithium alloy target according to an embodiment of the present invention;

FIG. 3 is a schematic view of a target tube used in a method for preparing a lithium alloy target according to yet another embodiment of the present invention;

fig. 4 is a schematic view of a target tube used in a method for preparing a lithium alloy target according to yet another embodiment of the present invention.

Detailed Description

In order that the invention may be more fully understood, a more particular description of the invention will now be rendered by reference to specific embodiments thereof that are illustrated in the appended drawings. This invention may, however, be embodied in many different forms and should not be construed as limited to the embodiments set forth herein. Rather, these embodiments are provided so that this disclosure will be thorough and complete.

Unless defined otherwise, all technical and scientific terms used herein have the same meaning as commonly understood by one of ordinary skill in the art to which this invention belongs. The terminology used in the description of the invention herein is for the purpose of describing particular embodiments only and is not intended to be limiting of the invention. As used herein, the term "and/or" includes any and all combinations of one or more of the associated listed items.

Generally, a lithium supplement material is combined on a target tube by adopting a casting method to prepare the lithium target material, however, researchers of the invention find that the problem that the lithium supplement material is not tightly combined with the stainless steel smooth target tube exists in the casting forming process, so that the lithium supplement material cannot be completely tightly attached to the stainless steel target tube in the cooling process, local foaming, bulging and other problems are generated, the quality and the performance of the lithium target material are influenced, and the expected lithium supplement effect cannot be achieved. Therefore, how to prepare the lithium target material with the lithium supplement material tightly combined with the target tube is the key to solve the problems of volume expansion of the lithium ion battery and improvement of the first efficiency.

Based on this, an embodiment of the invention provides a preparation method of a lithium alloy target.

Fig. 1 shows a schematic view of a casting step in a method for preparing a lithium alloy target according to an embodiment of the present invention; fig. 2 is a schematic view of a target tube used in the method for manufacturing a lithium alloy target according to an embodiment of the present invention; fig. 3 shows a schematic view of a target tube used in a method for manufacturing a lithium alloy target according to yet another embodiment of the present invention; fig. 4 shows a schematic view of a target tube used in a method for manufacturing a lithium alloy target according to yet another embodiment of the present invention.

Referring to fig. 1, a method for preparing a lithium alloy target according to an embodiment of the present invention includes the following steps S1-S4.

S1, providing a mold 2 and a target tube 1, arranging the target tube 1 in the mold 2, and forming a forming cavity 3 for forming between the target tube 1 and the inner wall of the mold 2; the outer wall of the target tube 1 has a recess and/or the outer wall of the target tube 1 has a texture.

In one embodiment, the recess is an annular structure disposed around the circumference of the target tube 1.

It should be noted that the concave portion on the target tube 1 can be arranged at any position on the target tube 1, except for two ends of the target tube 1, it can also be arranged in the middle of the target tube 1; the number of the recesses may be one or more, and the size of each recess may be the same or different.

In one embodiment, the concave parts are arranged at two ends of the outer wall of the target tube 1, further, the depth of the concave parts is 1 mm-10 mm, the width of the concave parts is 1 mm-20 cm, and the gradient of the concave parts is 5-85 degrees.

The slope of the concave part is an included angle between an oblique line formed by connecting the bottommost point of the concave part and any point on the edge of the concave part and a horizontal line where the bottommost point of the concave part is located.

Referring to fig. 2, in a specific example, depressions are provided at both ends of the outer wall of the target tube 1, the depressions having a depth of 5mm, a width of 5cm, and a slope of 30 °.

Providing the outer wall of the target tube with the recessed portion increases the contact area of the surface of the target tube with the molten reaction liquid, so that stress relaxation at the time of cooling shrinkage of the molten reaction liquid occurs first in the recessed portion.

In some embodiments, the texture may be a convex texture or a concave texture.

The depth here refers to the maximum distance the ridges are recessed inwardly relative to the outer wall surface where no ridges are provided.

In one embodiment, the outer wall of the target tube 1 has concave grains, further, the depth of the grains is 0.01 mm-20 mm, and further, the depth of the grains is 1 mm.

It is understood that the height of the convex texture is relative to the outer wall without the texture, specifically, the maximum distance of the convex texture outwards protrudes relative to the surface of the outer wall without the texture.

The concave grains are arranged on the outer wall of the target tube 1, so that the contact area between the surface of the target tube and the molten reaction liquid can be increased, and the stress release when the molten reaction liquid is cooled and contracted is firstly found in the concave grains.

In one embodiment, the outer wall of the target tube 1 has convex grains, further, the height of the grains is 0.01 mm-20 mm, and further, the height of the grains is 1 mm.

It will be appreciated that the height of the raised ridges is relative to the outer wall where the ridges are not provided.

The outer wall of the target pipe 1 is provided with the convex grains, so that the contact area between the surface of the target pipe 1 and the molten reaction liquid can be increased, and at the moment, the outer wall which is not provided with the convex grains is an inward concave part relative to the convex grains, so that the stress release when the molten reaction liquid is cooled and contracted is firstly carried out on the outer wall which is not provided with the convex grains.

It should be noted that the outer wall of the target tube 1 may have a plurality of lines, and the depth or height of each line may be the same or different, and the depth or height of different places of the same line may also be the same or different, and the lines may be criss-cross lines with irregular shapes.

In some of these embodiments, the texture is a criss-cross wavy texture.

Referring to fig. 3, in a specific example, the outer wall of the target tube 1 is provided with a plurality of concave lines, the depth of the lines is 0.01 mm-20 mm, and the lines are in a criss-cross wavy shape.

In one embodiment, the bottom of the mold 2 is provided with a fixing screw groove, by which the target tube 1 is fixed in the mold 2.

It will be appreciated that the mold 2 is detachable from the target tube 1 and that after a subsequent cold forming step, the mold 2 is removed.

In one embodiment, the material of the mold 2 is at least one of stainless steel, aluminum, iron, graphite, or copper.

In one embodiment, the inner wall of the mold 2 is covered with a metal foil, and further, the metal foil is any one selected from the group consisting of an aluminum foil, a copper foil, an iron foil, a graphite foil, and a stainless steel foil.

When the mixed liquid is poured into the molding cavity 3 in the subsequent step, the mixed liquid is coated by the metal foil, and after the mixed liquid is further cooled and molded, the target material is coated by the metal foil.

The smooth metal foil is beneficial to forming the lithium alloy target with high flatness and low surface roughness, and the quality of the lithium alloy target is improved, so that a good lithium supplement effect is ensured.

It will be appreciated that after the subsequent step of removing the mould 2, the metal foil coated on the target is removed.

It will be appreciated that the shape and size of the mold 2 may be determined according to the shape and size of the target to be finally produced, for example, in an embodiment of the present invention, the final target is cylindrical, and the mold 2 is cylindrical.

In one embodiment, the material of the target tube 1 is stainless steel.

In one embodiment, the target tube 1 is a cylindrical target tube having a diameter of 30mm to 200mm and a length of 100mm to 5000 mm.

In one of the embodiments, the target tube 1 may be solid or hollow. In the subsequent cooling step, a cooling liquid may be injected into the hollow interior of the hollow target tube 1 to assist in cooling the molten reaction liquid.

And S2, mixing the first simple substance and the second simple substance, and heating to obtain a mixed solution.

The first simple substance is molten lithium, and the second simple substance is any one selected from boron powder, silicon powder and molten sulfur.

In some embodiments, the second element is selected from boron powder, and further, the molar ratio of the molten lithium to the boron powder is (2-8): 1-9.

Preferably, in some embodiments, the second element is selected from boron powder, and further, the molar ratio of molten lithium to boron powder is 5 (2-8).

Further, in some embodiments, the molar ratio of molten lithium to boron powder is 5 (3-7).

In some embodiments, the second element is selected from silicon powder, and further, the molar ratio of the molten lithium to the silicon powder is (8-2): 1-9.

Preferably, in some embodiments, the second element is selected from silicon powder, and further, the molar ratio of the molten lithium to the silicon powder is 5 (2-8).

The second simple substance is selected from silicon powder, and the molar ratio of the molten lithium to the silicon powder is 5 (3-6).

In some of these embodiments, the second element is selected from molten sulfur, and further, the molar ratio of molten lithium to molten sulfur is (1-9): (1-9).

Preferably, in some embodiments, the second element is selected from molten sulfur, and further, the molar ratio of molten lithium to molten sulfur is 9 (1-9).

Further, in some embodiments, the molar ratio of molten lithium to molten sulfur is 9 (1-4).

In some embodiments, the first element and the second element are stirred by a stirrer, so that the first element and the second element are uniformly mixed. Further, the stirring speed of the stirrer is not less than 1000 r/min.

In some of these embodiments, the temperature of the heating is from 190 ℃ to 1000 ℃. Further, the heating is gradual heating, and the heating rate is 10 ℃/min to 100 ℃/min.

In some of these embodiments, the heating step is performed under an inert gas blanket.

In some embodiments, when the second simple substance is selected from boron powder, in step S2, when the molten lithium is mixed with the boron powder, the boron powder is added in batches, the adding weight of each time does not exceed 10 wt% of the total mass of the boron powder and the molten lithium in the raw materials, the adding time interval is not less than 5min, the temperature is gradually increased to 300-400 ℃, a uniform mixed melt is formed after the boron powder is added, and then the temperature is gradually increased to 400-500 ℃, and finally the lithium-boron alloy mixed solution is formed.

In some embodiments, when the second simple substance is selected from silicon powder, in step S2, when the molten lithium and boron powder are mixed, the silicon powder is added in batches, the weight of each addition does not exceed 10 wt% of the total mass of the silicon powder and the molten lithium in the raw materials, the time interval of the addition is not less than 5min, the heating is gradually carried out to 300-400 ℃, after the addition of the silicon powder is finished, a uniform mixed melt is formed, and then the heating is gradually carried out to 400-500 ℃, and finally the lithium-silicon alloy mixed solution is formed.

In some embodiments, when the second element is selected from molten sulfur, in step S2, after mixing the molten lithium with the molten sulfur, the molten lithium is gradually heated to 1000 ℃, and the molten lithium and the molten sulfur form lithium sulfide, and finally form a lithium-sulfur alloy mixed solution.

In one embodiment, the preparation of molten lithium comprises the following steps: under the protection of inert gas, heating the lithium ingot to 180-500 ℃ to form molten lithium.

In one embodiment, the molten sulfur is prepared by the steps of: under the protection of inert gas, heating the lithium ingot to 115-400 ℃ to form molten sulfur.

It is understood that other methods of preparing molten lithium or molten sulfur may be used as long as liquid molten lithium and molten sulfur are obtained.

It should be noted that step S1 and step S2 do not have a specific sequence.

S3, the mixed liquid obtained in step S2 is poured into the molding cavity 3 in step S1, cooled, and molded.

Referring to fig. 1, in a specific example, the prepared mixed solution is poured into a molding cavity 3 formed between a target pipe 1 and an inner wall of a mold 2, cooled, and molded.

In one embodiment, in step S3, the mixed liquid is cooled by natural cooling or cooling with a cooling liquid.

Further, in some of the embodiments, the mixed solution is poured into the molding cavity 3, a cooling liquid is added into the hollow target tube 1, and the molten reaction liquid is rapidly cooled by the cooling liquid.

The cooling liquid mode can accelerate the cooling speed of the mixed liquid, and is favorable for eliminating air holes and shrinkage cavities in the mixed liquid, thereby.

Generally, in the casting and forming process, due to the shrinkage of the mixed liquid in the cooling process, the mixed liquid cannot be completely and tightly attached to the target tube 1, so that the problems of local foaming, bulging and the like of the formed lithium alloy material exist, the quality of the lithium alloy target material is further influenced, an uneven lithium alloy material thin layer is deposited on the surface of an electrode material when the electrode material of the lithium ion battery is subjected to PVD lithium supplement, the expected lithium supplement effect cannot be achieved, and the problem of volume expansion of the lithium ion battery cannot be solved. According to the technical scheme, the concave parts or the grains are arranged on the outer wall of the target tube 1, so that the contact area between the surface of the target tube 1 and the molten reaction liquid can be increased, stress release during cooling and shrinkage of the mixed liquid is firstly released at the concave part, the mixed liquid can be tightly attached to the target tube 1 in the cooling process, and the lithium alloy target with excellent quality is obtained.

And S4, removing the die 2 to obtain the lithium alloy target.

In one embodiment, after step S4, the method further includes a step of polishing the prepared lithium alloy target.

Further, an embodiment of the present invention provides a lithium alloy target material, including a target tube and a lithium alloy material coated on the target tube, wherein the outer wall of the target tube has a recess and/or the outer wall of the target tube has grains, and the lithium alloy material is lithium boride, lithium silicide or lithium sulfide.

The contact area between the surface of the target tube 1 and the molten reaction liquid can be increased by arranging the concave parts or the grains on the outer wall of the target tube 1, and the stress released when the mixed liquid is cooled and contracted is firstly released in the concave part, so that the mixed liquid can be tightly attached to the target tube 1 in the cooling process, and the lithium alloy target with excellent quality is obtained.

In one embodiment, the lithium alloy target is a magnetron sputtering target. Correspondingly, the magnetron sputtering target can be realized by the following steps: a first magnetic pole 11 and a second magnetic pole 12 are oppositely arranged in the hollow part of the target tube 1, wherein one of the first magnetic pole and the second magnetic pole is an S magnetic pole, and the other one is an N magnetic pole.

When the magnetron sputtering target material is adopted to supplement lithium for the electrode material, the magnetron sputtering target material is placed in magnetron sputtering system equipment, the magnetron sputtering target material serves as a cathode, the wall of a coating chamber serves as an anode, required inert gas (such as Ar gas) is filled in a high vacuum chamber, a magnetic field and an electric field are added between the cathode and the anode, and the magnetic field and the high voltage electric field form an orthogonal electromagnetic field. Under the action of an electromagnetic field, Ar gas is ionized into positive ions and electrons, the Ar ions accelerate to fly to a cathode target under the action of the electric field and bombard the surface of the target at high energy, so that a lithium alloy compound on the target is sputtered, and the sputtered atoms are separated from the target surface by high kinetic energy according to a momentum conversion principle and fly to a substrate to deposit and form a film.

Referring to fig. 4, in a specific example, the lithium alloy target may also be a bi-directional magnetron sputtering target. Correspondingly, a first magnetic pole 11 and two second magnetic poles 12 respectively arranged on two opposite sides of the first magnetic pole are arranged in the hollow part of the target tube 1 of the lithium alloy target material, wherein one of the first magnetic pole 11 and the second magnetic pole 12 is an S magnetic pole, and the other is an N magnetic pole.

In the specific example shown in fig. 4, the first magnetic pole 11 is an N magnetic pole, and the second magnetic pole 12 is an S magnetic pole.

It is understood that in other embodiments, the first magnetic pole 11 of the lithium alloy target can also be an S-pole and the second magnetic pole 12 can be an N-pole.

Thus, a first pole 11 and two second magnetic poles 12 are arranged in the hollow part of the target tube, in the magnetron sputtering process, Ar ions bombard the surface of the target with high energy under the action of an electric field, so that the lithium alloy compound on the target material is sputtered, the sputtered atoms are separated from the target surface with higher kinetic energy according to the momentum conversion principle, and simultaneously, under the action of different magnetic poles of the magnetron sputtering target, the sputtered atoms on the target fly to the substrate along different directions to deposit and form a film, so that bidirectional sputtering is realized, and the corresponding lithium alloy target material is a bidirectional magnetron target material.

It should be noted that more magnetic poles may be provided in parallel with and spaced apart from the first magnetic pole 11 or the second magnetic pole 12, or bidirectional magnetron sputtering may be implemented.

Further, referring to fig. 4, the first magnetic pole 11 in the hollow portion of the target tube 1 and the two second magnetic poles respectively disposed on the two opposite sides of the first magnetic pole are a row of magnetic poles. Multiple rows of magnetic poles can be arranged according to actual needs, and two rows of electrode materials respectively arranged on two sides of the lithium alloy target can be sputtered simultaneously by controlling the arrangement position of the lithium alloy target and the arrangement of the sputtering magnetic field and the sputtering power.

The embodiment of the invention also provides a lithium alloy target material prepared by the preparation method of the lithium alloy target material or an application of the lithium alloy target material in preparation of a lithium battery.

In one embodiment, the lithium battery is a lithium ion battery.

In one embodiment, the lithium alloy target is used as a lithium supplement material for supplementing lithium to an electrode material of a battery. Further, a magnetron sputtering method is adopted for lithium supplement.

It can be understood that, when the lithium alloy target is used as a lithium supplement material to supplement lithium for an electrode material of a battery, the method for supplementing lithium is not limited to the magnetron sputtering method, but also can be other methods capable of plating a uniform lithium supplement material layer on the surface of the electrode material.

The contact area between the surface of the target tube 1 and the molten reaction liquid can be increased by arranging the concave parts or the grains on the outer wall of the target tube 1, and the stress released when the mixed liquid is cooled and contracted is firstly released in the concave part, so that the mixed liquid can be tightly attached to the target tube 1 in the cooling process, and the lithium alloy target with excellent quality is obtained. When the lithium ion battery is prepared, the lithium alloy target material is subjected to magnetron sputtering, a uniform lithium alloy thin layer can be deposited on the surface of an electrode material, the expected lithium supplement effect is achieved, the problem of volume expansion of the lithium ion battery is solved, and the cycle service life of the lithium ion battery is prolonged.

It should be noted that, in the process of preparing the lithium ion battery, the battery obtained from the material to the assembly is subjected to a plurality of processes including the preparation of the target material, the preparation of the positive and negative electrode plates, and the like, and therefore, the application of the lithium composite material prepared by the preparation method of the lithium alloy target material or the lithium alloy in the preparation of the lithium ion battery includes the application of the lithium alloy target material in each process of preparing the lithium ion battery, such as the application in the preparation of the electrode material.

While the present invention will be described with respect to particular embodiments, it is to be understood that the invention is not limited to the disclosed embodiments, but is intended to cover by the appended claims the scope of the invention, and that certain changes in the embodiments of the invention will be suggested to those skilled in the art and are intended to be covered by the appended claims.