Lead frame
阅读说明:本技术 引线框 (Lead frame ) 是由 菱木薰 大泷启一 佐佐木英彦 留冈浩太郎 于 2020-02-26 设计创作,主要内容包括:课题在于提供一种引线框,其为在引线框基材的整个面实施了银镀覆作为最表层镀敷的引线框,能够减少成本、操作时间,提高生产率,同时将包括银镀层的镀层整体的厚度抑制为较薄,而且使得与密封树脂的密合性显著提高。解决手段为在由铜系材料构成的引线框基材(10)的整个面具备具有针状的突起组的粗糙化银镀层(11)作为最表层镀层,粗糙化银镀层具有在晶体取向<001>、<111>、<101>各自的比率中晶体取向<101>的比率最高的晶体结构。(The lead frame is plated with silver on the whole surface of a lead frame base material as an outermost layer, and can reduce cost and operation time, improve productivity, reduce the thickness of the whole plating layer including the silver plating layer to be thin, and remarkably improve adhesion with a sealing resin. The surface of a lead frame base material (10) made of a copper material is provided with a roughened silver plating layer (11) having needle-like protrusions as an outermost plating layer, and the roughened silver plating layer has a crystal structure in which the ratio of crystal orientation <101> is the highest among the ratios of crystal orientations <001>, <111>, <101 >.)
1. A lead frame is characterized in that a roughened silver plating layer having needle-like projection groups is provided as an outermost plating layer on the entire surface of a lead frame base material made of a copper-based material, and the roughened silver plating layer has a crystal structure in which the ratio of the crystal orientation <101> is the highest among the ratios of the crystal orientations <001>, <111>, and <101 >.
2. The lead frame of claim 1, wherein the roughened silver plating has an average crystal grain size of less than 0.28 μm.
3. The lead frame according to claim 1 or 2, wherein a base plating is provided between the lead frame substrate and the roughened silver plating.
Technical Field
The present invention relates to a lead frame for a semiconductor, in which silver plating is applied as outermost plating to the entire surface of a lead frame base.
Background
The lead frame is one of the semiconductor element mounting members. Conventionally, a lead frame plated with silver as an outermost plating layer on the entire surface or a part of a lead frame base material has been used in many cases, but the adhesion between silver or an alloy containing silver and a sealing resin is poor, and the lead frame and the sealing resin are easily peeled off by impact or heat, which causes a problem in reliability.
For this problem, the following methods are known: the surface of the lead frame base material is roughened by microetching treatment to form irregularities, thereby producing a physical anchoring effect and improving adhesion to the sealing resin.
However, lead frame substrates used in large quantities in the manufacture of lead frames are made of copper alloys containing silicon, and an impurity residue called smear (Smut) is generated by microetching treatment. Therefore, it is impossible to use a method of roughening the surface of the lead frame base material made of a copper alloy by microetching.
In addition, in the case of a lead frame using a lead frame base material made of a copper alloy, in order to ensure good bondability with a metal wire used in bonding a semiconductor element, it is necessary to minimize the influence of diffusion of copper present in the lead frame base material made of a copper alloy of the base. Therefore, when a plating layer made of a noble metal such as silver or a silver-containing alloy or a noble metal alloy is directly formed on a lead frame base made of a copper alloy without providing an undercoat plating layer, it is generally necessary to make the thickness of the plating layer made of the noble metal or the
On the other hand, in recent years, for the purpose of downsizing and cost reduction, high-density mounting with a small size and a thin thickness is required for a semiconductor package. In order to reduce the size, the thickness of the plating layer is required to be thinner, and from the viewpoint of cost reduction, the thickness of the plating layer made of a noble metal or a noble metal alloy is also required to be thinner.
In a lead frame using a lead frame base material made of a copper alloy, as one of measures for reducing the thickness of a plating layer made of a noble metal or a noble metal alloy, there is a method of: the base plating layer, which is a plating layer made of a noble metal or a noble metal alloy, is formed of nickel or an alloy containing nickel, which has an effect of suppressing the diffusion of copper, so that the thickness of the plating layer made of a noble metal or a noble metal alloy is made thin.
However, even if the thickness of the plating layer made of a noble metal or a noble metal alloy is made thin, the adhesion to the resin cannot be improved.
As a prior art relating to these problems,
Patent document 3 discloses a technique of forming a noble metal plating layer composed of a gold layer and a silver layer on a nickel layer having a rough surface.
Disclosure of Invention
Problems to be solved by the invention
The techniques of these patent documents are the following: in order to improve adhesion to a resin, a base plating layer is formed so that the surface thereof becomes a roughened surface, and a noble metal plating layer is laminated thereon so as to follow the shape of the roughened surface. However, in order to form the roughened surface on the surface of the base plating layer into a surface having irregularities capable of improving adhesion to the resin even when the noble metal plating layer is laminated, it is necessary to form the base plating layer thick, and the plating speed is slow to form the base plating layer into the roughened surface, so that the working time increases, the cost increases, and the productivity decreases.
In addition, as another means for improving the adhesion to the resin, it is conceivable to form a smooth noble metal plating layer on the surface of the lead frame base material and then roughen the surface of the noble metal plating layer, but in order to form the surface of the noble metal plating layer into a roughened surface having a concavo-convex shape capable of improving the adhesion to the resin, it is necessary to form the smooth noble metal plating layer before forming the roughened surface to be thick, and therefore the cost of the noble metal plating layer increases and the productivity decreases.
Further, if the surface is roughened after the smooth plating layer is formed, the plating metal removed at the time of roughening is wasted.
However, as a result of trial and error, the present inventors have found that there is still room for: as compared with the techniques disclosed in the above patent documents, the cost and the working time for forming the roughened surface on the surface can be reduced, the productivity can be improved, and the thickness of the entire plating layer can be controlled to be small, and the adhesion to the sealing resin can be remarkably improved.
The present invention has been made in view of the above problems, and an object of the present invention is to provide a lead frame in which silver plating is applied as an outermost plating layer on the entire surface of a lead frame base material, which can reduce cost and operation time, improve productivity, reduce the thickness of the entire plating layer including the silver plating layer to be thin, and significantly improve adhesion to a sealing resin.
Means for solving the problems
In order to solve the above problem, a lead frame according to the present invention includes: a roughened silver plating layer having needle-like projection groups is provided as an outermost plating layer on the entire surface of a lead frame base material made of a copper-based material, and has a crystal structure in which the ratio of the crystal orientation <101> is the highest among the ratios of the crystal orientations <001>, <111>, <101 >.
Further, in the lead frame of the present invention, it is preferable that the average crystal grain size of the roughened silver plating layer is less than 0.28 μm.
In the lead frame of the present invention, it is preferable that the base plating layer is provided between the lead frame base material and the roughened silver plating layer.
ADVANTAGEOUS EFFECTS OF INVENTION
According to the present invention, a lead frame in which silver plating is applied as the outermost plating layer on the entire surface of a lead frame base material can be obtained, which can reduce the cost, the working time, and the productivity, and can suppress the thickness of the entire plating layer including the silver plating layer to be thin, and can significantly improve the adhesion to a sealing resin.
Drawings
Fig. 1 is a view showing an example of a lead frame according to
Fig. 2 is a plan view showing an example of a lead frame arranged in a plurality of rows according to
Fig. 3 is an explanatory view showing an example of a manufacturing process of a lead frame for mounting a semiconductor element according to
Fig. 4 is an explanatory view showing an example of a manufacturing process of a semiconductor package using the lead frame for mounting a semiconductor element according to
Fig. 5 is a view showing an example of a lead frame according to
Fig. 6 is a plan view showing an example of a lead frame arranged in a plurality of rows according to
Fig. 7 is an explanatory view showing an example of a manufacturing process of a lead frame for mounting a semiconductor element according to
Fig. 8 is an explanatory view showing an example of a manufacturing process of a semiconductor package using the lead frame for mounting a semiconductor element according to
Description of the symbols
1. 1' -a lead frame; 2. 2' -semiconductor packaging; 10-lead frame substrate (metal plate); 10 a-terminal part for internal connection; 10 b-terminal part for external connection; 10 c-a pad portion; 11-roughening silver plating; 14-soldering tin; 15-sealing resin; 16-die attach paste; 17-a bond wire; 20-a semiconductor element; 32-resist mask for etching; r1-resist layer.
Detailed Description
Before describing the embodiments, the process of the present invention and the operational effects of the present invention will be described.
The present inventors considered that, in order to reduce the cost and the working time for forming the roughened surface on the surface, improve productivity, improve adhesion to the sealing resin, and reduce the thickness of the entire plating layer, the following measures must be taken: for the lead frame base material, the surface-roughened base plating layer is not provided, and the surface-roughened silver plating layer is formed without roughening the smooth silver plating layer surface, or the base plating layer is smoothly formed, on which the surface-roughened silver plating layer is formed without roughening the smooth silver plating layer surface.
In view of the above, the present inventors have conducted experiments repeatedly to derive a lead frame having a roughened silver plating layer having needle-like projection groups as an outermost plating layer on the entire surface of a lead frame base material made of a copper-based material, as a surface-roughened silver plating layer that does not roughen the surface of a smooth silver plating layer.
In the present application, the group of needle-like protrusions of the roughened silver plating layer refers to an aggregate of a plurality of needle-like protrusions having a surface area ratio (here, a ratio of the surface area of the roughened silver plating layer to the surface area of the smooth surface) of 1.30 to 6.00.
It was found that if the roughened silver plating layer is formed in the form of a group of needle-like projections having such a surface area ratio, the sealing resin easily flows into the base of each needle-like projection, and the physical anchoring effect due to the increase in contact area and the uneven shape at the time of curing the sealing resin can be exhibited.
Further, the present inventors have conducted experiments repeatedly and found that the roughened silver plating layer having needle-like projection groups is different from the conventional smooth silver plating layer and the roughened silver plating layer having a roughened surface formed by roughening the surface of the smooth silver plating layer in crystal structure, and is formed by growing a crystal structure in which a ratio of a predetermined crystal orientation is increased, and that the roughened surface having needle-like projection groups formed by greatly growing the crystal structure has an effect of remarkably improving adhesion to a sealing resin as compared with the roughened surface formed by the conventional technique, and have led to the present invention.
The lead frame of the invention is provided with a roughened silver plating layer with needle-shaped protrusion groups as an outermost plating layer on the whole surface of a lead frame base material made of a copper-based material, wherein the roughened silver plating layer has a crystal structure with the highest ratio of crystal orientation <101> in the ratios of crystal orientations <001>, <111>, <101 >.
If the roughened silver plating has a group of needle-like projections having a surface area ratio (here, the ratio of the surface area of the roughened silver plating to the surface area of the smooth surface) of 1.30 to 6.00 as in the lead frame of the present invention, the sealing resin easily flows into the base of each needle-like projection. Therefore, the physical anchoring effect due to the increase in contact area and the uneven shape at the time of curing the sealing resin can be exhibited, and good adhesion can be obtained. The extending direction of each needle-like projection in the needle-like projection group is not the same, and includes not only the upward direction and the oblique direction but also the curved needle shape. If the needle-like projections in the needle-like projection group are in a form extending randomly in a radial direction, the anchoring effect to the sealing resin can be further improved.
Further, if the roughened silver plating layer having a needle-like projection group provided as the outermost plating layer on the entire surface of the lead frame base material made of a copper-based material is configured to have a crystal structure having the highest ratio of the crystal orientation <101> among the ratios of the crystal orientations <001>, <111>, <101>, as in the lead frame of the present invention, the sealing resin can more easily enter into the deep portion of the roughened silver plating layer than the conventional crystal structure having a crystal structure different from the highest ratio of the crystal orientation <101> among the ratios of the crystal orientations <001>, <111>, <101> than the silver plating layer having a roughened surface formed by roughening the surface of the smooth silver plating layer, for example, which has a roughened surface having an uneven surface with a surface area ratio (here, the ratio of the surface area of the silver plating layer to the surface area of the smooth surface) of less than 1.30, the adhesion to the sealing resin is further improved.
Further, if the lead frame of the present invention is manufactured, the contact area between the needle-like projection group of the roughened silver plating layer and the connection member such as solder or solder paste is increased in the semiconductor element mounting portion where the semiconductor element is mounted on the upper surface side, the internal connection terminal portion electrically connected to the semiconductor element directly or via a wire, and the external connection terminal portion electrically connected to the external device on the lower surface side, whereby the penetration of moisture can be prevented, and the deformation due to thermal expansion is suppressed, and the interlayer peeling between the connection member and the plating film is suppressed.
In the lead frame of the present invention, the roughened silver plating layer having a crystal structure in which the ratio of the crystal orientation <101> is the highest among the ratios of the crystal orientations <001>, <111>, <101>, and having needle-like projection groups may be formed using the lead frame base material as a base.
Further, if a lead frame of the present invention is manufactured, the adhesion to the sealing resin can be significantly improved by the roughened silver plating layer having a crystal structure with the highest ratio of the crystal orientation <101> among the ratios of the crystal orientations <001>, <111>, <101> and having needle-like projection groups, and as a result, when it is necessary to form a barrier plating layer for suppressing the diffusion of copper which is a base material of the lead frame in a high-temperature environment as the base plating layer, it is sufficient to form the barrier plating layer to be thin and smoothly in a thickness for suppressing the diffusion of copper which is a base, and it is not necessary to form the barrier plating layer with a roughened surface.
Further, the roughened silver plating layer having a crystal structure in which the ratio of the crystal orientation <101> is the highest among the ratios of the crystal orientations <001>, <111>, <101>, and having needle-like projection groups can be formed by silver plating under the conditions described later without roughening the smooth silver plating surface.
Therefore, if a lead frame of the present invention is manufactured, the cost for forming the roughened surface for improving adhesion to the resin can be minimized, and the thickness of the entire plating layer can be minimized.
Further, it is preferable that in the lead frame of the present invention, the average crystal grain size of the roughened silver plating layer is less than 0.28 μm.
If the average crystal grain size of the roughened silver plating layer is 0.28 μm or more, the spacing between crystals becomes wider when the crystals of the silver plating layer grow in the height direction, and a surface area ratio (here, a ratio of the surface area of the roughened silver plating layer to the surface area of the smooth surface) of 1.30 to 6.00 cannot be obtained.
If the average crystal grain size of the roughened silver plating is made smaller than 0.28. mu.m, the spacing between crystals becomes narrow when the crystals of the silver plating grow in the height direction, resulting in a surface area ratio (here, the ratio of the surface area of the roughened silver plating to the surface area of the smooth surface) of 1.30 to 6.00. More preferably, the average crystal grain size of the roughened silver plating layer is 0.15 μm or more and 0.25 μm or less.
In the lead frame of the present invention, the base plating layer may be provided between the lead frame base material and the roughened silver plating layer.
In the lead frame of the present invention, the shape of the needle-like projection group of the roughened silver plating layer preferably does not affect the surface morphology of the base, and is formed only by the roughened silver plating layer, and the surface state of the base may be smooth or rough. In view of the cost such as productivity, it is preferable that the base is a surface of the lead frame base material only which is subjected to an activation treatment to form the roughened silver plating thereon. In consideration of the influence of diffusion of copper, which is a material of the base lead frame base material, in a high-temperature environment, a smooth base plating layer may be provided as a barrier plating layer between the lead frame base material and the roughened silver plating layer. In this case, it is sufficient to form the plating layer to be thin and smooth to a thickness that suppresses diffusion of copper in the base, and therefore a thin base plating layer is preferable.
In the lead frame of the present invention, when the silver plating layer including the roughened silver plating layer is directly formed without providing the base plating layer on the entire surface of the lead frame base material, the thickness of the entire plating layer provided on the entire surface of the lead frame base material is preferably 0.4 μm or more and 6.0 μm or less. Specifically, it is preferable to form a silver strike plating layer of 0.2 μm to 3.0 μm, more preferably 1.5 μm, on the entire surface of the lead frame substrate, and to laminate a roughened silver plating layer of 0.2 μm to 3.0 μm, more preferably 0.5 μm, having needle-like projection groups on the surface.
When a nickel plating layer is provided as a barrier plating layer on the base, for example, the thickness of the nickel plating layer provided on the entire surface of the lead frame base is preferably 0.3 μm or more and 3.0 μm or less. Specifically, it is preferable to form a nickel plating layer of 0.3 μm to 3.0 μm, preferably 1.0 μm, on the entire surface of the lead frame substrate, and to laminate a roughened silver plating layer of 0.2 μm to 3.0 μm, preferably 0.5 μm, having needle-like projection groups on the surface.
In the case where, for example, a palladium plating layer is provided between the base nickel plating layer and the roughened silver plating layer, the thickness of the palladium plating layer is preferably 0.005 μm or more and 0.1 μm or less. Specifically, it is preferable to form a palladium plating layer of 0.005 μm to 0.1 μm, preferably 0.01 μm, on the nickel plating layer formed on the entire surface of the lead frame substrate.
When a gold plating layer is provided between the base nickel plating layer and the palladium plating layer and the roughened silver plating layer, for example, the thickness of the gold plating layer is preferably 0.0005 μm or more and 0.01 μm or less. Specifically, it is preferable to form a gold plating layer of 0.0005 μm to 0.01 μm, preferably 0.001 μm, on the nickel plating layer and the palladium plating layer formed on the entire surface of the lead frame base.
The lead frame of the present invention has a crystal orientation<001>、<111>、<101>Crystal orientation in respective ratio<101>The roughened silver plating layer having a needle-like projection group with the highest ratio of (A) can be formed at a temperature of 55 ℃ to 65 ℃ and a current density of 3A/dm by using a silver plating bath having a silver concentration of 1.0g/L to 10g/L, the silver plating bath being composed of a methane sulfonic acid-based silver plating solution2Above 20A/dm2Electroplating for 5-60 seconds.
Therefore, according to the present invention, a lead frame in which silver plating is applied as the outermost plating layer on the entire surface of a lead frame base material can be obtained, which can reduce the cost and the working time for forming a roughened surface of the surface, improve the productivity, and suppress the thickness of the entire plating layer including the silver plating layer to be thin, and significantly improve the adhesion to the sealing resin.
The following describes a lead frame to which the present invention is applied and a method for manufacturing the same. It is to be understood that, unless otherwise specified, the present invention is not limited by the following detailed description.
Fig. 1 is a view showing an example of a lead frame according to
As shown in fig. 1 (a), the
The roughened
The roughened
The average crystal grain size of the roughened
In the present embodiment, the roughened
As a modification of the present embodiment, the lead
Specifically, for example, when the base plating layer functions as a barrier plating layer for preventing diffusion of copper when the base plating layer is electrically connected to the semiconductor element by solder, and when the base plating layer is formed of a plating layer formed by nickel/palladium plating or a plating layer formed by nickel/palladium/gold plating, the roughened
In the
Next, an example of a manufacturing process of the
First, a
Next, resist layers R1 are formed on both surfaces of the metal plate 10 (see fig. 3 (b)).
Next, exposure and development are performed using a glass mask in which a predetermined lead frame shape is drawn, thereby forming an etching resist mask 32 (see fig. 3 (c)).
Next, etching is performed on both surfaces to form a predetermined lead frame shape (see fig. 3 (d)).
Next, the etching resist
Next, the roughened silver plating 11 having needle-like projection groups is formed as an outermost plating layer on the entire surface of the
Thereby, the
The step of forming the roughened silver plating 11 having the needle-like projection groups as the outermost plating layer is, for example, a step of forming the roughened silver plating by activating only the surface of the lead
In this case, in order to form the roughened
If the silver concentration is less than 1.0g/L, a sufficient roughened silver plating film cannot be formed, and therefore, it is not preferable. If the silver concentration is higher than 10g/L, the formed roughened silver plating film will form a smooth surface, and needle-like crystals of silver will not be obtained, which is not preferable.
Further, by using a plating layer of palladium or a palladium-containing alloy as a substitute for the silver strike plating layer used for improving the bondability of the substrate to the roughened
Further, a gold or gold-containing alloy plating layer may be formed under the roughened
In the case where the base plating layer is not provided but is formed directly on the lead frame base material, the thickness of the roughened
When the base plating layer is a plating layer formed by nickel/palladium plating or a plating layer formed by nickel/palladium/gold plating, the thickness of the roughened
Next, an example of a manufacturing process of a semiconductor package using the
First, the
Next, solder 14 is printed on the semiconductor element mounting region of the internal
Next, the space region of the lower surface of the
Finally, the semiconductor packages arranged in a plurality of rows are singulated by dicing, pressing, or the like (see fig. 4 (d)).
Thus, a
Fig. 5 is a view showing an example of a lead frame according to
As shown in fig. 5 (a), the lead frame 1' of the present embodiment includes a
The roughened
The roughened
The average crystal grain size of the roughened
In the present embodiment, the roughened
As a modification of the present embodiment, the lead
In detail, for example, the base plating layer functions as a barrier plating layer that prevents diffusion of copper in the case where electrical connection with the semiconductor element is performed by wire bonding, and when the base plating layer is formed of a plating layer including nickel plating, the roughened
Further, for example, in the case where the base plating layer functions as a barrier plating layer that prevents diffusion of copper in the case where electrical connection with the semiconductor element is made by wire bonding, and when the base plating layer is constituted by a plating layer including nickel/palladium plating, the roughened
In the lead frame 1 'of the present embodiment, as shown in fig. 6, the lead frames 1' are arranged in a plurality of rows.
Next, an example of a manufacturing process of the lead frame 1' of the present embodiment will be described with reference to fig. 7.
The manufacturing process of the lead frame 1' of the present embodiment is substantially the same as the manufacturing process of the
In the case where the base plating layer is not provided but is formed directly on the lead frame base material, the thickness of the roughened
Further, the base plating layer functions as a barrier against diffusion of copper in the case of electrical connection with the semiconductor element by wire bonding, and when a nickel plating layer is provided as the base plating layer, the thickness of the roughened
Further, the base plating layer functions as a barrier against diffusion of copper in the case where electrical connection with the semiconductor element is made by wire bonding, and in the case where a plating layer including nickel/palladium plating is provided as the base plating layer, the thickness of the roughened
Next, an example of a manufacturing process of a semiconductor package using the lead frame 1' of the present embodiment will be described with reference to fig. 8.
First, a lead frame 1' according to the present embodiment manufactured by the manufacturing steps shown in fig. 7 is prepared (see fig. 8 (a)).
Next, the
Next, the space region of the lower surface of the lead frame 1' other than the external
Finally, the semiconductor packages arranged in a plurality of rows are singulated by dicing, pressing, or the like (see fig. 8 (d)).
Thus, a semiconductor package 2 'using the lead frame 1' of the present embodiment is obtained (see fig. 8 (e)).
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