阅读说明：本技术 一种750MPa级连续油管用热轧钢带及其制造方法 (Hot-rolled steel strip for 750 MPa-grade continuous oil pipe and manufacturing method thereof ) 是由 孙照阳 胡学文 杨森 余宣洵 王海波 吴志文 李忠义 游慧超 赵虎 文亮 郑晴 于 2021-07-27 设计创作，主要内容包括：本发明公开了一种750MPa级连续油管用热轧钢带及其制造方法,涉及油井管线用钢技术领域。本发明的一种750MPa级连续油管用热轧钢带及其制造方法,采用铁水预处理→转炉炼钢→LF炉外精炼→RH炉外精炼→连铸→热轧,钢中化学成分重量百分比：0.12％～0.14％C、0.3％～0.4％Si、1.50％～2％Mn、P≤0.015％、S≤0.005％、0.5％～0.7％Cr、0.1％～0.4％Cu、0.1％～0.3％Ni、0.2％～0.5％Mo、0.05％～0.07％Nb、0.04～0.05％V、0.01～0.02％Ti、0.02～0.035％Als；其余为Fe及不可避免的夹杂；热轧钢带的厚度在3～5mm,其金相组织为铁素体+马氏体组织,以满足超深井的连续油管用热轧钢带的需要。(The invention discloses a hot-rolled steel strip for a 750 MPa-grade continuous oil pipe and a manufacturing method thereof, and relates to the technical field of steel for oil well pipelines. The invention relates to a hot-rolled steel strip for a 750 MPa-level continuous oil pipe and a manufacturing method thereof, wherein molten iron pretreatment → converter steel making → LF external refining → RH external refining → continuous casting → hot rolling are adopted, and the steel comprises the following chemical components in percentage by weight: 0.12 to 0.14 percent of C, 0.3 to 0.4 percent of Si, 1.50 to 2 percent of Mn, less than or equal to 0.015 percent of P, less than or equal to 0.005 percent of S, 0.5 to 0.7 percent of Cr, 0.1 to 0.4 percent of Cu, 0.1 to 0.3 percent of Ni, 0.2 to 0.5 percent of Mo, 0.05 to 0.07 percent of Nb, 0.04 to 0.05 percent of V, 0.01 to 0.02 percent of Ti and 0.02 to 0.035 percent of Als; the balance of Fe and inevitable impurities; the thickness of the hot-rolled steel strip is 3-5 mm, and the metallographic structure of the hot-rolled steel strip is ferrite and martensite so as to meet the requirement of the hot-rolled steel strip for the coiled tubing of the ultra-deep well.)

1. A hot rolled steel strip for 750 MPa-grade continuous oil pipes is characterized in that: the weight percentage of the chemical components is as follows: c: 0.12% -0.14%, Si: 0.30-0.40%, Mn: 1.50% -2.00%, P: less than or equal to 0.015%, S: less than or equal to 0.0050%, Cr: 0.50-0.70%, Cu: 0.10% -0.40%, Ni: 0.10% -0.30%, Mo: 0.20% -0.50%, Nb: 0.050% -0.070%, V: 0.040-0.050%, Ti: 0.010-0.020%, Als: 0.020-0.035%; the balance of Fe and inevitable impurities; the thickness of the produced hot-rolled steel strip is 3-5 mm, the metallographic structure of the hot-rolled steel strip is ferrite and martensite, the grain size is more than or equal to 12 grade, and the banded structure is less than or equal to 1.5 grade.

2. The method of manufacturing a hot-rolled steel strip for a 750MPa grade coiled tubing according to claim 1, comprising the steps of:

firstly, pretreating molten iron: controlling the desulfurized molten iron [ S ] to be less than or equal to 0.0050 percent;

step two, smelting in a converter: the argon station is used for carrying out top-bottom strong stirring, the strong stirring time is more than or equal to 4min, the P is removed in the strengthening process, and deoxidation alloying is carried out during tapping to strengthen the slag stopping operation;

step three, refining in an LF furnace: fully reducing the ladle top slag, adjusting the components to a target value or approach the target value, and discharging the steel ladle to a station at the temperature: 1600-1615 ℃;

step four, refining in an RH furnace: the vacuum degree is less than or equal to 2.6mbar, the vacuum time is more than or equal to 12min, and all the components are adjusted to target values;

step five, continuous casting: controlling the target temperature of the tundish to be 15-30 ℃ above the liquidus temperature, and applying dynamic soft reduction and electromagnetic braking in the continuous casting process;

step six, heating: heating the casting blank in a heating furnace;

step seven, rolling: the rolling adopts two-stage rolling, the first stage is rolling in a recrystallization region, and the rolling temperature is controlled to be 1000-1060 ℃; the second stage is rolling in the non-recrystallization region, and the rolling temperature is controlled to be 900-1000 ℃.

Step eight, performing laminar cooling and coiling on the rolled steel plate: 4-6 groups of edge shielding devices are thrown in the laminar cooling process, the temperature drop of the edge of the strip steel is reduced, and the strip steel is cooled to the temperature of 400-550 ℃ for coiling.

3. The method of manufacturing a hot-rolled steel strip for a 750MPa grade continuous oil pipe according to claim 2, wherein: and step six, controlling the discharging temperature of the casting blank to be 1230-1270 ℃, and keeping the temperature of the soaking section for not less than 60 min.

4. The method of manufacturing a hot-rolled steel strip for a 750MPa grade continuous oil pipe according to claim 3, wherein: and stacking and slowly cooling the casting blank for more than 48 hours before the casting blank enters a heating furnace.

5. The method of manufacturing a hot-rolled steel strip for a 750MPa grade continuous oil pipe according to claim 2, wherein: and seventhly, rolling in an austenite recrystallization region in the rough rolling stage, wherein the rolling temperature is controlled within the range of 1000-1060 ℃.

6. The method of manufacturing a hot-rolled steel strip for a 750MPa grade continuous oil pipe according to claim 2, wherein: and seventhly, in the finish rolling stage, a 7-frame four-roller CVC rolling mill is adopted for continuous rolling, and the finish rolling temperature is controlled to be 830-870 ℃.

7. The method of manufacturing a hot-rolled steel strip for a 750MPa grade continuous oil pipe according to claim 2, wherein: and step eight, controlling the cooling speed to be 20-30 ℃/s.

8. The method of manufacturing a hot-rolled steel strip for a 750MPa grade continuous oil pipe according to claim 2, wherein: and step eight, coiling within the range of 400-550 ℃.

Technical Field

The invention relates to the technical field of steel for oil well pipelines, in particular to a hot rolled steel strip for a 750 MPa-grade continuous oil pipe and a manufacturing method thereof.

Background

The Coiled Tubing (CT) is a novel oil-gas tubing with high strength, high plasticity and certain corrosion resistance, the length of a single tube can reach thousands of meters or even thousands of meters, the Coiled tubing is wound on a winding drum to be transported and used, and is matched with a Coiled tubing operation machine, so that dozens of operations in the fields of oil-gas field well repair, well logging, well drilling, well completion, oil-gas transmission and the like can be carried out, and the Coiled tubing has the advantages of small floor area, safe and efficient operation, small environmental pollution, convenient transportation and installation and the like.

Along with the development needs of shale gas in domestic ultra-deep wells and southwest regions, the number of domestic land ultra-deep wells (6000-9000 m) is rapidly increased, the operation depth of the coiled tubing also exceeds 6000m, the underground operation pressure is high, the conventional high-strength coiled tubing cannot completely meet the production requirements, the coiled tubing cannot bear the heavy dead weight and the high pressure in the steel pipe during the operation process, and a coiled tubing product with higher strength is needed.

Through search, relevant patents have been published for solving the above-mentioned deficiencies. For example, the Chinese patent application number is: 200810040895.6, application date is: 24 days in 2008, 7 and 24 days, and the date of authorized bulletin: 7/20/2011, discloses a steel for a CT 90-grade continuous oil pipe and a manufacturing method thereof, wherein the steel comprises the following chemical components in percentage by weight: c: 0.02 to 0.25%, Si: 0.10 to 0.60%, Mn: 0.50-2.0%, P is less than or equal to 0.015%, S is less than or equal to 0.005%, Cr: 0.30 to 1.50%, Nb: 0.02 to 0.13%, Ti: 0.01-0.10%, V: 0.01 to 0.10%, Mo: 0.05 to 0.35%, Cu: 0.10 to 0.50%, Ni: 0.10 to 0.40%, Ca: 0.0010-0.0050%, Al: 0.01-0.05%, N is less than or equal to 0.012, and the balance is Fe and inevitable impurities, and the strength is improved through processes of smelting, casting, slab reheating, rolling, cooling, coiling and the like, but the strength is not enough to meet the requirement of ultra-deep well operation; meanwhile, the component design of the alloy contains higher V, which is unfavorable for the toughness and welding performance of the product; the yield ratio of the steel plate is more than 0.90, the deformability is poor, and the requirement of repeated plastic deformation in the operation process of the product cannot be met.

As another example, the chinese patent has an application number: 201711324677.0, application date is: 13 days 12 and 12 months 2017, and the authorized announcement date are as follows: 3, 8 days in 2019, discloses a hot-rolled steel strip for a CT 110-grade continuous tube and a production method, and the hot-rolled steel strip comprises the following components in percentage by weight: c: 0.11 to 0.15%, Si: 0.10 to 0.30%, Mn: 0.90-1.30%, P: less than or equal to 0.015 percent, S: less than or equal to 0.0020 percent, Cu: 0.25 to 0.40%, Ni: 0.15-0.35%, Cr: 0.60 to 1.00%, Nb: 0.020-0.050%, V: less than or equal to 0.010 percent, T i: 0.010-0.030%, N: less than or equal to 0.0050%, Al: 0.015 to 0.060%, Mo: 0.10-0.30%, Ca: 0.0008-0.0025%, and the production steps are as follows: continuously casting into a blank after the working procedures of converter smelting and the like; heating a casting blank; rough rolling; fine rolling; the steel is cooled and coiled to make the yield strength of the steel about 700MPa, but the steel is also exposed to the risk of insufficient strength in the operation of ultra-deep wells.

Disclosure of Invention

1. Technical problem to be solved by the invention

Aiming at the problem that the strength of steel for the continuous oil pipe in the prior art is not enough to meet the requirement of ultra-deep well operation, the invention provides a hot-rolled steel strip for the continuous oil pipe with the level of 750MPa and a manufacturing method thereof, wherein the hot-rolled steel strip is prepared by hot metal pretreatment → converter steel making → LF external refining → RH external refining → continuous casting → hot rolling, and after the LF external refining, the chemical components in the steel meet the weight percentage (wt%): c: 0.12% -0.14%, Si: 0.30-0.40%, Mn: 1.50% -2.00%, P: less than or equal to 0.015%, S: less than or equal to 0.0050%, Cr: 0.50-0.70%, Cu: 0.10% -0.40%, Ni: 0.10% -0.30%, Mo: 0.20% -0.50%, Nb: 0.050% -0.070%, V: 0.040-0.050%, Ti: 0.010-0.020%, Als: 0.020-0.035%; the balance of Fe and inevitable impurities; the thickness of the produced hot-rolled steel strip is 3-5 mm, the metallographic structure of the hot-rolled steel strip is ferrite and martensite, the grain size is more than or equal to 12 grade, and the banded structure is less than or equal to 1.5 grade. The yield strength of the produced hot rolled steel strip is 782-809 MPa, and the tensile strength is 1077-1143 MPa, so that the requirements of the hot rolled steel strip for the coiled tubing of the ultra-deep well are met.

2. Technical scheme

In order to achieve the purpose, the technical scheme provided by the invention is as follows:

a hot rolled steel strip for 750 MPa-grade continuous oil pipes and a manufacturing method thereof are disclosed, and the hot rolled steel strip comprises the following chemical components in percentage by weight: c: 0.12% -0.14%, Si: 0.30-0.40%, Mn: 1.50% -2.00%, P: less than or equal to 0.015%, S: less than or equal to 0.0050%, Cr: 0.50-0.70%, Cu: 0.10% -0.40%, Ni: 0.10% -0.30%, Mo: 0.20% -0.50%, Nb: 0.050% -0.070%, V: 0.040-0.050%, Ti: 0.010-0.020%, Als: 0.020-0.035%; the balance of Fe and inevitable impurities; the thickness of the produced hot-rolled steel strip is 3-5 mm, the metallographic structure of the hot-rolled steel strip is ferrite and martensite, the grain size is more than or equal to 12 grade, and the banded structure is less than or equal to 1.5 grade. The yield strength of the produced hot rolled steel strip is 782-809 MPa, and the tensile strength is 1077-1143 MPa, so that the requirements of the hot rolled steel strip for the coiled tubing of the ultra-deep well are met.

A manufacturing method of a hot rolled steel strip for a 750 MPa-grade continuous oil pipe comprises the following steps:

firstly, pretreating molten iron: controlling the desulfurized molten iron [ S ] to be less than or equal to 0.0050 percent;

step two, smelting in a converter: the argon station is used for carrying out top-bottom strong stirring, the strong stirring time is more than or equal to 4min, the P is removed in the strengthening process, and deoxidation alloying is carried out during tapping to strengthen the slag stopping operation;

step three, refining in an LF furnace: fully reducing the ladle top slag, adjusting the components to a target value or approach the target value, and discharging the steel ladle to a station at the temperature: 1600-1615 ℃;

step four, refining in an RH furnace: the vacuum degree is less than or equal to 2.6mbar, the vacuum time is more than or equal to 12min, and all the components are adjusted to target values;

step five, continuous casting: controlling the target temperature of the tundish to be 15-30 ℃ above the liquidus temperature, and applying dynamic soft reduction and electromagnetic braking in the continuous casting process;

step six, heating: heating the casting blank in a heating furnace;

step seven, rolling: the rolling adopts two-stage rolling, the first stage is recrystallization zone rolling, the rolling temperature is controlled to be 1000-1060 ℃, and austenite grains are obviously refined through repeated deformation and recrystallization; the second stage is rolling in a non-recrystallization region, the rolling temperature is controlled to be 900-1000 ℃, deformation and phase change are carried out simultaneously, austenite grains are elongated in the second stage, a slip zone is generated simultaneously, favorable conditions are provided for ferrite nucleation due to increase of austenite grain boundaries and occurrence of the slip zone, and then fine-grained ferrite is obtained;

step eight, performing laminar cooling and coiling on the rolled steel plate: 4-6 groups of edge shielding devices are thrown in the laminar cooling process, the temperature drop of the edge of the strip steel is reduced, and the strip steel is cooled to the temperature of 400-550 ℃ for coiling.

According to the further technical scheme, in the sixth step, the discharging temperature of the casting blank is controlled to be 1230-1270 ℃, and the heat preservation time of the soaking section is not less than 60min, so that the material is completely austenitized, alloy elements are fully dissolved in the solution, and excessive growth of austenite grains can be inhibited.

According to a further technical scheme, the casting blank is stacked and slowly cooled for more than 48 hours before entering a heating furnace.

In the seventh technical scheme, in the step seven, the rough rolling stage is rolled in an austenite recrystallization zone, and the rolling temperature is controlled within the range of 1000-1060 ℃.

In the seventh technical scheme, in the finish rolling stage, a 7-frame four-roller CVC rolling mill is adopted for continuous rolling, the finish rolling temperature is controlled to be 830-870 ℃, the deformation zone and the dislocation density in the deformation austenite are increased by accumulating large deformation, and the phase change nucleation point refined grains are increased.

According to the further technical scheme, in the step eight, the cooling speed is controlled to be 20-30 ℃/s.

According to the further technical scheme, in the step eight, coiling is carried out within the range of 400-550 ℃.

3. Advantageous effects

Compared with the prior art, the technical scheme provided by the invention has the following beneficial effects:

(1) the invention relates to a hot-rolled steel strip for a 750 MPa-level continuous oil pipe and a manufacturing method thereof, which adopts molten iron pretreatment → converter steel making → LF external refining → RH external refining → continuous casting → hot rolling, and after the LF external refining, the chemical components in the steel meet the weight percentage (wt%): c: 0.12% -0.14%, Si: 0.30-0.40%, Mn: 1.50% -2.00%, P: less than or equal to 0.015%, S: less than or equal to 0.0050%, Cr: 0.50-0.70%, Cu: 0.10% -0.40%, Ni: 0.10% -0.30%, Mo: 0.20% -0.50%, Nb: 0.050% -0.070%, V: 0.040-0.050%, Ti: 0.010-0.020%, Als: 0.020-0.035%; the balance of Fe and inevitable impurities; the thickness of the produced hot-rolled steel strip is 3-5 mm, the metallographic structure of the hot-rolled steel strip is ferrite and martensite, the grain size is more than or equal to 12 grade, and the banded structure is less than or equal to 1.5 grade. The yield strength of the produced hot rolled steel strip is 782-809 MPa, and the tensile strength is 1077-1143 MPa, so that the requirements of the hot rolled steel strip for the coiled tubing of the ultra-deep well are met;

(2) the hot rolled steel strip for the 750 MPa-grade continuous oil pipe and the manufacturing method thereof have the advantages that the rolling adopts two-stage rolling, the first stage is rolling in a recrystallization region, the rolling temperature is controlled to be 1000-1060 ℃, and austenite grains are obviously refined through repeated deformation and recrystallization; the second stage is rolling in a non-recrystallization region, the rolling temperature is controlled to be 900-1000 ℃, deformation and phase change are carried out simultaneously, austenite grains are elongated in the second stage, a slip zone is generated simultaneously, favorable conditions are provided for ferrite nucleation due to increase of austenite grain boundaries and occurrence of the slip zone, and then fine-grained ferrite is obtained;

(3) the hot rolled steel strip for the 750 MPa-level continuous oil pipe and the manufacturing method thereof control the discharging temperature of a casting blank to be 1230-1270 ℃, and the heat preservation time of a soaking section is not less than 60min, and mainly aim at ensuring the complete austenitization of the material, fully dissolving alloy elements in a solid solution and simultaneously inhibiting the excessive growth of austenite grains;

(4) the invention relates to a hot rolled steel strip for a 750 MPa-level continuous oil pipe and a manufacturing method thereof.A 7-frame four-roller CVC rolling mill is adopted for continuous rolling in a finish rolling stage, the finish rolling temperature is controlled to be 830-870 ℃, through accumulation of large deformation, the deformation band and dislocation density in deformation austenite are increased, and the refined grains of a phase change nucleation point are increased.

Drawings

FIG. 1 is a metallographic photograph of a hot rolled steel strip according to the present invention;

FIG. 2 is an electron micrograph of a hot rolled steel strip according to the present invention.

Detailed Description

For a further understanding of the invention, reference should be made to the following detailed description taken in conjunction with the accompanying drawings.

Example 1

The hot rolled steel strip for the 750 MPa-grade continuous oil pipe comprises the following chemical components in percentage by weight: c: 0.12% -0.14%, Si: 0.30-0.40%, Mn: 1.50% -2.00%, P: less than or equal to 0.015%, S: less than or equal to 0.0050%, Cr: 0.50-0.70%, Cu: 0.10% -0.40%, Ni: 0.10% -0.30%, Mo: 0.20% -0.50%, Nb: 0.050% -0.070%, V: 0.040-0.050%, Ti: 0.010-0.020%, Als: 0.020-0.035%; the balance of Fe and inevitable impurities; the thickness of the produced hot-rolled steel strip is 3-5 mm, the metallographic structure of the hot-rolled steel strip is ferrite and martensite, the grain size is more than or equal to 12 grade, and the banded structure is less than or equal to 1.5 grade. The yield strength of the produced hot rolled steel strip is 782-809 MPa, and the tensile strength is 1077-1143 MPa, so that the requirements of the hot rolled steel strip for the coiled tubing of the ultra-deep well are met.

Example 2

The basic structure of the manufacturing method of the hot rolled steel strip for the 750 MPa-level continuous oil pipe in the embodiment is the same as that of the embodiment 1, and the differences and the improvements are that: the method comprises the following steps:

firstly, pretreating molten iron: controlling the desulfurized molten iron [ S ] to be less than or equal to 0.0050 percent;

step two, smelting in a converter: the argon station is used for carrying out top-bottom strong stirring, the strong stirring time is more than or equal to 4min, the P is removed in the strengthening process, and deoxidation alloying is carried out during tapping to strengthen the slag stopping operation;

step three, refining in an LF furnace: fully reducing the ladle top slag, adjusting the components to a target value or approach the target value, and discharging the steel ladle to a station at the temperature: 1600-1615 ℃;

step four, refining in an RH furnace: the vacuum degree is less than or equal to 2.6mbar, the vacuum time is more than or equal to 12min, and all the components are adjusted to target values;

step five, continuous casting: controlling the target temperature of the tundish to be 15-30 ℃ above the liquidus temperature, applying dynamic soft reduction and electromagnetic braking in the continuous casting process, and carrying out protective casting in the whole continuous casting process;

step six, heating: heating the casting blank in a heating furnace;

step seven, rolling: the rolling adopts two-stage rolling, the first stage is recrystallization zone rolling, the rolling temperature is controlled to be 1000-1060 ℃, and austenite grains are obviously refined through repeated deformation and recrystallization; the second stage is rolling in a non-recrystallization region, the rolling temperature is controlled to be 900-1000 ℃, deformation and phase change are carried out simultaneously, austenite grains are elongated in the second stage, a slip zone is generated simultaneously, favorable conditions are provided for ferrite nucleation due to increase of austenite grain boundaries and occurrence of the slip zone, and then fine-grained ferrite is obtained;

step eight, performing laminar cooling and coiling on the rolled steel plate: 4-6 groups of edge shielding devices are thrown in the laminar cooling process, the temperature drop of the edge of the strip steel is reduced, and the strip steel is cooled to the temperature of 400-550 ℃ for coiling.

In the sixth step, the tapping temperature of the casting blank is controlled to be 1230-1270 ℃, the heat preservation time of the soaking section is not less than 60min, and the method mainly aims to ensure that the material is completely austenitized, so that alloy elements are fully dissolved in solid, and meanwhile, the excessive growth of austenite grains can be inhibited. And stacking and slowly cooling the casting blank for more than 48 hours before the casting blank enters a heating furnace.

Step seven, rolling in an austenite recrystallization region in a rough rolling stage, wherein the rolling temperature is controlled within the range of 1000-1060 ℃; and in the finish rolling stage, 7 four-roller CVC rolling mills are adopted for continuous rolling, the finish rolling temperature is controlled to be 830-870 ℃, and deformation bands and dislocation density in deformation austenite are increased and phase change nucleation points are increased to refine grains by accumulating large deformation.

In the eighth step, the cooling speed is controlled to be 20-30 ℃/s; coiling is carried out within the range of 400-550 ℃.

Example 3

The basic structure of the manufacturing method of the hot rolled steel strip for the 750 MPa-level continuous oil pipe in the embodiment is the same as that of the embodiment 2, and the differences and the improvements are that: adopting molten iron pretreatment → converter steelmaking → LF external refining → RH external refining → continuous casting → hot rolling. After LF external refining, the chemical components in the steel meet the following weight percentages (wt%): c: 0.12% -0.14%, Si: 0.30-0.40%, Mn: 1.50% -2.00%, P: less than or equal to 0.015%, S: less than or equal to 0.0050%, Cr: 0.50-0.70%, Cu: 0.10% -0.40%, Ni: 0.10% -0.30%, Mo: 0.20% -0.50%, Nb: 0.050% -0.070%, V: 0.040-0.050%, Ti: 0.010-0.020%, Als: 0.020-0.035%; the balance of Fe and inevitable impurities.

Table 1 shows the chemical compositions of the examples in the experiment. The component detection is carried out according to GB/T4336 atomic emission spectrometry (conventional method) for spark sources of carbon steel and medium and low alloy steel.

TABLE 1 chemical composition of examples of the invention

In the rolling process, the slab is heated to 1230-1270 ℃ → high-pressure water descaling → 2-frame rough rolling → 7-frame finish rolling → laminar cooling → coiling, and the main parameters of the rolling process are shown in table 2.

TABLE 2 Main Process parameters of the Rolling procedure

The microstructure of the test steel of the present invention was ferrite and a small amount of martensite, and the mechanical properties are shown in table 3.

TABLE 3 non-metallic inclusions of test steels of the invention

The test steels of the present invention were excellent in low-temperature impact properties, and the impact energy converted into a standard sample is shown in Table 4.

TABLE 4 impact energy of the test steels of the invention

In conclusion, the yield strength of the hot rolled steel strip for the continuous oil pipe produced according to the chemical composition, hot rolling and process design provided by the invention reaches more than 750MPa, and the transverse mechanical property is as follows: yield strength: 782-809 MPa, tensile strength: 1077 to 1143MPa, A50: 12 to 14.4 percent; longitudinal mechanical properties: yield strength: 770-806 MPa, tensile strength: 1081 to 1141MPa, A50: 13.3% -15.8%; the yield ratio of the product is lower than 0.75, and the product has good deformability; the product has impact power of more than 30J at the temperature of-20 ℃ and good toughness.

The present invention and its embodiments have been described above schematically, without limitation, and what is shown in the drawings is only one of the embodiments of the present invention, and the actual structure is not limited thereto. Therefore, if the person skilled in the art receives the teaching, without departing from the spirit of the invention, the person skilled in the art shall not inventively design the similar structural modes and embodiments to the technical solution, but shall fall within the scope of the invention.