Hard alloy milling cutter with high impact resistance and preparation method thereof

文档序号：1811366 发布日期：2021-11-09 浏览：25次中文

阅读说明：本技术 一种抗冲击力强的硬质合金铣刀及其制备方法 (Hard alloy milling cutter with high impact resistance and preparation method thereof ) 是由刘天桂高建华刘阳肖孝超黎明林于 2021-08-17 设计创作，主要内容包括：本分明提供了一种抗冲击力强的硬质合金铣刀及其制备方法,其中,制备铣刀的硬质合金采用固溶强化的方法增加合金的硬度,通过淬火、回火等热处理工艺,提高合金的硬度以及抗冲击性能；添加调和相,使合金中的不同金相组织能均匀的分散在合金中,提高了合金的综合性能。淬冷液由高分子组合而成,其中的主要成分具有优良的催冷效果,同时具有热安定性,优良的光良性以及清洁光亮性。对铣刀的表面进行处理,通过等离子喷涂技术,可将硬化粉末喷涂在合金表面,粉状涂层经过高温烘烤流平固化,变成最终涂层,最终涂层具有耐高温的性能,同时不会降低铣刀的切削能力。(The hard alloy milling cutter with strong impact resistance and the preparation method thereof are obviously provided, wherein the hardness of the alloy is increased by adopting a solid solution strengthening method for preparing the hard alloy of the milling cutter, and the hardness and the impact resistance of the alloy are improved through heat treatment processes such as quenching, tempering and the like; the harmonic phase is added, so that different metallographic structures in the alloy can be uniformly dispersed in the alloy, and the comprehensive performance of the alloy is improved. The quenching liquid is formed by combining polymers, and the main components of the quenching liquid have excellent cooling acceleration effect, thermal stability, excellent light virtues and clean brightness. The surface of the milling cutter is treated, the hardened powder can be sprayed on the surface of the alloy by a plasma spraying technology, the powdery coating is baked, leveled and solidified at high temperature to form a final coating, and the final coating has high temperature resistance and can not reduce the cutting capacity of the milling cutter.)

1. An impact-resistant hard milling cutter is characterized in that: the milling cutter comprises the following raw materials: 70-75 parts of No. 45 steel, 35-45 parts of iron, 1-2 parts of titanium, 0.03-0.05 part of boron, 0.5-1.2 parts of nickel and 0.1-0.2 part of cobalt.

2. A method of making an impact resistant hard milling cutter as claimed in claim 1, wherein: the specific preparation process of the milling cutter comprises the following steps:

firstly), the preparation method of the alloy blank comprises the following steps:

1) preparing the raw materials according to the proportion;

2) putting No. 45 steel into a high-temperature furnace, heating, raising the temperature to 1600 ℃, and preserving heat for 2-3 hours for later use after the steel is completely melted to form uniform molten metal;

3) putting raw materials with iron mass of 60-70% into a high-temperature furnace, heating to 1740 ℃ at the speed of 10-15 ℃/min, preserving heat for 2-3h, adding titanium, nickel, cobalt and boron into the furnace, heating to 2250 ℃ at the speed of 4-7 ℃/min, preserving heat for 1-1.5h, and then cooling to 1775 ℃ at the speed of 1-3 ℃/min to obtain an intermediate a;

4) putting the rest iron raw material into a high-temperature furnace, heating to 1820 ℃ until the iron raw material is melted into uniform molten metal, adding the reinforcing concoction mass, heating to 1980 ℃ at the rate of 4-6 ℃, and then preserving heat for 3 hours to obtain an intermediate b;

5) uniformly mixing the intermediate a and the intermediate b, heating the mixture to 2200 ℃, preserving heat for 2-3h, adding the molten metal prepared in the step 2), heating the mixture to 2400 ℃, and preserving heat for 1-2h to obtain mixed alloy liquid;

6) heating the mixed alloy liquid prepared in the step 5) to 2500 ℃ at the speed of 7-9 ℃/min, preserving heat for 15-30min, then slowly cooling to 1500 ℃ at the speed of 7-9 ℃/min, preserving heat for 4-5h, heating to 1550 ℃ at the speed of 3-5 ℃/min, preserving heat for 3-4h, then cooling to 1000 ℃ at the speed of 3-6 ℃/min, and preserving heat for 3-4 h; then putting the alloy into quenching liquid for quenching to obtain an alloy body i;

7) heating the alloy body i to 770 ℃ at the speed of 7-10 ℃/min, and preserving heat for 1-2 h; cooling to 300 deg.C at 2 deg.C/min, maintaining for 3-4 hr, heating to 330 deg.C at 1 deg.C/min, maintaining for 3 hr, and cooling to room temperature at 2 deg.C/min to obtain the final product;

II) preparation of roughing milling cutter

Preparing a metal piece blank from the prepared hard alloy, and preparing a rough milling cutter for later use by the metal piece blank through centerless grinding, rough pouring, fine grinding, downstep, grinding center grooving and fine grinding processes;

three) surface treatment of milling cutter

I) soaking the prepared rough milling cutter in a binder, heating the solution to 60 ℃, and keeping the temperature for 4-6 h;

and ii) placing the milling cutter treated in the step i) into a control chamber, and spraying the hardened powder in an atmosphere plasma spraying device until the spraying thickness is 5 microns to obtain the powder.

3. A method of making an impact resistant hard milling cutter as claimed in claim 2, wherein: the raw materials for enhancing the harmonious substance are as follows: 0.06-0.12 part of manganese, 10-15 parts of iron, 0.2-0.3 part of vanadium, 0.03-0.05 part of scandium, 0.01-0.03 part of lanthanum and 0.01-0.02 part of cerium.

4. A method of making an impact resistant hard milling cutter as claimed in claim 2 or 3, wherein: the specific preparation method of the reinforced harmonious substance comprises the following steps:

putting iron into a high-temperature furnace, heating to 1650 ℃ until the iron is melted into molten metal, adding scandium, lanthanum and cerium, heating to 2010 ℃ at the speed of 3-5 ℃/min, preserving the temperature for 15-30min, adding manganese and vanadium, preserving the temperature for 30-45min, cooling to 700 ℃ at the speed of 2-4 ℃/min, preserving the temperature for 3-4h, cooling to 400-fold-by-phase 500 ℃ by quenching, and preserving the temperature for 4-5h to obtain the iron-based alloy.

5. A method of making an impact resistant hard milling cutter as claimed in claim 2, wherein: the preparation method of the quenching liquid comprises the following steps:

1) putting 4-7 parts of bis-cinnamoyl thiodipropionate and 3-5 parts of 2, 6-tertiary butyl-4-methylphenol into a reactor, adding a dichlorotoluene solution, heating to 110 ℃ at the speed of 3-5 ℃/min, and carrying out heat preservation reaction for 4-5h to obtain a reactant a;

2) adding 8-10 parts of ternary ethylene propylene into the reactant a, adding a 1.2-dichloromethane solution, heating to 150 ℃ at the speed of 6-8 ℃/min, and carrying out heat preservation reaction for 3 hours to obtain a reactant b;

3) adding 3-5 parts of adipic anhydride into the reactant b, adding an acetone solution, heating to 110 ℃ at the speed of 3-6 ℃/min, carrying out heat preservation reaction for 5-6 h, dropwise adding 6-9 parts of bis (3, 5-tertiary butyl-4-hydroxyphenyl) thioether into a reactor at the speed of 10-13 drops/min, heating to 130 ℃ at the speed of 2-4 ℃/min, and carrying out heat preservation reaction for 3-4h to obtain a reactant c;

4) adding 5-7 parts of imidazoline sodium oleate and 3-5 parts of diethylene glycol mono [ (1, 1, 3, 3-tetramethylbutyl) phenyl ] ether into the reactant c, adding an ethyl acetate solution, heating to 105 ℃ and 110 ℃ at the speed of 1-3 ℃/min, keeping the temperature for reaction for 6h, adding 15-20 parts of liquid paraffin into the mixture, and uniformly stirring to obtain a reactant d;

5) and adding the reactant d into 120 parts of 100-one base oil with 75SN, and uniformly stirring to obtain the catalyst.

6. A method of making an impact resistant hard milling cutter as claimed in claim 2, wherein: the preparation of the binder is as follows:

putting 5-8 parts of polyvinyl ester and 3-5 parts of N-aminoethyl-3-aminopropylmethyldimethoxysilane into a reactor, adding an ethyl acetate solution, slowly heating to 125-130 ℃ at the speed of 3-5 ℃/min, and carrying out heat preservation reaction for 3-4h to obtain an intermediate product a;

adding 3-5 parts of dimethyl phthalate into the intermediate product a, adding a toluene solution, heating to 110 ℃ at the speed of 5-7 ℃/min, and carrying out heat preservation reaction for 4-6h to obtain an intermediate product b;

thirdly, 10-13 parts of the spinel wax is added into the intermediate product b, the temperature is slowly raised to 50-60 ℃ at the speed of 3-4 ℃/min, the mixture is stirred while being heated, and the mixture is subjected to heat preservation reaction for 3-4 hours, so that the catalyst is obtained.

7. A method of making an impact resistant hard milling cutter as claimed in claim 2, wherein: the hardening powder is mixed powder formed by mixing 3-5 parts of titanium nitride powder, 4-6 parts of chromium nitride powder, 6-8 parts of hexagonal boron nitride powder, 5-7 parts of alumina powder, 1-3 parts of titanium carbide powder and 3-5 parts of tungsten carbide.

Technical Field

The invention relates to the technical field related to machining, in particular to a hard alloy milling cutter with strong impact resistance and a preparation method thereof.

Technical Field

A milling cutter is a rotating tool with one or more cutter teeth for milling. When in work, each cutter tooth cuts off the allowance of the workpiece in sequence and intermittently. The milling cutter is mainly used for processing planes, steps, grooves, formed surfaces, cut-off workpieces and the like on a milling machine. Milling cutters are broadly classified into the following two categories: the sharp-tooth milling cutter grinds a narrow cutting edge on the rear cutter face to form a rear angle, and the service life of the sharp-tooth milling cutter is longer due to the reasonable cutting angle. The tooth back of the sharp tooth milling cutter has 3 forms of straight line, curve and broken line. Straight tooth backs are commonly used in fine tooth finishing mills. The cutter teeth of the curved line tooth back and the broken line tooth back have good strength, can bear heavy cutting load and are commonly used for a coarse-tooth milling cutter. The back of the relieving milling cutter is processed into the tooth back of the Archimedes spiral line by a relieving method, and the milling cutter only needs to regrind the front after being blunt, so that the original tooth shape can be kept unchanged, and the relieving milling cutter is used for manufacturing various formed milling cutters such as gear milling cutters and the like.

With the further development of the Chinese industry, the cutting technology gradually advances towards high speed, high efficiency and dry type. High-speed milling is a main process applied to high-speed cutting at present, and a high-speed milling cutter is one of important technologies for realizing high-speed milling. The high-speed cutting technology integrates high efficiency, high quality and low consumption, not only has high cutting efficiency, but also has good surface processing quality and small unit cutting force, but also puts higher requirements on the wear resistance and the red hardness of the cutter material. However, in the using process, the milling cutter is subjected to impact force in a high-temperature environment, so that the milling cutter is seriously abraded, and the service life of the milling cutter is shortened. Therefore, the milling cutter with strong impact resistance and high temperature resistance has positive significance to the technical field of milling cutter preparation. The present milling cutter prolongs the service life of the milling cutter by improving the structure of the milling cutter, but the treatment is not fundamental, and the performance of the milling cutter is easily influenced by the problem of material, so the invention provides a method for preparing the milling cutter by preparing hard alloy with strong impact resistance, and simultaneously provides a surface treatment method of the milling cutter, thereby effectively solving the problem of impact wear of the milling cutter.

Disclosure of Invention

The invention mainly aims to provide a hard alloy milling cutter with strong impact resistance and a preparation method thereof.

The second purpose of the invention is to provide a preparation process of the hard alloy with strong impact resistance.

The third purpose of the invention is to provide a surface treatment method of the hard alloy milling cutter with strong impact resistance.

The preparation method comprises the following steps:

the hard milling cutter with impact resistance is prepared from the following hard alloy raw materials: 70-75 parts of No. 45 steel, 35-45 parts of iron, 1-2 parts of titanium, 0.03-0.05 part of boron, 0.5-1.2 parts of nickel and 0.1-0.2 part of cobalt.

The specific preparation process of the impact-resistant hard milling cutter comprises the following steps:

firstly), the preparation method of the alloy blank comprises the following steps:

1) preparing the raw materials according to the proportion;

5) uniformly mixing the intermediate a and the intermediate b, heating the mixture to 2200 ℃, preserving heat for 2-3h, adding the molten metal prepared in the step 2), jointly heating the mixture to 2400 ℃, and preserving heat for 1-2h to obtain mixed alloy liquid;

II) preparation of roughing milling cutter

three) surface treatment of milling cutter

I) soaking the prepared rough milling cutter in a binder, heating the solution to 60 ℃, and keeping the temperature for 4-6 h;

Wherein the raw materials of the reinforced harmonious substance are as follows: 0.06-0.12 part of manganese, 10-15 parts of iron, 0.2-0.3 part of vanadium, 0.03-0.05 part of scandium, 0.01-0.03 part of lanthanum and 0.01-0.02 part of cerium.

The specific preparation method of the reinforced harmonious substance comprises the following steps:

The preparation method of the quenching liquid comprises the following steps:

5) and adding the reactant d into 120 parts of 100-one base oil with 75SN, and uniformly stirring to obtain the catalyst.

Wherein, the preparation of the binder is as follows:

The hardening powder is mixed powder formed by mixing 3-5 parts of titanium nitride powder, 4-6 parts of chromium nitride powder, 6-8 parts of hexagonal boron nitride powder, 5-7 parts of alumina powder, 1-3 parts of titanium carbide powder and 3-5 parts of tungsten carbide.

The invention has the following advantages:

to obtain a hard alloy milling cutter with strong impact resistance, the alloy for preparing the milling cutter must have excellent impact resistance. The invention selects No. 45 steel and iron as the alloy substrate, and adds solid solution elements such as titanium, boron, nickel, cobalt and the like to carry out solid solution strengthening. According to the invention, alloy raw materials are heated and melted to obtain uniform molten metal, then solid solution metal is added into the molten metal, atoms in the metal are arranged and combined to form a solid solution through a specific heating and cooling process, the strength of the alloy is improved by using a solid solution strengthening method, and the hardness of the hard alloy is greatly enhanced. The alloy is subjected to heat treatment processes such as quenching, tempering, annealing and the like, and the composition of a metal phase in the alloy is controlled, wherein the quenching can increase the strength and the hardness of the alloy, and the tempering can eliminate the internal stress generated by the quenching and reduce the hardness and the brittleness so as to obtain the expected mechanical property. The structural defects are eliminated by annealing, the metallographic structure is improved, the components are homogenized, the crystal grains are refined, the mechanical property of the steel is improved, and the residual stress is reduced; meanwhile, the hardness can be reduced, the plasticity and the toughness are improved, and the cutting processability is improved. However, as a large amount of impurity atoms are added to the alloy raw material to perform solid solution strengthening on the alloy, the defects such as dislocation and the like in a microstructure are increased, the phenomena such as partial aggregation of solid solution atoms occur, the impact resistance of the alloy is reduced, and the alloy is easily subjected to brittle fracture, so that a harmonic phase is added to the alloy, different metal phases in the microstructure of the alloy can be uniformly dispersed in the alloy, and the metal performance of the alloy is improved. Meanwhile, elements capable of increasing the diffusion activation energy of the grain boundary, such as boron and rare earth, are added into the alloy, so that the grain boundary sliding can be hindered, the surface energy of a grain boundary crack surface can be increased, and the endurance strength limit of the alloy can be improved. The addition of rare earth elements improves the cutting performance of the metal and enhances the hardness and toughness of the metal.

Because the types and the number of the solid solution atoms blended in the alloy are more, a special quenching liquid is needed to promote the formation of the metallographic phase in the alloy, otherwise, the solid solution atoms are slowly gathered together and cannot form a relatively uniform solid solution, so that the hardness and the impact resistance of the alloy are reduced. The quenching liquid is formed by combining polymers, and the main components of the quenching liquid have excellent cooling acceleration effect, thermal stability, excellent light virtuous property and clean brightness; the added bis-cinnamoyl thiodipropionate has excellent antioxidant effect and can prevent the alloy from being oxidized; meanwhile, the surfactant is added, so that the adhesion of impurities on the surface of the alloy is reduced, and the stability of the alloy components is protected.

Because the impact strength of the alloy is greatly improved under the influence of quenching liquid and solid solution atoms added in the alloy, but a large amount of heat is generated in the cutting process of the milling cutter, so that the temperature of the milling cutter is increased, a large amount of impurity atoms and dislocation crystal boundaries exist in the prepared alloy, the material easily reaches the creep limit, the milling cutter generates creep due to high temperature, and the milling cutter is broken, so that the surface of the milling cutter needs to be treated, and the service life of the milling cutter is prolonged. The general surface treatment can not reach the condition of the milling cutter in a high-temperature environment, even can slightly corrode the surface of the milling cutter in the high-temperature environment, so that special high-temperature treatment needs to be carried out on the surface of the milling cutter, the high-temperature resistance of the milling cutter is improved, the creep fracture of the milling cutter is reduced, and the service life of the milling cutter is prolonged. The hexagonal boron nitride has a graphite-like layered structure, has good lubricity, electrical insulation, thermal conductivity, chemical corrosion resistance and neutron absorption capacity, is stable in chemical property and inert to all molten metal chemistry, a formed product is convenient to machine, and has high moisture resistance; the hard compound gold alloy powder can be effectively converted into a high-temperature resistant coating under the high-temperature environment under the action of the binder, and the service life of the milling cutter is effectively prolonged. By the plasma spraying technology, effective components can be sprayed on the surface of the alloy, the powdery coating is baked at high temperature, leveled and solidified to form final coatings with different effects (different kinds of effects of the powdery coating), and the final coatings have high-temperature resistance and cannot reduce the cutting capacity of the milling cutter.

Specific preparation method

Example 1

The hard milling cutter with impact resistance is prepared from the following hard alloy raw materials: 73 parts of No. 45 steel, 40 parts of iron, 1.5 parts of titanium, 0.04 part of boron, 0.8 part of nickel and 0.15 part of cobalt.

The specific preparation process of the impact-resistant hard milling cutter comprises the following steps:

firstly), the preparation method of the alloy blank comprises the following steps:

1) preparing the raw materials according to the proportion;

2) putting No. 45 steel into a high-temperature furnace, heating, raising the temperature to 1600 ℃, and preserving heat for 2.5 hours for later use after the steel is completely melted to form uniform molten metal;

3) putting raw materials with iron mass of 65% into a high-temperature furnace, heating to 1740 ℃ at the speed of 13 ℃/min, preserving heat for 2.5 hours, adding titanium, nickel, cobalt and boron into the furnace, heating to 2250 ℃ at the speed of 6 ℃/min, preserving heat for 1.3 hours, and then cooling to 1775 ℃ at the speed of 2 ℃/min to obtain an intermediate a;

4) putting the rest iron raw material into a high-temperature furnace, heating to 1820 ℃ until the iron raw material is melted into uniform molten metal, adding the reinforced blend, heating to 1980 ℃ at the rate of 5 ℃, and preserving heat for 3 hours to obtain an intermediate b;

5) uniformly mixing the intermediate a and the intermediate b, heating the mixture to 2200 ℃, preserving heat for 2.5 hours, adding the molten metal prepared in the step 2), heating the mixture to 2400 ℃ together, and preserving heat for 1.5 hours to obtain mixed alloy liquid;

6) heating the mixed alloy liquid prepared in the step 5) to 2500 ℃ at the speed of 8 ℃/min, preserving heat for 22min, then slowly cooling the mixed alloy liquid to 1500 ℃ at the speed of 8 ℃/min, preserving heat for 4.5h, heating the mixed alloy liquid to 1550 ℃ at the speed of 4 ℃/min, preserving heat for 3.5h, then cooling the mixed alloy liquid to 1000 ℃ at the speed of 5 ℃/min, and preserving heat for 3.5 h; then putting the alloy into quenching liquid for quenching to obtain an alloy body i;

7) heating the alloy body i to 770 ℃ at the speed of 9 ℃/min, and preserving the heat for 1.5 h; cooling to 300 deg.C at 2 deg.C/min, maintaining for 3.5 hr, heating to 330 deg.C at 1 deg.C/min, maintaining for 3 hr, and cooling to room temperature at 2 deg.C/min to obtain the final product;

II) preparation of roughing milling cutter

three) surface treatment of milling cutter

I) soaking the prepared rough milling cutter in a binder, heating the solution to 60 ℃, and keeping the temperature for 5 hours;

The reinforced harmonious substance comprises the following raw materials: 0.09 part of manganese, 13 parts of iron, 0.25 part of vanadium, 0.04 part of scandium, 0.02 part of lanthanum and 0.015 part of cerium.

The specific preparation method of the reinforced harmonious substance comprises the following steps:

putting iron into a high-temperature furnace, heating the molten metal heated to 1650 ℃, adding scandium, lanthanum and cerium, heating to 2010 ℃ at the speed of 4 ℃/min, preserving heat for 23min, adding manganese and vanadium, preserving heat for 38min, cooling to 700 ℃ at the speed of 3 ℃/min, preserving heat for 3.5h, cooling to 450 ℃ by quenching, and preserving heat for 4.5h to obtain the magnesium-based alloy.

The preparation method of the quenching liquid comprises the following steps:

1) putting 6 parts of bis-cinnamoyl thiodipropionate and 4 parts of 2, 6-tertiary butyl-4-methylphenol into a reactor, adding a dichlorotoluene solution, heating to 110 ℃ at the speed of 4 ℃/min, and carrying out heat preservation reaction for 4.5 hours to obtain a reactant a;

2) adding 9 parts of ternary ethylene propylene into the reactant a, adding a 1.2-dichloromethane solution, heating to 150 ℃ at the speed of 7 ℃/min, and carrying out heat preservation reaction for 3 hours to obtain a reactant b;

3) adding 4 parts of adipic anhydride into the reactant b, adding an acetone solution, heating to 110 ℃ at the speed of 5 ℃/min, carrying out heat preservation reaction for 5.5 hours, dropwise adding 8 parts of bis (3, 5-tertiary butyl-4-hydroxyphenyl) thioether into a reactor at the speed of 12 drops/min, heating to 130 ℃ at the speed of 3 ℃/min, and carrying out heat preservation reaction for 3.5 hours to obtain a reactant c;

4) adding 6 parts of imidazoline sodium oleate and 4 parts of diethylene glycol mono [ (1, 1, 3, 3-tetramethylbutyl) phenyl ] ether into the reactant c, adding an ethyl acetate solution, heating to 108 ℃ at the speed of 2 ℃/min, preserving heat, reacting for 6 hours, adding 18 parts of liquid paraffin, and stirring uniformly to obtain a reactant d;

5) and adding the reactant d into 110 parts of base oil of 75SN, and uniformly stirring to obtain the catalyst.

Wherein, the preparation of the binder is as follows:

putting 7 parts of polyvinyl ester and 4 parts of N-aminoethyl-3-aminopropyl methyl dimethoxysilane into a reactor, adding an ethyl acetate solution, slowly heating to 128 ℃ at a speed of 4 ℃/min, and carrying out heat preservation reaction for 3.5 hours to obtain an intermediate product a;

adding 4 parts of dimethyl phthalate into the intermediate product a, adding a toluene solution, heating to 105 ℃ at the speed of 6 ℃/min, and carrying out heat preservation reaction for 4.5 hours to obtain an intermediate product b;

and thirdly, adding 12 parts of the spinel wax into the intermediate product b, slowly heating to 55 ℃ at the speed of 3.5 ℃/min, stirring while heating, and carrying out heat preservation reaction for 3.5 hours to obtain the product.

The hardening powder is mixed powder formed by mixing 4 parts of titanium nitride powder, 5 parts of chromium nitride powder, 7 parts of hexagonal boron nitride powder, 6 parts of alumina powder, 2 parts of titanium carbide powder and 4 parts of tungsten carbide.

Example 2

The hard milling cutter with impact resistance is prepared from the following hard alloy raw materials: 70 portions of No. 45 steel, 45 portions of iron, 1 portion of titanium, 0.05 portion of boron, 0.5 portion of nickel and 0.2 portion of cobalt.

The specific preparation process of the impact-resistant hard milling cutter comprises the following steps:

firstly), the preparation method of the alloy blank comprises the following steps:

1) preparing the raw materials according to the proportion;

2) putting No. 45 steel into a high-temperature furnace, heating, raising the temperature to 1600 ℃, and preserving heat for 2 hours for later use after the steel is completely melted to form uniform molten metal;

3) putting raw materials with iron mass of 70% into a high-temperature furnace, heating to 1740 ℃ at the speed of 10 ℃/min, preserving heat for 3 hours, adding titanium, nickel, cobalt and boron into the furnace, heating to 2250 ℃ at the speed of 4 ℃/min, preserving heat for 1.5 hours, and then cooling to 1775 ℃ at the speed of 1 ℃/min to obtain an intermediate a;

4) putting the rest iron raw material into a high-temperature furnace, heating to 1820 ℃ until the iron raw material is melted into uniform molten metal, adding the reinforced blend, heating to 1980 ℃ at the rate of 6 ℃, and preserving heat for 3 hours to obtain an intermediate b;

5) uniformly mixing the intermediate a and the intermediate b, heating the mixture to 2200 ℃, preserving heat for 2 hours, adding the molten metal prepared in the step 2), heating the mixture to 2400 ℃, and preserving heat for 2 hours to obtain mixed alloy liquid;

6) heating the mixed alloy liquid prepared in the step 5) to 2500 ℃ at the speed of 7 ℃/min, preserving heat for 30min, then slowly cooling the mixed alloy liquid to 1500 ℃ at the speed of 7 ℃/min, preserving heat for 5h, heating the mixed alloy liquid to 1550 ℃ at the speed of 3 ℃/min, preserving heat for 4h, then cooling the mixed alloy liquid to 1000 ℃ at the speed of 3 ℃/min, and preserving heat for 4 h; then putting the alloy into quenching liquid for quenching to obtain an alloy body i;

7) heating the alloy body i to 770 ℃ at the speed of 7 ℃/min, and preserving the heat for 2 hours; then cooling to 300 ℃ at the speed of 2 ℃/min, preserving heat for 3h, then heating to 330 ℃ at the speed of 1 ℃/min, preserving heat for 3h, and then cooling to room temperature at the speed of 2 ℃/min to obtain the product.

II) preparation of roughing milling cutter

three) surface treatment of milling cutter

I) soaking the prepared rough milling cutter in a binder, heating the solution to 60 ℃, and keeping the temperature for 4 hours;

The reinforced harmonious substance comprises the following raw materials: 0.06 part of manganese, 15 parts of iron, 0.2 part of vanadium, 0.05 part of scandium, 0.01 part of lanthanum and 0.02 part of cerium.

The specific preparation method of the reinforced harmonious substance comprises the following steps:

putting iron into a high-temperature furnace, heating the molten metal heated to 1650 ℃, adding scandium, lanthanum and cerium, heating to 2010 ℃ at the speed of 5 ℃/min, preserving heat for 15min, adding manganese and vanadium, preserving heat for 45min, cooling to 700 ℃ at the speed of 2 ℃/min, preserving heat for 4h, cooling to 400 ℃ by quenching, and preserving heat for 5h to obtain the magnesium-aluminum alloy.

The preparation method of the quenching liquid comprises the following steps:

1) putting 4 parts of bis-cinnamoyl thiodipropionate and 5 parts of 2, 6-tertiary butyl-4-methylphenol into a reactor, adding a dichlorotoluene solution, heating to 110 ℃ at the speed of 3 ℃/min, and carrying out heat preservation reaction for 5 hours to obtain a reactant a;

2) adding 8 parts of ternary ethylene propylene into the reactant a, adding a 1.2-dichloromethane solution, heating to 150 ℃ at the speed of 8 ℃/min, and carrying out heat preservation reaction for 3 hours to obtain a reactant b;

3) adding 3 parts of adipic anhydride into the reactant b, adding an acetone solution, heating to 110 ℃ at the speed of 6 ℃/min, carrying out heat preservation reaction for 5 hours, dropwise adding 9 parts of bis (3, 5-tertiary butyl-4-hydroxyphenyl) thioether into the reactor at the speed of 10 drops/min, heating to 130 ℃ at the speed of 4 ℃/min, and carrying out heat preservation reaction for 3 hours to obtain a reactant c;

4) adding 7 parts of imidazoline sodium oleate and 3 parts of diethylene glycol mono [ (1, 1, 3, 3-tetramethylbutyl) phenyl ] ether into the reactant c, adding an ethyl acetate solution, heating to 105 ℃ at the speed of 3 ℃/min, keeping the temperature for reaction for 6 hours, adding 20 parts of liquid paraffin, and uniformly stirring to obtain a reactant d;

5) and adding the reactant d into 100 parts of base oil of 75SN, and uniformly stirring to obtain the catalyst.

Wherein, the preparation of the binder is as follows:

putting 5 parts of polyvinyl ester and 5 parts of N-aminoethyl-3-aminopropyl methyl dimethoxysilane into a reactor, adding an ethyl acetate solution, slowly heating to 130 ℃ at the speed of 3 ℃/min, and carrying out heat preservation reaction for 3 hours to obtain an intermediate product a;

adding 5 parts of dimethyl phthalate into the intermediate product a, adding a toluene solution, heating to 110 ℃ at the speed of 5 ℃/min, and carrying out heat preservation reaction for 4 hours to obtain an intermediate product b;

thirdly, 13 parts of the microcrystalline wax is added into the intermediate product b, the temperature is slowly raised to 60 ℃ at the speed of 3 ℃/min, the temperature is raised while stirring, and the heat preservation reaction is carried out for 3 hours, thus obtaining the product.

The hardening powder is mixed powder formed by mixing 5 parts of titanium nitride powder, 4 parts of chromium nitride powder, 8 parts of hexagonal boron nitride powder, 5 parts of alumina powder, 3 parts of titanium carbide powder and 3 parts of tungsten carbide.

Example 3

The hard milling cutter with impact resistance is prepared from the following hard alloy raw materials: 75 parts of No. 45 steel, 35 parts of iron, 2 parts of titanium, 0.03 part of boron, 1.2 parts of nickel and 0.1 part of cobalt.

The specific preparation process of the impact-resistant hard milling cutter comprises the following steps:

firstly), the preparation method of the alloy blank comprises the following steps:

1) preparing the raw materials according to the proportion;

2) putting No. 45 steel into a high-temperature furnace, heating, raising the temperature to 1600 ℃, and preserving heat for 3 hours for later use after the steel is completely melted to form uniform molten metal;

3) putting raw materials with the iron mass of 60 into a high-temperature furnace, heating to 1740 ℃ at the speed of 15 ℃/min, preserving heat for 2 hours, adding titanium, nickel, cobalt and boron into the furnace, heating to 2250 ℃ at the speed of 7 ℃/min, preserving heat for 1 hour, and then cooling to 1775 ℃ at the speed of 3 ℃/min to obtain an intermediate a;

4) putting the rest iron raw material into a high-temperature furnace, heating to 1820 ℃ until the iron raw material is melted into uniform molten metal, adding the reinforcing concoction mass, heating to 1980 ℃ at the rate of 4 ℃, and preserving heat for 3 hours to obtain an intermediate b;

5) uniformly mixing the intermediate a and the intermediate b, heating the mixture to 2200 ℃, preserving heat for 3 hours, adding the molten metal prepared in the step 2), heating the mixture to 2400 ℃, and preserving heat for 1 hour to obtain mixed alloy liquid;

6) heating the mixed alloy liquid prepared in the step 5) to 2500 ℃ at the speed of 9 ℃/min, preserving heat for 15min, then slowly cooling the mixed alloy liquid to 1500 ℃ at the speed of 9 ℃/min, preserving heat for 4h, heating the mixed alloy liquid to 1550 ℃ at the speed of 5 ℃/min, preserving heat for 3h, then cooling the mixed alloy liquid to 1000 ℃ at the speed of 6 ℃/min, and preserving heat for 3 h; then putting the alloy into quenching liquid for quenching to obtain an alloy body i;

7) heating the alloy body i to 770 ℃ at the speed of 10 ℃/min, and preserving the heat for 1 h; cooling to 300 deg.C at 2 deg.C/min, maintaining for 4 hr, heating to 330 deg.C at 1 deg.C/min, maintaining for 3 hr, and cooling to room temperature at 2 deg.C/min.

II) preparation of roughing milling cutter

three) surface treatment of milling cutter

I) soaking the prepared rough milling cutter in a binder, heating the solution to 60 ℃, and keeping the temperature for 6 hours;

The reinforced harmonious substance comprises the following raw materials: 0.12 part of manganese, 10 parts of iron, 0.3 part of vanadium, 0.03 part of scandium, 0.03 part of lanthanum and 0.01 part of cerium.

The specific preparation method of the reinforced harmonious substance comprises the following steps:

putting iron into a high-temperature furnace, heating the molten metal heated to 1650 ℃, adding scandium, lanthanum and cerium, heating to 2010 ℃ at the speed of 3 ℃/min, preserving heat for 30min, adding manganese and vanadium, preserving heat for 30min, cooling to 700 ℃ at the speed of 4 ℃/min, preserving heat for 3h, cooling to 500 ℃ by quenching, and preserving heat for 4h to obtain the product.

The preparation method of the quenching liquid comprises the following steps:

1) putting 7 parts of bis-cinnamoyl thiodipropionate and 3 parts of 2, 6-tertiary butyl-4-methylphenol into a reactor, adding a dichlorotoluene solution, heating to 110 ℃ at the speed of 5 ℃/min, and carrying out heat preservation reaction for 4 hours to obtain a reactant a;

2) adding 10 parts of ternary ethylene propylene into the reactant a, adding a 1.2-dichloromethane solution, heating to 150 ℃ at the speed of 6 ℃/min, and carrying out heat preservation reaction for 3 hours to obtain a reactant b;

3) adding 5 parts of adipic anhydride into the reactant b, adding an acetone solution, heating to 110 ℃ at the speed of 3 ℃/min, carrying out heat preservation reaction for 6 hours, dropwise adding 6 parts of bis (3, 5-tertiary butyl-4-hydroxyphenyl) thioether into the reactor at the speed of 13 drops/min, heating to 130 ℃ at the speed of 2 ℃/min, and carrying out heat preservation reaction for 4 hours to obtain a reactant c;

4) adding 5 parts of imidazoline sodium oleate and 5 parts of diethylene glycol mono [ (1, 1, 3, 3-tetramethylbutyl) phenyl ] ether into the reactant c, adding an ethyl acetate solution, heating to 110 ℃ at the speed of 1 ℃/min, keeping the temperature for reaction for 6 hours, adding 15 parts of liquid paraffin, and uniformly stirring to obtain a reactant d;

5) and adding the reactant d into 120 parts of base oil of 75SN, and uniformly stirring to obtain the catalyst.

The surface treatment of the milling cutter is as follows:

1) preparing a metal piece blank from the prepared hard alloy, and preparing a rough milling cutter for later use by the metal piece blank through centerless grinding, rough pouring, fine grinding, downstep, grinding center grooving and fine grinding processes;

2) soaking the milling cutter prepared in the step 1) in a binder, heating the solution to 60 ℃, and keeping the temperature for 6 hours;

3) returning the milling cutter treated in the step 2) to a control room, and spraying the hardened powder in an atmosphere plasma spraying device until the spraying thickness is 5 microns to obtain the powder.

Wherein, the preparation of the binder is as follows:

putting 8 parts of polyvinyl ester and 3 parts of N-aminoethyl-3-aminopropyl methyl dimethoxysilane into a reactor, adding an ethyl acetate solution, slowly heating to 125 ℃ at the speed of 5 ℃/min, and carrying out heat preservation reaction for 4 hours to obtain an intermediate product a;

adding 3 parts of dimethyl phthalate into the intermediate product a, adding a toluene solution, heating to 100 ℃ at the speed of 7 ℃/min, and carrying out heat preservation reaction for 6 hours to obtain an intermediate product b;

and thirdly, adding 10 parts of the spinel wax into the intermediate product b, slowly heating to 50 ℃ at the speed of 4 ℃/min, stirring while heating, and carrying out heat preservation reaction for 4 hours to obtain the product.

The hardening powder is mixed powder formed by mixing 3 parts of titanium nitride powder, 6 parts of chromium nitride powder, 6 parts of hexagonal boron nitride powder, 7 parts of alumina powder, 1 part of titanium carbide powder and 5 parts of tungsten carbide.

Comparative example 1

A method for preparing a hard alloy milling cutter with strong impact resistance.

The hard alloy for preparing the milling cutter comprises the following raw materials: 73 parts of No. 45 steel, 40 parts of iron, 1.5 parts of titanium, 0.01 part of boron, 0.8 part of nickel and 0.15 part of cobalt.

The rest is the same as example 1.

Comparative example 2

A method for preparing a hard alloy milling cutter with strong impact resistance.

The hard alloy for preparing the milling cutter comprises the following raw materials: 73 parts of No. 45 steel, 40 parts of iron, 3.5 parts of titanium, 0.04 part of boron, 0.8 part of nickel and 0.15 part of cobalt.

The rest is the same as example 1.

Comparative example 3

A method for preparing a hard alloy milling cutter with strong impact resistance.

The rest is the same as example 1.

Comparative example 4

A method for preparing a hard alloy milling cutter with strong impact resistance.

The preparation method of the alloy blank comprises the following steps:

1) preparing the raw materials according to the proportion;

3) putting iron into a high-temperature furnace, heating to 1740 ℃ at the speed of 13 ℃/min, preserving heat for 2.5 hours, adding titanium, nickel, cobalt and boron into the furnace, heating to 2250 ℃ at the speed of 6 ℃/min, preserving heat for 1.3 hours, and then cooling to 1775 ℃ at the speed of 2 ℃/min to obtain an intermediate a;

4) putting the enhanced blend into a high-temperature furnace, heating, and heating to 18200 ℃ until the enhanced blend is melted into uniform molten metal to obtain an intermediate b;

5) uniformly mixing the intermediate a and the intermediate b, heating the mixture to 2200 ℃, preserving heat for 2.5 hours, adding the molten metal prepared in the step 1), heating the mixture to 2400 ℃ together, and preserving heat for 1.5 hours to obtain mixed alloy liquid;

The rest is the same as example 1.

Comparative example 5

A method for preparing a hard alloy milling cutter with strong impact resistance.

The preparation method of the alloy blank comprises the following steps:

1) preparing the raw materials according to the proportion;

4) putting the rest iron raw material into a high-temperature furnace, heating, and heating to 1820 ℃ until the iron raw material is melted into uniform molten metal to obtain an intermediate b;

The rest is the same as example 1.

Comparative example 6

A method for preparing a hard alloy milling cutter with strong impact resistance.

The preparation method of the alloy blank comprises the following steps:

1) preparing the raw materials according to the proportion;

3) putting raw materials with iron mass of 65% into a high-temperature furnace, adding titanium, nickel, cobalt and boron into the furnace, heating to 1740 ℃ at the speed of 13 ℃/min, preserving heat for 2.5h, then heating to 2250 ℃ at the speed of 6 ℃/min, preserving heat for 1.3h, and cooling to 1775 ℃ at the speed of 2 ℃/min to obtain an intermediate a;

The rest is the same as example 1.

Comparative example 7

A method for preparing a hard alloy milling cutter with strong impact resistance.

The preparation method of the alloy blank comprises the following steps:

1) preparing the raw materials according to the proportion;

6) heating the mixed alloy liquid prepared in the step 5) to 2500 ℃ at the speed of 8 ℃/min, preserving heat for 22min, heating the mixed alloy liquid to 1550 ℃ at the speed of 4 ℃/min, preserving heat for 3.5h, cooling the mixed alloy liquid to 1000 ℃ at the speed of 5 ℃/min, and preserving heat for 3.5 h; then putting the alloy into quenching liquid for quenching to obtain an alloy body i;

The rest is the same as example 1.

Comparative example 8

A method for preparing a hard alloy milling cutter with strong impact resistance.

The preparation method of the alloy blank comprises the following steps:

1) preparing the raw materials according to the proportion;

6) heating the mixed alloy liquid prepared in the step 5) to 2500 ℃ at the speed of 8 ℃/min, preserving heat for 22min, then slowly cooling to 1500 ℃ at the speed of 8 ℃/min, preserving heat for 4.5h, heating to 1550 ℃ at the speed of 4 ℃/min, preserving heat for 3.5h, then cooling to 1000 ℃ at the speed of 5 ℃/min, preserving heat for 3.5h, and then cooling to room temperature to obtain an alloy body i;

7) cooling the alloy body i to 770 ℃ at the speed of 9 ℃/min, and preserving heat for 1.5 h; cooling to 300 deg.C at 2 deg.C/min, maintaining for 3.5 hr, heating to 330 deg.C at 1 deg.C/min, maintaining for 3 hr, and cooling to room temperature at 2 deg.C/min.

The rest is the same as example 1.

Comparative example 9

A preparation method of a hard alloy mill with strong impact resistance.

The preparation method of the alloy blank comprises the following steps:

1) preparing the raw materials according to the proportion;

7) cooling the alloy body i to 800 ℃ at the speed of 9 ℃/min, and preserving the heat for 1.5 h; cooling to 300 deg.C at 2 deg.C/min, maintaining for 3.5 hr, heating to 330 deg.C at 1 deg.C/min, maintaining for 3 hr, and cooling to room temperature at 6 deg.C/min.

The rest is the same as example 1.

Comparative example 10

A method for preparing a hard alloy milling cutter with strong impact resistance.

The preparation method of the alloy blank comprises the following steps:

1) preparing the raw materials according to the proportion;

7) heating the alloy body i to 770 ℃ at the speed of 9 ℃/min, and preserving the heat for 1.5 h; cooling to 300 deg.C at 2 deg.C/min, maintaining for 3.5 hr, and cooling to room temperature at 2 deg.C/min.

The rest is the same as example 1.

Comparative example 11

A method for preparing a hard alloy milling cutter with strong impact resistance.

The preparation method of the alloy blank comprises the following steps:

1) preparing the raw materials according to the proportion;

4) putting the rest iron raw material into a high-temperature furnace, heating to 1820 ℃ until the iron raw material is melted into uniform molten metal, adding 0.09 part of manganese, 13 parts of iron, 0.25 part of vanadium, 0.04 part of scandium, 0.02 part of lanthanum and 0.015 part of cerium, heating to 1980 ℃ at the rate of 5 ℃, and then preserving heat for 3 hours to obtain an intermediate b;

The rest is the same as example 1.

Comparative example 12

A method for preparing a hard alloy milling cutter with strong impact resistance.

Wherein the raw materials of the reinforced harmonious substance are as follows: 0.09 part of manganese, 13 parts of iron, 0.25 part of vanadium, 0.07 part of scandium, 0.02 part of lanthanum and 0.015 part of cerium.

The specific preparation method of the reinforced harmonious substance comprises the following steps:

The rest is the same as example 1.

Comparative example 13

A method for preparing a hard alloy milling cutter with strong impact resistance.

Wherein the raw materials of the reinforced harmonious substance are as follows: 0.09 part of manganese, 13 parts of iron, 0.25 part of vanadium, 0.04 part of scandium, 0.02 part of lanthanum and 0.03 part of cerium.

The specific preparation method of the reinforced harmonious substance comprises the following steps:

The rest is the same as example 1.

Comparative example 14

A preparation method of a hard alloy mill with strong impact resistance.

The specific preparation method of the reinforced harmonious substance comprises the following steps:

putting iron into a high-temperature furnace, heating the molten metal heated to 1650 ℃, adding scandium, lanthanum and cerium, heating to 2010 ℃ at the speed of 4 ℃/min, preserving heat for 23min, adding manganese and vanadium, preserving heat for 38min, cooling to 700 ℃ at the speed of 9 ℃/min, preserving heat for 3.5h, then cooling to 450 ℃ by quenching, and preserving heat for 4.5h to obtain the magnesium-based alloy.

The rest is the same as example 1.

Comparative example 15

A method for preparing a hard alloy milling cutter with strong impact resistance.

The specific preparation method of the reinforced harmonious substance comprises the following steps:

putting iron into a high-temperature furnace, heating the molten metal heated to 1650 ℃, adding scandium, lanthanum and cerium, heating to 2010 ℃ at the speed of 4 ℃/min, preserving heat for 23min, adding manganese and vanadium, preserving heat for 38min, cooling to 650 ℃ at the speed of 3 ℃/min, preserving heat for 3.5h, cooling to 450 ℃ by quenching, and preserving heat for 4.5h to obtain the magnesium-based alloy.

The rest is the same as example 1.

Comparative example 16

A method for preparing a hard alloy milling cutter with strong impact resistance.

The specific preparation method of the reinforced harmonious substance comprises the following steps:

putting iron into a high-temperature furnace, heating the molten metal heated to 1650 ℃, adding scandium, lanthanum, cerium, manganese and vanadium, heating to 2010 ℃ at the speed of 4 ℃/min, preserving heat for 50min, cooling to 700 ℃ at the speed of 3 ℃/min, preserving heat for 3.5h, cooling to 450 ℃ by quenching, and preserving heat for 4.5h to obtain the iron-based alloy.

The rest is the same as example 1.

Comparative example 17

A method for preparing a hard alloy milling cutter with strong impact resistance.

Wherein the quenching liquid is clear water.

The rest is the same as example 1.

Comparative example 18

A method for preparing a hard alloy milling cutter with strong impact resistance.

Wherein the quenching liquid is quick bright quenching oil LT-18B.

The rest is the same as example 1.

Comparative example 19

A method for preparing a hard alloy milling cutter with strong impact resistance.

The preparation method of the quenching liquid comprises the following steps:

1) putting 9 parts of bis-cinnamoyl thiodipropionate and 4 parts of 2, 6-tertiary butyl-4-methylphenol into a reactor, adding a dichlorotoluene solution, heating to 110 ℃ at the speed of 4 ℃/min, and carrying out heat preservation reaction for 4.5 hours to obtain a reactant a;

5) and adding the reactant d into 110 parts of base oil of 75SN, and uniformly stirring to obtain the catalyst.

The rest is the same as example 1.

Comparative example 20

A method for preparing a hard alloy milling cutter with strong impact resistance.

The preparation method of the quenching liquid comprises the following steps:

1) putting 6 parts of bis-cinnamoyl thiodipropionate and 4 parts of 2, 6-tertiary butyl-4-methylphenol into a reactor, adding a dichlorotoluene solution, heating to 90 ℃ at the speed of 4 ℃/min, and carrying out heat preservation reaction for 4.5 hours to obtain a reactant a;

5) and adding the reactant d into 110 parts of base oil of 75SN, and uniformly stirring to obtain the catalyst.

The rest is the same as example 1.

Comparative example 21

A method for preparing a hard alloy milling cutter with strong impact resistance.

The preparation method of the quenching liquid comprises the following steps:

2) adding 5 parts of ternary ethylene propylene into the reactant a, adding a 1.2-dichloromethane solution, heating to 150 ℃ at the speed of 7 ℃/min, and carrying out heat preservation reaction for 3 hours to obtain a reactant b;

5) and adding the reactant d into 110 parts of base oil of 75SN, and uniformly stirring to obtain the catalyst.

The rest is the same as example 1.

Comparative example 22

A method for preparing a hard alloy milling cutter with strong impact resistance.

The preparation method of the quenching liquid comprises the following steps:

3) adding 4 parts of adipic anhydride, 8 parts of bis (3, 5-tertiary butyl-4-hydroxyphenyl) thioether and an acetone solution into the reactant b, heating to 130 ℃ at the speed of 5 ℃/min, and carrying out heat preservation reaction for 8 hours to obtain a reactant c;

5) and adding the reactant d into 110 parts of base oil of 75SN, and uniformly stirring to obtain the catalyst.

The rest is the same as example 1.

Comparative example 23

A method for preparing a hard alloy milling cutter with strong impact resistance.

The preparation method of the quenching liquid comprises the following steps:

4) adding 9 parts of imidazoline sodium oleate and 4 parts of diethylene glycol mono [ (1, 1, 3, 3-tetramethylbutyl) phenyl ] ether into the reactant c, adding an ethyl acetate solution, heating to 108 ℃ at the speed of 2 ℃/min, preserving heat, reacting for 6 hours, adding 18 parts of liquid paraffin, and stirring uniformly to obtain a reactant d;

5) and adding the reactant d into 110 parts of base oil of 75SN, and uniformly stirring to obtain the catalyst.

The rest is the same as example 1.

Comparative example 24

A method for preparing a hard alloy milling cutter with strong impact resistance.

The preparation method of the quenching liquid comprises the following steps:

4) adding 6 parts of imidazoline sodium oleate and 4 parts of diethylene glycol mono [ (1, 1, 3, 3-tetramethylbutyl) phenyl ] ether into the reactant c, adding an ethyl acetate solution, heating to 108 ℃ at the speed of 8 ℃/min, preserving heat, reacting for 6 hours, adding 18 parts of liquid paraffin, and stirring uniformly to obtain a reactant d;

5) and adding the reactant d into 110 parts of base oil of 75SN, and uniformly stirring to obtain the catalyst.

The rest is the same as example 1.

Comparative example 25

A method for preparing a hard alloy milling cutter with strong impact resistance.

The preparation method of the quenching liquid comprises the following steps:

5) and adding the reactant d into 85 parts of base oil of 75SN, and uniformly stirring to obtain the catalyst.

The rest is the same as example 1.

Comparative example 26

A method for preparing a hard alloy milling cutter with strong impact resistance.

The preparation method of the quenching liquid comprises the following steps:

1) putting 6 parts of bis-cinnamoyl thiodipropionate, 4 parts of 2, 6-tertiary butyl-4-methylphenol and 9 parts of ternary ethyl propylene into a reactor, adding a dichlorotoluene solution, heating to 150 ℃ at the speed of 4 ℃/min, and carrying out heat preservation reaction for 4.5 hours to obtain a reactant a;

2) adding 4 parts of adipic anhydride into the reactant a, adding an acetone solution, heating to 110 ℃ at the speed of 5 ℃/min, carrying out heat preservation reaction for 5.5 hours, dropwise adding 8 parts of bis (3, 5-tertiary butyl-4-hydroxyphenyl) thioether into a reactor at the speed of 12 drops/min, heating to 130 ℃ at the speed of 3 ℃/min, and carrying out heat preservation reaction for 3.5 hours to obtain a reactant b;

4) adding 6 parts of imidazoline sodium oleate and 4 parts of diethylene glycol mono [ (1, 1, 3, 3-tetramethylbutyl) phenyl ] ether into the reactant b, adding an ethyl acetate solution, heating to 108 ℃ at the speed of 2 ℃/min, preserving heat, reacting for 6 hours, adding 18 parts of liquid paraffin, and stirring uniformly to obtain a reactant c;

5) and adding the reactant c into 85 parts of base oil of 75SN, and uniformly stirring to obtain the catalyst.

The rest is the same as example 1.

Comparative example 27

A method for preparing a hard alloy milling cutter with strong impact resistance.

Wherein, the surface treatment of the milling cutter is as follows:

2) soaking the milling cutter prepared in the step 1) in a binder for 4.5 hours;

The rest is the same as example 1.

Comparative example 28

A method for preparing a hard alloy milling cutter with strong impact resistance.

Wherein, the preparation of the binder is as follows:

putting 3 parts of polyvinyl ester and 4 parts of N-aminoethyl-3-aminopropyl methyl dimethoxysilane into a reactor, adding an ethyl acetate solution, slowly heating to 128 ℃ at a speed of 4 ℃/min, and carrying out heat preservation reaction for 3.5 hours to obtain an intermediate product a;

The rest is the same as example 1.

Comparative example 29

A method for preparing a hard alloy milling cutter with strong impact resistance.

Wherein, the preparation of the binder is as follows:

putting 7 parts of polyvinyl ester and 4 parts of N-aminoethyl-3-aminopropyl methyl dimethoxysilane into a reactor, adding an ethyl acetate solution, heating to 128 ℃ at the speed of 12 ℃/min, and carrying out heat preservation reaction for 3.5 hours to obtain an intermediate product a;

The rest is the same as example 1.

Comparative example 30

A method for preparing a hard alloy milling cutter with strong impact resistance.

Wherein, the preparation of the binder is as follows:

adding 7 parts of dimethyl phthalate into the intermediate product a, adding a toluene solution, heating to 105 ℃ at the speed of 6 ℃/min, and carrying out heat preservation reaction for 4.5 hours to obtain an intermediate product b;

The rest is the same as example 1.

Comparative example 31

A method for preparing a hard alloy milling cutter with strong impact resistance.

Wherein, the preparation of the binder is as follows:

adding 4 parts of dimethyl phthalate into the intermediate product a, adding a toluene solution, heating to 115 ℃ at the speed of 6 ℃/min, and carrying out heat preservation reaction for 4.5 hours to obtain an intermediate product b;

The rest is the same as example 1.

Comparative example 32

A method for preparing a hard alloy milling cutter with strong impact resistance.

Wherein, the preparation of the binder is as follows:

thirdly, 8 parts of the microcrystalline wax is added into the intermediate product b, the temperature is slowly raised to 55 ℃ at the speed of 3.5 ℃/min, the temperature is raised while stirring, and the heat preservation reaction is carried out for 3.5 hours, thus obtaining the product.

The rest is the same as example 1.

Comparative example 33

A method for preparing a hard alloy milling cutter with strong impact resistance.

Wherein, the preparation of the binder is as follows:

putting 7 parts of polyvinyl ester, 4 parts of N-aminoethyl-3-aminopropyl methyl dimethoxysilane and 4 parts of dimethyl phthalate into a reactor, adding an ethyl acetate solution, slowly heating to 128 ℃ at the speed of 4 ℃/min, and carrying out heat preservation reaction for 3.5 hours to obtain an intermediate product a;

② adding 12 parts of the microcrystalline wax into the intermediate product a, slowly heating to 55 ℃ at the speed of 3.5 ℃/min, stirring while heating, and reacting for 3.5h while keeping the temperature to obtain the final product.

The rest is the same as example 1.

Comparative example 34

A method for preparing a hard alloy milling cutter with strong impact resistance.

Wherein the binder is a ceramic binder JR 006.

The rest is the same as example 1.

Comparative example 35

A method for preparing a hard alloy milling cutter with strong impact resistance.

The hardening powder is mixed powder formed by mixing 4 parts of titanium nitride powder, 5 parts of chromium nitride powder, 4 parts of hexagonal boron nitride powder, 6 parts of alumina powder, 2 parts of titanium carbide powder and 4 parts of tungsten carbide.

The rest is the same as example 1.

Comparative example 36

A method for preparing a hard alloy milling cutter with strong impact resistance.

The rest is the same as example 1.

Comparative example 37

A method for preparing a hard alloy milling cutter with strong impact resistance.

Milling cutters made from the alloys prepared by the present invention were not surface treated.

The rest is the same as example 1.

Comparative example 38

The milling cutter made of the alloy prepared by the invention is subjected to TiC coating by adopting a PVD method in surface treatment.

Comparative example 39

A common steel alloy milling cutter.

Experimental example 1 hardness test of milling cutter

Testing and analyzing the hardness of the milling cutter prepared in the experimental example and the comparative example according to the national standard GB/T6118-2010 end mill technical conditions, and recording specific test results in a table 1;

TABLE 1 hardness of end mill

As can be seen from table 1, the results of rockwell hardness of the milling cutters prepared in examples 1 to 3 were all over 78, and possessed excellent hardness, which was much greater than that of the ordinary milling cutter of comparative example 39. The comparative examples 1 to 3 change the atom components dissolved in the alloy, so that the situations of atom segregation and the like are very easy to occur in the preparation of the alloy, and the hardness of the alloy is greatly reduced; comparative examples 4 to 10 change the process for preparing the alloy, particularly comparative example 5 does not add a reinforcing harmonious substance, and during the cooling process of the alloy, the segregation of solute atoms is easily caused, so that the hardness of the alloy is reduced. Comparative examples 11-16 were modified with respect to the process for preparing the cooling temper, and comparative example 11, in which only the raw materials for preparing the reinforcing temper were put into the mixed alloy liquid, resulted in that the elements in the reinforcing temper were not effectively adjusted with other alloy elements, so that the mill was prepared to have a rockwell hardness of only 36. Comparative examples 17 to 26 are changes in the preparation process and formulation of the quenching liquid, wherein, in the comparative example 17, clear water is used as the quenching liquid in the quenching process, and in the comparative example 18, rapid-cooling quenching oil LT-18B is used, but the alloy cannot be cooled down effectively due to the cooling effect, so that the hardness of the alloy is reduced, and the Rockwell hardness of the milling cutters prepared in the comparative examples 17 and 18 is only 33 and 34 respectively. Comparative examples 27 to 36 were modified for the surface treatment process of the milling cutter, but the hardness of the milling cutter was much lower than that of examples 1 to 3. Comparative example 37 prepared the milling cutter without modification and comparative example 38 used a general modification method, and its rockwell hardness was only 55 and 39, respectively. Therefore, the method provided by the invention can effectively improve the hardness of the milling cutter.

Experimental example 2 impact resistance test of milling cutter

Impact strength is one of the important indicators for measuring the service performance of cemented carbide cutting inserts. The research on the impact strength test and the detection method of the hard alloy blade has important significance for accurately mastering the mechanical property of the hard alloy blade, improving the production process and reasonably selecting the material and the cutting parameters of the blade.

Testing the prepared hard alloy milling cutter according to a testing method in a national standard GB/T1817-2017 ' test method for normal temperature impact toughness of hard alloy ', wherein the testing method adopts graded feed cutting, the back bite amount is kept to be 2mm, the cutting speed is 100/(mm/min), the feed amount per tooth is 0.25/(mm/tooth), the hard alloy milling cutter is tested, when the abrasion degree of the milling cutter reaches the standard in a national standard GB/T16460-2016 ' test method for the service life of an end mill, the impact frequency in the cutting process is recorded, and the specific testing result is recorded in a table 2;

TABLE 2 number of impacts of milling cutter

As can be seen from the data in Table 3, the impact numbers of examples 1 to 3 are far superior to those of comparative example 39, and the impact numbers can reach 12900 or more. Comparative examples 1 to 3 change the atomic composition of the solid solution in the alloy, which easily causes the segregation of the atoms of the solid solution in the alloy, and the like, so that the impact resistance of the milling cutter prepared by the method is sharply reduced.

Comparative examples 4 to 10 are adjusted according to the smelting preparation process of the alloy, comparative examples 4 and 6 change the feeding process of raw materials, comparative example 9 changes the temperature condition, comparative examples 7 to 8 and comparative example 10 change the heating speed or the annealing process, and comparative example 5 does not add a reinforcing harmonic substance, which all cause the uneven distribution of the metallographic phase of the alloy in the cooling process and further cause the reduction of the impact resistance of the milling cutter. Comparative examples 11 to 16 are changed for the reinforced harmonic substances added in the alloy, wherein the comparative examples 11 and 16 change the adding mode of the raw materials of the reinforced harmonic substances, the comparative examples 12 to 13 change the raw material proportion of the reinforced harmonic substances, and the comparative examples 14 to 15 change the preparation process of the reinforced harmonic substances, and the measures result in that the reinforced harmonic substances cannot exert the due efficacy in the alloy, so that the impact resistance times of the prepared milling cutter are only between 3279 and 5764 and are even lower than that of the common milling cutter of the comparative example 38.

The comparative example 17 selects clear water as the quenching liquid, and the comparative example 18 selects quick bright quenching oil LT-18B as the quenching liquid, but the components in the quenching liquid can not be effectively quenched and cooled, and the metallographic phase in the alloy is not uniformly distributed, so that the impact resistance of the milling cutter is reduced. Comparative examples 19 to 26 were modified with respect to the formulation and preparation process of the quenching medium, wherein comparative example 19, comparative example 21, comparative example 23, comparative example 25, comparative example 20, comparative example 22, comparative example 24, and comparative example 26 were modified with respect to the preparation process of the quenching medium, resulting in a decrease in the effective components therein, resulting in a decrease in the quenching effect, and therefore, the impact strength of the milling cutter was decreased. Comparative examples 27 to 36 were modified with respect to the surface treatment process of the milling cutter, and the impact resistance of the milling cutter was somewhat improved as compared with comparative examples 1 to 27, but still lower than that of examples 1 to 3. The milling cutter prepared in comparative example 37 was not modified, and in comparative example 38, the impact resistance times were 6406 and 3946, respectively, using a general modification method.

Experimental example 3 impact resistance test of milling cutter at high temperature

The milling cutters prepared in the examples and comparative examples were tested for cutting performance at 200 ℃ and 500 ℃ according to the test method of test example 2, and the number of impacts received during the cutting process was recorded, and the specific test results are recorded in table 3;

TABLE 3 impact resistance of milling cutter at high temperature

The milling cutter can generate a large amount of heat in the cutting process, so that the front section of the milling cutter can be heated rapidly, the alloy is easy to creep in a high-temperature environment, and the service life of the milling cutter is greatly reduced. Therefore, the milling cutter needs to be subjected to surface treatment, so that the service life of the milling cutter is prolonged. Examples 1-3 possessed impact resistance test times of 9800 and 7800 or more at 200 ℃ and 500 ℃ respectively, far exceeding that of comparative example 39. Comparative examples 27 to 36 were modified with respect to the surface treatment process of the milling cutter, wherein comparative example 27 modified the process of the adhesive adhering to the surface of the milling cutter, resulting in a decrease in the adhesive strength of the coating layer, resulting in a decrease in the impact resistance of the milling cutter at high temperatures. Comparative examples 28, 30 and 32 change the raw material ratio of the binder, and comparative examples 29, 31 and 33 change the preparation process of the binder, which results in the change of the composition or structure of the binder, and thus the decrease of the adhesive strength of the coating, and thus the high-temperature impact resistance of the milling cutter. Comparative example 34 used a conventional ceramic binder, but it did not allow effective bonding between the alloy and the coating, so the milling cutter was prepared with an impact resistance even lower than that of comparative example 39. Comparative examples 35-36 change the formulation of the hardening powder, resulting in a change in the structure of the coating, so that the properties are much lower than those of examples 1-3. Comparative example 37 the milling cutter was directly made from the prepared alloy without modification, so the high temperature impact resistance of the milling cutter was greatly reduced. Comparative example 38 the milling cutter was subjected to a general surface treatment, but the adhesion strength of the coating to the metal base surface was greatly reduced, so that the number of impact tests of the milling cutter at 500 c was only 2231.

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Hard alloy milling cutter with high impact resistance and preparation method thereof

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